JP5893041B2 - 紙強度を向上させるためのポリマーの表面塗布剤 - Google Patents
紙強度を向上させるためのポリマーの表面塗布剤 Download PDFInfo
- Publication number
- JP5893041B2 JP5893041B2 JP2013537748A JP2013537748A JP5893041B2 JP 5893041 B2 JP5893041 B2 JP 5893041B2 JP 2013537748 A JP2013537748 A JP 2013537748A JP 2013537748 A JP2013537748 A JP 2013537748A JP 5893041 B2 JP5893041 B2 JP 5893041B2
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- Prior art keywords
- component
- meth
- coating composition
- paper
- acrylamide
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
- C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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| US61/410,483 | 2010-11-05 | ||
| PCT/US2011/058620 WO2012061305A1 (en) | 2010-11-05 | 2011-10-31 | Surface application of polymers to improve paper strength |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US8999111B2 (en) * | 2012-12-28 | 2015-04-07 | Ecolab Usa Inc. | Method of increasing paper surface strength by using acrylic acid/acrylamide copolymer in a size press formulation containing starch |
| US9567708B2 (en) | 2014-01-16 | 2017-02-14 | Ecolab Usa Inc. | Wet end chemicals for dry end strength in paper |
| US9920482B2 (en) | 2014-10-06 | 2018-03-20 | Ecolab Usa Inc. | Method of increasing paper strength |
| US9702086B2 (en) * | 2014-10-06 | 2017-07-11 | Ecolab Usa Inc. | Method of increasing paper strength using an amine containing polymer composition |
| FI128576B (en) * | 2015-12-21 | 2020-08-14 | Kemira Oyj | A method for producing a sizing agent composition, a sizing agent composition and use thereof |
| WO2017197380A1 (en) | 2016-05-13 | 2017-11-16 | Ecolab Usa Inc. | Tissue dust reduction |
| US11407931B2 (en) | 2016-10-12 | 2022-08-09 | Schlumberger Technology Corporation | Crosslinking of cellulose fibers |
| US11180627B2 (en) * | 2017-01-11 | 2021-11-23 | The Regents Of The University Of Colorado, A Body Corporate | Cellulose enabled orientationally ordered flexible gels |
| US11028538B2 (en) * | 2019-02-28 | 2021-06-08 | Solenis Technologies, L.P. | Composition and method for increasing wet and dry paper strength |
| KR102776160B1 (ko) * | 2019-12-02 | 2025-03-07 | (주)엘엑스하우시스 | 표면 코팅용 조성물을 이용한 적층체 |
| JP7771186B2 (ja) | 2020-12-04 | 2025-11-17 | エージーシー ケミカルズ アメリカズ，インコーポレイテッド | 処理された物品、当該処理された物品の製造方法、及び当該処理された物品の製造に用いるための分散剤 |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2721140A (en) | 1952-09-19 | 1955-10-18 | Hercules Powder Co Ltd | Paper of high wet strength and process therefor |
| US3597374A (en) * | 1966-09-28 | 1971-08-03 | Nalco Chemical Co | Coating process for fibrous substrates |
| US3542707A (en) * | 1968-03-20 | 1970-11-24 | Cpc International Inc | Film-formers comprising starch,cationic polymer and aliphatic dialdehyde |
| JPS5323350B2 (enExample) * | 1972-06-03 | 1978-07-14 | ||
| US4191610A (en) | 1975-04-09 | 1980-03-04 | Prior Eric S | Upgrading waste paper by treatment with sulfite waste liquor |
| DE3128478A1 (de) | 1981-07-18 | 1983-02-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von linearen, basischen polymerisaten |
| DE3706525A1 (de) * | 1987-02-28 | 1988-09-08 | Basf Ag | Verfahren zur herstellung von papier, pappe und karton mit hoher trockenfestigkeit |
| EP0372557B1 (en) | 1988-12-09 | 1993-11-24 | Seiko Epson Corporation | Wire-dot printer having printing wire driving device and manufacturing method thereof |
| US5242545A (en) | 1989-02-27 | 1993-09-07 | Union Camp Corporation | Starch treated high crush linerboard and medium |
| US5281307A (en) | 1993-01-13 | 1994-01-25 | Air Products And Chemicals, Inc. | Crosslinked vinyl alcohol/vinylamine copolymers for dry end paper addition |
| JPH08269890A (ja) | 1995-03-30 | 1996-10-15 | Nippon P M C Kk | 製紙用添加剤及び製紙方法 |
| DE69603539T2 (de) | 1995-05-18 | 2000-01-13 | Fort James Corp., Richmond | Neue adhesive Zusammensetzungen zum Kreppen, Verfahren zum Kreppen und gekrepptes fibröses Gewebe |
| JP2939971B2 (ja) * | 1995-06-23 | 1999-08-25 | 日本製紙株式会社 | 吸水性を改良した印刷用紙、新聞印刷用紙、並びにその製造方法 |
| JP2877187B2 (ja) * | 1995-06-28 | 1999-03-31 | 岡田産業株式会社 | 化粧型枠パネル |
| US5824190A (en) * | 1995-08-25 | 1998-10-20 | Cytec Technology Corp. | Methods and agents for improving paper printability and strength |
| DE19607674A1 (de) | 1996-02-29 | 1997-09-04 | Basf Ag | Verwendung von hydrolysierten Polymerisaten von N-Vinylcarbonsäureamiden als Mittel zur Erhöhung der Trockenfestigkeit von Papier, Pappe und Karton |
| DE69700580T2 (de) * | 1996-07-12 | 2000-07-13 | Oji Paper Co., Ltd. | Tintenstrahlaufzeichnungsblatt mit einer hochglänzenden Schicht |
| GB9624031D0 (en) * | 1996-11-19 | 1997-01-08 | Allied Colloids Ltd | Manufacture of paper |
| DE19713755A1 (de) | 1997-04-04 | 1998-10-08 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton mit hoher Trockenfestigkeit |
| US6294645B1 (en) | 1997-07-25 | 2001-09-25 | Hercules Incorporated | Dry-strength system |
| JP4140080B2 (ja) * | 1998-04-30 | 2008-08-27 | 星光Ｐｍｃ株式会社 | 中性紙及びその製造方法 |
| BR9911766A (pt) * | 1998-05-12 | 2001-02-06 | Hercules Inc | Sistemas aquosos compreendendo um polìmero iÈnico e um promotor de viscosidade, processos para suas preparações, e usos do mesmo |
| US6303000B1 (en) | 1998-08-31 | 2001-10-16 | Omnova Solutions Inc. | Paper making process utilizing a reactive cationic starch composition |
| WO2000024791A1 (en) | 1998-10-28 | 2000-05-04 | Penn State Research Foundation | Process for polymerization of allylic compounds |
| FR2791688B1 (fr) | 1999-03-29 | 2005-03-18 | Snf Sa | Nouveaux procedes de synthese d'agents floculants et coagulants de type polyvinylamine pva, nouveaux agents obtenus, et leurs utilisations et papiers ameliores ainsi obtenus. |
| US6482883B1 (en) * | 2000-05-10 | 2002-11-19 | Kanzaki Specialty Papers, Inc. | Ink jet recording material demonstrating a balance of properties including improved imaging performance and good water resistance |
| US6710175B2 (en) * | 2001-08-31 | 2004-03-23 | Kevin Ray Anderson | Compositions suitable as additives in the paper industry, preparation; use; and, paper comprising such |
| US6939443B2 (en) | 2002-06-19 | 2005-09-06 | Lanxess Corporation | Anionic functional promoter and charge control agent |
| AU2003248076A1 (en) * | 2002-07-19 | 2004-02-09 | Kao Corporation | Paper improver |
| US6979481B2 (en) * | 2002-08-19 | 2005-12-27 | Mohawk Paper Mills, Inc. | Microporous photo glossy inkjet recording media |
| AU2003260833A1 (en) | 2002-09-17 | 2004-04-08 | International Paper Company | Papers comprising a boron-containing compound and a method of making same |
| US20050022956A1 (en) * | 2003-07-29 | 2005-02-03 | Georgia-Pacific Resins Corporation | Anionic-cationic polymer blend for surface size |
| US20050161182A1 (en) | 2003-11-21 | 2005-07-28 | Bercen Incorporated | Paper making process and starch compositions comprising a crosslinking agent for use in same |
| JP4605520B2 (ja) * | 2004-03-02 | 2011-01-05 | ハリマ化成株式会社 | カチオン性表面サイズ剤及び当該サイズ剤を用いた紙 |
| US7732525B2 (en) * | 2004-05-20 | 2010-06-08 | Ciba Specialty Chemicals Water Treatments Limited | Polymers for paper and paperboard coatings |
| US20050287385A1 (en) | 2004-06-28 | 2005-12-29 | Quick Thomas H | Paperboard material having increased strength and method for making same |
| HU226097B1 (en) | 2004-09-08 | 2008-04-28 | Welltech Kft | Method for surface treating of corrugated base papers |
| WO2006132872A1 (en) * | 2005-06-03 | 2006-12-14 | The Procter & Gamble Company | Fabric care compositions |
| WO2007116446A1 (ja) * | 2006-03-30 | 2007-10-18 | Harima Chemicals, Inc. | カチオン性表面サイズ剤、及び該サイズ剤を塗工した紙 |
| US20100273016A1 (en) * | 2007-10-12 | 2010-10-28 | Kao Corporation | Surface treatment agent for paper |
| JP5773370B2 (ja) * | 2009-11-06 | 2015-09-02 | ソレニス・テクノロジーズ・ケイマン・エル・ピー | 紙力を改善するためのポリマーおよびポリマー混合物の表面塗布 |
| JP2011212955A (ja) * | 2010-03-31 | 2011-10-27 | Nippon Paper Industries Co Ltd | インクジェット記録用紙 |
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| CA2813996A1 (en) | 2012-05-10 |
| US8900412B2 (en) | 2014-12-02 |
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| ZA201304082B (en) | 2014-12-23 |
| ES2641302T3 (es) | 2017-11-08 |
| CA2813996C (en) | 2015-01-27 |
| JP2013543066A (ja) | 2013-11-28 |
| AU2011323632B2 (en) | 2016-03-10 |
| AU2011323632A1 (en) | 2013-06-27 |
| KR101946221B1 (ko) | 2019-02-08 |
| US20120111517A1 (en) | 2012-05-10 |
| TWI575135B (zh) | 2017-03-21 |
| TW201229358A (en) | 2012-07-16 |
| CN103201348A (zh) | 2013-07-10 |
| CN103201348B (zh) | 2017-02-15 |
| WO2012061305A1 (en) | 2012-05-10 |
| MX2013004106A (es) | 2013-07-17 |
| KR101836210B1 (ko) | 2018-03-09 |
| EP2635645A1 (en) | 2013-09-11 |
| EP2635645B1 (en) | 2017-07-05 |
| PT2635645T (pt) | 2017-08-11 |
| MX343488B (es) | 2016-11-08 |
| KR20130117804A (ko) | 2013-10-28 |
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