HUE057995T2 - Sztereospecifikus polimerizációval elõállított 1,4-cisz/szindiotaktikus 1,2 szerkezetû sztereoreguláris kétblokkos polibutadiének - Google Patents

Sztereospecifikus polimerizációval elõállított 1,4-cisz/szindiotaktikus 1,2 szerkezetû sztereoreguláris kétblokkos polibutadiének

Info

Publication number
HUE057995T2
HUE057995T2 HUE14812613A HUE14812613A HUE057995T2 HU E057995 T2 HUE057995 T2 HU E057995T2 HU E14812613 A HUE14812613 A HU E14812613A HU E14812613 A HUE14812613 A HU E14812613A HU E057995 T2 HUE057995 T2 HU E057995T2
Authority
HU
Hungary
Prior art keywords
syndiotactic
cis
structure produced
stereospecific polymerization
stereoregular diblock
Prior art date
Application number
HUE14812613A
Other languages
English (en)
Hungarian (hu)
Inventor
Francesco Masi
Anna Sommazzi
Giovanni Ricci
Giuseppe Leone
Salvatore Coppola
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of HUE057995T2 publication Critical patent/HUE057995T2/hu

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F295/00Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602Component covered by group C08F4/60 with an organo-aluminium compound
    • C08F4/6028Component covered by group C08F4/60 with an organo-aluminium compound with an alumoxane, i.e. a compound containing an -Al-O-Al-group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003Bidentate ligand
    • C08F4/7004Neutral ligand
    • C08F4/7006NN
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003Bidentate ligand
    • C08F4/7004Neutral ligand
    • C08F4/7008NO
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7039Tridentate ligand
    • C08F4/704Neutral ligand
    • C08F4/7042NNN
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7039Tridentate ligand
    • C08F4/704Neutral ligand
    • C08F4/7044NNO

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
HUE14812613A 2013-11-05 2014-11-03 Sztereospecifikus polimerizációval elõállított 1,4-cisz/szindiotaktikus 1,2 szerkezetû sztereoreguláris kétblokkos polibutadiének HUE057995T2 (hu)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI20131830 ITMI20131830A1 (it) 2013-11-05 2013-11-05 Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica

Publications (1)

Publication Number Publication Date
HUE057995T2 true HUE057995T2 (hu) 2022-06-28

Family

ID=49683905

Family Applications (1)

Application Number Title Priority Date Filing Date
HUE14812613A HUE057995T2 (hu) 2013-11-05 2014-11-03 Sztereospecifikus polimerizációval elõállított 1,4-cisz/szindiotaktikus 1,2 szerkezetû sztereoreguláris kétblokkos polibutadiének

Country Status (18)

Country Link
US (1) US10066044B2 (enExample)
EP (1) EP3066140B1 (enExample)
JP (1) JP6526032B2 (enExample)
KR (1) KR102209232B1 (enExample)
CN (1) CN105683231B (enExample)
BR (1) BR112016009334B1 (enExample)
CA (1) CA2925377C (enExample)
EA (1) EA031605B1 (enExample)
ES (1) ES2903392T3 (enExample)
HU (1) HUE057995T2 (enExample)
IT (1) ITMI20131830A1 (enExample)
LT (1) LT3066140T (enExample)
MX (1) MX385680B (enExample)
MY (1) MY172668A (enExample)
PL (1) PL3066140T3 (enExample)
SG (1) SG11201603256RA (enExample)
TW (1) TWI653250B (enExample)
WO (1) WO2015068095A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20131828A1 (it) * 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
CN108431052B (zh) * 2016-03-11 2021-02-09 Jsr株式会社 聚合催化剂、共聚物、聚合物组合物和交联聚合物
IT201600105530A1 (it) * 2016-10-20 2018-04-20 Versalis Spa Procedimento per la preparazione di polibutadiene 1,2 sindiotattico in presenza di un sistema catalitico comprendente un complesso piridilico di ferro
IT201700006307A1 (it) * 2017-01-20 2018-07-20 Versalis Spa Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
IT201700059763A1 (it) 2017-05-31 2018-12-01 Versalis Spa Copolimeri butadiene-isoprene di-blocco e procedimento per la loro preparazione
WO2021232678A1 (zh) * 2020-05-21 2021-11-25 中国石油化工股份有限公司 液体聚丁二烯及其制备方法和应用以及组合物和聚合物涂层和胶粘剂和交联剂
IT202000028823A1 (it) 2020-11-27 2022-05-27 Consiglio Nazionale Ricerche Copolimeri dienici a stereoblocchi e relativo processo di preparazione.
CN115246913B (zh) * 2021-04-27 2023-10-10 中国石油化工股份有限公司 一种立构嵌段聚异戊二烯及其制备方法

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1158296A (en) 1966-09-26 1969-07-16 Japan Synthetic Rubber Co Ltd Unsaturated Hydrocarbon Polymers
US3522332A (en) 1967-06-02 1970-07-28 Japan Synthetic Rubber Co Ltd Process for the preparation of 1,2-polybutadiene
JPS4917666B1 (enExample) * 1970-12-25 1974-05-02
JPS4917667B1 (enExample) * 1970-12-25 1974-05-02
US3817968A (en) 1972-11-28 1974-06-18 Bridgestone Tire Co Ltd Method of producing equibinary (cis 1.4-1.2) polybutadiene
DE2447203C3 (de) 1974-10-03 1982-03-18 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Polybutadien
JPS53143685A (en) 1977-05-23 1978-12-14 Japan Synthetic Rubber Co Ltd Preparation of 1,2-polybutadiene
US4255296A (en) 1977-12-02 1981-03-10 Bridgestone Tire Company Limited Polybutadiene rubber composition
DE2911262A1 (de) 1979-03-22 1980-10-02 Bayer Ag Katalysator, dessen herstellung und verfahren zur polymerisation von butadien
DE3000708A1 (de) 1980-01-10 1981-07-16 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von reaktionsprodukten aus konjugierten diolefinen und aromatischen kohlenwasserstoffen
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IT1231774B (it) 1989-08-03 1991-12-21 Enichem Anic Spa Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine.
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
CA2024830A1 (en) 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
EP0427697B1 (en) 1989-10-10 1996-05-08 Fina Technology, Inc. Metallocene catalysts with Lewis acids and aluminum alkyls
ATE147761T1 (de) 1990-06-22 1997-02-15 Exxon Chemical Patents Inc Aluminiumfreie monocyclopentadienyl- metallocenkatalysatoren für olefinpolymerisation
DE69117520T2 (de) 1990-09-14 1996-08-01 Exxon Chemical Patents Inc Ionischer katalysator zur herstellung von polyalphaolefinen mit kontrollierter takticität
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
JP3463811B2 (ja) 1991-04-24 2003-11-05 Jsr株式会社 ブタジエン系重合体の製造方法
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5258475A (en) 1991-07-12 1993-11-02 Mobil Oil Corporation Catalyst systems for polymerization and copolymerization of olefins
US5879805A (en) 1997-09-09 1999-03-09 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization of vinylpolybutadiene
US6271313B1 (en) 1998-12-21 2001-08-07 The Goodyear Tire & Rubber Company Styrene-butadiene block copolymer
ITMI20011813A1 (it) 2001-08-24 2003-02-24 Enichem Spa Complessi di cobalto utili nella polimerizzazione del 1,3-butadiene
WO2004009652A1 (ja) 2002-07-22 2004-01-29 Jsr Corporation 結晶性1,2−ポリブタジエンの製造方法
WO2007135946A1 (ja) * 2006-05-22 2007-11-29 Ube Industries, Ltd. ポリブタジエンの製造方法
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
ITMI20122201A1 (it) 2012-12-20 2014-06-21 Versalis Spa Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati
ITMI20122203A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto
ITMI20122199A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto
ITMI20122206A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-immino-piridinico di cobalto
ITMI20131828A1 (it) * 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica

Also Published As

Publication number Publication date
PL3066140T3 (pl) 2022-02-28
KR20160084855A (ko) 2016-07-14
CA2925377A1 (en) 2015-05-14
EP3066140B1 (en) 2021-12-29
SG11201603256RA (en) 2016-05-30
TW201522394A (zh) 2015-06-16
MY172668A (en) 2019-12-09
JP6526032B2 (ja) 2019-06-05
BR112016009334A2 (enExample) 2017-08-01
LT3066140T (lt) 2022-04-11
BR112016009334B1 (pt) 2022-02-01
HK1223387A1 (zh) 2017-07-28
CN105683231A (zh) 2016-06-15
CA2925377C (en) 2021-10-26
US20160264706A1 (en) 2016-09-15
WO2015068095A1 (en) 2015-05-14
EA031605B1 (ru) 2019-01-31
ITMI20131830A1 (it) 2015-05-06
CN105683231B (zh) 2019-06-07
EP3066140A1 (en) 2016-09-14
MX2016005602A (es) 2016-12-09
MX385680B (es) 2025-03-18
JP2016536448A (ja) 2016-11-24
TWI653250B (zh) 2019-03-11
US10066044B2 (en) 2018-09-04
EA201690624A1 (ru) 2016-12-30
KR102209232B1 (ko) 2021-01-29
ES2903392T3 (es) 2022-04-01

Similar Documents

Publication Publication Date Title
HUE057995T2 (hu) Sztereospecifikus polimerizációval elõállított 1,4-cisz/szindiotaktikus 1,2 szerkezetû sztereoreguláris kétblokkos polibutadiének
LTPA2021003I1 (lt) Kompozicijos, naudojamos gydyti sutrikimams, susijusiems su KIT
EP3055318A4 (en) Dihydroxyalkyl substituted polygalactomannan, and methods for producing and using the same
EP4170633C0 (en) GALLBLADDER MODEL
EP2944691A4 (en) CETOSE 3 EPIMERASE DERIVED FROM ARTHROBACTER GLOBIFORMIS
EP3011079A4 (en) Method to produce metal matrix nanocomposite with graphene
HUE054788T2 (hu) Lyukasztótüskék, hozzátartozó perselyek és eljárások perselyek kialakítására felhasználva lyukasztótüskéket
EP3100269A4 (en) Bipolar gate driver
TWI561918B (en) Sulfonium salt, resist composition, and patterning process
SG11201507906SA (en) Method for producing synthetic isoprene polymer latex
LT2945641T (lt) Sacharidai, gauti iš cikloalkinų
SG11201600726QA (en) 1,3-disubstituted cyclopentane derivatives
PL2980053T3 (pl) Sposób wytwarzania butadienu
EP3053160A4 (en) Piano extended soft pedal
HUE043431T2 (hu) 1,4-cisz/szindiotaktikus 1,2 szerkezetû sztereoreguláris diblokk polibutadiének sztereospecifikus polimerizációból
EP3085007A4 (en) Push-based trust model for public cloud applications
PL2964861T3 (pl) Sposób otwierania drzwi
EP3039567A4 (en) Improving tamper resistance of aggregated data
EP3232566A4 (en) Program readable by computer, and sound volume operating device
TH1601002520A (th) พอลิบิวทะไดอีนแบบสองกลุ่มที่มีสเทริโอสม่ำเสมอซึ่งมีโครงสร้าง 1,4 ซิส/1,2 ซินดิโอแทกติกจากพอลิเมอไรเซชันแบบสเทริโอจำเพาะ
TH1301006096B (th) ยางไดอีนแบบคอนจูเกทชนิดดัดแปร, วิธีสำหรับผลิตยางชนิดเดียวกันนี้, และสารผสมยาง
TH1601002521A (th) พอลิบิวทะไดอีนแบบสองกลุ่มที่มีสเทริโอสม่ำเสมอซึ่งมีโครงสร้าง 1,4-ซิส/1,2 ซินดิโอแทกติกจากพอลิเมอไรเซชันแบบสเทริโอจำเพาะ
TH1501005758B (th) วิธีการสำหรับการผลิต ไอโซพรีน พอลิเมอร์ ลาเทกซ์ สังเคราะห์
TH1401005781A (th) วิธีสำหรับการผลิตพอลิเมอร์ที่มีลักษณะคล้ายยาง
TH149077B (th) โพลีเมอร์ที่มีพื้นฐานคอนจูเกตไดอีน, และ องค์ประกอบโพลีเมอร์ที่ประกอบด้วยโพลีเมอร์