JP2013543066A5 - - Google Patents
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- Publication number
- JP2013543066A5 JP2013543066A5 JP2013537748A JP2013537748A JP2013543066A5 JP 2013543066 A5 JP2013543066 A5 JP 2013543066A5 JP 2013537748 A JP2013537748 A JP 2013537748A JP 2013537748 A JP2013537748 A JP 2013537748A JP 2013543066 A5 JP2013543066 A5 JP 2013543066A5
- Authority
- JP
- Japan
- Prior art keywords
- coating composition
- meth
- component
- acrylamide
- cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 claims 16
- 239000000178 monomer Substances 0.000 claims 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 6
- -1 N, N-dimethylaminopropyl Chemical group 0.000 claims 5
- 229920003118 cationic copolymer Polymers 0.000 claims 4
- 125000002091 cationic group Chemical group 0.000 claims 4
- 238000004132 cross linking Methods 0.000 claims 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 229920002472 Starch Polymers 0.000 claims 3
- 150000001336 alkenes Chemical group 0.000 claims 3
- 229920006317 cationic polymer Polymers 0.000 claims 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 2
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims 2
- 235000019698 starch Nutrition 0.000 claims 2
- 239000008107 starch Substances 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 229920002261 Corn starch Polymers 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 240000003183 Manihot esculenta Species 0.000 claims 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims 1
- 229920000881 Modified starch Polymers 0.000 claims 1
- 239000004368 Modified starch Substances 0.000 claims 1
- MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 239000008120 corn starch Substances 0.000 claims 1
- 229940099112 cornstarch Drugs 0.000 claims 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 1
- 235000019426 modified starch Nutrition 0.000 claims 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims 1
- GBCKRQRXNXQQPW-UHFFFAOYSA-N n,n-dimethylprop-2-en-1-amine Chemical compound CN(C)CC=C GBCKRQRXNXQQPW-UHFFFAOYSA-N 0.000 claims 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 claims 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 claims 1
- 229930014626 natural product Natural products 0.000 claims 1
- 229920001592 potato starch Polymers 0.000 claims 1
- 229940116317 potato starch Drugs 0.000 claims 1
- QYUMESOEHIJKHV-UHFFFAOYSA-M prop-2-enamide;trimethyl(propyl)azanium;chloride Chemical compound [Cl-].NC(=O)C=C.CCC[N+](C)(C)C QYUMESOEHIJKHV-UHFFFAOYSA-M 0.000 claims 1
- 229940100486 rice starch Drugs 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 125000000542 sulfonic acid group Chemical group 0.000 claims 1
- VZTGWJFIMGVKSN-UHFFFAOYSA-O trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium Chemical compound CC(=C)C(=O)NCCC[N+](C)(C)C VZTGWJFIMGVKSN-UHFFFAOYSA-O 0.000 claims 1
- 229940117958 vinyl acetate Drugs 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000004034 viscosity adjusting agent Substances 0.000 claims 1
- 229940100445 wheat starch Drugs 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 6
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- JNDVNJWCRZQGFQ-UHFFFAOYSA-N 2-methyl-N,N-bis(methylamino)hex-2-enamide Chemical compound CCCC=C(C)C(=O)N(NC)NC JNDVNJWCRZQGFQ-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- HMLSBRLVTDLLOI-UHFFFAOYSA-N 1-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)C(C)OC(=O)C(C)=C HMLSBRLVTDLLOI-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41048310P | 2010-11-05 | 2010-11-05 | |
| US61/410,483 | 2010-11-05 | ||
| PCT/US2011/058620 WO2012061305A1 (en) | 2010-11-05 | 2011-10-31 | Surface application of polymers to improve paper strength |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013543066A JP2013543066A (ja) | 2013-11-28 |
| JP2013543066A5 true JP2013543066A5 (enExample) | 2015-11-12 |
| JP5893041B2 JP5893041B2 (ja) | 2016-03-23 |
Family
ID=44947252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013537748A Expired - Fee Related JP5893041B2 (ja) | 2010-11-05 | 2011-10-31 | 紙強度を向上させるためのポリマーの表面塗布剤 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US8900412B2 (enExample) |
| EP (1) | EP2635645B1 (enExample) |
| JP (1) | JP5893041B2 (enExample) |
| KR (2) | KR101946221B1 (enExample) |
| CN (1) | CN103201348B (enExample) |
| AU (1) | AU2011323632B2 (enExample) |
| CA (1) | CA2813996C (enExample) |
| ES (1) | ES2641302T3 (enExample) |
| MX (1) | MX343488B (enExample) |
| PL (1) | PL2635645T3 (enExample) |
| PT (1) | PT2635645T (enExample) |
| TW (1) | TWI575135B (enExample) |
| WO (1) | WO2012061305A1 (enExample) |
| ZA (1) | ZA201304082B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US8999111B2 (en) | 2012-12-28 | 2015-04-07 | Ecolab Usa Inc. | Method of increasing paper surface strength by using acrylic acid/acrylamide copolymer in a size press formulation containing starch |
| US9567708B2 (en) | 2014-01-16 | 2017-02-14 | Ecolab Usa Inc. | Wet end chemicals for dry end strength in paper |
| US9920482B2 (en) | 2014-10-06 | 2018-03-20 | Ecolab Usa Inc. | Method of increasing paper strength |
| US9702086B2 (en) * | 2014-10-06 | 2017-07-11 | Ecolab Usa Inc. | Method of increasing paper strength using an amine containing polymer composition |
| FI128576B (en) * | 2015-12-21 | 2020-08-14 | Kemira Oyj | A method for producing a sizing agent composition, a sizing agent composition and use thereof |
| CN109072558A (zh) | 2016-05-13 | 2018-12-21 | 艺康美国股份有限公司 | 薄纸粉尘减少 |
| US11407931B2 (en) | 2016-10-12 | 2022-08-09 | Schlumberger Technology Corporation | Crosslinking of cellulose fibers |
| US11180627B2 (en) | 2017-01-11 | 2021-11-23 | The Regents Of The University Of Colorado, A Body Corporate | Cellulose enabled orientationally ordered flexible gels |
| US11028538B2 (en) | 2019-02-28 | 2021-06-08 | Solenis Technologies, L.P. | Composition and method for increasing wet and dry paper strength |
| KR102776160B1 (ko) * | 2019-12-02 | 2025-03-07 | (주)엘엑스하우시스 | 표면 코팅용 조성물을 이용한 적층체 |
| CN116710612B (zh) | 2020-12-04 | 2025-10-10 | 旭硝子化学美国有限公司 | 处理制品，制造处理制品的方法，和用于制造处理制品的分散体 |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2721140A (en) | 1952-09-19 | 1955-10-18 | Hercules Powder Co Ltd | Paper of high wet strength and process therefor |
| US3597374A (en) * | 1966-09-28 | 1971-08-03 | Nalco Chemical Co | Coating process for fibrous substrates |
| US3542707A (en) * | 1968-03-20 | 1970-11-24 | Cpc International Inc | Film-formers comprising starch,cationic polymer and aliphatic dialdehyde |
| JPS5323350B2 (enExample) * | 1972-06-03 | 1978-07-14 | ||
| US4191610A (en) | 1975-04-09 | 1980-03-04 | Prior Eric S | Upgrading waste paper by treatment with sulfite waste liquor |
| DE3128478A1 (de) | 1981-07-18 | 1983-02-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von linearen, basischen polymerisaten |
| DE3706525A1 (de) * | 1987-02-28 | 1988-09-08 | Basf Ag | Verfahren zur herstellung von papier, pappe und karton mit hoher trockenfestigkeit |
| DE68910946T2 (de) | 1988-12-09 | 1994-04-28 | Seiko Epson Corp | Punktnadeldrucker mit Drucknadelantrieb und Verfahren zu seiner Herstellung. |
| US5242545A (en) | 1989-02-27 | 1993-09-07 | Union Camp Corporation | Starch treated high crush linerboard and medium |
| US5281307A (en) | 1993-01-13 | 1994-01-25 | Air Products And Chemicals, Inc. | Crosslinked vinyl alcohol/vinylamine copolymers for dry end paper addition |
| JPH08269890A (ja) | 1995-03-30 | 1996-10-15 | Nippon P M C Kk | 製紙用添加剤及び製紙方法 |
| EP0743172B1 (en) | 1995-05-18 | 1999-08-04 | Fort James Corporation | Novel creping adhesive formulations, method of creping and creped fibrous web |
| JP2939971B2 (ja) * | 1995-06-23 | 1999-08-25 | 日本製紙株式会社 | 吸水性を改良した印刷用紙、新聞印刷用紙、並びにその製造方法 |
| JP2877187B2 (ja) * | 1995-06-28 | 1999-03-31 | 岡田産業株式会社 | 化粧型枠パネル |
| US6034181A (en) * | 1995-08-25 | 2000-03-07 | Cytec Technology Corp. | Paper or board treating composition of carboxylated surface size and polyacrylamide |
| DE19607674A1 (de) | 1996-02-29 | 1997-09-04 | Basf Ag | Verwendung von hydrolysierten Polymerisaten von N-Vinylcarbonsäureamiden als Mittel zur Erhöhung der Trockenfestigkeit von Papier, Pappe und Karton |
| EP0818322B1 (en) * | 1996-07-12 | 1999-10-06 | Oji Paper Company Limited | Ink jet recording sheet having a gloss layer |
| GB9624031D0 (en) * | 1996-11-19 | 1997-01-08 | Allied Colloids Ltd | Manufacture of paper |
| DE19713755A1 (de) | 1997-04-04 | 1998-10-08 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton mit hoher Trockenfestigkeit |
| US6294645B1 (en) | 1997-07-25 | 2001-09-25 | Hercules Incorporated | Dry-strength system |
| JP4140080B2 (ja) * | 1998-04-30 | 2008-08-27 | 星光Ｐｍｃ株式会社 | 中性紙及びその製造方法 |
| JP2002514674A (ja) * | 1998-05-12 | 2002-05-21 | ハーキュリーズ・インコーポレイテッド | イオン性ポリマーおよび粘度プロモーターを含有する水系 |
| US6303000B1 (en) | 1998-08-31 | 2001-10-16 | Omnova Solutions Inc. | Paper making process utilizing a reactive cationic starch composition |
| US6303723B1 (en) | 1998-10-28 | 2001-10-16 | Penn State Research Foundation | Process for polymerization of allylic compounds |
| FR2791688B1 (fr) | 1999-03-29 | 2005-03-18 | Snf Sa | Nouveaux procedes de synthese d'agents floculants et coagulants de type polyvinylamine pva, nouveaux agents obtenus, et leurs utilisations et papiers ameliores ainsi obtenus. |
| US6482883B1 (en) * | 2000-05-10 | 2002-11-19 | Kanzaki Specialty Papers, Inc. | Ink jet recording material demonstrating a balance of properties including improved imaging performance and good water resistance |
| US6710175B2 (en) * | 2001-08-31 | 2004-03-23 | Kevin Ray Anderson | Compositions suitable as additives in the paper industry, preparation; use; and, paper comprising such |
| US6939443B2 (en) | 2002-06-19 | 2005-09-06 | Lanxess Corporation | Anionic functional promoter and charge control agent |
| WO2004009904A1 (ja) * | 2002-07-19 | 2004-01-29 | Kao Corporation | 紙質向上剤 |
| US6979481B2 (en) * | 2002-08-19 | 2005-12-27 | Mohawk Paper Mills, Inc. | Microporous photo glossy inkjet recording media |
| ATE478196T1 (de) | 2002-09-17 | 2010-09-15 | Int Paper Co | Papiere mit borhaltiger verbindung und verfahren zu ihrer herstellung |
| US20050022956A1 (en) * | 2003-07-29 | 2005-02-03 | Georgia-Pacific Resins Corporation | Anionic-cationic polymer blend for surface size |
| US20050161182A1 (en) | 2003-11-21 | 2005-07-28 | Bercen Incorporated | Paper making process and starch compositions comprising a crosslinking agent for use in same |
| JP4605520B2 (ja) * | 2004-03-02 | 2011-01-05 | ハリマ化成株式会社 | カチオン性表面サイズ剤及び当該サイズ剤を用いた紙 |
| US7732525B2 (en) * | 2004-05-20 | 2010-06-08 | Ciba Specialty Chemicals Water Treatments Limited | Polymers for paper and paperboard coatings |
| US20050287385A1 (en) | 2004-06-28 | 2005-12-29 | Quick Thomas H | Paperboard material having increased strength and method for making same |
| HU226097B1 (en) | 2004-09-08 | 2008-04-28 | Welltech Kft | Method for surface treating of corrugated base papers |
| WO2006132872A1 (en) * | 2005-06-03 | 2006-12-14 | The Procter & Gamble Company | Fabric care compositions |
| CA2647741C (en) * | 2006-03-30 | 2012-05-29 | Harima Chemicals, Inc. | Cationic surface sizing agent and paper coated with the same |
| US20100273016A1 (en) * | 2007-10-12 | 2010-10-28 | Kao Corporation | Surface treatment agent for paper |
| PT2496651E (pt) * | 2009-11-06 | 2015-08-24 | Solenis Technologies Cayman Lp | Aplicação superficial de polímeros e misturas de polímeros para melhorar a resistência de um papel |
| JP2011212955A (ja) * | 2010-03-31 | 2011-10-27 | Nippon Paper Industries Co Ltd | インクジェット記録用紙 |
-
2011
- 2011-10-31 CN CN201180053093.9A patent/CN103201348B/zh active Active
- 2011-10-31 WO PCT/US2011/058620 patent/WO2012061305A1/en not_active Ceased
- 2011-10-31 AU AU2011323632A patent/AU2011323632B2/en not_active Ceased
- 2011-10-31 KR KR1020187006119A patent/KR101946221B1/ko active Active
- 2011-10-31 JP JP2013537748A patent/JP5893041B2/ja not_active Expired - Fee Related
- 2011-10-31 PL PL11782337T patent/PL2635645T3/pl unknown
- 2011-10-31 KR KR1020137014321A patent/KR101836210B1/ko not_active Expired - Fee Related
- 2011-10-31 MX MX2013004106A patent/MX343488B/es active IP Right Grant
- 2011-10-31 EP EP11782337.7A patent/EP2635645B1/en active Active
- 2011-10-31 ES ES11782337.7T patent/ES2641302T3/es active Active
- 2011-10-31 CA CA2813996A patent/CA2813996C/en active Active
- 2011-10-31 US US13/285,382 patent/US8900412B2/en active Active
- 2011-10-31 PT PT117823377T patent/PT2635645T/pt unknown
- 2011-11-04 TW TW100140450A patent/TWI575135B/zh not_active IP Right Cessation
-
2013
- 2013-06-04 ZA ZA2013/04082A patent/ZA201304082B/en unknown
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