JP2018533771A - ブルーライトカット光学製品 - Google Patents
ブルーライトカット光学製品 Download PDFInfo
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- JP2018533771A JP2018533771A JP2018522722A JP2018522722A JP2018533771A JP 2018533771 A JP2018533771 A JP 2018533771A JP 2018522722 A JP2018522722 A JP 2018522722A JP 2018522722 A JP2018522722 A JP 2018522722A JP 2018533771 A JP2018533771 A JP 2018533771A
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- PODOEQVNFJSWIK-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethoxyphenyl)methanone Chemical compound COC1=CC(OC)=CC(OC)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 PODOEQVNFJSWIK-UHFFFAOYSA-N 0.000 description 1
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- AQHHHDLHHXJYJD-UHFFFAOYSA-N propranolol Chemical compound C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 AQHHHDLHHXJYJD-UHFFFAOYSA-N 0.000 description 1
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- FDJUBNCEVCSIAV-UHFFFAOYSA-N tetrakis(o-aminophenyl)porphyrin Chemical compound NC1=CC=CC=C1C(C1=CC=C(N1)C(C=1C(=CC=CC=1)N)=C1C=CC(=N1)C(C=1C(=CC=CC=1)N)=C1C=CC(N1)=C1C=2C(=CC=CC=2)N)=C2N=C1C=C2 FDJUBNCEVCSIAV-UHFFFAOYSA-N 0.000 description 1
- KBIOUJDBIXSYJT-UHFFFAOYSA-N tetramesitylporphyrin Chemical compound CC1=CC(C)=CC(C)=C1C(C1=CC=C(N1)C(C=1C(=CC(C)=CC=1C)C)=C1C=CC(=N1)C(C=1C(=CC(C)=CC=1C)C)=C1C=CC(N1)=C1C=2C(=CC(C)=CC=2C)C)=C2N=C1C=C2 KBIOUJDBIXSYJT-UHFFFAOYSA-N 0.000 description 1
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- 239000012974 tin catalyst Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- OVTCUIZCVUGJHS-VQHVLOKHSA-N trans-dipyrrin Chemical compound C=1C=CNC=1/C=C1\C=CC=N1 OVTCUIZCVUGJHS-VQHVLOKHSA-N 0.000 description 1
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/022—Ophthalmic lenses having special refractive features achieved by special materials or material structures
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
- G02B1/115—Multilayers
- G02B1/116—Multilayers including electrically conducting layers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/16—Optical coatings produced by application to, or surface treatment of, optical elements having an anti-static effect, e.g. electrically conducting coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
- G02C7/104—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses having spectral characteristics for purposes other than sun-protection
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Ophthalmology & Optometry (AREA)
- General Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Eyeglasses (AREA)
- Optical Filters (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
Description
− 光学製品の吸収スペクトルは、435nm〜460nmの曲線下面積と400nm〜435nmの曲線下面積の比R1が0.7より小さい、というものである。
− 光学製品は、その吸収ピークが500nm以上の波長にある少なくとも1種のカラーバランシング染料Bを含む。
− 光吸収染料Aの吸収ピークは400nm〜435nmの範囲にあり、これは、40nm以下の半値全幅を示す。
− 単官能(メタ)アクリレート:アリルメタクリレート、2−エトキシエチルアクリレート、2−エトキシエチルメタクリレート、カプロラクトンアクリレート、イソボルニルメタクリレート、ラウリルメタクリレメート、ポリプロピレングリコールモノメタクリレート、ヒドロキシエチルメタクリレート
− 二官能(メタ)アクリレート:1,4−ブタンジオールジアクリレート、1,4−ブタンジオールジメタクリレート、1,6−ヘキサンジオールジアクリレート、1,6−ヘキサンジオールジメタクリレート、エトキシ化ビスフェノールAジアクリレート、ポリエチレングリコールジ(メタ)アクリレート、例えばポリエチレングリコールジアクリレート、テトラエチレングリコールジアクリレート、ポリエチレングリコールジメタクリレート、ポリエチレングリコールジアクリレート、テトラエチレングリコールジアクリレート、トリプロピレングリコールジアクリレート、ネオペンチルグリコールジアクリレート、テトラエチレングリコールジメタクリレート、ジエチレングリコールジアクリレート
− 三官能(メタ)アクリレート:トリメチロールプロパントリメタクリレート、トリメチロールプロパントリアクリレート、ペンタエリトリトールトリアクリレート、エトキシ化トリメチロールプロパントリアクリレート、トリメチロールプロパントリメタクリレート
− テトラ乃至ヘキサ(メタ)アクリレート:ジペンタエリトリトールペンタアクリレート、ペンタエリトリトールテトラアクリレート、エトキシ化ペンタエリトリトールテトラアクリレート、ペンタアクリレートエステルである。
式中、λhigh及びλlowは、吸光度ピーク波長のそれぞれの側にあり、吸光度は(ピーク吸光度−ベースライン吸光度)/2に最も近い。
(1)435nmの波長での光透過率は10%以下である。
(2)450nmの波長での光透過率は70%以下である。
(3)480nmの波長での光透過率は80%以上である。
I.基板を有機溶媒及び/又は水性高温浴、好ましくは水性溶液中に数分間浸漬させるステップを含む含浸又は浸潤方式。有機レンズ基板等の有機材料から作られた基板は、最も多くの場合、90℃程度の温度に加熱され、その中にカラーバランシング手段がすでに分散させられている水溶液浴中に浸漬させることによって材料バルク内で「着色」される。この化合物はそれゆえ、基板の表面下に拡散し、色濃度は基板の本体中に拡散する化合物の量を調整することによって得られる、
II.日本特願2000−314088号及び日本特願2000−241601号に記載されている、暫定的な硬化コーティングを含む拡散方式、
III.米国特許第6534443号明細書及び米国特許第6554873号明細書に記載されているような、昇華性材料を使用する非接触着色、又は
IV.例えば鋳造又は射出成型による基板自体の製造中の、ただし鋳造又は射出成型中の高温に十分に耐えられる場合における化合物の包含。これは好ましくは、基板の組成物(光学材料樹脂又は重合性組成物)に化合物を混合させ、その後、適当な型の中で組成物を硬化させて基板を形成することによって実行される。
− 以下の関係により定義される、図1に示される関数B(λ)により重み付けされた400nm〜450nmの平均ブルーライト保護係数BVC:
− 可視スペクトルにおけるその相対光透過率Tvは80%以上、好ましくは89%以上であり、その比BVC/Yiは2より高く、好ましくは3より高く、ただしYiは光学製品の黄色度指数であり、BVCは400nm〜450nmの平均ブルーライト保護係数であり、以下の関係により定義され、図1に示される関数B(λ)により重み付けされる。
レンズの後(凹)面を検出器と対向させ、光がレンズの前面に入るようにして、可視スペクトル内の光透過率Tvを、HunterのCary 4000分光光度計を使って装用者の視角から透過モードで測定した。前述のように吸光度の値において透過率の値を変換することにより、吸光度を計算した。
Claims (17)
- 400〜500nmの範囲の波長を有する光の透過を選択的に、少なくとも部分的に遮蔽する少なくとも1種の光吸収染料Aを含む光学製品において、染料Aの吸収ピークは400nm〜460nmの範囲内にあり、前記光学製品の吸収スペクトルは、400〜435nmの範囲における吸収への寄与が435〜460nmの範囲におけるより高いものである光学製品。
- 前記光学製品の前記吸収スペクトルは、435〜460nmの曲線下面積と400〜435nmの曲線下面積の比R1が0.7未満である、というものである、請求項1に記載の光学製品。
- 前記光学製品の前記吸収スペクトルは、435〜460nmの曲線下面積と400〜435nmの曲線下面積の比R1が0.6未満である、というものである、請求項1に記載の光学製品。
- 染料Aの吸収ピークは400nm〜428nmの範囲内、好ましくは415nm〜428nmの範囲内にある、請求項1〜3の何れか1項に記載の光学製品。
- 染料Aの吸収ピークは400nm〜460nmの範囲内にあり、40nm以下の半値全幅を示す、請求項1〜4の何れか1項に記載の光学製品。
- その吸収ピークが500nm以上の波長にある少なくとも1種のカラーバランシング染料Bを含む、請求項1〜5の何れか1項に記載の光学製品。
- 前記カラーバランシング染料Bはアントラキノンである、請求項1〜6の何れか1項に記載の光学製品。
- 染料Aの比吸収率は塩化メチルにおいて2000L.g−1.cm−1より高い、請求項1〜7の何れか1項に記載の光学製品。
- 染料Aの吸収ピークは500nm以上の波長にある、請求項1〜8の何れか1項に記載の光学製品。
- 400〜500nmの範囲の波長を有する光の透過を少なくとも部分的に遮蔽する、染料Aとは異なる少なくとも1種の光学フィルタリング手段をさらに含む、請求項1〜9の何れか1項に記載の光学製品。
- 前記光学フィルタリング手段は干渉型フィルタ、好ましくは反射防止コーティングである、請求項10に記載の光学製品。
- 主前面と主後面を有する基板を含み、前記後面での280nm〜380nmの、ISO 13666:1998標準において定義される関数W(λ)により重み付けされた平均反射率RUVは、入射角30°及び入射角45°の両方について5%未満である、請求項1〜11の何れか1項に記載の光学製品。
- その吸収スペクトルは、460〜700nmの曲線下面積と400〜460nmの曲線下面積との比R2が3以下、好ましくは2.5以下である、というものである、請求項1〜12の何れか1項に記載の光学製品。
- 400nm〜450nmの、図1に示された、以下の関係を通じて定義される関数B(λ)により重み付けされた平均ブルーライト保護係数BVC:
- 少なくとも1種の調光染料C及び/又はフリーラジカルスカベンジャをさらに含む、請求項1〜14の何れか1項に記載の光学製品。
- その可視スペクトルにおける相対光透過率Tvは80%以上、好ましくは89%以上であり、そのBVC/Yiの比は2より高い、好ましくは3より高く、Yiは前記光学製品の黄色度指数であり、BVCは400nm〜450nmの、図1に示された、以下の関係を通じて定義される関数B(λ)により重み付けされた平均ブルーライト保護係数である:
- 眼科用レンズであるとさらに定義される、請求項1〜16の何れか1項に記載の光学製品。
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