SG11202104262XA - Method of olefin polymerization using alkane-soluble non-metallocene precatalyst - Google Patents

Method of olefin polymerization using alkane-soluble non-metallocene precatalyst

Info

Publication number
SG11202104262XA
SG11202104262XA SG11202104262XA SG11202104262XA SG11202104262XA SG 11202104262X A SG11202104262X A SG 11202104262XA SG 11202104262X A SG11202104262X A SG 11202104262XA SG 11202104262X A SG11202104262X A SG 11202104262XA SG 11202104262X A SG11202104262X A SG 11202104262XA
Authority
SG
Singapore
Prior art keywords
alkane
olefin polymerization
soluble non
metallocene precatalyst
precatalyst
Prior art date
Application number
SG11202104262XA
Inventor
Roger L Kuhlman
Bethany M Neilson
John F Szul
Ian M Munro
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG11202104262XA publication Critical patent/SG11202104262XA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/64141—Dianionic ligand
    • C08F4/64148—NN(R)N
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/05—Bimodal or multimodal molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/24—Polymer with special particle form or size
SG11202104262XA 2018-11-06 2019-10-11 Method of olefin polymerization using alkane-soluble non-metallocene precatalyst SG11202104262XA (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201862756237P 2018-11-06 2018-11-06
US201862756236P 2018-11-06 2018-11-06
US201862771699P 2018-11-27 2018-11-27
PCT/US2019/055908 WO2020096735A1 (en) 2018-11-06 2019-10-11 Method of olefin polymerization using alkane-soluble non-metallocene precatalyst

Publications (1)

Publication Number Publication Date
SG11202104262XA true SG11202104262XA (en) 2021-05-28

Family

ID=68461816

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202104262XA SG11202104262XA (en) 2018-11-06 2019-10-11 Method of olefin polymerization using alkane-soluble non-metallocene precatalyst

Country Status (9)

Country Link
US (1) US20210403615A1 (en)
EP (1) EP3877429A1 (en)
JP (1) JP2022505111A (en)
KR (1) KR20210091199A (en)
CN (1) CN112839966B (en)
BR (1) BR112021006524A2 (en)
CA (1) CA3118441A1 (en)
SG (1) SG11202104262XA (en)
WO (1) WO2020096735A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230406967A1 (en) 2020-10-28 2023-12-21 Exxonmobil Chemical Patents Inc. Non-Aromatic Hydrocarbon Soluble Olefin Polymerization Catalysts and Use Thereof
WO2023177957A1 (en) 2022-03-14 2023-09-21 Exxonmobil Chemical Patents Inc. Metal-containing bis(imino) per-substituted aryl compounds and methods thereof
WO2023177956A1 (en) 2022-03-14 2023-09-21 Exxonmobil Chemical Patents Inc. Metal bis(imino) aryl compounds and methods thereof
CN115677893A (en) * 2022-11-11 2023-02-03 山东京博石油化工有限公司 Gas-liquid mixing feeding method in polyolefin polymerization reaction process

Family Cites Families (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003712A (en) 1970-07-29 1977-01-18 Union Carbide Corporation Fluidized bed reactor
US3709853A (en) 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4011382A (en) 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
CA1168521A (en) 1982-02-01 1984-06-05 Clifford F. Thompson Leak detector
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4988783A (en) 1983-03-29 1991-01-29 Union Carbide Chemicals And Plastics Company Inc. Ethylene polymerization using supported vanadium catalyst
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
WO1988002378A1 (en) 1986-09-24 1988-04-07 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefin
JPH0780933B2 (en) 1986-11-20 1995-08-30 三井石油化学工業株式会社 Olefin Polymerization Method
JPH0742301B2 (en) 1987-02-14 1995-05-10 三井石油化学工業株式会社 Particulate aluminoxane, its manufacturing method and its use
JP2538588B2 (en) 1987-04-03 1996-09-25 三井石油化学工業株式会社 Method for producing solid catalyst for olefin polymerization
US5206199A (en) 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
FR2618786B1 (en) 1987-07-31 1989-12-01 Bp Chimie Sa PROCESS FOR THE POLYMERIZATION OF GASEOUS OLEFINS IN A FLUIDIZED BED REACTOR
US5091352A (en) 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
US5041584A (en) 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
US4908463A (en) 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5103031A (en) 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
US4968827A (en) 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
US4994534A (en) 1989-09-28 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Process for producing sticky polymers
AU9136391A (en) 1990-12-27 1992-08-17 Exxon Chemical Patents Inc. An amido transition metal compound and a catalyst system for the production of isotactic polypropylene
TW218884B (en) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5341124A (en) 1991-05-29 1994-08-23 Se-Kure Controls, Inc. Mountable product sensor and display stand
US5235081A (en) 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5157137A (en) 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5248801A (en) 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
US5939346A (en) 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5804678A (en) 1993-07-13 1998-09-08 Mitsui Petrochemical Industries, Ltd. Process for gas phase polymerization of olefin
EP0649992B1 (en) 1993-10-23 1997-07-30 WABCO GmbH Disc brake actuator
US5648310A (en) 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5506184A (en) 1994-06-22 1996-04-09 Mobil Oil Corporation Olefin polymerization catalyst system
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
JP3582181B2 (en) 1995-10-04 2004-10-27 住友化学工業株式会社 Carrier for olefin polymerization catalyst, olefin polymerization catalyst and method for producing olefin polymer
US5688880A (en) 1995-12-11 1997-11-18 The Dow Chemical Company Readily supportable metal complexes
US5665818A (en) 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
US5627242A (en) 1996-03-28 1997-05-06 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling gas phase fluidized bed polymerization reactor
ES2129323B1 (en) 1996-04-18 2000-09-16 Repsol Quimica Sa PROCEDURE FOR OBTAINING A CATALYTIC SYSTEM FOR THE POLYMERIZATION OF ALPHA-OLEFINS IN SUSPENSION IN GAS PHASE AT LOW AND HIGH TEMPERATURES OR IN MASS AT HIGH PRESSURES AND HIGH OR LOW TEMPERATURES
US6255419B1 (en) 1997-02-07 2001-07-03 Mitsui Chemicals, Inc. Olefin polymerization catalyst and process for producing olefin polymers
EP0878486B1 (en) 1997-02-21 2006-01-25 Council of Scientific and Industrial Research A process for the preparation of supported metallocene catalyst
US5889128A (en) 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
JP3458656B2 (en) 1997-05-27 2003-10-20 東ソー株式会社 Olefin polymerization catalyst and method for producing olefin polymer
US5972510A (en) 1997-06-05 1999-10-26 Isis Innovation Limited Spherulite particles of isotactic polypropylene
JP2002506906A (en) 1998-03-16 2002-03-05 ザ ダウ ケミカル カンパニー Polyolefin nanocomposite
HUP0102238A3 (en) 1998-03-26 2002-06-28 Dow Chemical Co Ion exchanged aluminium-magnesium or fluorinated magnesium silicate aerogels and catalyst supports therefrom
WO1999050311A1 (en) 1998-03-27 1999-10-07 Exxon Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
EP2261266B1 (en) 1998-05-18 2016-03-23 Chevron Phillips Chemical Company LP Process for the polymerization of a monomer with a catalyst composition containing an organometal compound, an organoaluminum compound and a treated solid oxide compound
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6489408B2 (en) 2000-11-30 2002-12-03 Univation Technologies, Llc Polymerization process
US7795366B2 (en) 2002-08-12 2010-09-14 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions
US6858684B2 (en) 2002-12-30 2005-02-22 Univation Technologies, Llc Processes for transitioning between various polymerization catalysts
US6949612B2 (en) 2002-12-31 2005-09-27 Univation Technologies, Llc Processes for transitioning between metallocene and Ziegler-Natta polymerization catalysts
US6967184B2 (en) 2004-02-17 2005-11-22 Univation Technologies, Llc Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
US20050182210A1 (en) 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
US7973112B2 (en) 2004-02-17 2011-07-05 Univation Technologies, Llc De-foaming spray dried catalyst slurries
DE102004047371A1 (en) 2004-09-29 2006-03-30 Siemens Ag Method for distributing software and configuration data and corresponding data network
JP4692761B2 (en) 2006-03-29 2011-06-01 カシオ計算機株式会社 OFDM receiving apparatus, OFDM receiving method, and terrestrial digital receiving apparatus
US7829641B2 (en) * 2008-07-16 2010-11-09 Equistar Chemicals, Lp Process for the preparation of multimodal polyethylene resins
EP2750797B1 (en) * 2011-11-08 2020-04-01 Univation Technologies, LLC Methods of preparing a catalyst system
EP2970526B1 (en) * 2013-03-15 2017-08-09 Univation Technologies, LLC Ligands for catalysts
KR102440033B1 (en) 2014-02-11 2022-09-06 유니베이션 테크놀로지즈, 엘엘씨 Method of producing polyethylene and polyethylene thereof
US10351646B2 (en) 2014-12-31 2019-07-16 Dow Global Technologies Llc Polyolefin composition and method of producing the same
US10221254B2 (en) 2015-04-08 2019-03-05 Univation Technologies, Llc Closed reactor transitions between metallocene catalysts
US10865259B2 (en) * 2015-04-17 2020-12-15 Univation Technologies, Llc Producing polyolefin products
WO2016172567A1 (en) * 2015-04-24 2016-10-27 Univation Technologies, Llc Methods for operating a polymerization reactor

Also Published As

Publication number Publication date
KR20210091199A (en) 2021-07-21
CA3118441A1 (en) 2020-05-14
CN112839966A (en) 2021-05-25
CN112839966B (en) 2023-07-28
WO2020096735A1 (en) 2020-05-14
JP2022505111A (en) 2022-01-14
US20210403615A1 (en) 2021-12-30
BR112021006524A2 (en) 2021-07-06
EP3877429A1 (en) 2021-09-15

Similar Documents

Publication Publication Date Title
SG11202104262XA (en) Method of olefin polymerization using alkane-soluble non-metallocene precatalyst
SG10202101020PA (en) Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization
SG11201610692RA (en) Process for olefin polymerization
EP3257875A4 (en) Olefin oligomerization method
FI3116921T3 (en) Catalyst components for the polymerization of olefins
EP3476869A4 (en) Olefin polymer and preparation method therefor
EP3339336A4 (en) Olefin polymer and preparation method therefor
EP3255067A4 (en) Production method for olefin-polymerization catalyst and production method for olefin polymer
EP3231506A4 (en) Olefin polymerization apparatus and olefin polymerization process
EP3476871A4 (en) Olefin polymer and preparation method therefor
EP3708593A4 (en) Catalyst for olefin polymerization and production method for polar group-containing olefin-based polymers
EP3135697A4 (en) Catalyst component for olefin polymerization and catalyst thereof
EP3138856A4 (en) Method for preparation of a catalyst component used for olefin polymerization
SG11202008672QA (en) Olefin polymerization activators
EP3160975A4 (en) Transition metal catalysts for olefin polymerization
SG11201604369RA (en) Solid catalyst component for olefin polymerization, method for producing the same, olefin polymerization catalyst, and method for producing olefin polymer
KR20220035323A (en) Olefin polymerization method and system
EP3173430A4 (en) Olefin polymerization catalyst and method for producing olefin polymer
SG11202008074SA (en) Olefin polymer and method for producing olefin polymer
SG11201708410UA (en) Bridged bi-aromatic ligands and olefin polymerization catalysts prepared therefrom
EP3543245A4 (en) Method for preparing modified polymerization initiator by using continuous reactor
EP3476870A4 (en) Olefin polymer and method for preparing same
SG10201912861YA (en) Method for producing catalyst for olefin polymerization
EP3953404C0 (en) New bis-phosphinimide catalysts for olefin polymerization
SG11202008656PA (en) Olefin polymerization activators