JP2016187879A - 化粧シート及び化粧板 - Google Patents
化粧シート及び化粧板 Download PDFInfo
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- JP2016187879A JP2016187879A JP2015067909A JP2015067909A JP2016187879A JP 2016187879 A JP2016187879 A JP 2016187879A JP 2015067909 A JP2015067909 A JP 2015067909A JP 2015067909 A JP2015067909 A JP 2015067909A JP 2016187879 A JP2016187879 A JP 2016187879A
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- resin
- decorative sheet
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- sheet
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
Landscapes
- Laminated Bodies (AREA)
Abstract
【解決手段】基材シート上に、樹脂を含む凸部が少なくとも形成されている化粧シートであって、
(1)前記凸部の高さが10μm以上であり、
(2)前記凸部は、平均粒子径が11〜30μmの無機粒子を、樹脂100質量部に対して10〜30質量部含有する、
ことを特徴とする化粧シート。
【選択図】なし
Description
1.基材シート上に、樹脂を含む凸部が少なくとも形成されている化粧シートであって、
(1)前記凸部の高さが10μm以上であり、
(2)前記凸部は、平均粒子径が11〜30μmの無機粒子を、樹脂100質量部に対して10〜30質量部含有する、
ことを特徴とする化粧シート。
2.前記樹脂は、電離放射線硬化型樹脂である、項1に記載の化粧シート。
3.基材シート上に、少なくとも絵柄模様層及び透明性樹脂層がこの順に積層されており、前記透明性樹脂層上に、前記樹脂を含む凸部が形成されている、項1又は2に記載の化粧シート。
4.前記絵柄模様層と、前記樹脂を含む凸部とが同調している、項3に記載の化粧シート。
5.項1〜4のいずれかに記載の化粧シートを被着材に貼着してなる化粧板。
本発明の化粧シートは、基材シート上に、樹脂を含む凸部が少なくとも形成されており、(1)前記凸部の高さが10μm以上であり、(2)前記凸部は、平均粒子径が11〜30μmの無機粒子を、樹脂100質量部に対して10〜30質量部含有することを特徴とする。
基材シートとしては限定されず、繊維質シート、プラスチック基材、金属基材、木質系基材等を用いることができる。
本発明の化粧シートは、基材シート上に樹脂を含む凸部が少なくとも形成されている。本発明における凸部は、いわゆる厚盛り印刷層として、所望の意匠を表現するように厚盛り印刷によって形成されることが好ましい。なお、本発明において、凸部とは、図1及び2に示すような断面模式図において凸形状で示される形態であり、例えば、化粧シート表面において円錐形や円柱形の突起が形成されている形態だけでなく、導管模様のような、突起が線状に伸びて形成されている形態も含む。
本発明の化粧シートは、基材シート上に、樹脂を含む凸部が少なくとも形成されていれば、その具体的構成(層構成)については限定されない。例えば、基材シート上に、少なくとも絵柄模様層及び透明性樹脂層が積層されており、透明性樹脂層上に、樹脂を含む凸部が形成されている化粧シートが挙げられる。図1に本発明の化粧シートの層構成の上記一例を示す。図1において、本発明の化粧シート1は、基材シート2上に、絵柄模様層3、透明性樹脂層4がこの順に積層されており透明性樹脂層4上に樹脂を含む凸部5が形成されている。また、本発明の化粧シートは、図2のように、基材シート2と絵柄模様層3との間に、更に着色隠蔽層6が形成されていてもよい。
以下、かかる層構成のシートを代表例として、各層について具体的に説明する。
本発明の化粧シートは、基材シート又は後述する着色隠蔽層の上には、必要に応じて絵柄模様層を形成してもよい。なお、本発明の化粧シートにおいては、絵柄模様層と、上記凸部とが同調している構成とすることにより、より意匠性に優れた化粧シートとなる。具体的には、図1及び図2に示されるように、絵柄模様層の絵柄が形成された部分に凸部が同調した構成であってもよいし、逆に絵柄模様層の絵柄が形成されていない部分に凸部が同調した構成であってもよい。
本発明の化粧シートは、絵柄模様層上に艶調整等を目的として、透明性樹脂層を形成してもよい。透明性樹脂層は、透明性のものであれば特に限定されず、無色透明、着色透明、半透明等のいずれも含む。前記透明性樹脂層を構成する樹脂としては、例えば、フェノール樹脂、尿素樹脂、ジアリルフタレート、メラミン樹脂、グアナミン樹脂、不飽和ポリエステル樹脂、ポリウレタン樹脂、エポキシ樹脂、アミノアルキッド樹脂、メラミン−尿素共縮合体、珪素樹脂、ポリシロキサン、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリアミド、ポリエチレン、ポリプロピレン、エチレン・酢酸ビニル共重合体、エチレン・アクリル酸共重合体、エチレン・アクリル酸エステル共重合体、アイオノマー、ポリメチルペンテン、アクリル酸エステル、メタアクリル酸エステル、ポリカーボネート、セルローストリアセテート等を挙げることができる。また、上述の電離放射線硬化型樹脂を用いてもよい。これら樹脂は単独で又は2種以上を組み合わせて用いることができる。
基材シート上には、必要に応じて着色隠蔽層を形成してもよい。着色隠蔽層は、基材シート上に全面ベタ印刷層として形成される。着色隠蔽層は、例えば、顔料及び結着材樹脂を含む層とすることができる。この着色隠蔽層は、例えば、着色材、結着材樹脂、溶剤を含む印刷インキを使用し、グラビア印刷、フレキソ印刷、シルクスクリーン印刷、オフセット印刷等の既知の印刷法により形成できる。これらのインキは公知又は市販のものを使用してもよい。
基材シート、着色隠蔽性、絵柄模様層又は透明性樹脂層の上には、凸部との密着性を向上させること等を目的として、必要に応じてプライマー層を形成してもよい。
基材シートの裏面(凸部が形成される面とは反対側の面)には、必要に応じて、裏面プライマー層を設けてもよい。裏面プライマー層は、本発明の化粧シートと被着材とを積層して化粧板を作製する際に効果的である。
上記化粧シートを被着材上に貼着することにより、化粧板とすることができる。被着材は、限定的でなく、公知の化粧板に用いられるものと同様のものを用いることができる。上記被着材としては、例えば、木質材、金属、セラミックス、プラスチックス、ガラス等が挙げられる。特に、上記化粧シートは、木質材に好適に使用することができる。木質材としては、具体的には、杉、檜、欅、松、ラワン、チーク、メラピー等の各種素材から作られた突板、木材単板、木材合板、パーティクルボード、中密度繊維板(MDF)、チップボード、又はチップボードが積層された複合基材等が挙げられる。上記木質材としては、木材合板、パーティクルボード、中密度繊維板(MDF)を用いることが好ましい。
化粧シートの製造方法としては、例えば、基材シートの上に少なくとも樹脂を含む凸部を形成する製造方法が挙げられる。
基材シートとして、米秤量30g/m2の建材用一般紙を用意し、その片面にアクリル樹脂と硝化綿をバインダーとし、チタン白、弁柄、黄鉛を着色剤とするインキを用いて、塗工量5g/m2の(全面ベタ)層をグラビア印刷にて施して着色隠蔽層とした。その上に硝化綿をバインダーとし、弁柄を主成分とする着色剤を含有するインキを用いて、木目模様の絵柄模様層をグラビア印刷にて形成した。
凸部に含まれる無機粒子の種類及び配合量を表1のように変更した以外は実施例1と同様にして、化粧シートを調製した。
化粧シートの表面を、20代〜40代の成人男女15人が手で触って触感を判定し、下記評価基準に従って評価した。なお、下記評価基準において、4以上であれば優れた触感を示すと判断できる。
5:成人男女10人以上が、触感が良好と感じた
4:成人男女8〜9人が、触感が良好と感じた
3:成人男女6〜7人が、触感が良好と感じた
2:成人男女4〜5人が、触感が良好と感じた
1:成人男女のうち触感が良好と感じたのが3人以下であった
実施例及び比較例で調製した化粧シートをMDFに貼付して化粧板を調製した。当該化粧板を、マーチンデール摩耗試験機(「Martindale 1300シリーズ モデル1302(型番)」 James Heal社製)の摩擦テーブル部に取り付け、化粧板の上にスコッチ・ブライト工業用パッド7446(スリーエムジャパン(株)製)を重ねて荷重6Nを掛けて、摩擦回数100回の条件でリサージュ図形運動による摩擦試験を行った。試験後の外観を目視により観察し、下記評価基準に従って評価した。なお、下記評価基準において、3以上であれば耐擦傷性に優れると判断される。
5:傷付きなし
4:軽微な艶変化あり
3:軽微な傷付きはあるが、実使用上問題なし
2:傷付きあり
1:著しい傷付きあり
凸部形成用樹脂組成物を塗工した際の、表面の転移の状態を目視にて観察し、下記評価基準に従って塗工適性を評価した。
○ 塗工面に凸部が安定して転移されている
× 塗工面の凸部の抜けが有るか、又は凸部の形状が不安定である
結果を表1に示す。
2.基材シート
3.絵柄模様層
4.透明性樹脂層
5.樹脂を含む凸部
6.着色隠蔽層
Claims (5)
- 基材シート上に、樹脂を含む凸部が少なくとも形成されている化粧シートであって、
(1)前記凸部の高さが10μm以上であり、
(2)前記凸部は、平均粒子径が11〜30μmの無機粒子を、樹脂100質量部に対して10〜30質量部含有する、
ことを特徴とする化粧シート。 - 前記樹脂は、電離放射線硬化型樹脂である、請求項1に記載の化粧シート。
- 基材シート上に、少なくとも絵柄模様層及び透明性樹脂層がこの順に積層されており、前記透明性樹脂層上に、前記樹脂を含む凸部が形成されている、請求項1又は2に記載の化粧シート。
- 前記絵柄模様層と、前記樹脂を含む凸部とが同調している、請求項3に記載の化粧シート。
- 請求項1〜4のいずれかに記載の化粧シートを被着材に貼着してなる化粧板。
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WO2019135360A1 (ja) * | 2018-01-05 | 2019-07-11 | 凸版印刷株式会社 | 化粧材 |
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JP2019119138A (ja) * | 2018-01-05 | 2019-07-22 | 凸版印刷株式会社 | 化粧材 |
JP7003667B2 (ja) | 2018-01-05 | 2022-02-10 | 凸版印刷株式会社 | 化粧材 |
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