JP2018530852A5 - - Google Patents
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- Publication number
- JP2018530852A5 JP2018530852A5 JP2017509778A JP2017509778A JP2018530852A5 JP 2018530852 A5 JP2018530852 A5 JP 2018530852A5 JP 2017509778 A JP2017509778 A JP 2017509778A JP 2017509778 A JP2017509778 A JP 2017509778A JP 2018530852 A5 JP2018530852 A5 JP 2018530852A5
- Authority
- JP
- Japan
- Prior art keywords
- lithium ion
- solvent
- ion battery
- high voltage
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 58
- 229910001416 lithium ion Inorganic materials 0.000 claims description 58
- 239000003792 electrolyte Substances 0.000 claims description 44
- 239000002904 solvent Substances 0.000 claims description 32
- 239000003960 organic solvent Substances 0.000 claims description 31
- 239000008151 electrolyte solution Substances 0.000 claims description 22
- 229910003002 lithium salt Inorganic materials 0.000 claims description 21
- 159000000002 lithium salts Chemical class 0.000 claims description 21
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 15
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical group O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 10
- 239000011737 fluorine Substances 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 9
- 150000005676 cyclic carbonates Chemical group 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 8
- 239000002808 molecular sieve Substances 0.000 claims description 8
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 7
- 239000012046 mixed solvent Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 6
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 6
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- STSCVKRWJPWALQ-UHFFFAOYSA-N TRIFLUOROACETIC ACID ETHYL ESTER Chemical compound CCOC(=O)C(F)(F)F STSCVKRWJPWALQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- UHOPWFKONJYLCF-UHFFFAOYSA-N 2-(2-sulfanylethyl)isoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)C2=C1 UHOPWFKONJYLCF-UHFFFAOYSA-N 0.000 claims description 4
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 4
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 claims description 4
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 3
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 3
- 229910012424 LiSO 3 Inorganic materials 0.000 claims description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical group COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 3
- VMVNZNXAVJHNDJ-UHFFFAOYSA-N methyl 2,2,2-trifluoroacetate Chemical group COC(=O)C(F)(F)F VMVNZNXAVJHNDJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- -1 propio Chemical class 0.000 claims description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 claims 1
- 229940017219 methyl propionate Drugs 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 description 24
- 229910052744 lithium Inorganic materials 0.000 description 11
- 230000001351 cycling effect Effects 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 239000010405 anode material Substances 0.000 description 3
- 239000013538 functional additive Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 150000008053 sultones Chemical group 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- JZTPKAROPNTQQV-UHFFFAOYSA-N 3-fluorobenzonitrile Chemical compound FC1=CC=CC(C#N)=C1 JZTPKAROPNTQQV-UHFFFAOYSA-N 0.000 description 2
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 2
- KLLQVNFCMHPYGL-UHFFFAOYSA-N 5h-oxathiole 2,2-dioxide Chemical compound O=S1(=O)OCC=C1 KLLQVNFCMHPYGL-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000004651 carbonic acid esters Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- VCYZVXRKYPKDQB-UHFFFAOYSA-N ethyl 2-fluoroacetate Chemical compound CCOC(=O)CF VCYZVXRKYPKDQB-UHFFFAOYSA-N 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 1
- DCLQQAFGIBQTAP-UHFFFAOYSA-N 2,2,3,3-tetrafluoro-1-(2,2,3,3-tetrafluoropentoxy)pentane Chemical compound CCC(F)(F)C(F)(F)COCC(F)(F)C(F)(F)CC DCLQQAFGIBQTAP-UHFFFAOYSA-N 0.000 description 1
- PCRSJGWFEMHHEW-UHFFFAOYSA-N 2,3,5,6-tetrafluorobenzene-1,4-dicarbonitrile Chemical compound FC1=C(F)C(C#N)=C(F)C(F)=C1C#N PCRSJGWFEMHHEW-UHFFFAOYSA-N 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 239000002000 Electrolyte additive Substances 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- ZYXUQEDFWHDILZ-UHFFFAOYSA-N [Ni].[Mn].[Li] Chemical compound [Ni].[Mn].[Li] ZYXUQEDFWHDILZ-UHFFFAOYSA-N 0.000 description 1
- CLDYDTBRUJPBGU-UHFFFAOYSA-N butyl 2,2,2-trifluoroacetate Chemical compound CCCCOC(=O)C(F)(F)F CLDYDTBRUJPBGU-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- FRMOHNDAXZZWQI-UHFFFAOYSA-N lithium manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Ni+2].[Li+] FRMOHNDAXZZWQI-UHFFFAOYSA-N 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical group O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511017147.2A CN105428719B (zh) | 2015-12-31 | 2015-12-31 | 高电压宽温锂离子电池电解液及其制备方法及应用 |
| CN201511017147.2 | 2015-12-31 | ||
| PCT/CN2016/096166 WO2017113820A1 (zh) | 2015-12-31 | 2016-08-22 | 高电压宽温锂离子电池电解液及其制备方法及应用 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018530852A JP2018530852A (ja) | 2018-10-18 |
| JP2018530852A5 true JP2018530852A5 (https=) | 2019-07-18 |
| JP6712588B2 JP6712588B2 (ja) | 2020-06-24 |
Family
ID=55506755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017509778A Active JP6712588B2 (ja) | 2015-12-31 | 2016-08-22 | 高電圧広温度範囲リチウムイオン電池の電解液、その調製方法及びその応用 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP6712588B2 (https=) |
| CN (1) | CN105428719B (https=) |
| WO (1) | WO2017113820A1 (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105428719B (zh) * | 2015-12-31 | 2018-12-18 | 石家庄圣泰化工有限公司 | 高电压宽温锂离子电池电解液及其制备方法及应用 |
| WO2018031983A1 (en) * | 2016-08-12 | 2018-02-15 | Pellion Technologies, Inc. | Additive containing electrolytes for high energy rechargeable metal anode batteries |
| CN106450462B (zh) * | 2016-12-27 | 2019-01-08 | 石家庄圣泰化工有限公司 | 高电压宽温锂离子电池电解液 |
| CN108270035B (zh) * | 2016-12-30 | 2020-07-07 | 浙江省化工研究院有限公司 | 一种含有高浓度锂盐的电池电解液 |
| JP6944644B2 (ja) * | 2017-10-19 | 2021-10-06 | トヨタ自動車株式会社 | リチウム二次電池用電解液 |
| CN110343043A (zh) * | 2018-04-04 | 2019-10-18 | 浙江蓝天环保高科技股份有限公司 | 一种三氟乙酸乙酯的纯化方法 |
| CN118099525A (zh) | 2018-10-04 | 2024-05-28 | 魁北克电力公司 | 用于Li离子电池中的电解质的添加剂 |
| CN110544795B (zh) * | 2019-08-20 | 2024-08-13 | 大同新成新材料股份有限公司 | 一种高电压锂电池电解液的制备方法及制备装置 |
| CN110931876A (zh) * | 2019-12-21 | 2020-03-27 | 中南大学 | 一种高压锂离子电池电解液及锂离子电池 |
| CN111092264A (zh) * | 2019-12-27 | 2020-05-01 | 安普瑞斯（无锡）有限公司 | 一种高电压电解液及含有该电解液的锂离子电池 |
| CN111443123A (zh) * | 2020-04-03 | 2020-07-24 | 河南华瑞高新材料有限公司 | 一种快速判定电解液内锂盐、添加剂性能优劣的方法 |
| CN111952671A (zh) * | 2020-07-20 | 2020-11-17 | 复旦大学 | 一种以氟代乙酸乙酯为溶剂的低温电解液及其应用 |
| CN112086685B (zh) * | 2020-10-26 | 2024-03-08 | 长兴中俄新能源材料技术研究院 | 三锂盐-四元溶剂体系性能互补型5v锂离子电池电解液 |
| CN113540570B (zh) * | 2021-09-16 | 2021-12-10 | 北京壹金新能源科技有限公司 | 一种电解液、制备方法及包含其的锂离子电池 |
| CN113903993B (zh) * | 2021-11-18 | 2024-04-09 | 中国科学院大学 | 一种锂金属电池电解液添加剂及其电解液和电池 |
| WO2023216130A1 (zh) * | 2022-05-11 | 2023-11-16 | 宁德时代新能源科技股份有限公司 | 一种电解液、二次电池、电池模块、电池包和用电装置 |
| CN115494116A (zh) * | 2022-09-28 | 2022-12-20 | 江苏海基新能源股份有限公司 | 一种石墨与pc兼容性临界点的判断方法 |
| CN115377489B (zh) * | 2022-10-11 | 2024-09-13 | 中国人民解放军军事科学院防化研究院 | 一种用于锂离子电池的宽温域电解质制备方法 |
| EP4611091A1 (en) * | 2022-10-27 | 2025-09-03 | Kyocera Corporation | Non-aqueous electrolyte solution and lithium-ion secondary battery using same |
| CN115579519B (zh) * | 2022-10-31 | 2024-01-26 | 江西安驰新能源科技有限公司 | 一种锂离子电池电解液添加剂及锂离子电池电解液 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070031584A (ko) * | 2005-09-15 | 2007-03-20 | 주식회사 엘지화학 | 비수 전해액 첨가제 및 이를 이용한 이차 전지 |
| TWI395359B (zh) * | 2005-09-15 | 2013-05-01 | Lg Chemical Ltd | 改善效能用之非水性電解質及包含該電解質之鋰二次電池 |
| WO2007043624A1 (ja) * | 2005-10-12 | 2007-04-19 | Mitsui Chemicals, Inc. | 非水電解液、それを用いたリチウム二次電池 |
| JP4807072B2 (ja) * | 2005-12-28 | 2011-11-02 | 株式会社Ｇｓユアサ | 非水電解質二次電池 |
| CN102017270B (zh) * | 2008-04-25 | 2014-07-16 | 株式会社Lg化学 | 锂二次电池用非水电解质溶液和含有该非水电解质溶液的锂二次电池 |
| JP5089828B2 (ja) * | 2011-03-28 | 2012-12-05 | パナソニック株式会社 | 非水電解質およびそれを用いた非水電解質二次電池 |
| WO2012174704A1 (en) * | 2011-06-20 | 2012-12-27 | Dow Global Technologies Llc | Battery electrolyte solutions containing aromatic phosphite compounds |
| JP6320876B2 (ja) * | 2013-10-29 | 2018-05-09 | パナソニック株式会社 | 非水電解質二次電池 |
| US10355312B2 (en) * | 2014-03-27 | 2019-07-16 | Daikin Industries, Ltd. | Electrolyte and electrochemical device |
| CN105006593B (zh) * | 2014-04-21 | 2017-12-12 | 宁德时代新能源科技股份有限公司 | 锂离子二次电池及其电解液 |
| CN103956517A (zh) * | 2014-05-14 | 2014-07-30 | 华南师范大学 | 一种高电压锂离子电池电解液及其制备方法与应用 |
| CN104934638A (zh) * | 2015-04-24 | 2015-09-23 | 江苏华盛精化工有限责任公司 | 一种锂离子电池用高电压电解液 |
| CN105428719B (zh) * | 2015-12-31 | 2018-12-18 | 石家庄圣泰化工有限公司 | 高电压宽温锂离子电池电解液及其制备方法及应用 |
-
2015
- 2015-12-31 CN CN201511017147.2A patent/CN105428719B/zh active Active
-
2016
- 2016-08-22 WO PCT/CN2016/096166 patent/WO2017113820A1/zh not_active Ceased
- 2016-08-22 JP JP2017509778A patent/JP6712588B2/ja active Active
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