JP2018059261A - 温度調節セルロース系繊維及びその用途 - Google Patents
温度調節セルロース系繊維及びその用途 Download PDFInfo
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- JP2018059261A JP2018059261A JP2017251516A JP2017251516A JP2018059261A JP 2018059261 A JP2018059261 A JP 2018059261A JP 2017251516 A JP2017251516 A JP 2017251516A JP 2017251516 A JP2017251516 A JP 2017251516A JP 2018059261 A JP2018059261 A JP 2018059261A
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Abstract
Description
本出願は、2001年9月21日付けの「増強した可逆的熱特性を有する多成分繊維」という題のMagillらの米国特許出願第09/960,591号の一部継続出願である2002年1月15日付けの「増強した可逆的熱特性を有する多成分繊維及びその製造方法」という題のMagillらの米国特許出願第10/052,232号の一部継続出願である2003年8月7日付けの「増強した可逆的熱特性を有するセルロース系繊維及びその形成方法」という題のHartmannらの米国特許出願第10/638,290号の一部継続出願である2006年7月27日付け米国特許出願第11/495,156号の利益を請求するものである。上述の各出願の開示は、その全体が本明細書に参考により組み入れられている。
本発明の実施形態は、増強した可逆的熱特性を有する繊維及びかかる繊維の用途に関する。特に、本発明のさまざまな実施形態が、相変化材料を含むセルロース系繊維に関する。本発明のさまざまな実施形態に従ったセルロース系繊維は、異なる環境条件下で熱エネルギーを吸収しそして放出する能力を有する。さらに、セルロース系繊維は、加工性の改善(例えばセルロース系繊維又はそれから作られる製品の形成中)、より低いコスト(例えばセルロース系繊維又はそれから作られる製品の形成中)、機械的特性の改善、セルロース系繊維内への相変化材料の封じ込めの改善、及び相変化材料のより高い負荷レベルを示す可能性がある。
(2)約2秒〜約60秒、例えば約3秒〜約20秒又は約4秒から約10秒のシンク時間;(3)約13cN/tex〜約40cN/tex、例えば約16cN/tex〜約30cN/tex又は約18cN/tex〜約25cN/texの引張り強度;(4)約10パーセント〜約40パーセント、例えば約14パーセント〜約30パーセント又は約17パーセント〜約22パーセントといった破断点伸び;(5)約0パーセントから約6パーセント、例えば約0パーセント〜約4パーセント又は約0パーセント〜約3パーセントの沸とう水中収縮及び(6)約10g/m2〜約500g/m2、例えば約15g/m2〜約400g/m2又は約40g/m2〜約150g/m2である単位体積重量。
実施例1
[1]
セルロース系材料及びこのセルロース系材料中に分散した複数のマイクロカプセルを含む繊維本体を含むセルロース系繊維において、複数のマイクロカプセルが、少なくとも40J/gの潜熱及び0℃〜100℃の範囲内の転移温度をもつ相変化材料を封じ込め、相変化材料が、転移温度での潜熱の吸収及び放出のうちの少なくとも1つに基づいた熱調節を提供する、セルロース系繊維。
[2]
セルロース系材料がセルロース及び酢酸セルロースのうちの少なくとも1つを含む、項目1に記載のセルロース系繊維。
[3]
複数のマイクロカプセルが0.1〜20ミクロンの範囲内のサイズを有する、項目1に記載のセルロース系繊維。
[4]
複数のマイクロカプセルが、そのサイズに関して単分散である、項目1に記載のセルロース系繊維。
[5]
相変化材料の潜熱が60J/g〜400J/gの範囲内にある、項目1に記載のセルロース系繊維。
[6]
相変化材料の転移温度が0℃〜50℃の範囲内にある、項目1に記載のセルロース系繊維。
[7]
相変化材料がパラフィン系炭化水素を含んでいる項目1に記載のセルロース系繊維。
[8]
相変化材料が多価アルコールを含む、項目1に記載のセルロース系繊維。
[9]
相変化材料がポリエチレングリコール、ポリエチレンオキシド、ポリテトラメチレングリコール及びポリエステルのうちの1つを含む、項目1に記載のセルロース系繊維。
[10]
相変化材料を封じ込める複数のマイクロカプセルを5重量パーセント〜40重量パーセント含む、項目1に記載のセルロース系繊維。
[11]
6パーセント〜15パーセントの範囲内の吸湿率を有する、項目1に記載のセルロース系繊維。
[12]
0.1デシテックス〜60デシテックスである、項目1に記載のセルロース系繊維。
[13]
増強された可逆的熱特性を有しかつ
− セルロース系材料及び該セルロース系材料の内部に分散した温度調節材料を含む延長部材を含む繊維本体であって、該温度調節材料には0℃〜50℃の範囲内の転移温度を有する相変化材料が含まれている繊維本体、
を含むセルロース系繊維を含んでいる複数のセルロース系繊維の配合物を含む布帛。
[14]
複数のセルロース系繊維が不織プロセスにより共に配合されている、項目13に記載の布帛。
[15]
5J/g〜60J/gの範囲内の潜熱を有する、項目13に記載の布帛。
[16]
12グラム/グラム〜35グラム/グラムの範囲内の吸湿率を有する、項目13に記載の布帛。
[17]
15グラム/グラム〜30グラム/グラムの範囲内の吸湿率を有する、項目13に記載の布帛。
[18]
15g/m 2 〜400g/m 2 の範囲内の単位体積重量を有する項目13に記載の布帛。
[19]
セルロース系材料がセルロースと酢酸セルロースのうちの1つを含む、項目13に記載の布帛。
[20]
相変化材料の転移温度が22℃〜40℃の範囲内にある、項目13に記載の布帛。
[21]
相変化材料がパラフィン系炭化水素、多価アルコール、ポリエチレングリコール、ポリエチレンオキシド、ポリテトラメチレングリコール及びポリエステルのうちの1つを含む、項目13に記載の布帛。
[22]
温度調節材料がさらに、相変化材料を封じ込める複数のマイクロカプセルをさらに含む、項目13に記載の布帛。
[23]
繊維本体が、前記延長部材を含んでいる複数の延長部材で形成されている、項目13に記載の布帛。
[24]
複数の延長部材が、アイランド・イン・シー構成、セグメント化パイ構成、コア・シース構成、サイドバイサイド構成及びストライプ構成のうちの1つの形に配置されている、項目23に記載の布帛。
[25]
セルロース系繊維が第1のセルロース系繊維であり、温度調節材料が第1の温度調節材料であり、複数のセルロース系繊維が、増強した可逆的熱特性を有し第2の温度調節材料を含む第2のセルロース系繊維を含む、項目13に記載の布帛。
[26]
第1の温度調節材料と第2の温度調節材料が異なるものである、項目25に記載の布帛。
Claims (26)
- セルロース系材料及びこのセルロース系材料中に分散した複数のマイクロカプセルを含む繊維本体を含むセルロース系繊維において、複数のマイクロカプセルが、少なくとも40J/gの潜熱及び0℃〜100℃の範囲内の転移温度をもつ相変化材料を封じ込め、相変化材料が、転移温度での潜熱の吸収及び放出のうちの少なくとも1つに基づいた熱調節を提供する、セルロース系繊維。
- セルロース系材料がセルロース及び酢酸セルロースのうちの少なくとも1つを含む、請求項1に記載のセルロース系繊維。
- 複数のマイクロカプセルが0.1〜20ミクロンの範囲内のサイズを有する、請求項1に記載のセルロース系繊維。
- 複数のマイクロカプセルが、そのサイズに関して単分散である、請求項1に記載のセルロース系繊維。
- 相変化材料の潜熱が60J/g〜400J/gの範囲内にある、請求項1に記載のセルロース系繊維。
- 相変化材料の転移温度が0℃〜50℃の範囲内にある、請求項1に記載のセルロース系繊維。
- 相変化材料がパラフィン系炭化水素を含んでいる請求項1に記載のセルロース系繊維。
- 相変化材料が多価アルコールを含む、請求項1に記載のセルロース系繊維。
- 相変化材料がポリエチレングリコール、ポリエチレンオキシド、ポリテトラメチレングリコール及びポリエステルのうちの1つを含む、請求項1に記載のセルロース系繊維。
- 相変化材料を封じ込める複数のマイクロカプセルを5重量パーセント〜40重量パーセント含む、請求項1に記載のセルロース系繊維。
- 6パーセント〜15パーセントの範囲内の吸湿率を有する、請求項1に記載のセルロース系繊維。
- 0.1デシテックス〜60デシテックスである、請求項1に記載のセルロース系繊維。
- 増強された可逆的熱特性を有しかつ
− セルロース系材料及び該セルロース系材料の内部に分散した温度調節材料を含む延長部材を含む繊維本体であって、該温度調節材料には0℃〜50℃の範囲内の転移温度を有する相変化材料が含まれている繊維本体、
を含むセルロース系繊維を含んでいる複数のセルロース系繊維の配合物を含む布帛。 - 複数のセルロース系繊維が不織プロセスにより共に配合されている、請求項13に記載の布帛。
- 5J/g〜60J/gの範囲内の潜熱を有する、請求項13に記載の布帛。
- 12グラム/グラム〜35グラム/グラムの範囲内の吸湿率を有する、請求項13に記載の布帛。
- 15グラム/グラム〜30グラム/グラムの範囲内の吸湿率を有する、請求項13に記載の布帛。
- 15g/m2〜400g/m2の範囲内の単位体積重量を有する請求項13に記載の布帛。
- セルロース系材料がセルロースと酢酸セルロースのうちの1つを含む、請求項13に記載の布帛。
- 相変化材料の転移温度が22℃〜40℃の範囲内にある、請求項13に記載の布帛。
- 相変化材料がパラフィン系炭化水素、多価アルコール、ポリエチレングリコール、ポリエチレンオキシド、ポリテトラメチレングリコール及びポリエステルのうちの1つを含む、請求項13に記載の布帛。
- 温度調節材料がさらに、相変化材料を封じ込める複数のマイクロカプセルをさらに含む、請求項13に記載の布帛。
- 繊維本体が、前記延長部材を含んでいる複数の延長部材で形成されている、請求項13に記載の布帛。
- 複数の延長部材が、アイランド・イン・シー構成、セグメント化パイ構成、コア・シース構成、サイドバイサイド構成及びストライプ構成のうちの1つの形に配置されている、請求項23に記載の布帛。
- セルロース系繊維が第1のセルロース系繊維であり、温度調節材料が第1の温度調節材料であり、複数のセルロース系繊維が、増強した可逆的熱特性を有し第2の温度調節材料を含む第2のセルロース系繊維を含む、請求項13に記載の布帛。
- 第1の温度調節材料と第2の温度調節材料が異なるものである、請求項25に記載の布帛。
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TW200833898A (en) | 2008-08-16 |
TWI406994B (zh) | 2013-09-01 |
JP2016145447A (ja) | 2016-08-12 |
JP2013237967A (ja) | 2013-11-28 |
TWI512164B (zh) | 2015-12-11 |
WO2008014164A1 (en) | 2008-01-31 |
TWI649476B (zh) | 2019-02-01 |
US20070026228A1 (en) | 2007-02-01 |
JP5964787B2 (ja) | 2016-08-03 |
JP6659936B2 (ja) | 2020-03-04 |
US20070287008A1 (en) | 2007-12-13 |
EP2046572A4 (en) | 2012-04-18 |
EP2046572B1 (en) | 2016-08-24 |
JP2009544866A (ja) | 2009-12-17 |
US8173257B2 (en) | 2012-05-08 |
US20100294980A1 (en) | 2010-11-25 |
TW201414900A (zh) | 2014-04-16 |
US7790283B2 (en) | 2010-09-07 |
EP2046572A1 (en) | 2009-04-15 |
US7579078B2 (en) | 2009-08-25 |
TW201621114A (zh) | 2016-06-16 |
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