ES2641302T3 - Aplicación superficial de polímeros para mejorar la resistencia del papel - Google Patents

Aplicación superficial de polímeros para mejorar la resistencia del papel Download PDF

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Publication number
ES2641302T3
ES2641302T3 ES11782337.7T ES11782337T ES2641302T3 ES 2641302 T3 ES2641302 T3 ES 2641302T3 ES 11782337 T ES11782337 T ES 11782337T ES 2641302 T3 ES2641302 T3 ES 2641302T3
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meth
acrylamide
acrylate
component
starch
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Sachin Borkar
Marc C. Putnam
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Solenis Technologies Cayman LP
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Solenis Technologies Cayman LP
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/24—Homopolymers or copolymers of amides or imides
    • C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/64—Paper recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paper (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Composición de recubrimiento que comprende el componente a) copolímero catiónico que comprende de 0,01 a 100 por ciento molar de monómero catiónico, en la que dicho copolímero catiónico se prepara a partir de un monómero seleccionado del grupo que consiste en (met)acrilato de dimetilaminoetilo, (met)acrilato de dietilaminoetilo, (met)acrilato de dimetilaminopropilo, (met)acrilato de dietilaminopropilo, (met)acrilamida de N,N-dimetilaminopropilo, cloruro de acrilamidapropiltrimetilamonio, cloruro de trimetilamoniopropilmetacrilamida, dialquilalilamina, dialilamina y alilamina, y un comonómero seleccionado del grupo que consiste en acrilamida, metacrilamida, (met)acrilamida de N-metilo, (met)acrilamida de N-etilo, (met)acrilamida de N,N-dimetilo, (met)acrilamida de N-isopropilo, ácido acrílico, N-vinilformamida, N-vinilacetamida y vinil-N-ftalimida, el componente b) almidón, o bien nativo o bien derivatizado, y opcionalmente, el componente c) un producto químico modificador de la viscosidad; en la que la composición carece de precipitados, coagulados y geles.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
*: Comparativo, no según invención
Ejemplo 4 – Comparativo -No según invención
5 Se preparó una mezcla de poliacrilamida catiónica y polivinilamina o polivinilamina modificada (aditivos de rendimiento del papel Hercobond® 6000, disponibles de Ashland Incorporated) mezclando las dos disoluciones de polímero. En un experimento típico, se cargó un tarro de 4 oz con 100 g disolución de poliacrilamida catiónica (PAM) tal como se prepara siguiendo el protocolo del ejemplo 1, a esta se le añadió este producto Hercobond® 6000 al 5%
10 en peso (base sólida total). Se agitó la mezcla de polímeros en un agitador Lab Line® Orbit Environ durante 1 hora a 25ºC.
TABLA 4: Mezcla de poliacrilamida catiónica con polivinilamina
Ejemplos
Denominación PAM Polivinilamina
4-1
Ejemplo 1-4 Hercobond® 6350 al 2,5% en peso
4-2
Ejemplo 1-4 Hercobond® 6350 al 5,0% en peso
15 Ejemplo 5
Usando el método de aplicación al papel anteriormente descrito, se evaluaron las poliacrilamidas catiónicas para determinar el efecto sobre la resistencia de la hoja. Todas las series, excepto la 5-1, contenían el 3% en peso de
20 ExcelSize 15 en la disolución de la prensa encoladora. Los copolímeros que contienen o bien dialilamina o bien dimetilaminopropilmetacrilamida proporcionan resistencia mejorada cuando se aplican a la superficie de hojas de soporte del cartón de cobertura reciclado. Las concentraciones de los aditivos indicados a continuación son en base seca del papel (Aditivo seco sobre peso seco del papel, “d/d”).
25 TABLA 5: Efecto de aditivos a base de acrilamida sobre la resistencia en seco del cartón de cobertura reciclado. La hoja de soporte fabricada usando cartulina ondulada vieja china, peso base = 100 g/m2, espesor 7,4 mil, ExcelSize 15 = almidón de tapioca oxidado
Ejemplos
Aditivo % de aditivo (d/d) Datos de resistencia
Mullen (lb/in2)
RCT (lbf/6 in.)
5-1
Sin almidón - 19,0 21,3
5-2
Sólo almidón - 24,2 29,1
5-3
2-2 0,50 28,2 30,3
5-4
2-2 1,00 33,0 35,5
5-5
1-1 0,50 26,6 28,6
5-6
1-1 1,00 32,0 36,4
5-7
1-3 0,30 27,6 34,7
30 Ejemplo 6
Usando el método de aplicación al papel anteriormente descrito, se evaluaron las poliacrilamidas catiónicas para determinar el efecto sobre la resistencia de la hoja. Todas las series, excepto la 6-1, contenían el 2% en peso de ExcelSize C155 en la disolución de la prensa encoladora. Los copolímeros que contienen metacrilato de N,N
35 dimetilaminoetilo demuestran algo menos de mejora de la resistencia eficaz en comparación con copolímeros que contienen o bien dialilamina o bien dimetilaminopropilmetacrilamida. En el caso de poli(acrilamida-covinilformamida), la eficacia mejora cuanto más hidrolizado está el polímero. Las concentraciones de los aditivos indicados a continuación son en base seca del papel. (Aditivo seco sobre peso seco de papel)
40 TABLA 6: Efecto de aditivos a base de acrilamida sobre la resistencia en seco del cartón de cobertura reciclado. La hoja de soporte fabricada usando cartulina ondulada vieja americana, peso base = 198 g/m2, espesor = 11,5 mil, ExcelSize C155 = almidón de tapioca oxidado y ligeramente catiónico.
Ejemplos
Aditivo % de aditivo (d/d) Datos de resistencia
Mullen (lb/in2)
RCT (lbf/6 in.)
6-1
Sin almidón - 58,1 84,4
6-2
Sólo almidón - 69,8 98,7
6-3
1-1 0,5 77,6 105,8
6-4
1-1 1,0 81,6 115,4
6-5
1-5 0,5 68,4 106,9
6-6
1-5 1,0 73,4 109,2
6-7
1-6 0,5 74,6 107,4
6-8
1-6 1,0 74,0 112,6
8
6-9
2-1 0,5 73,6 107,1
6-10
2-1 1,0 80,4 108,6
Comparativo 6-11
3-1 0,5 66,0 98,0
Comparativo 6-12
3-1 1,0 72,4 106,3
6-13
3-2 0,5 71,6 105,9
6-14
3-2 1,0 71,1 109,4
6-15
3-3 0,5 73,7 105,2
6-16
3-3 1,0 76,0 107,9
6-17
3-4 0,5 73,4 109,6
6-18
3-4 1,0 77,9 109,0
Ejemplo 7
Usando el método de aplicación al papel anteriormente descrito, se evaluaron las poliacrilamidas catiónicas para
5 determinar el efecto sobre la resistencia de la hoja usando cartulina ondulada vieja americana, una hoja de soporte fuerte. Todas las series, excepto la 7-1, contenían el 2% en peso de almidón ExcelSize 15 en la disolución de la prensa encoladora. El uso de aditivo catiónico mostró mejora de la resistencia, sin embargo, la mejora de la resistencia global observada es menor en comparación con la observada en cartulina ondulada vieja china. Las concentraciones de los aditivos indicados a continuación son en base seca en el papel.
10 TABLA 7 Efecto de aditivos a base de acrilamida sobre la resistencia en seco del cartón de cobertura reciclado. La hoja de soporte fabricada usando cartulina ondulada vieja americana, peso base = 198 g/m2, espesor = 11,5 mil, ExcelSize 15 = almidón de tapioca oxidado
Ejemplos
Aditivo % de aditivo (d/d) Datos de resistencia
Mullen (lb/in2)
RCT (lbf/6 in.)
7-1
Sin almidón - 58,1 97,8
7-2
Sólo almidón - 76,1 123,3
7-3
2-2 0,5 84,4 119,9
7-4
2-2 1,0 82,4 125,4
7-5
1-6 1,0 76,6 126,8
7-6
1-1 0,25 78,0 131,3
7-7
1-1 0,5 81,8 126,6
9

Claims (1)

  1. imagen1
ES11782337.7T 2010-11-05 2011-10-31 Aplicación superficial de polímeros para mejorar la resistencia del papel Active ES2641302T3 (es)

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US41048310P 2010-11-05 2010-11-05
US410483P 2010-11-05
PCT/US2011/058620 WO2012061305A1 (en) 2010-11-05 2011-10-31 Surface application of polymers to improve paper strength

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EP (1) EP2635645B1 (es)
JP (1) JP5893041B2 (es)
KR (2) KR101836210B1 (es)
CN (1) CN103201348B (es)
AU (1) AU2011323632B2 (es)
CA (1) CA2813996C (es)
ES (1) ES2641302T3 (es)
MX (1) MX343488B (es)
PL (1) PL2635645T3 (es)
PT (1) PT2635645T (es)
TW (1) TWI575135B (es)
WO (1) WO2012061305A1 (es)
ZA (1) ZA201304082B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8088250B2 (en) 2008-11-26 2012-01-03 Nalco Company Method of increasing filler content in papermaking
US8999111B2 (en) * 2012-12-28 2015-04-07 Ecolab Usa Inc. Method of increasing paper surface strength by using acrylic acid/acrylamide copolymer in a size press formulation containing starch
US9567708B2 (en) 2014-01-16 2017-02-14 Ecolab Usa Inc. Wet end chemicals for dry end strength in paper
US9702086B2 (en) * 2014-10-06 2017-07-11 Ecolab Usa Inc. Method of increasing paper strength using an amine containing polymer composition
US9920482B2 (en) 2014-10-06 2018-03-20 Ecolab Usa Inc. Method of increasing paper strength
FI128576B (en) * 2015-12-21 2020-08-14 Kemira Oyj Process for preparing an adhesive composition, adhesive composition and use thereof
CN109072558A (zh) 2016-05-13 2018-12-21 艺康美国股份有限公司 薄纸粉尘减少
US11407931B2 (en) 2016-10-12 2022-08-09 Schlumberger Technology Corporation Crosslinking of cellulose fibers
US11180627B2 (en) * 2017-01-11 2021-11-23 The Regents Of The University Of Colorado, A Body Corporate Cellulose enabled orientationally ordered flexible gels
US11028538B2 (en) 2019-02-28 2021-06-08 Solenis Technologies, L.P. Composition and method for increasing wet and dry paper strength

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2721140A (en) 1952-09-19 1955-10-18 Hercules Powder Co Ltd Paper of high wet strength and process therefor
US3597374A (en) * 1966-09-28 1971-08-03 Nalco Chemical Co Coating process for fibrous substrates
US3542707A (en) * 1968-03-20 1970-11-24 Cpc International Inc Film-formers comprising starch,cationic polymer and aliphatic dialdehyde
JPS5323350B2 (es) * 1972-06-03 1978-07-14
US4191610A (en) 1975-04-09 1980-03-04 Prior Eric S Upgrading waste paper by treatment with sulfite waste liquor
DE3128478A1 (de) 1981-07-18 1983-02-03 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von linearen, basischen polymerisaten
DE3706525A1 (de) * 1987-02-28 1988-09-08 Basf Ag Verfahren zur herstellung von papier, pappe und karton mit hoher trockenfestigkeit
EP0372557B1 (en) 1988-12-09 1993-11-24 Seiko Epson Corporation Wire-dot printer having printing wire driving device and manufacturing method thereof
US5242545A (en) 1989-02-27 1993-09-07 Union Camp Corporation Starch treated high crush linerboard and medium
US5281307A (en) 1993-01-13 1994-01-25 Air Products And Chemicals, Inc. Crosslinked vinyl alcohol/vinylamine copolymers for dry end paper addition
JPH08269890A (ja) 1995-03-30 1996-10-15 Nippon P M C Kk 製紙用添加剤及び製紙方法
EP0743172B1 (en) 1995-05-18 1999-08-04 Fort James Corporation Novel creping adhesive formulations, method of creping and creped fibrous web
JP2939971B2 (ja) * 1995-06-23 1999-08-25 日本製紙株式会社 吸水性を改良した印刷用紙、新聞印刷用紙、並びにその製造方法
JP2877187B2 (ja) * 1995-06-28 1999-03-31 岡田産業株式会社 化粧型枠パネル
US5824190A (en) * 1995-08-25 1998-10-20 Cytec Technology Corp. Methods and agents for improving paper printability and strength
DE19607674A1 (de) 1996-02-29 1997-09-04 Basf Ag Verwendung von hydrolysierten Polymerisaten von N-Vinylcarbonsäureamiden als Mittel zur Erhöhung der Trockenfestigkeit von Papier, Pappe und Karton
EP0818322B1 (en) * 1996-07-12 1999-10-06 Oji Paper Company Limited Ink jet recording sheet having a gloss layer
GB9624031D0 (en) * 1996-11-19 1997-01-08 Allied Colloids Ltd Manufacture of paper
DE19713755A1 (de) 1997-04-04 1998-10-08 Basf Ag Verfahren zur Herstellung von Papier, Pappe und Karton mit hoher Trockenfestigkeit
US6294645B1 (en) 1997-07-25 2001-09-25 Hercules Incorporated Dry-strength system
JP4140080B2 (ja) * 1998-04-30 2008-08-27 星光Ｐｍｃ株式会社 中性紙及びその製造方法
US6359040B1 (en) * 1998-05-12 2002-03-19 Hercules Incorporated Aqueous systems comprising an ionic polymer and a viscosity promoter, processes for their preparation, and uses thereof
US6303000B1 (en) 1998-08-31 2001-10-16 Omnova Solutions Inc. Paper making process utilizing a reactive cationic starch composition
US6303723B1 (en) 1998-10-28 2001-10-16 Penn State Research Foundation Process for polymerization of allylic compounds
FR2791688B1 (fr) 1999-03-29 2005-03-18 Snf Sa Nouveaux procedes de synthese d'agents floculants et coagulants de type polyvinylamine pva, nouveaux agents obtenus, et leurs utilisations et papiers ameliores ainsi obtenus.
US6482883B1 (en) * 2000-05-10 2002-11-19 Kanzaki Specialty Papers, Inc. Ink jet recording material demonstrating a balance of properties including improved imaging performance and good water resistance
US6710175B2 (en) * 2001-08-31 2004-03-23 Kevin Ray Anderson Compositions suitable as additives in the paper industry, preparation; use; and, paper comprising such
US6939443B2 (en) 2002-06-19 2005-09-06 Lanxess Corporation Anionic functional promoter and charge control agent
CN100552132C (zh) * 2002-07-19 2009-10-21 花王株式会社 纸质改进剂
US6979481B2 (en) * 2002-08-19 2005-12-27 Mohawk Paper Mills, Inc. Microporous photo glossy inkjet recording media
ATE478196T1 (de) 2002-09-17 2010-09-15 Int Paper Co Papiere mit borhaltiger verbindung und verfahren zu ihrer herstellung
US20050022956A1 (en) * 2003-07-29 2005-02-03 Georgia-Pacific Resins Corporation Anionic-cationic polymer blend for surface size
WO2005052256A2 (en) 2003-11-21 2005-06-09 Bercen Incorporated Paper making process and starch compositions comprising a crosslinking agent for use in same
JP4605520B2 (ja) * 2004-03-02 2011-01-05 ハリマ化成株式会社 カチオン性表面サイズ剤及び当該サイズ剤を用いた紙
US7732525B2 (en) * 2004-05-20 2010-06-08 Ciba Specialty Chemicals Water Treatments Limited Polymers for paper and paperboard coatings
US20050287385A1 (en) 2004-06-28 2005-12-29 Quick Thomas H Paperboard material having increased strength and method for making same
HU226097B1 (en) 2004-09-08 2008-04-28 Welltech Kft Method for surface treating of corrugated base papers
WO2006132872A1 (en) * 2005-06-03 2006-12-14 The Procter & Gamble Company Fabric care compositions
CA2647741C (en) * 2006-03-30 2012-05-29 Harima Chemicals, Inc. Cationic surface sizing agent and paper coated with the same
US20100273016A1 (en) * 2007-10-12 2010-10-28 Kao Corporation Surface treatment agent for paper
CN102648254B (zh) * 2009-11-06 2014-09-10 赫尔克里士公司 用于改善纸张强度的聚合物及聚合物混合物的表面涂敷
JP2011212955A (ja) * 2010-03-31 2011-10-27 Nippon Paper Industries Co Ltd インクジェット記録用紙

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PL2635645T3 (pl) 2017-11-30
EP2635645A1 (en) 2013-09-11
AU2011323632B2 (en) 2016-03-10
CA2813996C (en) 2015-01-27
MX2013004106A (es) 2013-07-17
TWI575135B (zh) 2017-03-21
KR20180027633A (ko) 2018-03-14
KR20130117804A (ko) 2013-10-28
ZA201304082B (en) 2014-12-23
WO2012061305A1 (en) 2012-05-10
EP2635645B1 (en) 2017-07-05
CA2813996A1 (en) 2012-05-10
KR101836210B1 (ko) 2018-03-09
CN103201348A (zh) 2013-07-10
US8900412B2 (en) 2014-12-02
KR101946221B1 (ko) 2019-02-08
PT2635645T (pt) 2017-08-11
JP2013543066A (ja) 2013-11-28
JP5893041B2 (ja) 2016-03-23
MX343488B (es) 2016-11-08
TW201229358A (en) 2012-07-16
AU2011323632A1 (en) 2013-06-27
US20120111517A1 (en) 2012-05-10
CN103201348B (zh) 2017-02-15

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