JP2019507809A - エポキシ樹脂組成物、エポキシ樹脂組成物の使用、光電子デバイス、およびエポキシ樹脂組成物の製造方法 - Google Patents
エポキシ樹脂組成物、エポキシ樹脂組成物の使用、光電子デバイス、およびエポキシ樹脂組成物の製造方法 Download PDFInfo
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- epoxy resin
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- inorganic filler
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
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- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/505—Wavelength conversion elements characterised by the shape, e.g. plate or foil
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K2201/005—Additives being defined by their particle size in general
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Abstract
Description
A)脂環式エポキシ樹脂を用意するステップ、
B)ポリ酪酸ブチルを、50℃〜80℃の温度で添加するステップ、
C)カチオン性促進剤を、45℃の最高温度で添加して、マトリックスを形成するステップ、
D)ステップC)により生成されたマトリックスを、金属または半金属の酸化物または窒化物である少なくとも1種の無機充填剤と混合するステップ、および
E)ステップD)により生成された混合物を、120℃〜190℃の温度で硬化するステップ
1.85質量%の脂環式エポキシ樹脂、
2.10質量%のエポキシフェノール・ノボラック、
3.1質量%のアルコール、
4.3質量%のポリ酪酸ビニル、および
5.1質量%のカチオン性促進剤。
1.95.5質量%の脂環式エポキシ樹脂、
2.1質量%のアルコール、
3.2質量%のポリ酪酸ビニル、および
4.1.5質量%のカチオン性促進剤。
1.96.8質量%の脂環式エポキシ樹脂、
2.1質量%のアルコール、
3.1質量%のポリ酪酸ビニル、および
4.1.2質量%のカチオン性促進剤
F1 充填剤1
F2 充填剤2
F3 充填剤3
ρ 密度
AO 比表面積
d50 粒径
dmax 上限粒径または上限粒径値
κ 導電率
EH エポキシ樹脂
m 充填剤の含量
η 粘度
S 剪断速度
TI チキソトロピー指数
TT チキソトロピー
G 合計充填レベル
SM 貯蔵弾性率
GVT 300℃での重量損失
TGVT 1%の重量損失での温度
1 リードフレーム
2 半導体積層体
3 ハウジング
4 注型剤
5 キャリア
6 凹部
7 基板
8 変換素子
9 反射素子
100 光電子デバイス
Claims (15)
- 金属または半金属の酸化物または窒化物である、上限粒径(dmax)が30μm以下の少なくとも1種の無機充填剤(F)、
少なくとも1種の脂環式エポキシ樹脂、
ポリ酪酸ビニル、
少なくとも1種のカチオン性促進剤
を含み、一成分系である、エポキシ樹脂組成物。 - 前記ポリ酪酸ビニルの平均分子量が、10000g/mol〜80000g/molである、
請求項1に記載のエポキシ樹脂組成物。 - 前記無機充填剤(F)の比表面積(AO)が2g/cm2以上20g/cm2以下であり、
粒径(d50)が20μm以下であり、上限粒径(dmax)が30μm以下である、
請求項1または2に記載のエポキシ樹脂組成物。 - 前記無機充填剤(F)が、二酸化ケイ素、二酸化チタン、酸化アルミニウム、および酸化ジルコニウムを含む群から選択される、
請求項1〜3のいずれか一項に記載のエポキシ樹脂組成物。 - 無水物を含まず、シリコーンを含まず、および/またはシロキサンを含まない、
請求項1〜4のいずれか一項に記載のエポキシ樹脂組成物。 - 塩素含量が100ppm未満である、
請求項1〜5のいずれか一項に記載のエポキシ樹脂組成物。 - 前記無機充填剤(F)の含量が、前記エポキシ樹脂組成物の全重量に対して50質量%〜85質量%である、
請求項1〜6のいずれか一項に記載のエポキシ樹脂組成物。 - 前記脂環式エポキシ樹脂の含量が、前記エポキシ樹脂組成物の全重量に対して3質量%〜50質量%である、
請求項1〜7のいずれか一項に記載のエポキシ樹脂組成物。 - 前記エポキシ樹脂組成物の全重量に対して、
前記ポリ酪酸ビニルの含量が0.1質量%〜10質量%であり、かつ
前記カチオン性促進剤の含量が0.1質量%〜3質量%である、
請求項1〜8のいずれか一項に記載のエポキシ樹脂組成物。 - アルコールおよび他のエポキシ樹脂をさらに含み、
前記アルコールの含量が、前記エポキシ樹脂組成物の全重量に対して0.1質量%〜3質量%である、
請求項1〜9のいずれか一項に記載のエポキシ樹脂組成物。 - 前記カチオン性促進剤がチオラニウム塩である、
請求項1〜10のいずれか一項に記載のエポキシ樹脂組成物。 - 4℃〜10℃の温度で貯蔵安定性を有する、請求項1〜11のいずれか一項に記載のエポキシ樹脂組成物。
- 発光ダイオード、光ダイオード、光トランジスタ、光アレイ、光カプラ、SMDデバイス、およびSMD対応デバイスからなる群から選択される光電子デバイス(100)のための、請求項1〜12のいずれか一項に記載のエポキシ樹脂組成物の使用。
- 請求項1〜12のいずれか一項に記載のエポキシ樹脂組成物を含み、
前記エポキシ樹脂組成物が、ハウジング(3)、反射素子(9)、注型剤(4)、変換素子(8)、および/または基板(7)として形成される、光電子デバイス(100)。 - 請求項1〜12のいずれか一項に記載のエポキシ樹脂組成物の製造方法であって、下記の方法ステップを含む、
A)脂環式エポキシ樹脂を用意するステップ、
B)ポリ酪酸ブチルを、50℃〜80℃の温度で添加するステップ、
C)カチオン性促進剤を、45℃の最高温度で添加して、マトリックスを生成するステップ、
D)ステップC)により生成された前記マトリックスを、金属または半金属の酸化物または窒化物である少なくとも1種の無機充填剤(F)と混合するステップ、および
E)ステップD)により生成された混合物を、120℃〜190℃の温度で硬化するステップ
エポキシ樹脂組成物の製造方法。
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DE102016102685.9A DE102016102685B4 (de) | 2016-02-16 | 2016-02-16 | Epoxidharzsystem, Verwendung eines Epoxidharzsystems und Verfahren zur Herstellung eines Epoxidharzsystems |
PCT/EP2017/053155 WO2017140621A1 (de) | 2016-02-16 | 2017-02-13 | Epoxidharzsystem, verwendung eines epoxidharzsystems, optoelektronisches bauelement und verfahren zur herstellung eines epoxidharzsystems |
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