JP2021500924A - ナトリウム低減用の結晶形態 - Google Patents
ナトリウム低減用の結晶形態 Download PDFInfo
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- JP2021500924A JP2021500924A JP2020543246A JP2020543246A JP2021500924A JP 2021500924 A JP2021500924 A JP 2021500924A JP 2020543246 A JP2020543246 A JP 2020543246A JP 2020543246 A JP2020543246 A JP 2020543246A JP 2021500924 A JP2021500924 A JP 2021500924A
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- salt
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- antisolvent
- salt crystals
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- 239000013078 crystal Substances 0.000 title claims abstract description 148
- 239000011734 sodium Substances 0.000 title description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title description 9
- 229910052708 sodium Inorganic materials 0.000 title description 9
- 230000009467 reduction Effects 0.000 title description 3
- 150000003839 salts Chemical class 0.000 claims abstract description 237
- 239000000203 mixture Substances 0.000 claims abstract description 73
- 239000012266 salt solution Substances 0.000 claims description 75
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 65
- 239000000243 solution Substances 0.000 claims description 56
- 239000012296 anti-solvent Substances 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 33
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 28
- 235000013305 food Nutrition 0.000 claims description 27
- 239000007787 solid Substances 0.000 claims description 17
- 239000011780 sodium chloride Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 125000001475 halogen functional group Chemical group 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000005185 salting out Methods 0.000 description 20
- 238000002156 mixing Methods 0.000 description 19
- 238000010828 elution Methods 0.000 description 15
- 239000002245 particle Substances 0.000 description 15
- 238000003756 stirring Methods 0.000 description 14
- 239000000654 additive Substances 0.000 description 13
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 10
- 235000019600 saltiness Nutrition 0.000 description 10
- 238000013019 agitation Methods 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- 230000000875 corresponding effect Effects 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000001509 sodium citrate Substances 0.000 description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 235000019643 salty taste Nutrition 0.000 description 5
- 239000004471 Glycine Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- HNYOPLTXPVRDBG-UHFFFAOYSA-N barbituric acid Chemical compound O=C1CC(=O)NC(=O)N1 HNYOPLTXPVRDBG-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000003760 magnetic stirring Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000120 Artificial Saliva Substances 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000008447 perception Effects 0.000 description 3
- 235000021484 savory snack Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000019640 taste Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000013606 potato chips Nutrition 0.000 description 2
- 235000012434 pretzels Nutrition 0.000 description 2
- 235000021148 salty food Nutrition 0.000 description 2
- 235000011888 snacks Nutrition 0.000 description 2
- 235000008371 tortilla/corn chips Nutrition 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 description 1
- 235000005135 Micromeria juliana Nutrition 0.000 description 1
- 241000246354 Satureja Species 0.000 description 1
- 235000007315 Satureja hortensis Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- BUJHNFUAPWGZDP-UHFFFAOYSA-N [P].[Ca].[Ca].[Ca] Chemical compound [P].[Ca].[Ca].[Ca] BUJHNFUAPWGZDP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940125717 barbiturate Drugs 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000021491 salty snack Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/40—Table salts; Dietetic salt substitutes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
- C01D3/08—Preparation by working up natural or industrial salt mixtures or siliceous minerals
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Nutrition Science (AREA)
- Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Seasonings (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
Description
(式中、cmaxは達した最大伝導度である)
さらなる実施形態
Claims (20)
- 少なくとも0.19〜0.23 m2/gの表面積および0.8 g/cm3未満のホール密度を有する複数の塩結晶を含む塩組成物。
- 複数の塩結晶が0.90 g/cm3未満のかさ密度をさらに含む、請求項1に記載の塩組成物。
- 複数の塩結晶の各々が少なくとも10μmの大きさである、請求項1に記載の塩組成物。
- 複数の塩結晶が成熟ホッパーキューブ形態を有する第1の部分を含む、請求項3に記載の塩組成物。
- 第1の部分の複数の塩結晶が80〜150μmの大きさである、請求項4に記載の塩組成物。
- 複数の塩結晶が、単純なホッパーキューブ形態を有する第2の部分、ハローキューブ形態を有する第3の部分、および固体キューブ形態を有する第4の部分をさらに含む、請求項3に記載の塩組成物。
- 第2の部分の複数の塩結晶が50〜100μmの大きさであり、第3の部分の複数の塩結晶が30〜50μmの大きさであり、第4の部分の複数の塩結晶が15〜25μmの大きさである、請求項6に記載の塩組成物。
- 複数の塩結晶が複雑なホッパーキューブ形態を有する第5の部分をさらに含む、請求項3に記載の塩組成物。
- 第5の部分の複数の塩結晶が80〜150μmの大きさである、請求項8に記載の塩組成物。
- 複数の塩結晶が塩化ナトリウムを含む、請求項1に記載の塩組成物。
- 塩組成物を形成する方法であって:
アンチソルベント溶液を提供し;
塩溶液をアンチソルベント溶液に添加して過飽和溶液を形成し、ここで塩溶液は15重量%の溶質を超える濃度を有し、塩溶液とアンチソルベント溶液の質量比は1:20〜1:1.25の範囲であり;および
過飽和溶液を結晶化して、少なくとも0.19〜0.23 m2/gの表面積および0.8 g/cm3未満のホール密度を有する複数の塩結晶を有する塩組成物を形成する
ことを含む方法。 - 塩溶液は溶媒に溶解した溶質を含み、ここで、塩溶液溶質27重量%未満である、請求項11に記載の方法。
- 溶質は塩化ナトリウムを含み、溶媒は水を含む、請求項12に記載の方法。
- アンチソルベントはエタノールである、請求項11に記載の方法。
- アンチソルベントは100体積%未満のエタノールである、請求項14に記載の方法。
- 方法の工程を20〜30℃の温度で行う、請求項11に記載の方法。
- 外側表面;および
食品の外側表面に適用する塩組成物を含む食品であって、塩組成物は少なくとも0.19〜0.23 m2/gの表面積および0.8 g/cm3未満のホール密度を有する複数の塩結晶を含む、食品。 - 複数の塩結晶の各々は10μmの大きさである、請求項17に記載の食品。
- 複数の塩結晶は成熟ホッパーキューブ形態を有する第1の部分、単純なホッパーキューブ形態を有する第2の部分、ハローキューブ形態を有する第3の部分、および固体キューブ形態を有する第4の部分の少なくとも1つを含む、請求項18に記載の食品。
- 複数の塩結晶は塩化ナトリウムを含む、請求項17に記載の食品。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2023084689A JP2023109912A (ja) | 2017-10-27 | 2023-05-23 | ナトリウム低減用の結晶形態 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/795,910 US10881123B2 (en) | 2017-10-27 | 2017-10-27 | Crystal morphology for sodium reduction |
US15/795,910 | 2017-10-27 | ||
PCT/US2018/057777 WO2019084447A1 (en) | 2017-10-27 | 2018-10-26 | CRYSTALLINE MORPHOLOGY FOR SODIUM REDUCTION |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2023084689A Division JP2023109912A (ja) | 2017-10-27 | 2023-05-23 | ナトリウム低減用の結晶形態 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2021500924A true JP2021500924A (ja) | 2021-01-14 |
JP7321169B2 JP7321169B2 (ja) | 2023-08-04 |
Family
ID=66245714
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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JP2020543246A Active JP7321169B2 (ja) | 2017-10-27 | 2018-10-26 | ナトリウム低減用の結晶形態 |
JP2023084689A Pending JP2023109912A (ja) | 2017-10-27 | 2023-05-23 | ナトリウム低減用の結晶形態 |
Family Applications After (1)
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JP2023084689A Pending JP2023109912A (ja) | 2017-10-27 | 2023-05-23 | ナトリウム低減用の結晶形態 |
Country Status (9)
Country | Link |
---|---|
US (2) | US10881123B2 (ja) |
EP (1) | EP3700864A4 (ja) |
JP (2) | JP7321169B2 (ja) |
CN (1) | CN111278775A (ja) |
AU (1) | AU2018354413B2 (ja) |
CA (1) | CA3075647A1 (ja) |
MX (1) | MX2020003975A (ja) |
SG (1) | SG11202003547VA (ja) |
WO (1) | WO2019084447A1 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023200910A2 (en) * | 2022-04-15 | 2023-10-19 | Creighton University | Accelerated tooth remineralization technology |
Citations (4)
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JP2006282476A (ja) * | 2005-04-04 | 2006-10-19 | Doshisha | 塩化ナトリウムの結晶の製造方法 |
JP2006281193A (ja) * | 2005-03-08 | 2006-10-19 | Doshisha | 液−液界面を利用する結晶析出方法及び新規な結晶体 |
JP2006524565A (ja) * | 2003-04-29 | 2006-11-02 | アクゾ ノーベル ナムローゼ フェンノートシャップ | アンチ溶媒凝固プロセス |
US20080008790A1 (en) * | 2006-06-30 | 2008-01-10 | Michael Jensen | Seasoned food, seasoning, and method for seasoning a food product |
Family Cites Families (17)
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US2655438A (en) * | 1950-12-06 | 1953-10-13 | Diamond Crystal Salt Co | Salt crystallization process |
FR2759076B1 (fr) | 1997-02-06 | 1999-04-30 | Saline D Einville | Procede de fabrication de petales de sel |
FI110474B (fi) * | 1999-01-27 | 2003-02-14 | Modulpo Salts Oy | Ravintofysiologinen suolatuote, sen käyttö ja menetelmä sen valmistamiseksi |
EA005635B1 (ru) | 2001-07-09 | 2005-04-28 | Акцо Нобель Н.В. | Способ получения высокочистой мокрой соли, мокрая соль, получаемая таким способом, и ее применение в процессе электролиза |
NZ515527A (en) * | 2001-11-15 | 2003-08-29 | Auckland Uniservices Ltd | Method, apparatus and software for lossy data compression and function estimation |
US7972390B2 (en) * | 2002-03-21 | 2011-07-05 | Gr Intellectual Reserve, Llc | Methods for controlling crystal growth, crystallization, structures and phases in materials and systems |
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EP1620192A1 (en) | 2003-04-29 | 2006-02-01 | Akzo Nobel N.V. | Processes involving the use of antisolvent crystallisation |
WO2005066075A1 (en) * | 2003-12-24 | 2005-07-21 | Council Of Scientific And Industrial Research | Process for production of glycine enriched sodium chloride crystals with improved flow |
WO2006045795A2 (en) | 2004-10-29 | 2006-05-04 | Akzo Nobel N.V. | Processes involving the use of antisolvent crystallization |
WO2009087645A1 (en) * | 2008-01-07 | 2009-07-16 | Council Of Scientific & Industrial Research | Free flowing 100 - 500 mm size spherical crystals of common salt and process for preparation thereof |
CN101565190B (zh) | 2009-05-08 | 2011-01-05 | 江苏大学 | 一种微米级超细氯化钠的制备方法 |
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US20150201657A1 (en) | 2014-01-22 | 2015-07-23 | Grain Processing Corporation | Method for the Manufacture of Larger Particle Forms of Low Sodium Salts |
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2017
- 2017-10-27 US US15/795,910 patent/US10881123B2/en active Active
-
2018
- 2018-10-26 CN CN201880069883.8A patent/CN111278775A/zh active Pending
- 2018-10-26 WO PCT/US2018/057777 patent/WO2019084447A1/en unknown
- 2018-10-26 SG SG11202003547VA patent/SG11202003547VA/en unknown
- 2018-10-26 CA CA3075647A patent/CA3075647A1/en active Pending
- 2018-10-26 JP JP2020543246A patent/JP7321169B2/ja active Active
- 2018-10-26 MX MX2020003975A patent/MX2020003975A/es unknown
- 2018-10-26 EP EP18871800.1A patent/EP3700864A4/en active Pending
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CA3075647A1 (en) | 2019-05-02 |
AU2018354413A1 (en) | 2020-04-02 |
MX2020003975A (es) | 2020-08-13 |
US20210015136A1 (en) | 2021-01-21 |
CN111278775A (zh) | 2020-06-12 |
EP3700864A1 (en) | 2020-09-02 |
AU2018354413B2 (en) | 2024-01-25 |
JP7321169B2 (ja) | 2023-08-04 |
US20190124967A1 (en) | 2019-05-02 |
EP3700864A4 (en) | 2021-08-11 |
JP2023109912A (ja) | 2023-08-08 |
SG11202003547VA (en) | 2020-05-28 |
US10881123B2 (en) | 2021-01-05 |
WO2019084447A1 (en) | 2019-05-02 |
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