JP2019534924A5 - - Google Patents
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- JP2019534924A5 JP2019534924A5 JP2019518562A JP2019518562A JP2019534924A5 JP 2019534924 A5 JP2019534924 A5 JP 2019534924A5 JP 2019518562 A JP2019518562 A JP 2019518562A JP 2019518562 A JP2019518562 A JP 2019518562A JP 2019534924 A5 JP2019534924 A5 JP 2019534924A5
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- JP
- Japan
- Prior art keywords
- group
- meth
- silicone
- segment
- mol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000178 monomer Substances 0.000 claims 37
- 229920001296 polysiloxane Polymers 0.000 claims 27
- 239000000203 mixture Substances 0.000 claims 24
- -1 2-isocyanatoethyl Chemical group 0.000 claims 22
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 12
- 229920001519 homopolymer Polymers 0.000 claims 11
- 229920001577 copolymer Polymers 0.000 claims 10
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 9
- 239000000017 hydrogel Substances 0.000 claims 9
- 229910052757 nitrogen Inorganic materials 0.000 claims 9
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 7
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 229910052760 oxygen Inorganic materials 0.000 claims 5
- 125000004103 aminoalkyl group Chemical group 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 3
- 125000006165 cyclic alkyl group Chemical group 0.000 claims 3
- 125000004990 dihydroxyalkyl group Chemical group 0.000 claims 3
- 239000003085 diluting agent Substances 0.000 claims 3
- 125000000524 functional group Chemical group 0.000 claims 3
- 230000001404 mediated effect Effects 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 3
- 238000010526 radical polymerization reaction Methods 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- 239000006096 absorbing agent Substances 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 2
- 239000000975 dye Substances 0.000 claims 2
- 125000001153 fluoro group Chemical group F* 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 2
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 claims 2
- 125000005702 oxyalkylene group Chemical group 0.000 claims 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 235000019260 propionic acid Nutrition 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims 1
- ZVEMLYIXBCTVOF-UHFFFAOYSA-N 1-(2-isocyanatopropan-2-yl)-3-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC(C(C)(C)N=C=O)=C1 ZVEMLYIXBCTVOF-UHFFFAOYSA-N 0.000 claims 1
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 125000000143 2-carboxyethyl group Chemical group [H]OC(=O)C([H])([H])C([H])([H])* 0.000 claims 1
- IHNDNMHBSSSIPV-UHFFFAOYSA-N 2-methyl-n-[3-tris(trimethylsilyloxy)silylpropyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C IHNDNMHBSSSIPV-UHFFFAOYSA-N 0.000 claims 1
- MEVLIJVLXBOGSQ-UHFFFAOYSA-N 3-(ethenoxycarbonylamino)propanoic acid Chemical compound OC(=O)CCNC(=O)OC=C MEVLIJVLXBOGSQ-UHFFFAOYSA-N 0.000 claims 1
- BESKSSIEODQWBP-UHFFFAOYSA-N 3-tris(trimethylsilyloxy)silylpropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C BESKSSIEODQWBP-UHFFFAOYSA-N 0.000 claims 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 1
- 102000016943 Muramidase Human genes 0.000 claims 1
- 108010014251 Muramidase Proteins 0.000 claims 1
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 claims 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000003368 amide group Chemical group 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- YEFRPIVYJOVOMW-UHFFFAOYSA-N butyl-dimethylsilyloxy-dimethylsilane Chemical compound CCCC[Si](C)(C)O[SiH](C)C YEFRPIVYJOVOMW-UHFFFAOYSA-N 0.000 claims 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims 1
- 229960005286 carbaryl Drugs 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 235000015872 dietary supplement Nutrition 0.000 claims 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 1
- 239000003814 drug Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 claims 1
- FXPHJTKVWZVEGA-UHFFFAOYSA-N ethenyl hydrogen carbonate Chemical compound OC(=O)OC=C FXPHJTKVWZVEGA-UHFFFAOYSA-N 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 125000003709 fluoroalkyl group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 150000002632 lipids Chemical class 0.000 claims 1
- 235000010335 lysozyme Nutrition 0.000 claims 1
- 229960000274 lysozyme Drugs 0.000 claims 1
- 239000004325 lysozyme Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000006082 mold release agent Substances 0.000 claims 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 claims 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 claims 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 claims 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 claims 1
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 1
- 230000035699 permeability Effects 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 125000005504 styryl group Chemical group 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 229920001897 terpolymer Polymers 0.000 claims 1
- IXSPLXSQNNZJJU-UHFFFAOYSA-N trimethyl(silyloxy)silane Chemical compound C[Si](C)(C)O[SiH3] IXSPLXSQNNZJJU-UHFFFAOYSA-N 0.000 claims 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 claims 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662404817P | 2016-10-06 | 2016-10-06 | |
| US62/404,817 | 2016-10-06 | ||
| US15/691,829 US10676575B2 (en) | 2016-10-06 | 2017-08-31 | Tri-block prepolymers and their use in silicone hydrogels |
| US15/691,829 | 2017-08-31 | ||
| PCT/US2017/051456 WO2018067284A1 (en) | 2016-10-06 | 2017-09-14 | Tri-block prepolymers and their use in silicone hydrogels |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019534924A JP2019534924A (ja) | 2019-12-05 |
| JP2019534924A5 true JP2019534924A5 (enExample) | 2020-09-24 |
| JP6995847B2 JP6995847B2 (ja) | 2022-01-17 |
Family
ID=61830512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019518562A Active JP6995847B2 (ja) | 2016-10-06 | 2017-09-14 | トリブロックプレポリマー及びシリコーンヒドロゲルにおけるそれらの使用 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10676575B2 (enExample) |
| EP (1) | EP3523338B9 (enExample) |
| JP (1) | JP6995847B2 (enExample) |
| KR (1) | KR102452750B1 (enExample) |
| CN (1) | CN109790243B (enExample) |
| AR (1) | AR109808A1 (enExample) |
| AU (1) | AU2017340269A1 (enExample) |
| BR (1) | BR112019006669A2 (enExample) |
| CA (1) | CA3037871A1 (enExample) |
| MA (1) | MA46451A (enExample) |
| RU (1) | RU2762252C2 (enExample) |
| TW (1) | TWI753953B (enExample) |
| WO (1) | WO2018067284A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10676575B2 (en) | 2016-10-06 | 2020-06-09 | Johnson & Johnson Vision Care, Inc. | Tri-block prepolymers and their use in silicone hydrogels |
| JP7102503B2 (ja) * | 2017-07-26 | 2022-07-19 | ベーイプシロンカー ヘミー ゲゼルシャフト ミット ベシュレンクター ハフトゥング | ポリエーテルおよびポリシロキサンセグメントを有するポリマー |
| US10996491B2 (en) * | 2018-03-23 | 2021-05-04 | Johnson & Johnson Vision Care, Inc. | Ink composition for cosmetic contact lenses |
| WO2020009747A1 (en) * | 2018-07-03 | 2020-01-09 | Bausch & Lomb Incorporated | Water extractable ophthalmic devices |
| TWI685545B (zh) * | 2018-11-30 | 2020-02-21 | 晶碩光學股份有限公司 | 矽水膠組成物、矽水膠鏡片、以及矽水膠鏡片的製造方法 |
| JP6729667B2 (ja) * | 2018-12-04 | 2020-07-22 | 横浜ゴム株式会社 | ブロック共重合体 |
| US20200385532A1 (en) * | 2019-06-06 | 2020-12-10 | Apexlens Co., Ltd. | Hydrophilic and oxygen permeable polymer material |
| US11891526B2 (en) | 2019-09-12 | 2024-02-06 | Johnson & Johnson Vision Care, Inc. | Ink composition for cosmetic contact lenses |
| US12180318B2 (en) * | 2020-06-16 | 2024-12-31 | Johnson & Johnson Vision Care, Inc. | Imidazolium zwitterion polymerizable compounds and ophthalmic devices incorporating them |
| EP4165446B9 (en) * | 2020-06-16 | 2024-07-10 | Johnson & Johnson Vision Care, Inc. | Imidazolium zwitterion polymerizable compounds and ophthalmic devices incorporating them |
| WO2022054851A1 (ja) * | 2020-09-09 | 2022-03-17 | 日本ペイント・オートモーティブコーティングス株式会社 | 塗料用組成物 |
| TWI775271B (zh) * | 2021-01-13 | 2022-08-21 | 創元光學股份有限公司 | 用於製造隱形眼鏡的材料以及其隱形眼鏡 |
| US11945966B2 (en) * | 2021-12-09 | 2024-04-02 | Canon Kabushiki Kaisha | Photocurable composition with enhanced thermal stability |
| KR102710838B1 (ko) * | 2023-11-13 | 2024-09-26 | 한국광학기술 주식회사 | 세륨 나노입자에 의하여 항균성 및 자외선 차단기능을 부여한 실리콘 하이드로겔 콘택트렌즈 |
| WO2025215096A1 (en) * | 2024-04-11 | 2025-10-16 | Bausch + Lomb Ireland Limited | Silicone contact lens-forming prepolymer and silicone contact lens formed therefrom |
| CN121064549B (zh) * | 2025-11-05 | 2026-02-27 | 厦门理工学院 | 一种亲水改性hdpe组合物及其应用 |
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-
2017
- 2017-08-31 US US15/691,829 patent/US10676575B2/en active Active
- 2017-09-14 CA CA3037871A patent/CA3037871A1/en not_active Abandoned
- 2017-09-14 EP EP17784060.0A patent/EP3523338B9/en active Active
- 2017-09-14 KR KR1020197012713A patent/KR102452750B1/ko active Active
- 2017-09-14 RU RU2019112872A patent/RU2762252C2/ru active
- 2017-09-14 WO PCT/US2017/051456 patent/WO2018067284A1/en not_active Ceased
- 2017-09-14 BR BR112019006669A patent/BR112019006669A2/pt not_active Application Discontinuation
- 2017-09-14 AU AU2017340269A patent/AU2017340269A1/en not_active Abandoned
- 2017-09-14 JP JP2019518562A patent/JP6995847B2/ja active Active
- 2017-09-14 MA MA046451A patent/MA46451A/fr unknown
- 2017-09-14 CN CN201780061969.1A patent/CN109790243B/zh active Active
- 2017-10-03 TW TW106134125A patent/TWI753953B/zh not_active IP Right Cessation
- 2017-10-05 AR ARP170102777A patent/AR109808A1/es unknown
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