JP2019536779A5 - - Google Patents
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- JP2019536779A5 JP2019536779A5 JP2019526520A JP2019526520A JP2019536779A5 JP 2019536779 A5 JP2019536779 A5 JP 2019536779A5 JP 2019526520 A JP2019526520 A JP 2019526520A JP 2019526520 A JP2019526520 A JP 2019526520A JP 2019536779 A5 JP2019536779 A5 JP 2019536779A5
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- Prior art keywords
- group
- alkyl
- hydrocarbyl
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- complex according
- Prior art date
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 41
- 125000005843 halogen group Chemical group 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 239000003446 ligand Substances 0.000 claims description 6
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052735 hafnium Chemical group 0.000 claims description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 14
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 9
- 239000003054 catalyst Substances 0.000 claims 9
- 125000003118 aryl group Chemical group 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 6
- 239000007788 liquid Substances 0.000 claims 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 6
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 5
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 4
- 125000006717 (C3-C10) cycloalkenyl group Chemical group 0.000 claims 4
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims 4
- 125000006376 (C3-C10) cycloalkyl group Chemical group 0.000 claims 3
- 239000000839 emulsion Substances 0.000 claims 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 3
- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 claims 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 2
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 229910052796 boron Inorganic materials 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- -1 dimethylsilyl Chemical group 0.000 claims 2
- 229910021482 group 13 metal Inorganic materials 0.000 claims 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 229920005606 polypropylene copolymer Polymers 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 238000005580 one pot reaction Methods 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229920005629 polypropylene homopolymer Polymers 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 claims 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical group [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000012279 sodium borohydride Substances 0.000 claims 1
- 229910000033 sodium borohydride Inorganic materials 0.000 claims 1
- 239000011949 solid catalyst Substances 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16199646 | 2016-11-18 | ||
| EP16199646.7 | 2016-11-18 | ||
| PCT/EP2017/079662 WO2018091684A1 (en) | 2016-11-18 | 2017-11-17 | Catalysts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019536779A JP2019536779A (ja) | 2019-12-19 |
| JP2019536779A5 true JP2019536779A5 (enExample) | 2020-08-06 |
| JP7037562B2 JP7037562B2 (ja) | 2022-03-16 |
Family
ID=57389239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019526520A Active JP7037562B2 (ja) | 2016-11-18 | 2017-11-17 | 触媒 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11352376B2 (enExample) |
| EP (1) | EP3541823B1 (enExample) |
| JP (1) | JP7037562B2 (enExample) |
| KR (1) | KR102505086B1 (enExample) |
| CN (1) | CN110177798B (enExample) |
| WO (1) | WO2018091684A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3541823B1 (en) | 2016-11-18 | 2020-12-30 | Borealis AG | Catalysts |
| WO2018108918A1 (en) | 2016-12-15 | 2018-06-21 | Borealis Ag | Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| WO2018108917A1 (en) | 2016-12-15 | 2018-06-21 | Borealis Ag | New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| EP3562831B1 (en) | 2016-12-29 | 2021-10-20 | Borealis AG | Catalysts |
| KR102307179B1 (ko) * | 2017-07-07 | 2021-09-30 | 보레알리스 아게 | 헤테로상 프로필렌 공중합체의 제조 방법 |
| CN112292406B (zh) | 2018-03-19 | 2023-04-04 | 博里利斯股份公司 | 烯烃聚合催化剂 |
| JP7497336B2 (ja) * | 2018-05-09 | 2024-06-10 | ボレアリス エージー | プロピレンポリマーの調製方法 |
| EP3814388A1 (en) | 2018-06-28 | 2021-05-05 | Borealis AG | Catalysts |
| EP3647356B8 (en) | 2018-10-31 | 2022-03-30 | Borealis AG | Polyolefin composition with improved balance of properties |
| JP7680965B2 (ja) | 2019-05-29 | 2025-05-21 | ボレアリス エージー | 触媒系の改善された調製 |
| WO2021058740A1 (en) | 2019-09-25 | 2021-04-01 | Borealis Ag | Catalysts |
| WO2025051400A1 (en) * | 2023-09-07 | 2025-03-13 | Borealis Ag | Methods of producing metallocene catalyst components |
| WO2025016565A1 (en) | 2023-07-14 | 2025-01-23 | Borealis Ag | Catalysts for olefin polymerization |
| WO2025016570A1 (en) | 2023-07-14 | 2025-01-23 | Borealis Ag | Catalysts for olefin polymerization |
| WO2025016566A1 (en) * | 2023-07-14 | 2025-01-23 | Borealis Ag | Metallocenes for the manufacture of polypropylene |
| WO2025016568A1 (en) | 2023-07-14 | 2025-01-23 | Borealis Ag | Metallocenes for the manufacture of polypropylene |
| WO2025016569A1 (en) | 2023-07-14 | 2025-01-23 | Borealis Ag | Metallocenes for the manufacture of polypropylene |
| WO2025016564A1 (en) | 2023-07-14 | 2025-01-23 | Borealis Ag | Metallocenes for the manufacture of polypropylene |
| KR20250026537A (ko) * | 2023-08-17 | 2025-02-25 | 한화솔루션 주식회사 | 전이금속 화합물을 이용한 에틸렌-α-올레핀 공중합체의 용액중합방법 |
| WO2025190884A1 (en) | 2024-03-13 | 2025-09-18 | Borealis Gmbh | Metallocenes for the manufacture of propylene copolymers |
Family Cites Families (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| FI96866C (fi) | 1993-11-05 | 1996-09-10 | Borealis As | Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö |
| WO1997014727A1 (en) | 1995-10-19 | 1997-04-24 | Amoco Corporation | Homogeneous metallocene-based olefin polymerization system with increased activity |
| DE19544828A1 (de) | 1995-12-01 | 1997-06-05 | Hoechst Ag | Hochmolekulare Copolymere |
| CN1762957B (zh) | 1997-03-07 | 2010-05-12 | 巴塞尔聚烯烃股份有限公司 | 2,3-二氢-1-茚酮类化合物以及其制备方法 |
| US6252019B1 (en) | 1997-05-13 | 2001-06-26 | Montell Technology Company Bv | Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes |
| CA2337380C (en) | 1998-08-11 | 2010-11-09 | The Dow Chemical Company | Catalyst activator composition |
| RU2232766C2 (ru) | 1998-10-23 | 2004-07-20 | Эксонмобил Кемикэл Пейтентс Инк. | Связанные мостиками металлоцены, способ полимеризации |
| CN1125834C (zh) | 1998-10-23 | 2003-10-29 | 埃克森美孚化学专利公司 | 使用桥接二茂铪的烯烃共聚方法 |
| DE60112307T8 (de) * | 2000-06-30 | 2007-02-15 | Exxonmobil Chemical Patents Inc., Baytown | Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen |
| WO2003049856A1 (en) | 2001-12-05 | 2003-06-19 | Exxonmobil Chemical Patents Inc. | Bulky borate activators |
| EP1640377B1 (en) * | 2001-12-10 | 2007-07-25 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| US6756455B2 (en) | 2002-05-31 | 2004-06-29 | Equistar Chemicals, Lp | High-temperature solution process for polyolefin manufacture |
| EP2511305B1 (en) | 2002-09-27 | 2019-05-29 | Mitsui Chemicals, Inc. | Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same |
| US7285608B2 (en) | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US20050288461A1 (en) | 2004-06-25 | 2005-12-29 | Jensen Michael D | Polymerization catalysts for producing polymers with low levels of long chain branching |
| US8222175B2 (en) | 2004-12-31 | 2012-07-17 | Borealis Technology Oy | Process for the preparation of an olefin polymerisation catalyst |
| PL1858907T3 (pl) | 2005-03-18 | 2009-04-30 | Basell Polyolefine Gmbh | Metalocenowe związki |
| WO2006100258A1 (en) | 2005-03-23 | 2006-09-28 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| JP2009533382A (ja) * | 2006-04-12 | 2009-09-17 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
| JP5295098B2 (ja) | 2006-04-21 | 2013-09-18 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレンコポリマーの製造方法 |
| US7429635B2 (en) | 2006-09-28 | 2008-09-30 | Equistar Chemicals, Lp | Preparation of ultra high molecular weight linear low density polyethylene |
| EP2203486B9 (en) | 2007-10-25 | 2012-08-01 | Lummus Novolen Technology Gmbh | Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
| WO2010052260A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| WO2010052263A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| WO2010052264A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| CN102666603B (zh) | 2009-12-22 | 2014-10-15 | 北欧化工公司 | 在单活性中心催化剂存在的情况下的聚丙烯制备 |
| EP2516486B1 (en) | 2009-12-22 | 2018-02-07 | Borealis AG | Catalysts |
| JP6026995B2 (ja) | 2010-04-28 | 2016-11-16 | ボレアリス エージー | 触媒 |
| EP2383299B1 (en) | 2010-04-28 | 2017-12-20 | Borealis AG | Solid particulate catalysts comprising bridged metallocenes |
| EP2402353B1 (en) | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
| EP2402354B1 (en) | 2010-07-01 | 2016-03-02 | Borealis AG | Process for olefin polymerisation using group 4 metallocene as catalysts |
| CA2724943A1 (en) | 2010-12-10 | 2012-06-10 | Nova Chemicals Corporation | Catalyst activation in a dual reactor process |
| WO2012084961A1 (en) | 2010-12-22 | 2012-06-28 | Borealis Ag | Bridged metallocene catalysts |
| EP2532687A3 (en) | 2011-06-10 | 2013-04-10 | Borealis AG | Bridged Metallocene Catalysts |
| BR112014000465B1 (pt) | 2011-07-08 | 2020-03-31 | Borealis Ag | Catalisadores |
| EP2657285B1 (en) | 2012-04-25 | 2015-07-22 | Borealis AG | moulded polypropylene with high content of beta form |
| EP2722346A1 (en) | 2012-10-18 | 2014-04-23 | Borealis AG | Polymerisation process and catalyst |
| JP6193398B2 (ja) | 2012-12-21 | 2017-09-06 | ボレアリス エージー | 触媒 |
| ES2645256T3 (es) * | 2012-12-21 | 2017-12-04 | Borealis Ag | Catalizadores |
| JP5710035B2 (ja) | 2013-02-27 | 2015-04-30 | 日本ポリエチレン株式会社 | メタロセン化合物およびオレフィン重合体の製造方法 |
| EP2813517B2 (en) | 2013-06-10 | 2019-06-26 | Borealis AG | Process for the preparation of a propylene polymer |
| US9834628B2 (en) * | 2013-07-17 | 2017-12-05 | Exxonmobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
| ES2612627T3 (es) * | 2013-07-24 | 2017-05-17 | Borealis Ag | Proceso |
| EP2933277A1 (en) | 2014-04-17 | 2015-10-21 | Borealis AG | New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| US10167355B2 (en) | 2014-04-17 | 2019-01-01 | Borealis Ag | Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| WO2016038211A1 (en) | 2014-09-12 | 2016-03-17 | Borealis Ag | Process for the preparation of copolymers of propylene |
| EP2995629B1 (en) | 2014-09-12 | 2018-03-07 | Borealis AG | Process for producing propylene copolymers in gas phase |
| WO2017204830A1 (en) | 2016-05-27 | 2017-11-30 | Exxonmobil Chemical Patents, Inc. | Metallocene catalyst compositions and polymerization process therewith |
| EP3541823B1 (en) | 2016-11-18 | 2020-12-30 | Borealis AG | Catalysts |
| WO2018108918A1 (en) | 2016-12-15 | 2018-06-21 | Borealis Ag | Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| WO2018108917A1 (en) | 2016-12-15 | 2018-06-21 | Borealis Ag | New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| EP3562831B1 (en) | 2016-12-29 | 2021-10-20 | Borealis AG | Catalysts |
| CN109790232A (zh) | 2017-06-29 | 2019-05-21 | 博里利斯股份公司 | 制备聚丙烯组合物的方法 |
| PT3456776T (pt) | 2017-09-13 | 2020-03-09 | Borealis Ag | Composição de polipropileno |
| CN112292406B (zh) | 2018-03-19 | 2023-04-04 | 博里利斯股份公司 | 烯烃聚合催化剂 |
-
2017
- 2017-11-17 EP EP17800546.8A patent/EP3541823B1/en active Active
- 2017-11-17 WO PCT/EP2017/079662 patent/WO2018091684A1/en not_active Ceased
- 2017-11-17 JP JP2019526520A patent/JP7037562B2/ja active Active
- 2017-11-17 KR KR1020197017336A patent/KR102505086B1/ko active Active
- 2017-11-17 CN CN201780083860.8A patent/CN110177798B/zh active Active
- 2017-11-17 US US16/461,517 patent/US11352376B2/en active Active
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