DE69705720T2 - Verfahren zur herstellung von heterogenem bimetallischen palladium-gold-katalysator für die herstellung von vinylacetat - Google Patents

Verfahren zur herstellung von heterogenem bimetallischen palladium-gold-katalysator für die herstellung von vinylacetat

Info

Publication number
DE69705720T2
DE69705720T2 DE69705720T DE69705720T DE69705720T2 DE 69705720 T2 DE69705720 T2 DE 69705720T2 DE 69705720 T DE69705720 T DE 69705720T DE 69705720 T DE69705720 T DE 69705720T DE 69705720 T2 DE69705720 T2 DE 69705720T2
Authority
DE
Germany
Prior art keywords
producing
heterogenic
vinyl acetate
gold catalyst
bimetallic palladium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69705720T
Other languages
English (en)
Other versions
DE69705720D1 (de
Inventor
Tao Wang
A Broussard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese International Corp
Original Assignee
Celanese International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese International Corp filed Critical Celanese International Corp
Publication of DE69705720D1 publication Critical patent/DE69705720D1/de
Application granted granted Critical
Publication of DE69705720T2 publication Critical patent/DE69705720T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
DE69705720T 1996-05-24 1997-05-15 Verfahren zur herstellung von heterogenem bimetallischen palladium-gold-katalysator für die herstellung von vinylacetat Expired - Lifetime DE69705720T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/655,571 US5700753A (en) 1996-05-24 1996-05-24 Heterogeneous bimetallic palladium-gold catalyst for vinyl acetate production
PCT/US1997/008491 WO1997044130A1 (en) 1996-05-24 1997-05-15 Heterogeneous bimetallic palladium-gold catalyst for vinyl acetate production

Publications (2)

Publication Number Publication Date
DE69705720D1 DE69705720D1 (de) 2001-08-23
DE69705720T2 true DE69705720T2 (de) 2002-06-13

Family

ID=24629432

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69705720T Expired - Lifetime DE69705720T2 (de) 1996-05-24 1997-05-15 Verfahren zur herstellung von heterogenem bimetallischen palladium-gold-katalysator für die herstellung von vinylacetat

Country Status (28)

Country Link
US (1) US5700753A (de)
EP (1) EP0906151B1 (de)
JP (1) JP4043520B2 (de)
CN (1) CN1093001C (de)
AR (2) AR007116A1 (de)
AT (1) ATE203187T1 (de)
AU (1) AU713368B2 (de)
BR (1) BR9709033A (de)
CA (1) CA2254912C (de)
CZ (1) CZ297144B6 (de)
DE (1) DE69705720T2 (de)
DK (1) DK0906151T3 (de)
ES (1) ES2159137T3 (de)
HU (1) HUP9904003A3 (de)
ID (1) ID16953A (de)
IN (1) IN191380B (de)
MY (1) MY114044A (de)
NO (1) NO316363B1 (de)
NZ (1) NZ332917A (de)
PL (1) PL189150B1 (de)
RU (1) RU2182516C2 (de)
SA (1) SA97180048B1 (de)
TR (1) TR199802415T2 (de)
TW (1) TW448074B (de)
UA (1) UA61073C2 (de)
WO (1) WO1997044130A1 (de)
YU (1) YU49149B (de)
ZA (1) ZA973748B (de)

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US6034030A (en) * 1994-02-22 2000-03-07 Celanese International Corporation Vinyl acetate catalyst preparation method
DE4443701C1 (de) * 1994-12-08 1996-08-29 Degussa Schalenkatalysator, Verfahren zu seiner Herstellung und seine Verwendung
US5968869A (en) * 1997-06-03 1999-10-19 Celanese International Corporation Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
US5948724A (en) * 1997-10-28 1999-09-07 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
EP1060016A4 (de) * 1998-02-05 2002-11-27 Engelhard Corp Verhinderung der alterung von pd-au-vinyl-acetat-katalysatoren
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
US6017847A (en) * 1998-06-02 2000-01-25 Celanese International Corporation Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper
ID26891A (id) * 1998-06-02 2001-02-15 Celanese Internasional Corp Katalis vinil asetat yang terdiri dari palladium logam dan emas yang dibuat dengan potasium aurat
JP2000070718A (ja) * 1998-06-17 2000-03-07 Nippon Shokubai Co Ltd ベンジルエステルの製造方法
DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
US6821923B1 (en) * 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
DE60020841D1 (de) 1999-04-14 2005-07-21 Showa Denko Kk Katalysator für die herstellung von essigsäure oder essigsäure und ethylacetat, verfahren für seine herstellung und verfahren für die herstellung von essigsäure oder essigsäure und ethylacetat unter verwendung derselben
US6303537B1 (en) 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6509292B1 (en) 2001-03-30 2003-01-21 Sud-Chemie Inc. Process for selective hydrogenation of acetylene in an ethylene purification process
US6936568B2 (en) * 2002-06-12 2005-08-30 Sud-Chemie Inc. Selective hydrogenation catalyst
FR2842125B1 (fr) * 2002-07-09 2006-03-31 Sicat Methode de preparation par impregnation biphasique de nouveaux catalyseurs pour catalyse heterogene, et utilisation desdits catalyseurs
US7655021B2 (en) * 2003-03-10 2010-02-02 Boston Scientific Scimed, Inc. Dilator with expandable member
TW201240725A (en) * 2003-12-19 2012-10-16 Celanese Int Corp Layered support material for catalysts
JP4772694B2 (ja) * 2003-12-19 2011-09-14 セラニーズ・インターナショナル・コーポレーション 触媒のための層状担持材
CA2586584C (en) * 2004-12-20 2011-01-18 Celanese International Corporation Modified support materials for catalysts
US7507495B2 (en) * 2004-12-22 2009-03-24 Brookhaven Science Associates, Llc Hydrogen absorption induced metal deposition on palladium and palladium-alloy particles
JP4261502B2 (ja) * 2005-03-14 2009-04-30 富士通マイクロエレクトロニクス株式会社 検証支援装置、検証支援方法、検証支援プログラム、および記録媒体
US8227369B2 (en) * 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
KR20080047950A (ko) * 2006-11-27 2008-05-30 나노스텔라 인코포레이티드 팔라듐-금을 포함하는 엔진 배기가스 촉매
US8258070B2 (en) * 2006-11-27 2012-09-04 WGCH Technology Limited Engine exhaust catalysts containing palladium-gold
US7534738B2 (en) * 2006-11-27 2009-05-19 Nanostellar, Inc. Engine exhaust catalysts containing palladium-gold
US7709414B2 (en) * 2006-11-27 2010-05-04 Nanostellar, Inc. Engine exhaust catalysts containing palladium-gold
US7811968B2 (en) * 2007-05-11 2010-10-12 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025356A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025358A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators
DE102008059341A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung
US8071504B2 (en) * 2008-12-19 2011-12-06 Caterpillar Inc. Exhaust system having a gold-platinum group metal catalyst
GB201110850D0 (en) 2011-03-04 2011-08-10 Johnson Matthey Plc Catalyst and mehtod of preparation
WO2016143490A1 (ja) * 2015-03-09 2016-09-15 国立研究開発法人産業技術総合研究所 金ヒドロキソ陰イオン錯体溶液

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DE1185604B (de) * 1962-02-03 1965-01-21 Bayer Ag Verfahren zur Herstellung von Vinylacetat
DE1252662B (de) * 1965-06-25
CH534005A (de) * 1968-02-01 1973-02-28 Bayer Ag Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators
GB1333449A (en) * 1970-11-20 1973-10-10 Hoechst Ag Process for the oxacylation of olefins in the gaseous phase
US3939199A (en) * 1971-01-06 1976-02-17 Hoechst Aktiengesellschaft Oxacylation of olefins in the gaseous phase
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US4133962A (en) * 1975-02-14 1979-01-09 Hoechst Aktiengesellschaft Process for the preparation of carboxylic acid alkenyl esters
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
US4089096A (en) * 1976-08-13 1978-05-16 John Graham Michael Method of making school ring top
FR2523149A1 (fr) * 1982-03-15 1983-09-16 Catalyse Soc Prod Francais Nouveau catalyseur supporte palladium-or, sa preparation et son utilisation dans les reactions d'hydrogenation selective d'hydrocarbures diolefiniques et/ou acetyleniques
DE3803900A1 (de) * 1988-02-09 1989-08-17 Hoechst Ag Verfahren zur herstellung von vinylacetat
US4933204A (en) * 1988-09-23 1990-06-12 Rockwell International Corporation Method of producing a gold film
US5179057A (en) * 1991-05-06 1993-01-12 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for alkenyl alkanoate production
US5185308A (en) * 1991-05-06 1993-02-09 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
US5194417A (en) * 1991-12-05 1993-03-16 Quantum Chemical Corporation Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis
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DE4239876C1 (de) * 1992-11-27 1994-07-28 Degussa Verfahren zur gleichmäßigen und reproduzierbaren Schalenimprägnierung von als Schüttgut vorliegenden Festbett-Katalysatorträgern und Vorrichtung zur Durchführung des Verfahrens
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Also Published As

Publication number Publication date
CA2254912C (en) 2006-02-14
DE69705720D1 (de) 2001-08-23
JP2000511105A (ja) 2000-08-29
CN1219893A (zh) 1999-06-16
US5700753A (en) 1997-12-23
RU2182516C2 (ru) 2002-05-20
WO1997044130A1 (en) 1997-11-27
ID16953A (id) 1997-11-27
YU49149B (sh) 2004-03-12
AR011995A2 (es) 2000-09-13
DK0906151T3 (da) 2001-09-24
PL330065A1 (en) 1999-04-26
TR199802415T2 (xx) 1999-02-22
HUP9904003A1 (hu) 2000-03-28
ATE203187T1 (de) 2001-08-15
SA97180048B1 (ar) 2005-12-21
NO985446D0 (no) 1998-11-23
UA61073C2 (en) 2003-11-17
HUP9904003A3 (en) 2000-09-28
NO316363B1 (no) 2004-01-19
NZ332917A (en) 2000-03-27
CN1093001C (zh) 2002-10-23
YU15897A (sh) 1999-06-15
AU3072097A (en) 1997-12-09
EP0906151B1 (de) 2001-07-18
BR9709033A (pt) 1999-08-03
AR007116A1 (es) 1999-10-13
NO985446L (no) 1998-11-23
ZA973748B (en) 1998-10-30
CZ382598A3 (cs) 1999-08-11
ES2159137T3 (es) 2001-09-16
CZ297144B6 (cs) 2006-09-13
AU713368B2 (en) 1999-12-02
IN191380B (de) 2003-11-29
TW448074B (en) 2001-08-01
PL189150B1 (pl) 2005-06-30
JP4043520B2 (ja) 2008-02-06
CA2254912A1 (en) 1997-11-27
EP0906151A1 (de) 1999-04-07
MY114044A (en) 2002-07-31

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