JP2014530956A - 高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 - Google Patents
高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 Download PDFInfo
- Publication number
- JP2014530956A JP2014530956A JP2014539069A JP2014539069A JP2014530956A JP 2014530956 A JP2014530956 A JP 2014530956A JP 2014539069 A JP2014539069 A JP 2014539069A JP 2014539069 A JP2014539069 A JP 2014539069A JP 2014530956 A JP2014530956 A JP 2014530956A
- Authority
- JP
- Japan
- Prior art keywords
- group
- catalyst system
- saturated
- main chain
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 Cyclic organosilicon compounds Chemical class 0.000 title claims abstract description 30
- 229920001155 polypropylene Polymers 0.000 title abstract description 16
- 239000011954 Ziegler–Natta catalyst Substances 0.000 title abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 125000001424 substituent group Chemical group 0.000 claims description 15
- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- 238000007334 copolymerization reaction Methods 0.000 claims description 12
- 229920006395 saturated elastomer Polymers 0.000 claims description 12
- 150000001336 alkenes Chemical class 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- 125000002723 alicyclic group Chemical group 0.000 claims description 10
- 125000004429 atom Chemical group 0.000 claims description 10
- 239000004711 α-olefin Substances 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 6
- 229920001577 copolymer Polymers 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 18
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 17
- 239000001257 hydrogen Substances 0.000 abstract description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 16
- 230000004044 response Effects 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 description 19
- 150000003961 organosilicon compounds Chemical class 0.000 description 15
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 11
- 238000005160 1H NMR spectroscopy Methods 0.000 description 10
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 10
- IUXYVKZUDNLISR-UHFFFAOYSA-N 2-(tert-butylamino)ethanol Chemical compound CC(C)(C)NCCO IUXYVKZUDNLISR-UHFFFAOYSA-N 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- PTHDBHDZSMGHKF-UHFFFAOYSA-N 2-piperidin-2-ylethanol Chemical group OCCC1CCCCN1 PTHDBHDZSMGHKF-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 6
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 6
- FBQWYRWINBMTAG-UHFFFAOYSA-N C1C[SiH2]NO1 Chemical compound C1C[SiH2]NO1 FBQWYRWINBMTAG-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 2
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 230000037048 polymerization activity Effects 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- MNPBBWITKFNCBR-UHFFFAOYSA-N 1-(tert-butylamino)butan-2-ol Chemical group CCC(O)CNC(C)(C)C MNPBBWITKFNCBR-UHFFFAOYSA-N 0.000 description 1
- AYNBYSNISOAOHW-UHFFFAOYSA-N 1-(tert-butylamino)propan-2-ol Chemical group CC(O)CNC(C)(C)C AYNBYSNISOAOHW-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000011021 bench scale process Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012230 colorless oil Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical group CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical group CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/284,602 US10654947B2 (en) | 2011-10-28 | 2011-10-28 | Cyclic organosilicon compounds as electron donors in Zeigler-Natta catalyst systems for producing propylene polymer having high melt-flowability |
| US13/284,602 | 2011-10-28 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015180274A Division JP2015227469A (ja) | 2011-10-28 | 2015-09-14 | 高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2014530956A true JP2014530956A (ja) | 2014-11-20 |
Family
ID=47146732
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014539069A Pending JP2014530956A (ja) | 2011-10-28 | 2012-10-26 | 高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 |
| JP2015180274A Pending JP2015227469A (ja) | 2011-10-28 | 2015-09-14 | 高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 |
| JP2016253030A Active JP6612212B2 (ja) | 2011-10-28 | 2016-12-27 | 高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015180274A Pending JP2015227469A (ja) | 2011-10-28 | 2015-09-14 | 高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 |
| JP2016253030A Active JP6612212B2 (ja) | 2011-10-28 | 2016-12-27 | 高い融解流動性を有するプロピレンポリマーを作製するためのチーグラー−ナッタ触媒システムにおける電子供与体としての環状有機ケイ素化合物 |
Country Status (5)
| Country | Link |
|---|---|
| US (3) | US10654947B2 (OSRAM) |
| EP (1) | EP2771374A2 (OSRAM) |
| JP (3) | JP2014530956A (OSRAM) |
| CN (2) | CN104114587A (OSRAM) |
| WO (1) | WO2013063464A2 (OSRAM) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2019010509A (es) * | 2017-03-06 | 2019-12-18 | Grace W R & Co | Donantes de electrones para la preparacion del precatalizador ziegler-natta y sistema catalizador para la polimerizacion de olefina. |
| US11117995B2 (en) | 2018-08-23 | 2021-09-14 | Formosa Plastics Corporation, U.S.A. | Process for preparing high melt strength polypropylene |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10265519A (ja) * | 1997-03-26 | 1998-10-06 | Mitsui Chem Inc | オレフィン重合用触媒成分、これを含むオレフィン重合用触媒、予備重合触媒、オレフィンの重合方法 |
| JP2000109514A (ja) * | 1998-10-05 | 2000-04-18 | Tokuyama Corp | オレフィン重合用触媒及びこれを用いるオレフィンの重合方法 |
| JP2008094764A (ja) * | 2006-10-12 | 2008-04-24 | Ube Ind Ltd | 環状アミノシラン、重合用触媒及び重合方法 |
| WO2010120331A1 (en) * | 2009-04-13 | 2010-10-21 | Formosa Plastics Corporation, U.S.A. | Cyclic organosilicon compounds as electron donors for polyolefin catalysts |
| JP2012523491A (ja) * | 2009-04-13 | 2012-10-04 | フオルモサ・プラステイクス・コーポレイシヨン・ユー・エス・エイ | ポリオレフィン触媒のための電子供与体としての二環式有機ケイ素化合物 |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| US4342856A (en) * | 1980-11-14 | 1982-08-03 | El Paso Polyolefins Company | Propylene polymerization process and product |
| IT1190682B (it) | 1982-02-12 | 1988-02-24 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine |
| IT1190681B (it) | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| US4560671A (en) | 1983-07-01 | 1985-12-24 | Union Carbide Corporation | Olefin polymerization catalysts adapted for gas phase processes |
| US4581342A (en) | 1984-11-26 | 1986-04-08 | Standard Oil Company (Indiana) | Supported olefin polymerization catalyst |
| US4657882A (en) | 1984-11-26 | 1987-04-14 | Amoco Corporation | Supported olefin polymerization catalyst produced from a magnesium alkyl/organophosphoryl complex |
| JP2566420B2 (ja) | 1987-08-08 | 1996-12-25 | 清水建設株式会社 | 軽量盛土構造およびその構築方法 |
| IT1241062B (it) | 1990-01-10 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPH0486298A (ja) | 1990-07-31 | 1992-03-18 | Mimaki Eng:Kk | プロッタ |
| JP2879391B2 (ja) | 1992-04-14 | 1999-04-05 | 昭和電工株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造法 |
| US5684173A (en) | 1994-04-28 | 1997-11-04 | Toho Titanium Co., Ltd. | Organosilicon compound and ziegler-natta catalyst containing the same |
| JP3443990B2 (ja) | 1994-11-22 | 2003-09-08 | 宇部興産株式会社 | α−オレフィンの重合方法 |
| FR2738826B1 (fr) * | 1995-09-20 | 1997-10-17 | Atochem Elf Sa | Alcoxysilacycloalcanes, leur procede de preparation et leur utilisation pour la polymerisation des olefines |
| DE19545498A1 (de) * | 1995-12-06 | 1997-06-12 | Basf Ag | Verbesserte Propylenpolymerisate |
| JP3280920B2 (ja) * | 1998-09-28 | 2002-05-13 | 松下電器産業株式会社 | 車載用音響再生方法および装置 |
| SG80673A1 (en) | 1999-02-25 | 2001-05-22 | Sumitomo Chemical Co | Catalyst component, catalyst for olefin polymerization, process for producing olefin polymer and use of organosilicon compound |
| JP2000336112A (ja) | 1999-06-01 | 2000-12-05 | Idemitsu Petrochem Co Ltd | 有機ケイ素化合物、オレフィン重合体製造用触媒およびオレフィン重合体の製造方法 |
| KR20010102300A (ko) | 1999-12-22 | 2001-11-15 | 간디 지오프레이 에이치. | 방향족 실란 화합물을 함유하는 알파-올레핀 중합 촉매계 |
| EP1188774A4 (en) | 2000-04-24 | 2005-07-06 | Idemitsu Kosan Co | CATALYST FOR MASS POLYMERIZATION, CATALYST FOR STEAM PHASE POLYMERIZATION, METHOD FOR POLYMERIZATION IN ITS USE, AND OLEFINE POLYMER OBTAINED THEREWITH |
| MXPA02000431A (es) * | 2001-01-12 | 2005-06-06 | Fina Technology | Produccion de resinas de polipropileno de flujo de fundicion ultra rapido. |
| JP2002265477A (ja) * | 2001-03-07 | 2002-09-18 | Japan Science & Technology Corp | カチオン性ケイ素化合物とその製造方法、及び重合開始剤としての用途 |
| US20030069372A1 (en) | 2001-10-09 | 2003-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst and process for preparing polyolefins with said catalyst |
| EP1480988A4 (en) | 2002-03-01 | 2006-03-29 | Univ Columbia | REAGENTS FOR ASYMMETRIC ALLYLATION, ALDOL, DOUBLE ALDOL AND ALLYLATION REACTIONS |
| DE60336822D1 (de) | 2002-07-22 | 2011-06-01 | Jsr Corp | Verfahren zur herstellung von kristallinem 1,2-polybutadien |
| WO2004016662A1 (ja) | 2002-08-19 | 2004-02-26 | Ube Industries, Ltd. | α−オレフィンの重合又は共重合に用いられるα−オレフィンの重合又は重合用触媒、その触媒成分及びその触媒を用いたα−オレフィン重合方法 |
| US7211534B2 (en) | 2003-02-12 | 2007-05-01 | Formosa Plastics Corporation, U.S.A. | Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same |
| US6992034B2 (en) | 2003-07-10 | 2006-01-31 | Formosa Plastics Corporation, U.S.A. | Catalyst component for olefin polymerization |
| US6956003B2 (en) | 2003-12-03 | 2005-10-18 | Formosa Plastics Corporation, U.S.A. | Catalyst system for ethylene (co)-polymerization |
| CN101245114A (zh) * | 2003-12-05 | 2008-08-20 | 中国石化扬子石油化工有限公司 | 丙烯超临界聚合催化剂体系及聚丙烯组合物的制备方法 |
| US7307036B2 (en) | 2004-07-22 | 2007-12-11 | Formosa Plastics Corporation U.S.A. | Highly active alpha-olefin polymerization catalyst |
| WO2006062901A2 (en) * | 2004-12-07 | 2006-06-15 | The Trustees Of Columbia University In The City Of New York | Silacycle compounds and methods of use thereof |
| US7399812B2 (en) | 2005-02-16 | 2008-07-15 | China Petroleum & Chemical Corporation | Silicon ether compounds and a method for the preparation thereof |
| KR100523474B1 (ko) | 2005-03-29 | 2005-10-24 | 삼성토탈 주식회사 | 매우 높은 용융흐름성을 갖는 프로필렌 중합체의 제조방법 |
| US7618913B2 (en) | 2006-08-31 | 2009-11-17 | Formosa Plastics Corporation, U.S.A. | Highly active alpha-olefin copolymerization catalyst system |
| US7718713B2 (en) | 2006-10-02 | 2010-05-18 | Formosa Plastics Corporation | Method of manufacturing the super-absorbent polymer (SAP) which is powdery, insoluble in water, and able to absorb water, blood and urine and has slight soluble things |
| US7651969B2 (en) | 2006-12-05 | 2010-01-26 | Formosa Plastics Corporation, U.S.A. | Catalyst system for producing ethylene (co) polymer with improved branch distribution |
| US7582712B1 (en) | 2008-05-09 | 2009-09-01 | Formosa Plastics Corporation, U.S.A. | Alpha-olefins polymerization catalyst |
-
2011
- 2011-10-28 US US13/284,602 patent/US10654947B2/en active Active
-
2012
- 2012-10-26 EP EP12783790.4A patent/EP2771374A2/en not_active Ceased
- 2012-10-26 WO PCT/US2012/062216 patent/WO2013063464A2/en not_active Ceased
- 2012-10-26 CN CN201280051801.XA patent/CN104114587A/zh active Pending
- 2012-10-26 JP JP2014539069A patent/JP2014530956A/ja active Pending
- 2012-10-26 CN CN201711368376.8A patent/CN108003260B/zh active Active
-
2015
- 2015-09-14 JP JP2015180274A patent/JP2015227469A/ja active Pending
-
2016
- 2016-12-27 JP JP2016253030A patent/JP6612212B2/ja active Active
-
2020
- 2020-05-15 US US16/875,043 patent/US11572425B2/en active Active
-
2022
- 2022-10-14 US US18/046,616 patent/US20230088145A1/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10265519A (ja) * | 1997-03-26 | 1998-10-06 | Mitsui Chem Inc | オレフィン重合用触媒成分、これを含むオレフィン重合用触媒、予備重合触媒、オレフィンの重合方法 |
| JP2000109514A (ja) * | 1998-10-05 | 2000-04-18 | Tokuyama Corp | オレフィン重合用触媒及びこれを用いるオレフィンの重合方法 |
| JP2008094764A (ja) * | 2006-10-12 | 2008-04-24 | Ube Ind Ltd | 環状アミノシラン、重合用触媒及び重合方法 |
| WO2010120331A1 (en) * | 2009-04-13 | 2010-10-21 | Formosa Plastics Corporation, U.S.A. | Cyclic organosilicon compounds as electron donors for polyolefin catalysts |
| JP2012523491A (ja) * | 2009-04-13 | 2012-10-04 | フオルモサ・プラステイクス・コーポレイシヨン・ユー・エス・エイ | ポリオレフィン触媒のための電子供与体としての二環式有機ケイ素化合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013063464A3 (en) | 2013-06-20 |
| JP2015227469A (ja) | 2015-12-17 |
| JP2017057418A (ja) | 2017-03-23 |
| JP6612212B2 (ja) | 2019-11-27 |
| CN108003260A (zh) | 2018-05-08 |
| EP2771374A2 (en) | 2014-09-03 |
| US20130109820A1 (en) | 2013-05-02 |
| CN104114587A (zh) | 2014-10-22 |
| CN108003260B (zh) | 2021-05-04 |
| US10654947B2 (en) | 2020-05-19 |
| US11572425B2 (en) | 2023-02-07 |
| WO2013063464A2 (en) | 2013-05-02 |
| US20200277414A1 (en) | 2020-09-03 |
| US20230088145A1 (en) | 2023-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9790291B2 (en) | Non-phthalate compounds as electron donors for polyolefin catalysts | |
| JP5918846B2 (ja) | オレフィン重合触媒、その製造方法及びその応用 | |
| JP5718314B2 (ja) | ポリオレフィン触媒のための電子供与体としての環式有機ケイ素化合物 | |
| TWI541259B (zh) | 烯烴類聚合用固體觸媒成分,烯烴類聚合用觸媒及烯烴類聚合體之製造方法 | |
| TW200408651A (en) | Solid catalyst component and catalyst for polymerization of olefins | |
| WO2012060361A1 (ja) | オレフィン類重合用固体触媒成分、オレフィン類重合用触媒およびオレフィン類重合体の製造方法 | |
| BRPI0615149A2 (pt) | componente de um catalisador para polimerização de olefina, catalisador para polimerização de olefinas, e, processo para a produção em polìmero de olefina | |
| US20230088145A1 (en) | Cyclic organosilicon compounds as electron donors in zeigler ?natta catalyst systems for producing propylene polymer having high melt-flowability | |
| PT773241E (pt) | Componente de um catalisador solido para a polimerizacao de olefinas e catalisador para a polimerizacao de olefinas | |
| JP2010030925A (ja) | アルコキシマグネシウムの合成方法、オレフィン類重合用固体触媒成分および触媒 | |
| US10364304B2 (en) | Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymer | |
| KR100361086B1 (ko) | 에틸렌중합용촉매의제조방법 | |
| JP2016164251A (ja) | 触媒プロセス改良およびそれによる重合 | |
| JP6900526B2 (ja) | オレフィン重合用の外部供与体 | |
| TW200835703A (en) | Process for manufacturing ethylene-propylene block copolymer | |
| BR112017003452B1 (pt) | Método para produzir um copolímero em bloco de propileno | |
| US9309332B2 (en) | Polymerization catalysts, methods and products | |
| JP5172205B2 (ja) | オレフィン類重合用固体触媒成分の製造方法 | |
| JP4079686B2 (ja) | オレフィン重合用固体触媒成分、オレフィン重合用触媒及びオレフィン重合体の製造方法 | |
| US20040072681A1 (en) | Solid catalyst component for olefin polymerization and catalyst | |
| JP3468611B2 (ja) | オレフィン類重合用固体触媒成分及び触媒 | |
| JP4879931B2 (ja) | オレフィン重合用固体触媒成分、オレフィン重合用触媒及びオレフィン重合体の製造方法 | |
| KR101624036B1 (ko) | 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법 | |
| JP2025130995A (ja) | オレフィン類重合用固体触媒成分、オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒およびオレフィン類重合体の製造方法 | |
| CN103374083A (zh) | 一种用于烯烃聚合反应的催化剂组分及其制备与应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140424 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150219 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150312 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150612 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150710 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150811 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150914 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20151026 |