RU2016119349A - Способ получения алюмоксанов - Google Patents
Способ получения алюмоксанов Download PDFInfo
- Publication number
- RU2016119349A RU2016119349A RU2016119349A RU2016119349A RU2016119349A RU 2016119349 A RU2016119349 A RU 2016119349A RU 2016119349 A RU2016119349 A RU 2016119349A RU 2016119349 A RU2016119349 A RU 2016119349A RU 2016119349 A RU2016119349 A RU 2016119349A
- Authority
- RU
- Russia
- Prior art keywords
- paragraphs
- alkylaluminum
- methyl
- group
- oxide
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 12
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 150000004808 allyl alcohols Chemical class 0.000 claims 3
- XXROGKLTLUQVRX-UHFFFAOYSA-N hydroxymethylethylene Natural products OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims 3
- 239000003960 organic solvent Substances 0.000 claims 3
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 239000000395 magnesium oxide Substances 0.000 claims 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 2
- QFXSWGXWZXSGLC-GQCTYLIASA-N (e)-3-methylpent-2-en-1-ol Chemical compound CC\C(C)=C\CO QFXSWGXWZXSGLC-GQCTYLIASA-N 0.000 claims 1
- PUCCIVZQJKKAET-UHFFFAOYSA-N 3-ethylpent-2-en-1-ol Chemical compound CCC(CC)=CCO PUCCIVZQJKKAET-UHFFFAOYSA-N 0.000 claims 1
- CKWCTBJSFBLMOH-UHFFFAOYSA-N 3-methylhex-2-en-1-ol Chemical compound CCCC(C)=CCO CKWCTBJSFBLMOH-UHFFFAOYSA-N 0.000 claims 1
- SAOXPNBHKSWHGW-UHFFFAOYSA-N 4-methylpent-3-en-2-ol Chemical compound CC(O)C=C(C)C SAOXPNBHKSWHGW-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 241001594894 Mesites Species 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- -1 heptanes or hexanes Chemical class 0.000 claims 1
- 150000002430 hydrocarbons Chemical group 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 229910001629 magnesium chloride Inorganic materials 0.000 claims 1
- 229910052901 montmorillonite Inorganic materials 0.000 claims 1
- 238000006384 oligomerization reaction Methods 0.000 claims 1
- 229910052615 phyllosilicate Inorganic materials 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- ASUAYTHWZCLXAN-UHFFFAOYSA-N prenol Chemical compound CC(C)=CCO ASUAYTHWZCLXAN-UHFFFAOYSA-N 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/025—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
- C08F4/6028—Component covered by group C08F4/60 with an organo-aluminium compound with an alumoxane, i.e. a compound containing an -Al-O-Al-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Claims (16)
1. Способ получения алкилалюмоксанов посредством реакции алкилалюминия с замещенным аллильным спиртом формулы
где каждая из групп R1 и R2 независимо представляет собой алифатическую или ароматическую углеводородную группу, и R3, R4 и R5 каждая независимо могут быть такой же углеводородной группой, как и R1 и R2, или атомом водорода
в присутствии инертного органического растворителя.
2. Способ по п. 1, в котором каждая из групп R1 и R2 независимо представляет собой разветвленную или неразветвленную алкильную или алкиленовую группу, содержащую до 20 атомов углерода, и в котором R3, R4 и R5 каждая независимо могут быть такой же алкильной или алкиленовой группой, как и R1 и R2, или атомом водорода.
3. Способ по пп. 1 или 2, в котором замещенный аллильный спирт выбирают из группы, состоящей из 4-метил-3-пентен-2-ола, 3-метил-2-пентен-1-ола, 3-метил-2-гексен-1-ола, 3-этил-2-пентен-1-ола, транс-3,7-диметил-2,6-октадиен-1-ола и 3-метил-2-бутен-1-ола.
4. Способ по любому из пп. 1-3, в котором алкилалюминий представляет собой триалкилалюминий, в котором алкильные группы представляют собой алкильные группы, содержащие до 8 атомов углерода.
5. Способ по п. 4, в котором одна или более из алкильных групп в алкилалюминии представляют собой изобутил, этил или метил.
6. Способ по любому из пп. 1-5, в котором алкилалюминий представляет собой соединение, в котором по меньшей мере 50% алкильных групп представляют собой метил.
7. Способ по любому из пп. 1-6, в котором алкилалюминий содержит триметилалюминий.
8. Способ по любому из пп. 1-7, в котором органический растворитель выбирают из группы алканов, таких как гептаны или гексаны, или ароматических соединений, таких как толуол, ксилол, этилбензол, кумол или мезителен.
9. Способ по любому из пп. 1-8, в котором реакция алкилалюминия с замещенным аллильным спиртом осуществляется в присутствии алюмоксана.
10. Способ по любому из пп. 1-9, в котором инертный органический растворитель содержит носитель.
11. Способ по п. 10, в котором носитель выбирают из группы, состоящей из оксида кремния, оксида магния, оксида титана, оксида циркония, монтмориллонита, филлосиликата, оксида алюминия, смешанного оксида кремния-алюминия, смешанного оксида кремния-хрома, смешанного оксида кремния-титана, хлорида магния, графита, оксида магния, оксида титана, оксида циркония и их сочетания.
12. Продукт, получаемый согласно данному способу по любому из пп. 1-11.
13. Применение продукта по п. 12 как компонента катализатора в катализаторе, используемом в процессе полимеризации или олигомеризации олефинов.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13190471.6 | 2013-10-28 | ||
| EP13190471 | 2013-10-28 | ||
| PCT/EP2014/072807 WO2015062977A1 (en) | 2013-10-28 | 2014-10-24 | Process to prepare aluminoxanes by reaction of alkylaluminium with allylic alcohols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2016119349A true RU2016119349A (ru) | 2017-12-05 |
| RU2016119349A3 RU2016119349A3 (ru) | 2018-05-31 |
| RU2668553C2 RU2668553C2 (ru) | 2018-10-02 |
Family
ID=49484232
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2016119349A RU2668553C2 (ru) | 2013-10-28 | 2014-10-24 | Способ получения алюмоксанов |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US9505788B2 (ru) |
| EP (1) | EP3063155B1 (ru) |
| JP (1) | JP6149157B2 (ru) |
| KR (1) | KR102311466B1 (ru) |
| CN (1) | CN105745216B (ru) |
| AR (1) | AR098200A1 (ru) |
| BR (1) | BR112016008354A2 (ru) |
| CA (1) | CA2927359A1 (ru) |
| ES (1) | ES2645848T3 (ru) |
| PL (1) | PL3063155T3 (ru) |
| PT (1) | PT3063155T (ru) |
| RU (1) | RU2668553C2 (ru) |
| SA (1) | SA516370979B1 (ru) |
| SG (1) | SG11201603213VA (ru) |
| TW (1) | TWI633110B (ru) |
| WO (1) | WO2015062977A1 (ru) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10323047B2 (en) | 2015-04-24 | 2019-06-18 | Akzo Nobel Chemicals International B.V. | Process to prepare aluminoxanes |
| EP3464301B1 (en) * | 2016-05-24 | 2020-11-25 | Nouryon Chemicals International B.V. | Process to prepare aluminoxanes |
| US11161922B2 (en) | 2017-10-31 | 2021-11-02 | Exxonmobil Chemical Patents Inc. | Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents |
| WO2019089145A1 (en) * | 2017-10-31 | 2019-05-09 | Exxonmobil Chemical Patents Inc. | Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents |
| RU2697658C1 (ru) * | 2018-08-20 | 2019-08-16 | Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук | Способ получения диастереомерно чистых 4-метил(этил)-2-н-алкил-замещенных 1-алканолов |
| RU2697657C1 (ru) * | 2018-08-20 | 2019-08-16 | Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук | Однореакторный способ получения диастереомерно чистых функционально замещенных олигомеров пропена |
| CN116438212A (zh) | 2020-11-23 | 2023-07-14 | 埃克森美孚化学专利公司 | 不含甲苯的负载型甲基铝氧烷前体 |
| CN116601160A (zh) | 2020-11-23 | 2023-08-15 | 埃克森美孚化学专利公司 | 由原位形成的铝氧烷制备催化剂的改进方法 |
| EP4247825A1 (en) | 2020-11-23 | 2023-09-27 | ExxonMobil Chemical Patents Inc. | Metallocene polypropylene prepared using aromatic solvent-free supports |
| CN116490510A (zh) | 2020-11-23 | 2023-07-25 | 埃克森美孚化学专利公司 | Smao和催化剂的非水解制备 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH602108A5 (ru) * | 1974-02-22 | 1978-07-31 | Hoffmann La Roche | |
| SU1754717A1 (ru) * | 1989-10-25 | 1992-08-15 | Государственный научно-исследовательский институт химии и технологии элементоорганических соединений | Способ получени несольватированных алкилалюмоксанов |
| JP2866434B2 (ja) | 1990-03-20 | 1999-03-08 | 出光興産株式会社 | アルミノキサンの製造方法 |
| US5670589A (en) | 1995-02-08 | 1997-09-23 | Phillips Petroleum Company | Organoaluminoxy product, catalyst systems, preparation, and use |
| ATE153675T1 (de) | 1995-09-13 | 1997-06-15 | Witco Gmbh | Verfahren zur herstellung von metallocen- katalysatorsystemen auf inerten trägermaterialien unter verwendung von gasphasenreaktoren |
| US5777143A (en) | 1995-12-22 | 1998-07-07 | Akzo Nobel Nv | Hydrocarbon soluble alkylaluminoxane compositions formed by use of non-hydrolytic means |
| US5831109A (en) * | 1995-12-22 | 1998-11-03 | Akzo Nobel Nv | Polyalkylaluminoxane compositions formed by non-hydrolytic means |
| US5663394A (en) | 1996-07-15 | 1997-09-02 | Albemarle Corporation | High yield aluminoxane synthesis process |
| EP1264847A1 (fr) | 2001-06-06 | 2002-12-11 | SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) | Procédé pour la polymérisation des alpha-oléfines |
| EP1963379A2 (en) | 2005-12-21 | 2008-09-03 | Albermarle Corporation | Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins |
| EP2119732A1 (en) | 2008-05-16 | 2009-11-18 | Borealis Technology Oy | Metallocene catalyst compositions with improved properties, process for its preparation and use for preparing polyolefin homo- or copolymers |
| EP2440564A4 (en) | 2009-06-11 | 2014-07-09 | Grace W R & Co | PROCESS FOR PRODUCING ALUMINOXANE AND CATALYSTS COMPRISING ALUMINOXANE THUS PREPARED |
| BR112012001942B1 (pt) * | 2009-07-29 | 2019-10-22 | Dow Global Technologies Llc | agente de permuta de cadeia multifuncional, processo para preparar um agente de permuta de cadeia multifuncional, processo para preparar uma composição multifuncional, composição multifuncional, processo para preparar um agente de permuta de cadeia multifuncional contendo poli-radical poliolefina, poliolefina telequélica, processo para preparar uma poliolefina com funcionalidade terminal e separador de bateria |
| KR101502673B1 (ko) | 2010-07-01 | 2015-03-13 | 토탈 리서치 앤드 테크놀로지 펠루이 | 개질된 촉매 지지체 |
| TWI555574B (zh) | 2011-03-09 | 2016-11-01 | 亞比馬利股份有限公司 | 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途 |
| WO2014105614A1 (en) | 2012-12-28 | 2014-07-03 | Univation Technologies, Llc | Methods of integrating aluminoxane production into catalyst production |
-
2014
- 2014-10-24 WO PCT/EP2014/072807 patent/WO2015062977A1/en active Application Filing
- 2014-10-24 PT PT147964431T patent/PT3063155T/pt unknown
- 2014-10-24 PL PL14796443T patent/PL3063155T3/pl unknown
- 2014-10-24 BR BR112016008354A patent/BR112016008354A2/pt not_active Application Discontinuation
- 2014-10-24 ES ES14796443.1T patent/ES2645848T3/es active Active
- 2014-10-24 KR KR1020167009906A patent/KR102311466B1/ko active IP Right Grant
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- 2014-10-24 RU RU2016119349A patent/RU2668553C2/ru not_active IP Right Cessation
- 2014-10-24 CA CA2927359A patent/CA2927359A1/en not_active Abandoned
- 2014-10-24 US US15/032,368 patent/US9505788B2/en active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| PL3063155T3 (pl) | 2018-02-28 |
| EP3063155B1 (en) | 2017-09-20 |
| KR20160078961A (ko) | 2016-07-05 |
| CN105745216B (zh) | 2018-03-09 |
| US20160272658A1 (en) | 2016-09-22 |
| AR098200A1 (es) | 2016-05-18 |
| JP2016535018A (ja) | 2016-11-10 |
| KR102311466B1 (ko) | 2021-10-12 |
| SG11201603213VA (en) | 2016-05-30 |
| TW201522354A (zh) | 2015-06-16 |
| CN105745216A (zh) | 2016-07-06 |
| SA516370979B1 (ar) | 2017-03-20 |
| CA2927359A1 (en) | 2015-05-07 |
| RU2016119349A3 (ru) | 2018-05-31 |
| TWI633110B (zh) | 2018-08-21 |
| BR112016008354A2 (pt) | 2017-09-12 |
| EP3063155A1 (en) | 2016-09-07 |
| ES2645848T3 (es) | 2017-12-11 |
| PT3063155T (pt) | 2017-12-11 |
| RU2668553C2 (ru) | 2018-10-02 |
| JP6149157B2 (ja) | 2017-06-14 |
| WO2015062977A1 (en) | 2015-05-07 |
| US9505788B2 (en) | 2016-11-29 |
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| MM4A | The patent is invalid due to non-payment of fees |
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