JP2014501809A5 - - Google Patents
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- JP2014501809A5 JP2014501809A5 JP2013539926A JP2013539926A JP2014501809A5 JP 2014501809 A5 JP2014501809 A5 JP 2014501809A5 JP 2013539926 A JP2013539926 A JP 2013539926A JP 2013539926 A JP2013539926 A JP 2013539926A JP 2014501809 A5 JP2014501809 A5 JP 2014501809A5
- Authority
- JP
- Japan
- Prior art keywords
- composition
- compound
- aluminoxane
- mixture
- polyfunctional compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 21
- 239000012190 activator Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052768 actinide Inorganic materials 0.000 claims description 2
- 150000001255 actinides Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 2
- 150000002602 lanthanoids Chemical class 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims 8
- 125000003118 aryl group Chemical group 0.000 claims 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 5
- -1 aluminum compound Chemical class 0.000 claims 5
- 239000012876 carrier material Substances 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- 125000004429 atom Chemical group 0.000 claims 4
- 239000000463 material Substances 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 239000002243 precursor Substances 0.000 claims 3
- URFNSYWAGGETFK-UHFFFAOYSA-N 4,4'-Dihydroxybibenzyl Chemical compound C1=CC(O)=CC=C1CCC1=CC=C(O)C=C1 URFNSYWAGGETFK-UHFFFAOYSA-N 0.000 claims 2
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 claims 2
- 239000013543 active substance Substances 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims 2
- YVSMQHYREUQGRX-UHFFFAOYSA-N 2-ethyloxaluminane Chemical compound CC[Al]1CCCCO1 YVSMQHYREUQGRX-UHFFFAOYSA-N 0.000 claims 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 claims 1
- ZAAQJFLUOUQAOG-UHFFFAOYSA-N 4-benzyl-2,6-ditert-butylphenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=CC=CC=2)=C1 ZAAQJFLUOUQAOG-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 1
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 claims 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 claims 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41609210P | 2010-11-22 | 2010-11-22 | |
| US61/416,092 | 2010-11-22 | ||
| PCT/US2011/060595 WO2012071205A2 (en) | 2010-11-22 | 2011-11-14 | Activator compositions, their preparation, and their use in catalysis |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014501809A JP2014501809A (ja) | 2014-01-23 |
| JP2014501809A5 true JP2014501809A5 (enExample) | 2014-11-06 |
| JP6023069B2 JP6023069B2 (ja) | 2016-11-09 |
Family
ID=45217663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013539926A Active JP6023069B2 (ja) | 2010-11-22 | 2011-11-14 | 活性剤組成物、その製造及び触媒中でのその使用 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8895465B2 (enExample) |
| EP (1) | EP2643366B1 (enExample) |
| JP (1) | JP6023069B2 (enExample) |
| KR (2) | KR101846489B1 (enExample) |
| CN (1) | CN103380154B (enExample) |
| BR (1) | BR112013010627B1 (enExample) |
| CA (1) | CA2815336C (enExample) |
| ES (1) | ES2540117T3 (enExample) |
| MX (1) | MX2013005612A (enExample) |
| RU (1) | RU2581361C2 (enExample) |
| SG (1) | SG189518A1 (enExample) |
| TW (1) | TWI546123B (enExample) |
| WO (1) | WO2012071205A2 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102064629B1 (ko) * | 2012-04-27 | 2020-01-08 | 더블유.알. 그레이스 앤드 캄파니-콘. | 활성제 조성물, 이들의 제조, 및 촉매에서 이들의 용도 |
| CN107922537B (zh) | 2015-06-05 | 2021-07-27 | 埃克森美孚化学专利公司 | 气相或淤浆相中多相聚合物的制备 |
| WO2016197037A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| CN107690441A (zh) | 2015-06-05 | 2018-02-13 | 埃克森美孚化学专利公司 | 聚合物在气相或淤浆相中的单反应器制备 |
| EP3318544B1 (en) | 2016-11-07 | 2020-03-18 | Scg Chemicals Co. Ltd. | Process for the preparation of polymerized polyethylene wax |
| US11161922B2 (en) | 2017-10-31 | 2021-11-02 | Exxonmobil Chemical Patents Inc. | Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents |
| SG11202001743RA (en) * | 2017-10-31 | 2020-05-28 | Exxonmobil Chemical Patents Inc | Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents |
| CN113164932B (zh) | 2019-05-17 | 2023-09-08 | Lg化学株式会社 | 使用无水烃溶剂制备助催化剂化合物的方法 |
| US20230242745A1 (en) | 2020-06-03 | 2023-08-03 | Exxonmobil Chemical Patents Inc | Process for Production of Thermoplastic Vulcanizates using Supported Catalyst Systems and Compositions Made Therefrom |
| TWI844939B (zh) * | 2022-09-02 | 2024-06-11 | 國立中正大學 | 金屬茂觸媒顆粒、其製備方法及應用 |
| WO2024253830A1 (en) | 2023-06-06 | 2024-12-12 | ExxonMobil Technology and Engineering Company | Non-coordinated alkylaluminum free cation modified alumoxanes and methods thereof |
| WO2024253831A1 (en) | 2023-06-06 | 2024-12-12 | ExxonMobil Technology and Engineering Company | Non-coordinated alkylaluminum free anion modified alumoxanes and methods thereof |
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| ES2627289T3 (es) | 2007-08-29 | 2017-07-27 | Albemarle Corporation | Activadores de catalizador de aluminoxano derivados de agentes precursores de catión dialquilaluminio y uso de los mismos en catalizadores y polimerización de olefinas |
| CN101407562B (zh) * | 2008-11-28 | 2011-06-01 | 北京化工大学 | 宽/双峰分子量分布聚烯烃的催化剂及其制备方法 |
-
2011
- 2011-11-14 MX MX2013005612A patent/MX2013005612A/es active IP Right Grant
- 2011-11-14 CA CA2815336A patent/CA2815336C/en active Active
- 2011-11-14 KR KR1020137012182A patent/KR101846489B1/ko active Active
- 2011-11-14 BR BR112013010627A patent/BR112013010627B1/pt active IP Right Grant
- 2011-11-14 JP JP2013539926A patent/JP6023069B2/ja active Active
- 2011-11-14 ES ES11793570.0T patent/ES2540117T3/es active Active
- 2011-11-14 SG SG2013031307A patent/SG189518A1/en unknown
- 2011-11-14 EP EP11793570.0A patent/EP2643366B1/en active Active
- 2011-11-14 RU RU2013128495/04A patent/RU2581361C2/ru active
- 2011-11-14 CN CN201180055919.5A patent/CN103380154B/zh active Active
- 2011-11-14 WO PCT/US2011/060595 patent/WO2012071205A2/en not_active Ceased
- 2011-11-14 US US13/988,886 patent/US8895465B2/en active Active
- 2011-11-14 KR KR1020187009343A patent/KR101972725B1/ko active Active
- 2011-11-21 TW TW100142479A patent/TWI546123B/zh active
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