JP2015020090A - リチウム吸着材料の製造方法およびリチウム吸着材料 - Google Patents
リチウム吸着材料の製造方法およびリチウム吸着材料 Download PDFInfo
- Publication number
- JP2015020090A JP2015020090A JP2013147845A JP2013147845A JP2015020090A JP 2015020090 A JP2015020090 A JP 2015020090A JP 2013147845 A JP2013147845 A JP 2013147845A JP 2013147845 A JP2013147845 A JP 2013147845A JP 2015020090 A JP2015020090 A JP 2015020090A
- Authority
- JP
- Japan
- Prior art keywords
- lithium
- manganese oxide
- adsorbing material
- aqueous solution
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 103
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000002245 particle Substances 0.000 claims abstract description 99
- 229910002102 lithium manganese oxide Inorganic materials 0.000 claims abstract description 94
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 claims abstract description 91
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 84
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 82
- 239000011572 manganese Substances 0.000 claims abstract description 73
- 239000007864 aqueous solution Substances 0.000 claims abstract description 62
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 60
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 60
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 43
- 238000010438 heat treatment Methods 0.000 claims abstract description 35
- 239000000725 suspension Substances 0.000 claims abstract description 26
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 238000001179 sorption measurement Methods 0.000 claims abstract description 21
- 239000003637 basic solution Substances 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 12
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 9
- 230000001590 oxidative effect Effects 0.000 claims abstract description 6
- 229910052744 lithium Inorganic materials 0.000 claims description 102
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 101
- 229910044991 metal oxide Inorganic materials 0.000 claims description 42
- 229910009343 Li1.33 Mn1.67 O4 Inorganic materials 0.000 claims description 12
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 239000012267 brine Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000011236 particulate material Substances 0.000 claims description 10
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 7
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 7
- 150000004692 metal hydroxides Chemical class 0.000 claims description 7
- 229910052596 spinel Inorganic materials 0.000 claims description 7
- 239000011029 spinel Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 3
- QEXMICRJPVUPSN-UHFFFAOYSA-N lithium manganese(2+) oxygen(2-) Chemical class [O-2].[Mn+2].[Li+] QEXMICRJPVUPSN-UHFFFAOYSA-N 0.000 claims description 3
- 239000013535 sea water Substances 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 claims description 3
- 239000007767 bonding agent Substances 0.000 claims description 2
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 claims 1
- 238000010828 elution Methods 0.000 abstract description 53
- 239000000243 solution Substances 0.000 abstract description 19
- 150000002739 metals Chemical class 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 2
- 229910021450 lithium metal oxide Inorganic materials 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 35
- 238000003795 desorption Methods 0.000 description 29
- 238000002336 sorption--desorption measurement Methods 0.000 description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 230000007423 decrease Effects 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 238000002441 X-ray diffraction Methods 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000005540 biological transmission Effects 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000005070 sampling Methods 0.000 description 6
- 239000013078 crystal Substances 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 229910000480 nickel oxide Inorganic materials 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 4
- 238000007323 disproportionation reaction Methods 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- CJYZTOPVWURGAI-UHFFFAOYSA-N lithium;manganese;manganese(3+);oxygen(2-) Chemical compound [Li+].[O-2].[O-2].[O-2].[O-2].[Mn].[Mn+3] CJYZTOPVWURGAI-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical group 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002641 lithium Chemical class 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Water Treatment By Sorption (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Secondary Cells (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013147845A JP2015020090A (ja) | 2013-07-16 | 2013-07-16 | リチウム吸着材料の製造方法およびリチウム吸着材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013147845A JP2015020090A (ja) | 2013-07-16 | 2013-07-16 | リチウム吸着材料の製造方法およびリチウム吸着材料 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017243512A Division JP6450446B2 (ja) | 2017-12-20 | 2017-12-20 | リチウム吸着材料の製造方法およびリチウム吸着材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015020090A true JP2015020090A (ja) | 2015-02-02 |
| JP2015020090A5 JP2015020090A5 (enrdf_load_stackoverflow) | 2016-08-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013147845A Pending JP2015020090A (ja) | 2013-07-16 | 2013-07-16 | リチウム吸着材料の製造方法およびリチウム吸着材料 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2015020090A (enrdf_load_stackoverflow) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101703635B1 (ko) | 2015-10-23 | 2017-02-08 | 인하대학교 산학협력단 | 리튬 회수를 위한 니켈산화물이 도입된 활성탄의 제조방법 |
| CN106861776A (zh) * | 2017-01-04 | 2017-06-20 | 潍坊学院 | 一种铁基锂离子提取材料的制备方法 |
| JP2019535503A (ja) * | 2016-11-14 | 2019-12-12 | ライラック ソリューションズ，インク． | コーティングされたイオン交換粒子を用いたリチウム抽出 |
| WO2020116607A1 (ja) * | 2018-12-07 | 2020-06-11 | 住友金属鉱山株式会社 | リチウム含有溶液の製造方法 |
| CN112678875A (zh) * | 2020-12-25 | 2021-04-20 | 中国科学院青海盐湖研究所 | 一种尖晶石型Li1.6Mn1.6O4微球粉体的制备方法 |
| US11253848B2 (en) | 2017-08-02 | 2022-02-22 | Lilac Solutions, Inc. | Lithium extraction with porous ion exchange beads |
| US11339457B2 (en) | 2020-01-09 | 2022-05-24 | Lilac Solutions, Inc. | Process for separating undesirable metals |
| US11358875B2 (en) | 2020-06-09 | 2022-06-14 | Lilac Solutions, Inc. | Lithium extraction in the presence of scalants |
| US11377362B2 (en) | 2020-11-20 | 2022-07-05 | Lilac Solutions, Inc. | Lithium production with volatile acid |
| US11865531B2 (en) | 2018-02-28 | 2024-01-09 | Lilac Solutions, Inc. | Ion exchange reactor with particle traps for lithium extraction |
| WO2024011796A1 (zh) * | 2022-07-13 | 2024-01-18 | 中国科学院青海盐湖研究所 | 一种锂吸附材料及其制备方法和应用 |
| US11986816B2 (en) | 2021-04-23 | 2024-05-21 | Lilac Solutions, Inc. | Ion exchange devices for lithium extraction |
| US12076662B2 (en) | 2022-03-28 | 2024-09-03 | Lilac Solutions, Inc. | Devices for efficient sorbent utilization in lithium extraction |
| US12162773B2 (en) | 2022-04-01 | 2024-12-10 | Lilac Solutions, Inc. | Extraction of lithium with chemical additives |
| US12374679B2 (en) | 2017-08-02 | 2025-07-29 | Lilac Solutions, Inc. | Ion exchange system for lithium extraction |
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|---|---|---|---|---|
| JP2000100433A (ja) * | 1998-09-25 | 2000-04-07 | Toyota Central Res & Dev Lab Inc | 酸化ニッケル被覆リチウムマンガン複合酸化物粉末とその製造方法 |
| JP2004142986A (ja) * | 2002-10-22 | 2004-05-20 | Ind Technol Res Inst | リチウム含有水溶液からのリチウム濃縮液の製造方法 |
-
2013
- 2013-07-16 JP JP2013147845A patent/JP2015020090A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000100433A (ja) * | 1998-09-25 | 2000-04-07 | Toyota Central Res & Dev Lab Inc | 酸化ニッケル被覆リチウムマンガン複合酸化物粉末とその製造方法 |
| JP2004142986A (ja) * | 2002-10-22 | 2004-05-20 | Ind Technol Res Inst | リチウム含有水溶液からのリチウム濃縮液の製造方法 |
Non-Patent Citations (2)
| Title |
|---|
| 公益財団法人ソルト・サイエンス研究財団, 平成２３年度助成研究報告集（Ｉ 理工学 農学・生物学編）, JPN6017015411, March 2013 (2013-03-01), pages 45 - 50, ISSN: 0003548162 * |
| 日本海水学会誌, vol. 66, no. 3, JPN6017015410, 25 May 2012 (2012-05-25), pages 145, ISSN: 0003548163 * |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101703635B1 (ko) | 2015-10-23 | 2017-02-08 | 인하대학교 산학협력단 | 리튬 회수를 위한 니켈산화물이 도입된 활성탄의 제조방법 |
| JP2023024975A (ja) * | 2016-11-14 | 2023-02-21 | ライラック ソリューションズ，インク． | コーティングされたイオン交換粒子を用いたリチウム抽出 |
| JP2019535503A (ja) * | 2016-11-14 | 2019-12-12 | ライラック ソリューションズ，インク． | コーティングされたイオン交換粒子を用いたリチウム抽出 |
| US11806641B2 (en) | 2016-11-14 | 2023-11-07 | Lilac Solutions, Inc. | Lithium extraction with coated ion exchange particles |
| CN106861776A (zh) * | 2017-01-04 | 2017-06-20 | 潍坊学院 | 一种铁基锂离子提取材料的制备方法 |
| US12374679B2 (en) | 2017-08-02 | 2025-07-29 | Lilac Solutions, Inc. | Ion exchange system for lithium extraction |
| US11253848B2 (en) | 2017-08-02 | 2022-02-22 | Lilac Solutions, Inc. | Lithium extraction with porous ion exchange beads |
| US11794182B2 (en) | 2017-08-02 | 2023-10-24 | Lilac Solutions, Inc. | Lithium extraction with porous ion exchange beads |
| US11975317B2 (en) | 2018-02-28 | 2024-05-07 | Lilac Solutions, Inc. | Ion exchange reactor with particle traps for lithium extraction |
| US11865531B2 (en) | 2018-02-28 | 2024-01-09 | Lilac Solutions, Inc. | Ion exchange reactor with particle traps for lithium extraction |
| JPWO2020116607A1 (enrdf_load_stackoverflow) * | 2018-12-07 | 2020-06-11 | ||
| JP7415948B2 (ja) | 2018-12-07 | 2024-01-17 | 住友金属鉱山株式会社 | リチウム含有溶液の製造方法 |
| WO2020116607A1 (ja) * | 2018-12-07 | 2020-06-11 | 住友金属鉱山株式会社 | リチウム含有溶液の製造方法 |
| US11339457B2 (en) | 2020-01-09 | 2022-05-24 | Lilac Solutions, Inc. | Process for separating undesirable metals |
| US11358875B2 (en) | 2020-06-09 | 2022-06-14 | Lilac Solutions, Inc. | Lithium extraction in the presence of scalants |
| US11964876B2 (en) | 2020-06-09 | 2024-04-23 | Lilac Solutions, Inc. | Lithium extraction in the presence of scalants |
| US11377362B2 (en) | 2020-11-20 | 2022-07-05 | Lilac Solutions, Inc. | Lithium production with volatile acid |
| CN112678875A (zh) * | 2020-12-25 | 2021-04-20 | 中国科学院青海盐湖研究所 | 一种尖晶石型Li1.6Mn1.6O4微球粉体的制备方法 |
| US11986816B2 (en) | 2021-04-23 | 2024-05-21 | Lilac Solutions, Inc. | Ion exchange devices for lithium extraction |
| US12076662B2 (en) | 2022-03-28 | 2024-09-03 | Lilac Solutions, Inc. | Devices for efficient sorbent utilization in lithium extraction |
| US12370468B2 (en) | 2022-03-28 | 2025-07-29 | Lilac Solutions, Inc. | Lithium extraction enhanced by an alternate phase |
| US12162773B2 (en) | 2022-04-01 | 2024-12-10 | Lilac Solutions, Inc. | Extraction of lithium with chemical additives |
| WO2024011796A1 (zh) * | 2022-07-13 | 2024-01-18 | 中国科学院青海盐湖研究所 | 一种锂吸附材料及其制备方法和应用 |
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