JP2021516172A - ポリアミドフィルム積層体 - Google Patents
ポリアミドフィルム積層体 Download PDFInfo
- Publication number
- JP2021516172A JP2021516172A JP2020543779A JP2020543779A JP2021516172A JP 2021516172 A JP2021516172 A JP 2021516172A JP 2020543779 A JP2020543779 A JP 2020543779A JP 2020543779 A JP2020543779 A JP 2020543779A JP 2021516172 A JP2021516172 A JP 2021516172A
- Authority
- JP
- Japan
- Prior art keywords
- benzene
- dicarbonyl group
- group
- polyamide
- film laminate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004952 Polyamide Substances 0.000 title claims abstract description 133
- 229920002647 polyamide Polymers 0.000 title claims abstract description 133
- -1 benzene-dicarbonyl group Chemical group 0.000 claims description 134
- 229920006122 polyamide resin Polymers 0.000 claims description 61
- 230000015572 biosynthetic process Effects 0.000 claims description 21
- 125000003118 aryl group Chemical group 0.000 claims description 16
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 16
- 229920001721 polyimide Polymers 0.000 claims description 16
- 238000003786 synthesis reaction Methods 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 239000004642 Polyimide Substances 0.000 claims description 8
- 239000004262 Ethyl gallate Substances 0.000 claims description 5
- UTDAGHZGKXPRQI-UHFFFAOYSA-N 4-[4-[4-(4-aminophenoxy)phenyl]sulfonylphenoxy]aniline Chemical compound C1=CC(N)=CC=C1OC1=CC=C(S(=O)(=O)C=2C=CC(OC=3C=CC(N)=CC=3)=CC=2)C=C1 UTDAGHZGKXPRQI-UHFFFAOYSA-N 0.000 claims description 4
- QGMGHALXLXKCBD-UHFFFAOYSA-N 4-amino-n-(2-aminophenyl)benzamide Chemical compound C1=CC(N)=CC=C1C(=O)NC1=CC=CC=C1N QGMGHALXLXKCBD-UHFFFAOYSA-N 0.000 claims description 3
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 claims description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 2
- UXOXUHMFQZEAFR-UHFFFAOYSA-N 2,2',5,5'-Tetrachlorobenzidine Chemical compound C1=C(Cl)C(N)=CC(Cl)=C1C1=CC(Cl)=C(N)C=C1Cl UXOXUHMFQZEAFR-UHFFFAOYSA-N 0.000 claims description 2
- FWOLORXQTIGHFX-UHFFFAOYSA-N 4-(4-amino-2,3,5,6-tetrafluorophenyl)-2,3,5,6-tetrafluoroaniline Chemical group FC1=C(F)C(N)=C(F)C(F)=C1C1=C(F)C(F)=C(N)C(F)=C1F FWOLORXQTIGHFX-UHFFFAOYSA-N 0.000 claims description 2
- VWCCEIUKGFGDDS-UHFFFAOYSA-N 4-(4-amino-2-methylphenyl)-3-methylaniline Chemical group CC1=C(C=CC(=C1)N)C1=C(C=C(N)C=C1)C.CC1=C(C=CC(=C1)N)C1=C(C=C(C=C1)N)C VWCCEIUKGFGDDS-UHFFFAOYSA-N 0.000 claims description 2
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 claims description 2
- BZIVKXRNXXPVJD-UHFFFAOYSA-N 4-[3-(4-aminophenoxy)phenoxy]aniline Chemical compound NC1=CC=C(OC2=CC(=CC=C2)OC2=CC=C(C=C2)N)C=C1.NC1=CC=C(OC2=CC(=CC=C2)OC2=CC=C(C=C2)N)C=C1 BZIVKXRNXXPVJD-UHFFFAOYSA-N 0.000 claims description 2
- MVODMCPZFNNNBR-UHFFFAOYSA-N 4-[4-amino-2-(trifluoromethyl)phenyl]-3-(trifluoromethyl)aniline Chemical compound FC(C1=C(C=CC(=C1)N)C1=C(C=C(N)C=C1)C(F)(F)F)(F)F.FC(C1=C(C=CC(=C1)N)C1=C(C=C(N)C=C1)C(F)(F)F)(F)F MVODMCPZFNNNBR-UHFFFAOYSA-N 0.000 claims description 2
- SNCJAJRILVFXAE-UHFFFAOYSA-N 9h-fluorene-2,7-diamine Chemical compound NC1=CC=C2C3=CC=C(N)C=C3CC2=C1 SNCJAJRILVFXAE-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 125000004989 dicarbonyl group Chemical group 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims 1
- KMKWGXGSGPYISJ-UHFFFAOYSA-N 4-[4-[2-[4-(4-aminophenoxy)phenyl]propan-2-yl]phenoxy]aniline Chemical compound C=1C=C(OC=2C=CC(N)=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OC1=CC=C(N)C=C1 KMKWGXGSGPYISJ-UHFFFAOYSA-N 0.000 claims 1
- KIFDSGGWDIVQGN-UHFFFAOYSA-N 4-[9-(4-aminophenyl)fluoren-9-yl]aniline Chemical compound C1=CC(N)=CC=C1C1(C=2C=CC(N)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 KIFDSGGWDIVQGN-UHFFFAOYSA-N 0.000 claims 1
- 229940018564 m-phenylenediamine Drugs 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920000307 polymer substrate Polymers 0.000 claims 1
- 239000000523 sample Substances 0.000 claims 1
- 229920006147 copolyamide elastomer Polymers 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 54
- 239000000178 monomer Substances 0.000 description 39
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- 235000019589 hardness Nutrition 0.000 description 22
- 239000000758 substrate Substances 0.000 description 14
- 150000001408 amides Chemical group 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 10
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- NVKGJHAQGWCWDI-UHFFFAOYSA-N 4-[4-amino-2-(trifluoromethyl)phenyl]-3-(trifluoromethyl)aniline Chemical group FC(F)(F)C1=CC(N)=CC=C1C1=CC=C(N)C=C1C(F)(F)F NVKGJHAQGWCWDI-UHFFFAOYSA-N 0.000 description 8
- 150000004984 aromatic diamines Chemical class 0.000 description 8
- 238000005755 formation reaction Methods 0.000 description 8
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 7
- ZKGNPQKYVKXMGJ-UHFFFAOYSA-N N,N-dimethylacetamide Chemical compound CN(C)C(C)=O.CN(C)C(C)=O ZKGNPQKYVKXMGJ-UHFFFAOYSA-N 0.000 description 7
- 239000012963 UV stabilizer Substances 0.000 description 7
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000009719 polyimide resin Substances 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 5
- 238000003556 assay Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 3
- 238000010640 amide synthesis reaction Methods 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- VIDMPJYSMVIJCN-UHFFFAOYSA-N CC=1C(C=CC(C1)(N)N)=C1C(=CC(N)(C=C1)N)C.CC=1C(C=CC(C1)(N)N)=C1C(=CC(N)(C=C1)N)C Chemical compound CC=1C(C=CC(C1)(N)N)=C1C(=CC(N)(C=C1)N)C.CC=1C(C=CC(C1)(N)N)=C1C(=CC(N)(C=C1)N)C VIDMPJYSMVIJCN-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000006748 scratching Methods 0.000 description 2
- 230000002393 scratching effect Effects 0.000 description 2
- QDBOAKPEXMMQFO-UHFFFAOYSA-N 4-(4-carbonochloridoylphenyl)benzoyl chloride Chemical compound C1=CC(C(=O)Cl)=CC=C1C1=CC=C(C(Cl)=O)C=C1 QDBOAKPEXMMQFO-UHFFFAOYSA-N 0.000 description 1
- XPAQFJJCWGSXGJ-UHFFFAOYSA-N 4-amino-n-(4-aminophenyl)benzamide Chemical compound C1=CC(N)=CC=C1NC(=O)C1=CC=C(N)C=C1 XPAQFJJCWGSXGJ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000012369 In process control Methods 0.000 description 1
- JDAXEXHITOOISE-UHFFFAOYSA-N NC1=CC=C(OC2=CC=C(C=C2)C(C)(C)C2=CC=C(C=C2)OC2=CC=C(C=C2)N)C=C1.NC1=CC=C(OC2=CC=C(C=C2)C(C)(C)C2=CC=C(C=C2)OC2=CC=C(C=C2)N)C=C1 Chemical compound NC1=CC=C(OC2=CC=C(C=C2)C(C)(C)C2=CC=C(C=C2)OC2=CC=C(C=C2)N)C=C1.NC1=CC=C(OC2=CC=C(C=C2)C(C)(C)C2=CC=C(C=C2)OC2=CC=C(C=C2)N)C=C1 JDAXEXHITOOISE-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- FYXKZNLBZKRYSS-UHFFFAOYSA-N benzene-1,2-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC=C1C(Cl)=O FYXKZNLBZKRYSS-UHFFFAOYSA-N 0.000 description 1
- XUYGNGMQMDMYHW-UHFFFAOYSA-N benzene-1,3-diamine Chemical compound NC1=CC=CC(N)=C1.NC1=CC=CC(N)=C1 XUYGNGMQMDMYHW-UHFFFAOYSA-N 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 210000004544 dc2 Anatomy 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000004190 ion pair chromatography Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/32—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31728—Next to second layer of polyamide
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Polyamides (AREA)
Abstract
Description
芳香族ジアミノグループ(diamino group)およびベンゼン−ジカルボニルグループによるアミド結合を含み、
ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が20モル%以下である、
第1ポリアミド樹脂層;および
B)
前記第1ポリアミド樹脂層の少なくとも一面に形成され、
芳香族ジアミノグループ(diamino group)およびベンゼン−ジカルボニルグループによるアミド結合を含み、
ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が20モル%を超過する、
第2ポリアミド樹脂層;
を含む、ポリアミドフィルム積層体が提供される。
A)
芳香族ジアミノグループ(diamino group)およびベンゼン−ジカルボニルグループによるアミド結合を含み、
ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が20モル%以下である、
第1ポリアミド樹脂層;および
B)
前記第1ポリアミド樹脂層の少なくとも一面に形成され、
芳香族ジアミノグループ(diamino group)およびベンゼン−ジカルボニルグループによるアミド結合を含み、
ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が20モル%を超過する、
第2ポリアミド樹脂層;
を含む、ポリアミドフィルム積層体が提供される。
I)第1ポリアミド樹脂層、および第2ポリアミド樹脂層を含む積層体の形態であって、
II)第1ポリアミド樹脂層は、第1ポリアミド共重合体を含み、第2ポリアミド樹脂層は第2ポリアミド共重合体を含み、
III)前記第1および第2ポリアミド共重合体は、それぞれ独立して、
A.前記芳香族ジアミンモノマーのアミン基と前記イソフタロイル系モノマーのカルボニル基がアミド結合を形成したアミド繰り返し単位(以下、第1アミド繰り返し単位)、および
B.前記芳香族ジアミンモノマーのアミン基と前記テレフタロイル系モノマーのカルボニル基がアミド結合を形成したアミド繰り返し単位(以下、第2アミド繰り返し単位)を全て含む、ポリアミド共重合体であって;
C.但し、第1および第2ポリアミドは、第1アミド繰り返し単位と第2アミド繰り返し単位を、互いに異なる比率で含む。
i)ベンゼン−1,3−ジカルボニルモノマー、ベンゼン−1,4−ジカルボニルモノマー、および芳香族ジアミンモノマーを混合し、
ii)この時、ベンゼン−1,3−ジカルボニルモノマーは、ベンゼン−1,3−ジカルボニルモノマーおよびベンゼン−1,4−ジカルボニルモノマーの総合に対して20モル%以下で含まれ、
iii)アミングループとカルボニルグループの間にアミド結合を形成して、第1ポリアミド共重合体を製造することができる。
i)ベンゼン−1,3−ジカルボニルモノマー、ベンゼン−1,4−ジカルボニルモノマー、および芳香族ジアミンモノマーを混合し、
ii)この時、ベンゼン−1,3−ジカルボニルモノマーは、ベンゼン−1,3−ジカルボニルモノマーおよびベンゼン−1,4−ジカルボニルモノマーの総合に対して20モル%を超過して含まれ、
iii)アミングループとカルボニルグループの間にアミド結合を形成して、第2ポリアミド共重合体を製造することができる。
YI1−YI0<3.0
YI1およびYI0は、それぞれASTM E313の基準によって測定されたポリアミドフィルム積層体の黄色度指数(Yellowness Index)であって、
YI0は、前記ポリアミドフィルム積層体の初期黄色度指数であり、
YI1は、前記ポリアミドフィルム積層体をASTM G53−96の基準によって96時間紫外線および水分に露出させた後に測定した黄色度指数である。
(第2ポリアミド樹脂層形成)
Claims (13)
- A)
芳香族ジアミノグループ(diamino group)およびベンゼン−ジカルボニルグループによるアミド結合を含み、
ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が20モル%以下である、
第1ポリアミド樹脂層;および
B)
前記第1ポリアミド樹脂層の少なくとも一面に形成され、
芳香族ジアミノグループ(diamino group)およびベンゼン−ジカルボニルグループによるアミド結合を含み、
ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が20モル%を超過する、
第2ポリアミド樹脂層;
を含む、
ポリアミドフィルム積層体。 - 全体ポリアミドフィルム積層体で、
ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中の前記ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が5〜25モル%である、
請求項1に記載のポリアミドフィルム積層体。 - 前記第1ポリアミド樹脂層内では、ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が2モル%以上20モル%以下である、
請求項1または2に記載のポリアミドフィルム積層体。 - 前記第2ポリアミド樹脂層内では、ベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)およびベンゼン−1,4−ジカルボニルグループ(benzene−1,4−dicarbonyl group)の総合中のベンゼン−1,3−ジカルボニルグループ(benzene−1,3−dicarbonyl group)の比率が20モル%超過40モル%以下である、
請求項1から3のいずれか1項に記載のポリアミドフィルム積層体。 - 前記第1ポリアミド樹脂層および第2ポリアミド樹脂層の厚さは、30:70〜1:99の比率で形成される、
請求項1から4のいずれか1項に記載のポリアミドフィルム積層体。 - 前記芳香族ジアミノグループは、2,2'−ビス(トリフルオロメチル)−4,4'−ビフェニルジアミン(2,2'−bis(trifluoromethyl)−4,4'−biphenyldiamine)、2,2'−ジメチル−4,4'−ジアミノベンジジン(2,2'−dimethyl−4,4'−diaminobenzidine)、4,4'−ジアミノジフェニルスルホン(4,4'−diaminodiphenyl sulfone)、4,4'−(9−フルオレニリデン)ジアニリン(4,4'−9−fluorenylidene)dianiline)、ビス(4−(4−アミノフェノキシ)フェニル)スルホン(bis(4−(4−aminophenoxy)phenyl)sulfone)、2,2',5,5'−テトラクロロベンジジン(2,2',5,5'−tetrachlorobenzidine)、2,7−ジアミノフルオレン(2,7−diaminofluorene)、4,4−ジアミノオクタフルオロビフェニル(4,4−diaminooctafluorobiphenyl)、m−フェニレンジアミン(m−phenylenediamine)、p−フェニレンジアミン(p−phenylenediamine)、4,4'−オキシジアニリン(4,4'−oxydianiline)、2,2'−ジメチル−4,4'−ジアミノビフェニル(2,2'−dimethyl−4,4'−diaminobiphenyl)、2,2−ビス[4−(4−アミノフェノキシ)フェニル]プロパン(2,2−bis[4−(4−aminophenoxy)phenyl]propane)、1,3−ビス(4−アミノフェノキシ)ベンゼン(1,3−bis(4−aminophenoxy)benzene)、および4,4'−ジアミノベンズアニリド(4,4'−diaminobenzanilide)からなる群より選択された1種以上に由来したジアミノグループを含む、
請求項1から5のいずれか1項に記載のポリアミドフィルム積層体。 - 下記数式1を満足する、
請求項1から6のいずれか1項に記載のポリアミドフィルム積層体:
[数式1]
YI1−YI0<3.0
上記数式1で、
YI1およびYI0は、それぞれASTM E313の基準によって測定されたポリアミドフィルム積層体の黄色度指数(Yellowness Index)であって、
YI0は、前記ポリアミドフィルム積層体の初期黄色度指数であり、
YI1は、前記ポリアミドフィルム積層体をASTM G53−96の基準によって96時間紫外線および水分に露出させた後に測定した黄色度指数である。 - ASTM D 1003基準によって測定されたヘイズ(haze)値が1.0以下である、
請求項1から7のいずれか1項に記載のポリアミドフィルム積層体。 - ISO 527−3基準によって測定されたモジュラス(Modulus)値が6以上である、
請求項1から8のいずれか1項に記載のポリアミドフィルム積層体。 - ISO 527−3基準によって測定された伸び(Elongation)値が10%以上である、
請求項1から9のいずれか1項に記載のポリアミドフィルム積層体。 - ASTM D3363基準によって測定された鉛筆硬度値が3H以上である、
請求項1から10のいずれか1項に記載のポリアミドフィルム積層体。 - 基材;
第1ポリアミド樹脂層;および
第2ポリアミド樹脂層を含む、
請求項1から11のいずれか1項に記載のポリアミドフィルム積層体。 - 前記基材は;
ポリイミド系、ポリカーボネート系、ポリエステル系、ポリアルキル(メタ)アクリレート系、ポリオレフィン系およびポリサイクリックオレフィン系高分子からなる群より選択された1種以上の高分子基材である、
請求項12に記載のポリアミドフィルム積層体。
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