JP2016536448A5 - - Google Patents
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- JP2016536448A5 JP2016536448A5 JP2016551097A JP2016551097A JP2016536448A5 JP 2016536448 A5 JP2016536448 A5 JP 2016536448A5 JP 2016551097 A JP2016551097 A JP 2016551097A JP 2016551097 A JP2016551097 A JP 2016551097A JP 2016536448 A5 JP2016536448 A5 JP 2016536448A5
- Authority
- JP
- Japan
- Prior art keywords
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- branched
- linear
- alkyl group
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005062 Polybutadiene Substances 0.000 claims description 65
- 229920002857 polybutadiene Polymers 0.000 claims description 65
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 40
- 125000000217 alkyl group Chemical group 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 34
- 125000003118 aryl group Chemical group 0.000 claims description 33
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 23
- 229910052757 nitrogen Inorganic materials 0.000 claims description 20
- 229920006395 saturated elastomer Polymers 0.000 claims description 20
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 17
- 125000004429 atom Chemical group 0.000 claims description 16
- 125000005842 heteroatom Chemical group 0.000 claims description 16
- 150000002466 imines Chemical group 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- 150000004700 cobalt complex Chemical group 0.000 claims description 11
- 125000005843 halogen group Chemical group 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 125000003107 substituted aryl group Chemical group 0.000 claims description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- 230000009477 glass transition Effects 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 238000004458 analytical method Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- -1 aromatic phosphines Chemical class 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 4
- 238000012721 stereospecific polymerization Methods 0.000 claims description 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 3
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 150000008040 ionic compounds Chemical class 0.000 claims description 2
- 239000003446 ligand Substances 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 150000002891 organic anions Chemical class 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 239000003426 co-catalyst Substances 0.000 claims 2
- 229910052732 germanium Chemical group 0.000 claims 1
- 230000026030 halogenation Effects 0.000 claims 1
- 238000005658 halogenation reaction Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 230000026045 iodination Effects 0.000 claims 1
- 238000006192 iodination reaction Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000005673 monoalkenes Chemical class 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 125000006732 (C1-C15) alkyl group Chemical group 0.000 description 22
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 239000011574 phosphorus Substances 0.000 description 8
- 229910052711 selenium Inorganic materials 0.000 description 8
- 239000011669 selenium Substances 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 6
- 229910052794 bromium Inorganic materials 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 5
- 125000002346 iodo group Chemical group I* 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229910018516 Al—O Inorganic materials 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI20131830 ITMI20131830A1 (it) | 2013-11-05 | 2013-11-05 | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
| ITMI2013A001830 | 2013-11-05 | ||
| PCT/IB2014/065768 WO2015068095A1 (en) | 2013-11-05 | 2014-11-03 | Stereoregular diblock polybutadienes having a 1,4-cis/syndiotactic 1,2 structure from stereospecific polymerization |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016536448A JP2016536448A (ja) | 2016-11-24 |
| JP2016536448A5 true JP2016536448A5 (enExample) | 2017-12-21 |
| JP6526032B2 JP6526032B2 (ja) | 2019-06-05 |
Family
ID=49683905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016551097A Active JP6526032B2 (ja) | 2013-11-05 | 2014-11-03 | 立体特異性重合による１，４−シス／シンジオタクチック１，２構造を有する立体規則性ジブロックポリブタジエン |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US10066044B2 (enExample) |
| EP (1) | EP3066140B1 (enExample) |
| JP (1) | JP6526032B2 (enExample) |
| KR (1) | KR102209232B1 (enExample) |
| CN (1) | CN105683231B (enExample) |
| BR (1) | BR112016009334B1 (enExample) |
| CA (1) | CA2925377C (enExample) |
| EA (1) | EA031605B1 (enExample) |
| ES (1) | ES2903392T3 (enExample) |
| HU (1) | HUE057995T2 (enExample) |
| IT (1) | ITMI20131830A1 (enExample) |
| LT (1) | LT3066140T (enExample) |
| MX (1) | MX385680B (enExample) |
| MY (1) | MY172668A (enExample) |
| PL (1) | PL3066140T3 (enExample) |
| SG (1) | SG11201603256RA (enExample) |
| TW (1) | TWI653250B (enExample) |
| WO (1) | WO2015068095A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20131828A1 (it) * | 2013-11-05 | 2015-05-06 | Versalis Spa | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
| KR102052439B1 (ko) * | 2016-03-11 | 2019-12-05 | 제이에스알 가부시끼가이샤 | 공중합체의 제조 방법, 중합체 조성물의 제조 방법 및 가교 중합체의 제조 방법 |
| IT201600105530A1 (it) * | 2016-10-20 | 2018-04-20 | Versalis Spa | Procedimento per la preparazione di polibutadiene 1,2 sindiotattico in presenza di un sistema catalitico comprendente un complesso piridilico di ferro |
| IT201700006307A1 (it) * | 2017-01-20 | 2018-07-20 | Versalis Spa | Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati |
| IT201700059763A1 (it) | 2017-05-31 | 2018-12-01 | Versalis Spa | Copolimeri butadiene-isoprene di-blocco e procedimento per la loro preparazione |
| WO2021232678A1 (zh) * | 2020-05-21 | 2021-11-25 | 中国石油化工股份有限公司 | 液体聚丁二烯及其制备方法和应用以及组合物和聚合物涂层和胶粘剂和交联剂 |
| IT202000028823A1 (it) | 2020-11-27 | 2022-05-27 | Consiglio Nazionale Ricerche | Copolimeri dienici a stereoblocchi e relativo processo di preparazione. |
| CN115246913B (zh) * | 2021-04-27 | 2023-10-10 | 中国石油化工股份有限公司 | 一种立构嵌段聚异戊二烯及其制备方法 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3498963A (en) | 1966-09-26 | 1970-03-03 | Japan Synthetic Rubber Co Ltd | Process for the catalytic preparation of 1,2-polybutadiene having a high percentage of vinyl configuration |
| US3522332A (en) | 1967-06-02 | 1970-07-28 | Japan Synthetic Rubber Co Ltd | Process for the preparation of 1,2-polybutadiene |
| JPS4917667B1 (enExample) * | 1970-12-25 | 1974-05-02 | ||
| JPS4917666B1 (enExample) * | 1970-12-25 | 1974-05-02 | ||
| US3817968A (en) | 1972-11-28 | 1974-06-18 | Bridgestone Tire Co Ltd | Method of producing equibinary (cis 1.4-1.2) polybutadiene |
| DE2447203C3 (de) | 1974-10-03 | 1982-03-18 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polybutadien |
| JPS53143685A (en) | 1977-05-23 | 1978-12-14 | Japan Synthetic Rubber Co Ltd | Preparation of 1,2-polybutadiene |
| US4255296A (en) | 1977-12-02 | 1981-03-10 | Bridgestone Tire Company Limited | Polybutadiene rubber composition |
| DE2911262A1 (de) | 1979-03-22 | 1980-10-02 | Bayer Ag | Katalysator, dessen herstellung und verfahren zur polymerisation von butadien |
| DE3000708A1 (de) | 1980-01-10 | 1981-07-16 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von reaktionsprodukten aus konjugierten diolefinen und aromatischen kohlenwasserstoffen |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| IT1231774B (it) | 1989-08-03 | 1991-12-21 | Enichem Anic Spa | Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine. |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| CA2024830A1 (en) | 1989-09-29 | 1991-03-30 | Richard E. Campbell, Jr. | Process for preparation of syndiotactic vinyl aromatic polymers |
| ATE137770T1 (de) | 1989-10-10 | 1996-05-15 | Fina Technology | Metallocenkatalysator mit lewissäure und alkylaluminium |
| WO1992000333A2 (en) | 1990-06-22 | 1992-01-09 | Exxon Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| WO1992005208A1 (en) | 1990-09-14 | 1992-04-02 | Exxon Chemical Patents Inc. | IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| JP3463811B2 (ja) * | 1991-04-24 | 2003-11-05 | Ｊｓｒ株式会社 | ブタジエン系重合体の製造方法 |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5258475A (en) | 1991-07-12 | 1993-11-02 | Mobil Oil Corporation | Catalyst systems for polymerization and copolymerization of olefins |
| US5879805A (en) | 1997-09-09 | 1999-03-09 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization of vinylpolybutadiene |
| US6271313B1 (en) | 1998-12-21 | 2001-08-07 | The Goodyear Tire & Rubber Company | Styrene-butadiene block copolymer |
| ITMI20011813A1 (it) | 2001-08-24 | 2003-02-24 | Enichem Spa | Complessi di cobalto utili nella polimerizzazione del 1,3-butadiene |
| EP1535931B1 (en) | 2002-07-22 | 2011-04-20 | JSR Corporation | Process for producing crystalline 1,2-polybutadiene |
| CN101448861B (zh) * | 2006-05-22 | 2012-04-25 | 宇部兴产株式会社 | 聚丁二烯的制备方法 |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| ITMI20122206A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-immino-piridinico di cobalto |
| ITMI20122201A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
| ITMI20122199A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto |
| ITMI20122203A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto |
| ITMI20131828A1 (it) * | 2013-11-05 | 2015-05-06 | Versalis Spa | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
-
2013
- 2013-11-05 IT ITMI20131830 patent/ITMI20131830A1/it unknown
-
2014
- 2014-10-30 TW TW103137597A patent/TWI653250B/zh active
- 2014-11-03 MX MX2016005602A patent/MX385680B/es unknown
- 2014-11-03 EA EA201690624A patent/EA031605B1/ru not_active IP Right Cessation
- 2014-11-03 HU HUE14812613A patent/HUE057995T2/hu unknown
- 2014-11-03 JP JP2016551097A patent/JP6526032B2/ja active Active
- 2014-11-03 PL PL14812613T patent/PL3066140T3/pl unknown
- 2014-11-03 BR BR112016009334-8A patent/BR112016009334B1/pt active IP Right Grant
- 2014-11-03 EP EP14812613.9A patent/EP3066140B1/en active Active
- 2014-11-03 MY MYPI2016000784A patent/MY172668A/en unknown
- 2014-11-03 KR KR1020167015093A patent/KR102209232B1/ko active Active
- 2014-11-03 LT LTEPPCT/IB2014/065768T patent/LT3066140T/lt unknown
- 2014-11-03 CA CA2925377A patent/CA2925377C/en active Active
- 2014-11-03 US US15/032,207 patent/US10066044B2/en active Active
- 2014-11-03 ES ES14812613T patent/ES2903392T3/es active Active
- 2014-11-03 CN CN201480059603.7A patent/CN105683231B/zh active Active
- 2014-11-03 WO PCT/IB2014/065768 patent/WO2015068095A1/en not_active Ceased
- 2014-11-03 SG SG11201603256RA patent/SG11201603256RA/en unknown
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