CN105683231B - 来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯 - Google Patents
来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯 Download PDFInfo
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- CN105683231B CN105683231B CN201480059603.7A CN201480059603A CN105683231B CN 105683231 B CN105683231 B CN 105683231B CN 201480059603 A CN201480059603 A CN 201480059603A CN 105683231 B CN105683231 B CN 105683231B
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- polybutadiene
- optionally
- alkyl
- branched
- optionally substituted
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
- C08F4/6028—Component covered by group C08F4/60 with an organo-aluminium compound with an alumoxane, i.e. a compound containing an -Al-O-Al-group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7004—Neutral ligand
- C08F4/7006—NN
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7004—Neutral ligand
- C08F4/7008—NO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7039—Tridentate ligand
- C08F4/704—Neutral ligand
- C08F4/7042—NNN
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7039—Tridentate ligand
- C08F4/704—Neutral ligand
- C08F4/7044—NNO
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI20131830 ITMI20131830A1 (it) | 2013-11-05 | 2013-11-05 | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
| ITMI2013A001830 | 2013-11-05 | ||
| PCT/IB2014/065768 WO2015068095A1 (en) | 2013-11-05 | 2014-11-03 | Stereoregular diblock polybutadienes having a 1,4-cis/syndiotactic 1,2 structure from stereospecific polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105683231A CN105683231A (zh) | 2016-06-15 |
| CN105683231B true CN105683231B (zh) | 2019-06-07 |
Family
ID=49683905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480059603.7A Active CN105683231B (zh) | 2013-11-05 | 2014-11-03 | 来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US10066044B2 (enExample) |
| EP (1) | EP3066140B1 (enExample) |
| JP (1) | JP6526032B2 (enExample) |
| KR (1) | KR102209232B1 (enExample) |
| CN (1) | CN105683231B (enExample) |
| BR (1) | BR112016009334B1 (enExample) |
| CA (1) | CA2925377C (enExample) |
| EA (1) | EA031605B1 (enExample) |
| ES (1) | ES2903392T3 (enExample) |
| HU (1) | HUE057995T2 (enExample) |
| IT (1) | ITMI20131830A1 (enExample) |
| LT (1) | LT3066140T (enExample) |
| MX (1) | MX385680B (enExample) |
| MY (1) | MY172668A (enExample) |
| PL (1) | PL3066140T3 (enExample) |
| SG (1) | SG11201603256RA (enExample) |
| TW (1) | TWI653250B (enExample) |
| WO (1) | WO2015068095A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20131828A1 (it) * | 2013-11-05 | 2015-05-06 | Versalis Spa | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
| KR20190030787A (ko) * | 2016-03-11 | 2019-03-22 | 제이에스알 가부시끼가이샤 | 중합 촉매 및 그의 제조 방법 |
| IT201600105530A1 (it) | 2016-10-20 | 2018-04-20 | Versalis Spa | Procedimento per la preparazione di polibutadiene 1,2 sindiotattico in presenza di un sistema catalitico comprendente un complesso piridilico di ferro |
| IT201700006307A1 (it) * | 2017-01-20 | 2018-07-20 | Versalis Spa | Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati |
| IT201700059763A1 (it) | 2017-05-31 | 2018-12-01 | Versalis Spa | Copolimeri butadiene-isoprene di-blocco e procedimento per la loro preparazione |
| CN113698520B (zh) * | 2020-05-21 | 2023-07-21 | 中国石油化工股份有限公司 | 液体聚丁二烯及其制备方法和应用以及组合物和聚合物涂层和胶粘剂和交联剂 |
| IT202000028823A1 (it) | 2020-11-27 | 2022-05-27 | Consiglio Nazionale Ricerche | Copolimeri dienici a stereoblocchi e relativo processo di preparazione. |
| CN115246913B (zh) * | 2021-04-27 | 2023-10-10 | 中国石油化工股份有限公司 | 一种立构嵌段聚异戊二烯及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0511015A1 (en) * | 1991-04-24 | 1992-10-28 | Japan Synthetic Rubber Co., Ltd. | Process for producing polybutadiene |
| CN101448861A (zh) * | 2006-05-22 | 2009-06-03 | 宇部兴产株式会社 | 聚丁二烯的制备方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3498963A (en) | 1966-09-26 | 1970-03-03 | Japan Synthetic Rubber Co Ltd | Process for the catalytic preparation of 1,2-polybutadiene having a high percentage of vinyl configuration |
| US3522332A (en) | 1967-06-02 | 1970-07-28 | Japan Synthetic Rubber Co Ltd | Process for the preparation of 1,2-polybutadiene |
| JPS4917666B1 (enExample) * | 1970-12-25 | 1974-05-02 | ||
| JPS4917667B1 (enExample) * | 1970-12-25 | 1974-05-02 | ||
| US3817968A (en) | 1972-11-28 | 1974-06-18 | Bridgestone Tire Co Ltd | Method of producing equibinary (cis 1.4-1.2) polybutadiene |
| DE2447203C3 (de) | 1974-10-03 | 1982-03-18 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polybutadien |
| JPS53143685A (en) | 1977-05-23 | 1978-12-14 | Japan Synthetic Rubber Co Ltd | Preparation of 1,2-polybutadiene |
| US4255296A (en) | 1977-12-02 | 1981-03-10 | Bridgestone Tire Company Limited | Polybutadiene rubber composition |
| DE2911262A1 (de) | 1979-03-22 | 1980-10-02 | Bayer Ag | Katalysator, dessen herstellung und verfahren zur polymerisation von butadien |
| DE3000708A1 (de) | 1980-01-10 | 1981-07-16 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von reaktionsprodukten aus konjugierten diolefinen und aromatischen kohlenwasserstoffen |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| IT1231774B (it) | 1989-08-03 | 1991-12-21 | Enichem Anic Spa | Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine. |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| CA2024830A1 (en) | 1989-09-29 | 1991-03-30 | Richard E. Campbell, Jr. | Process for preparation of syndiotactic vinyl aromatic polymers |
| ATE137770T1 (de) | 1989-10-10 | 1996-05-15 | Fina Technology | Metallocenkatalysator mit lewissäure und alkylaluminium |
| EP0551277B2 (en) | 1990-06-22 | 2005-03-09 | ExxonMobil Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| ES2084187T3 (es) | 1990-09-14 | 1996-05-01 | Exxon Chemical Patents Inc | Catalizadores ionicos para la produccion de poli(alfa-olefinas) con tacticidad controlada. |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5258475A (en) | 1991-07-12 | 1993-11-02 | Mobil Oil Corporation | Catalyst systems for polymerization and copolymerization of olefins |
| US5879805A (en) | 1997-09-09 | 1999-03-09 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization of vinylpolybutadiene |
| US6271313B1 (en) | 1998-12-21 | 2001-08-07 | The Goodyear Tire & Rubber Company | Styrene-butadiene block copolymer |
| ITMI20011813A1 (it) | 2001-08-24 | 2003-02-24 | Enichem Spa | Complessi di cobalto utili nella polimerizzazione del 1,3-butadiene |
| EP1535931B1 (en) | 2002-07-22 | 2011-04-20 | JSR Corporation | Process for producing crystalline 1,2-polybutadiene |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| ITMI20122199A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto |
| ITMI20122206A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-immino-piridinico di cobalto |
| ITMI20122201A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
| ITMI20122203A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto |
| ITMI20131828A1 (it) * | 2013-11-05 | 2015-05-06 | Versalis Spa | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
-
2013
- 2013-11-05 IT ITMI20131830 patent/ITMI20131830A1/it unknown
-
2014
- 2014-10-30 TW TW103137597A patent/TWI653250B/zh active
- 2014-11-03 MX MX2016005602A patent/MX385680B/es unknown
- 2014-11-03 CA CA2925377A patent/CA2925377C/en active Active
- 2014-11-03 LT LTEPPCT/IB2014/065768T patent/LT3066140T/lt unknown
- 2014-11-03 BR BR112016009334-8A patent/BR112016009334B1/pt active IP Right Grant
- 2014-11-03 US US15/032,207 patent/US10066044B2/en active Active
- 2014-11-03 PL PL14812613T patent/PL3066140T3/pl unknown
- 2014-11-03 SG SG11201603256RA patent/SG11201603256RA/en unknown
- 2014-11-03 ES ES14812613T patent/ES2903392T3/es active Active
- 2014-11-03 WO PCT/IB2014/065768 patent/WO2015068095A1/en not_active Ceased
- 2014-11-03 HU HUE14812613A patent/HUE057995T2/hu unknown
- 2014-11-03 MY MYPI2016000784A patent/MY172668A/en unknown
- 2014-11-03 CN CN201480059603.7A patent/CN105683231B/zh active Active
- 2014-11-03 EA EA201690624A patent/EA031605B1/ru not_active IP Right Cessation
- 2014-11-03 KR KR1020167015093A patent/KR102209232B1/ko active Active
- 2014-11-03 EP EP14812613.9A patent/EP3066140B1/en active Active
- 2014-11-03 JP JP2016551097A patent/JP6526032B2/ja active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0511015A1 (en) * | 1991-04-24 | 1992-10-28 | Japan Synthetic Rubber Co., Ltd. | Process for producing polybutadiene |
| CN101448861A (zh) * | 2006-05-22 | 2009-06-03 | 宇部兴产株式会社 | 聚丁二烯的制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 立构两嵌段聚丁二烯研究进展;王玉荣等;《合成橡胶工业》;19970515(第03期);130-134页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112016009334B1 (pt) | 2022-02-01 |
| KR20160084855A (ko) | 2016-07-14 |
| CA2925377A1 (en) | 2015-05-14 |
| CA2925377C (en) | 2021-10-26 |
| ES2903392T3 (es) | 2022-04-01 |
| EP3066140A1 (en) | 2016-09-14 |
| KR102209232B1 (ko) | 2021-01-29 |
| BR112016009334A2 (enExample) | 2017-08-01 |
| TW201522394A (zh) | 2015-06-16 |
| EA031605B1 (ru) | 2019-01-31 |
| TWI653250B (zh) | 2019-03-11 |
| ITMI20131830A1 (it) | 2015-05-06 |
| US20160264706A1 (en) | 2016-09-15 |
| MY172668A (en) | 2019-12-09 |
| HK1223387A1 (zh) | 2017-07-28 |
| WO2015068095A1 (en) | 2015-05-14 |
| MX385680B (es) | 2025-03-18 |
| SG11201603256RA (en) | 2016-05-30 |
| PL3066140T3 (pl) | 2022-02-28 |
| JP6526032B2 (ja) | 2019-06-05 |
| MX2016005602A (es) | 2016-12-09 |
| HUE057995T2 (hu) | 2022-06-28 |
| JP2016536448A (ja) | 2016-11-24 |
| US10066044B2 (en) | 2018-09-04 |
| LT3066140T (lt) | 2022-04-11 |
| EP3066140B1 (en) | 2021-12-29 |
| EA201690624A1 (ru) | 2016-12-30 |
| CN105683231A (zh) | 2016-06-15 |
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