RU2006133267A - Обеспенивание суспензий, высушенных распылением катализаторов - Google Patents

Обеспенивание суспензий, высушенных распылением катализаторов Download PDF

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RU2006133267A
RU2006133267A RU2006133267/04A RU2006133267A RU2006133267A RU 2006133267 A RU2006133267 A RU 2006133267A RU 2006133267/04 A RU2006133267/04 A RU 2006133267/04A RU 2006133267 A RU2006133267 A RU 2006133267A RU 2006133267 A RU2006133267 A RU 2006133267A
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catalyst
group
combining
slurry according
atoms
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Натараян МУРУГАНАНДАМ (US)
Натараян МУРУГАНАНДАМ
Керстен Анне ТЕРРИ (US)
Керстен Анне ТЕРРИ
Майкл Д. ОИ (US)
Майкл Д. ОИ
Джон Х. ОСКАМ (US)
Джон Х. ОСКАМ
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Юнивейшн Технолоджиз
Юнивейшн Технолоджиз, Ллс
Ллс (Us)
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
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  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1. Суспензия катализатора для полимеризации олефинов, включающая продуктвначале объединения минерального масла с одним или несколькими жидкими алканами, содержащими три или большее число углеродных атомов, с получением смеси;с последующим объединением с этой смесью каталитической системы, включающей один или несколько катализаторов, выбранных из ряда, включающего металлоцены, неметаллоцены и их сочетание.2. Суспензия катализатора по п.1, которая дополнительно включает один или несколько активаторов.3. Суспензия катализатора по п.1, которая включает до 20 мас.% одного или нескольких жидких алканов.4. Суспензия катализатора по п.1, которая включает в пределах от примерно 2 до 15 мас.% одного или нескольких жидких алканов.5. Суспензия катализатора по п.1, которая включает до 50 мас.% каталитической системы.6. Суспензия катализатора по п.1, которая включает по меньшей мере 10 мас.% каталитической системы.7. Суспензия катализатора по п.1, металлоценовый компонент которой отвечает формулеСрCpМХв которой М выбирают из ряда, включающего атомы элементов групп с 3 по 10;Сри Сркаждый независимо обозначает незамещенную или замещенную циклическую кольцевую группу;Х обозначает уходящую группу;а n обозначает ноль или целое число от 1 до 4.8. Суспензия катализатора по п.7, в которой каждый из Сри Срнезависимо выбирают из ряда, включающего циклопентадиенил, инденил, их сочетания и их производные.9. Суспензия катализатора по п.1, в которой неметаллоценовый компонент отвечает формуле αβγMX,М выбирают из ряда, включающего атомы элементов групп с 3 по 10;Х независимо выбирают из ряда, включающего галогенидные ионы, гидриды, алкилы с Cпо C, алкен�

Claims (11)

1. Суспензия катализатора для полимеризации олефинов, включающая продукт
вначале объединения минерального масла с одним или несколькими жидкими алканами, содержащими три или большее число углеродных атомов, с получением смеси;
с последующим объединением с этой смесью каталитической системы, включающей один или несколько катализаторов, выбранных из ряда, включающего металлоцены, неметаллоцены и их сочетание.
2. Суспензия катализатора по п.1, которая дополнительно включает один или несколько активаторов.
3. Суспензия катализатора по п.1, которая включает до 20 мас.% одного или нескольких жидких алканов.
4. Суспензия катализатора по п.1, которая включает в пределах от примерно 2 до 15 мас.% одного или нескольких жидких алканов.
5. Суспензия катализатора по п.1, которая включает до 50 мас.% каталитической системы.
6. Суспензия катализатора по п.1, которая включает по меньшей мере 10 мас.% каталитической системы.
7. Суспензия катализатора по п.1, металлоценовый компонент которой отвечает формуле
СрACpBМХn
в которой М выбирают из ряда, включающего атомы элементов групп с 3 по 10;
СрA и СрB каждый независимо обозначает незамещенную или замещенную циклическую кольцевую группу;
Х обозначает уходящую группу;
а n обозначает ноль или целое число от 1 до 4.
8. Суспензия катализатора по п.7, в которой каждый из СрA и СрB независимо выбирают из ряда, включающего циклопентадиенил, инденил, их сочетания и их производные.
9. Суспензия катализатора по п.1, в которой неметаллоценовый компонент отвечает формуле αaβbγgMXn,
М выбирают из ряда, включающего атомы элементов групп с 3 по 10;
Х независимо выбирают из ряда, включающего галогенидные ионы, гидриды, алкилы с C1 по C12, алкенилы с С2 по C12, арилы с С6 по C12, алкиларилы с C7 по С20, алкокси с C1 по C12, арилокси с С6 по C16, алкиларилокси с С7 по С18, фторалкилы с С1 по C12, фторарилы с С6 по C12, гетероатомсодержащих углеводороды с C1 по C12, галоидированные арилокси с С6 по C16 и их замещенные производные,
β и γ обозначают группы, каждая из которых включает по меньшей мере один атом элемента с группы 14 по группу 16; где по меньшей мере один из атомов элементов с группы 14 по группу 16 связан с М;
α обозначает связывающий остаток, который образует химическую связь с каждым из β и γ;
a a, b, g и n каждый обозначает целое число от 1 до 4.
10. Способ приготовления катализатора, включающий вначале объединение минерального масла с одним или несколькими жидкими алканами, содержащими три или большее число углеродных атомов, с получением смеси;
с последующим объединением с этой смесью каталитической системы, включающей один или несколько компонентов, выбранных из ряда, включающего металлоцены, неметаллоцены и их сочетание.
11. Способ полимеризации олефинов, включающий подачу суспензии катализатора по одному из предыдущих пунктов в газофазный реактор и объединение с олефинами.
RU2006133267/04A 2004-02-17 2005-01-20 Суспензия катализатора для полимеризации олефинов, способ приготовления суспензии катализатора и способ полимеризации олефинов RU2361887C2 (ru)

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US10/780,522 2004-02-17
US10/780,522 US20050182210A1 (en) 2004-02-17 2004-02-17 De-foaming spray dried catalyst slurries

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KR (1) KR101129935B1 (ru)
CN (1) CN101023104A (ru)
BR (1) BRPI0507760B1 (ru)
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US7276566B2 (en) 2007-10-02
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CA2553782A1 (en) 2005-09-09
BRPI0507760B1 (pt) 2021-10-13
RU2361887C2 (ru) 2009-07-20
CA2553782C (en) 2013-06-25
KR101129935B1 (ko) 2012-06-13
US20060172883A1 (en) 2006-08-03
EP1716183A4 (en) 2009-11-11
US20070191215A1 (en) 2007-08-16
US20050182210A1 (en) 2005-08-18
JP2007522334A (ja) 2007-08-09
EP1716183A1 (en) 2006-11-02
WO2005082947A1 (en) 2005-09-09
US7566677B2 (en) 2009-07-28
CN101023104A (zh) 2007-08-22
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