JP2015534708A5 - - Google Patents
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- Publication number
- JP2015534708A5 JP2015534708A5 JP2015534682A JP2015534682A JP2015534708A5 JP 2015534708 A5 JP2015534708 A5 JP 2015534708A5 JP 2015534682 A JP2015534682 A JP 2015534682A JP 2015534682 A JP2015534682 A JP 2015534682A JP 2015534708 A5 JP2015534708 A5 JP 2015534708A5
- Authority
- JP
- Japan
- Prior art keywords
- rechargeable battery
- anthraquinone
- hydroquinone
- quinone
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 50
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 46
- 230000004888 barrier function Effects 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 150000002500 ions Chemical class 0.000 claims description 8
- OKONMFPEKSWGEU-UHFFFAOYSA-N 9,10-dioxoanthracene-2,7-disulfonic acid Chemical group C1=C(S(O)(=O)=O)C=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 OKONMFPEKSWGEU-UHFFFAOYSA-N 0.000 claims description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 6
- 150000004056 anthraquinones Chemical class 0.000 claims description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052794 bromium Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- OZTBHAGJSKTDGM-UHFFFAOYSA-N 9,10-dioxoanthracene-1,5-disulfonic acid Chemical compound O=C1C=2C(S(=O)(=O)O)=CC=CC=2C(=O)C2=C1C=CC=C2S(O)(=O)=O OZTBHAGJSKTDGM-UHFFFAOYSA-N 0.000 claims description 4
- IJNPIHLZSZCGOC-UHFFFAOYSA-N 9,10-dioxoanthracene-1,8-disulfonic acid Chemical compound O=C1C2=CC=CC(S(O)(=O)=O)=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O IJNPIHLZSZCGOC-UHFFFAOYSA-N 0.000 claims description 4
- MMNWSHJJPDXKCH-UHFFFAOYSA-N 9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 MMNWSHJJPDXKCH-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- -1 SO 3 H Chemical group 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- MSSUFHMGCXOVBZ-UHFFFAOYSA-N anthraquinone-2,6-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 MSSUFHMGCXOVBZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 230000007717 exclusion Effects 0.000 claims description 4
- 125000001475 halogen functional group Chemical group 0.000 claims description 4
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 125000004043 oxo group Chemical group O=* 0.000 claims description 4
- 125000005499 phosphonyl group Chemical group 0.000 claims description 4
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical group [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- FINXYYKSUHDLOT-UHFFFAOYSA-N 2,3,5-trihydroxybenzene-1,4-disulfonic acid Chemical compound Oc1cc(c(O)c(O)c1S(O)(=O)=O)S(O)(=O)=O FINXYYKSUHDLOT-UHFFFAOYSA-N 0.000 claims description 3
- 150000004053 quinones Chemical class 0.000 claims description 3
- PZTGRDMCBZUJDL-UHFFFAOYSA-N 1,2-naphthoquinone-4-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC(=O)C(=O)C2=C1 PZTGRDMCBZUJDL-UHFFFAOYSA-N 0.000 claims description 2
- DURBTILWOVXSNP-UHFFFAOYSA-N 1,3,4-trihydroxy-9,10-dioxoanthracene-2-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=C(S(O)(=O)=O)C(O)=C2O DURBTILWOVXSNP-UHFFFAOYSA-N 0.000 claims description 2
- CCQSBGJULPBARL-UHFFFAOYSA-N 1,4-dihydroxy-9,10-dioxoanthracene-2-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=C(S(O)(=O)=O)C=C2O CCQSBGJULPBARL-UHFFFAOYSA-N 0.000 claims description 2
- IAGVANYWTGRDOU-UHFFFAOYSA-N 1,4-dioxonaphthalene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C(S(=O)(=O)O)=CC(=O)C2=C1 IAGVANYWTGRDOU-UHFFFAOYSA-N 0.000 claims description 2
- AWVNGKBCZDBCJB-UHFFFAOYSA-N 1,5-dihydroxy-9,10-dioxoanthracene-2,6-disulfonic acid Chemical compound O=C1C2=C(O)C(S(O)(=O)=O)=CC=C2C(=O)C2=C1C=CC(S(O)(=O)=O)=C2O AWVNGKBCZDBCJB-UHFFFAOYSA-N 0.000 claims description 2
- YHIUFLAYHWBDLL-UHFFFAOYSA-N 1,8-dihydroxy-9,10-dioxoanthracene-2,7-disulfonic acid Chemical compound O=C1C2=CC=C(S(O)(=O)=O)C(O)=C2C(=O)C2=C1C=CC(S(O)(=O)=O)=C2O YHIUFLAYHWBDLL-UHFFFAOYSA-N 0.000 claims description 2
- WWTKPFXBQJLRRR-UHFFFAOYSA-N 2,3,5,6-tetrahydroxybenzene-1,4-disulfonic acid Chemical compound Oc1c(O)c(c(O)c(O)c1S(O)(=O)=O)S(O)(=O)=O WWTKPFXBQJLRRR-UHFFFAOYSA-N 0.000 claims description 2
- APFTZGWMGKJYBL-UHFFFAOYSA-N 2,3,6-trihydroxybenzenesulfonic acid Chemical compound OC1=CC=C(O)C(S(O)(=O)=O)=C1O APFTZGWMGKJYBL-UHFFFAOYSA-N 0.000 claims description 2
- BBKIMXIAWFAUMV-UHFFFAOYSA-N 2,4,5,6-tetrahydroxybenzene-1,3-disulfonic acid Chemical compound Oc1c(O)c(c(O)c(c1O)S(O)(=O)=O)S(O)(=O)=O BBKIMXIAWFAUMV-UHFFFAOYSA-N 0.000 claims description 2
- NLGUDKZPDJFCOF-UHFFFAOYSA-N 2,4,5-trihydroxybenzene-1,3-disulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=C(O)C(S(O)(=O)=O)=C1O NLGUDKZPDJFCOF-UHFFFAOYSA-N 0.000 claims description 2
- QVYWFLYYMLNPPH-UHFFFAOYSA-N 3-bromo-1,4-dioxonaphthalene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C(S(=O)(=O)O)=C(Br)C(=O)C2=C1 QVYWFLYYMLNPPH-UHFFFAOYSA-N 0.000 claims description 2
- VGSQPIPVFVULQH-UHFFFAOYSA-N 3-chloro-1,4-dioxonaphthalene-2-sulfonic acid Chemical compound OS(=O)(=O)C1=C(Cl)C(=O)c2ccccc2C1=O VGSQPIPVFVULQH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- IPJDQEIWFZAWCA-UHFFFAOYSA-N OC1=C(C(=O)c2ccccc2C1=O)S(O)(=O)=O Chemical compound OC1=C(C(=O)c2ccccc2C1=O)S(O)(=O)=O IPJDQEIWFZAWCA-UHFFFAOYSA-N 0.000 claims description 2
- OBDVJARAMDHRQG-UHFFFAOYSA-N [9,10-dioxo-3-(sulfomethyl)anthracen-2-yl]methanesulfonic acid Chemical compound OS(=O)(=O)Cc1cc2C(=O)c3ccccc3C(=O)c2cc1CS(O)(=O)=O OBDVJARAMDHRQG-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- 229910000464 lead oxide Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 230000005012 migration Effects 0.000 claims description 2
- 238000013508 migration Methods 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261705845P | 2012-09-26 | 2012-09-26 | |
| US61/705,845 | 2012-09-26 | ||
| US201361823258P | 2013-05-14 | 2013-05-14 | |
| US61/823,258 | 2013-05-14 | ||
| US201361838589P | 2013-06-24 | 2013-06-24 | |
| US61/838,589 | 2013-06-24 | ||
| PCT/US2013/062057 WO2014052682A2 (en) | 2012-09-26 | 2013-09-26 | Small organic molecule based flow battery |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019118766A Division JP2019179768A (ja) | 2012-09-26 | 2019-06-26 | 低分子有機化合物ベースのフロー電池 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015534708A JP2015534708A (ja) | 2015-12-03 |
| JP2015534708A5 true JP2015534708A5 (enExample) | 2016-11-10 |
| JP6574382B2 JP6574382B2 (ja) | 2019-09-11 |
Family
ID=50389135
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015534682A Active JP6574382B2 (ja) | 2012-09-26 | 2013-09-26 | 低分子有機化合物ベースのフロー電池 |
| JP2019118766A Pending JP2019179768A (ja) | 2012-09-26 | 2019-06-26 | 低分子有機化合物ベースのフロー電池 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019118766A Pending JP2019179768A (ja) | 2012-09-26 | 2019-06-26 | 低分子有機化合物ベースのフロー電池 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US20150243991A1 (enExample) |
| EP (1) | EP2901520B1 (enExample) |
| JP (2) | JP6574382B2 (enExample) |
| KR (2) | KR102392089B1 (enExample) |
| CN (2) | CN113555594A (enExample) |
| AU (2) | AU2013323439A1 (enExample) |
| CA (1) | CA2885929C (enExample) |
| ES (1) | ES2968855T3 (enExample) |
| IN (1) | IN2015DN03105A (enExample) |
| WO (1) | WO2014052682A2 (enExample) |
| ZA (1) | ZA201502599B (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102392089B1 (ko) * | 2012-09-26 | 2022-04-28 | 프레지던트 앤드 펠로우즈 오브 하바드 칼리지 | 소형 유기 분자를 이용한 플로우 전지 |
| WO2014204985A1 (en) | 2013-06-17 | 2014-12-24 | University Of Southern California | Inexpensive metal-free organic redox flow battery (orbat) for grid-scale storage |
| AU2014324647B2 (en) | 2013-09-26 | 2018-12-20 | President And Fellows Of Harvard College | Quinone and hydroquinone based flow battery |
| CN105679985B (zh) * | 2014-11-17 | 2019-02-01 | 中国科学院大连化学物理研究所 | 一种醌多卤化物液流电池 |
| WO2016102069A2 (en) | 2014-12-23 | 2016-06-30 | Cambridge Display Technology, Ltd. | Organic flow cell batteries and materials for use in same |
| US20180048011A1 (en) * | 2015-03-06 | 2018-02-15 | President And Fellows Of Harvard College | HIGH pH ORGANIC FLOW BATTERY |
| US10253051B2 (en) | 2015-03-16 | 2019-04-09 | Lockheed Martin Energy, Llc | Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride |
| KR20170129884A (ko) | 2015-03-24 | 2017-11-27 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 다공성 전극 및 이로부터 제조된 전기화학 전지 및 액체 흐름 배터리 |
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| US10316047B2 (en) | 2016-03-03 | 2019-06-11 | Lockheed Martin Energy, Llc | Processes for forming coordination complexes containing monosulfonated catecholate ligands |
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| KR20180124940A (ko) | 2016-03-17 | 2018-11-21 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 전극 조립체, 막-전극 조립체 및 그로부터의 전기화학 전지 및 액체 흐름 배터리 |
| US20190051877A1 (en) | 2016-03-17 | 2019-02-14 | 3M Innovative Properties Company | Membrane assemblies, electrode assemblies, membrane-electrode assemblies and electrochemical cells and liquid flow batteries therefrom |
| JP2019509600A (ja) | 2016-03-17 | 2019-04-04 | スリーエム イノベイティブ プロパティズ カンパニー | 膜アセンブリ、電極アセンブリ、膜電極アセンブリ並びにこれらによる電気化学セル及び液体フロー電池 |
| CN109072088B (zh) | 2016-04-07 | 2021-07-30 | Cmblu企划股份公司 | 制备低分子量的芳香族木质素衍生化合物的方法 |
| FR3052598B1 (fr) * | 2016-06-10 | 2018-06-01 | Universite De Rennes 1 | Utilisation de liquides ioniques comme adjuvant en electrochimie |
| WO2018016592A1 (ja) * | 2016-07-21 | 2018-01-25 | 日立化成株式会社 | 二次電池、二次電池システム、正極電解液及び発電システム |
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| US11923581B2 (en) | 2016-08-12 | 2024-03-05 | President And Fellows Of Harvard College | Aqueous redox flow battery electrolytes with high chemical and electrochemical stability, high water solubility, low membrane permeability |
| KR102229442B1 (ko) * | 2016-09-22 | 2021-03-17 | 주식회사 엘지화학 | 수계 레독스 플로우 전지용 유기계 양극 활물질 |
| TWI625915B (zh) * | 2016-11-18 | 2018-06-01 | Industrial Technology Research Institute | 智慧型充電方法 |
| US10930937B2 (en) * | 2016-11-23 | 2021-02-23 | Lockheed Martin Energy, Llc | Flow batteries incorporating active materials containing doubly bridged aromatic groups |
| CN106654200B (zh) * | 2016-12-08 | 2019-09-06 | 南方科技大学 | 一种电极材料、其制备方法及用途 |
| US10497958B2 (en) | 2016-12-14 | 2019-12-03 | Lockheed Martin Energy, Llc | Coordinatively unsaturated titanium catecholate complexes and processes associated therewith |
| US10840532B2 (en) | 2017-01-27 | 2020-11-17 | President And Fellows Of Harvard College | Flow battery with electrolyte rebalancing system |
| EP3580389B1 (en) | 2017-02-13 | 2025-09-17 | CMBlu Energy AG | Novel methods for processing lignocellulosic material |
| CN110446771A (zh) * | 2017-02-13 | 2019-11-12 | Cmblu企划股份公司 | 氧化还原液流电池组电解质 |
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| JP6847446B2 (ja) * | 2017-02-17 | 2021-03-24 | 国立大学法人九州大学 | 電解液および発電装置 |
| EP3584866B1 (en) * | 2017-02-17 | 2023-12-13 | Kyushu University, National University Corporation | Electrolytic solution, electrolytic aqueous solution, and power generating devices |
| WO2018160618A1 (en) | 2017-02-28 | 2018-09-07 | Wisconsin Alumni Research Foundation | High-and low-potential, water-soluble, robust quinones |
| CN109411794A (zh) * | 2017-08-17 | 2019-03-01 | 江苏中安环能新能源科技有限公司 | 一种新型全醌水体系液流电池 |
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| US11245111B2 (en) * | 2017-10-17 | 2022-02-08 | University Of Southern California | Stable positive side material for all-organic flow battery |
| JP2019129037A (ja) * | 2018-01-23 | 2019-08-01 | 三菱瓦斯化学株式会社 | 電池用電解液及びレドックスフロー電池 |
| WO2019157437A1 (en) | 2018-02-09 | 2019-08-15 | President And Fellows Of Harvard College | Quinones having high capacity retention for use as electrolytes in aqueous redox flow batteries |
| AU2019220364A1 (en) | 2018-02-13 | 2020-07-30 | Cmblu Energy Ag | Aminated lignin-derived compounds and uses thereof |
| EP3753062A1 (en) | 2018-02-13 | 2020-12-23 | Cmblu Projekt AG | Redox flow battery electrolytes |
| WO2019178041A1 (en) * | 2018-03-12 | 2019-09-19 | University Of Southern California | Crossover resistant materials for aqueous organic redox flow batteries |
| WO2019240933A1 (en) * | 2018-06-10 | 2019-12-19 | University Of Southern California | Inexpensive and efficient organic redox flow battery configurations for large-scale energy storage |
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2013
- 2013-09-26 KR KR1020157010653A patent/KR102392089B1/ko active Active
- 2013-09-26 CA CA2885929A patent/CA2885929C/en active Active
- 2013-09-26 JP JP2015534682A patent/JP6574382B2/ja active Active
- 2013-09-26 CN CN202110624181.5A patent/CN113555594A/zh active Pending
- 2013-09-26 US US14/431,175 patent/US20150243991A1/en not_active Abandoned
- 2013-09-26 IN IN3105DEN2015 patent/IN2015DN03105A/en unknown
- 2013-09-26 AU AU2013323439A patent/AU2013323439A1/en not_active Abandoned
- 2013-09-26 ES ES13841221T patent/ES2968855T3/es active Active
- 2013-09-26 KR KR1020217010191A patent/KR20210041122A/ko not_active Ceased
- 2013-09-26 WO PCT/US2013/062057 patent/WO2014052682A2/en not_active Ceased
- 2013-09-26 CN CN201380061081.XA patent/CN105308785A/zh active Pending
- 2013-09-26 EP EP13841221.8A patent/EP2901520B1/en active Active
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2015
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- 2015-08-11 US US14/823,546 patent/US9966622B2/en active Active
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