DE69611789T2 - Verfahren zur herstellung von metallocen-katalysator-systemen - Google Patents
Verfahren zur herstellung von metallocen-katalysator-systemenInfo
- Publication number
- DE69611789T2 DE69611789T2 DE69611789T DE69611789T DE69611789T2 DE 69611789 T2 DE69611789 T2 DE 69611789T2 DE 69611789 T DE69611789 T DE 69611789T DE 69611789 T DE69611789 T DE 69611789T DE 69611789 T2 DE69611789 T2 DE 69611789T2
- Authority
- DE
- Germany
- Prior art keywords
- metallocene catalyst
- catalyst systems
- producing metallocene
- producing
- systems
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/506,995 US5635437A (en) | 1995-07-28 | 1995-07-28 | Method for preparing metallocene catalyst systems |
PCT/US1996/011904 WO1997005178A1 (en) | 1995-07-28 | 1996-07-18 | Improved method for preparing metallocene catalyst systems |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69611789D1 DE69611789D1 (de) | 2001-03-22 |
DE69611789T2 true DE69611789T2 (de) | 2001-08-02 |
Family
ID=24016855
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69611789T Expired - Lifetime DE69611789T2 (de) | 1995-07-28 | 1996-07-18 | Verfahren zur herstellung von metallocen-katalysator-systemen |
Country Status (9)
Country | Link |
---|---|
US (1) | US5635437A (de) |
EP (1) | EP0842205B1 (de) |
JP (1) | JP3955324B2 (de) |
KR (1) | KR100449404B1 (de) |
CN (1) | CN1116313C (de) |
CA (1) | CA2227897C (de) |
DE (1) | DE69611789T2 (de) |
ES (1) | ES2153965T3 (de) |
WO (1) | WO1997005178A1 (de) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI104826B (fi) * | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
IT1298616B1 (it) * | 1998-03-10 | 2000-01-12 | Enichem Spa | Complesso metallocenico pontato per la (co) polimerizzazione delle olefine |
US6251817B1 (en) | 1998-12-30 | 2001-06-26 | Union Carbide Chemicals & Plastics Technology Corporation | Method of reducing tube plugging using preactivated unsupported catalysts |
US6239060B1 (en) | 1998-12-31 | 2001-05-29 | Phillips Petroleum Company | Supported metallocene catalyst system and method for polymerizing olefins |
US6444605B1 (en) | 1999-12-28 | 2002-09-03 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed metal alkoxide and cycloalkadienyl catalysts for the production of polyolefins |
GB0111443D0 (en) * | 2001-05-10 | 2001-07-04 | Borealis Tech Oy | Olefin polymerisation process |
US6884749B2 (en) | 2002-10-17 | 2005-04-26 | Equistar Chemicals L.P. | Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof |
US7169864B2 (en) * | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
US20060247394A1 (en) * | 2005-04-29 | 2006-11-02 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
JP5339567B2 (ja) * | 2005-11-17 | 2013-11-13 | 旭化成ケミカルズ株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
US7538168B2 (en) * | 2005-12-14 | 2009-05-26 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
EP2573091A1 (de) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen |
WO2017054398A1 (zh) | 2015-09-28 | 2017-04-06 | 中国石油天然气股份有限公司 | 一种球形负载型过渡金属催化剂 |
KR102323807B1 (ko) * | 2018-01-12 | 2021-11-09 | 주식회사 엘지화학 | 촉매 조성물 내 브롬 화합물의 제거 방법 |
WO2020056119A1 (en) | 2018-09-14 | 2020-03-19 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
WO2020172306A1 (en) | 2019-02-20 | 2020-08-27 | Fina Technology, Inc. | Polymer compositions with low warpage |
US20220340723A1 (en) | 2021-04-26 | 2022-10-27 | Fina Technology, Inc. | Thin Single-Site Catalyzed Polymer Sheets |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
DE4004477A1 (de) * | 1990-02-14 | 1991-08-22 | Schering Ag | Verfahren zur herstellung von loesungen oligomerer methylaluminoxane |
KR940009020B1 (ko) * | 1990-07-24 | 1994-09-29 | 미쓰이 도오아쓰 가가쿠 가부시키가이샤 | α-올레핀의 중합촉매 및 그것을 이용한 폴리 α-올레핀의 제조방법 |
ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
DE59107973D1 (de) * | 1990-11-12 | 1996-08-08 | Hoechst Ag | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
ATE166077T1 (de) * | 1991-01-12 | 1998-05-15 | Targor Gmbh | Metallocen(co)polymere, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren; metallocene hierfür. |
TW218884B (de) * | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
US5235081A (en) * | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
JP3256276B2 (ja) * | 1992-05-29 | 2002-02-12 | 三井化学株式会社 | 安定化された遷移金属化合物及びその保存方法 |
US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
US5248801A (en) * | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
US5539069A (en) * | 1993-08-10 | 1996-07-23 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalysts and methods of olefin polymerization |
ES2141920T5 (es) * | 1994-01-11 | 2009-05-21 | Exxonmobil Chemical Patents Inc. | Alumoxanos y catalizadores que comprenden alumoxanos. |
JP3472941B2 (ja) * | 1995-03-08 | 2003-12-02 | 三井化学株式会社 | オレフィン重合用触媒の保存方法、オレフィン重合用触媒溶液、オレフィン重合用触媒およびオレフィンの重合方法 |
-
1995
- 1995-07-28 US US08/506,995 patent/US5635437A/en not_active Expired - Lifetime
-
1996
- 1996-07-18 JP JP50764497A patent/JP3955324B2/ja not_active Expired - Lifetime
- 1996-07-18 ES ES96924596T patent/ES2153965T3/es not_active Expired - Lifetime
- 1996-07-18 KR KR10-1998-0700610A patent/KR100449404B1/ko not_active IP Right Cessation
- 1996-07-18 DE DE69611789T patent/DE69611789T2/de not_active Expired - Lifetime
- 1996-07-18 CA CA002227897A patent/CA2227897C/en not_active Expired - Lifetime
- 1996-07-18 WO PCT/US1996/011904 patent/WO1997005178A1/en active IP Right Grant
- 1996-07-18 EP EP96924596A patent/EP0842205B1/de not_active Expired - Lifetime
- 1996-07-18 CN CN96196901A patent/CN1116313C/zh not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP3955324B2 (ja) | 2007-08-08 |
CA2227897A1 (en) | 1997-02-13 |
DE69611789D1 (de) | 2001-03-22 |
WO1997005178A1 (en) | 1997-02-13 |
ES2153965T3 (es) | 2001-03-16 |
KR100449404B1 (ko) | 2004-11-16 |
EP0842205B1 (de) | 2001-02-14 |
JPH11510203A (ja) | 1999-09-07 |
CA2227897C (en) | 2008-03-18 |
CN1116313C (zh) | 2003-07-30 |
EP0842205A1 (de) | 1998-05-20 |
US5635437A (en) | 1997-06-03 |
CN1196065A (zh) | 1998-10-14 |
KR19990035949A (ko) | 1999-05-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |