JP2013534218A - 化粧品調製物 - Google Patents
化粧品調製物 Download PDFInfo
- Publication number
- JP2013534218A JP2013534218A JP2013522123A JP2013522123A JP2013534218A JP 2013534218 A JP2013534218 A JP 2013534218A JP 2013522123 A JP2013522123 A JP 2013522123A JP 2013522123 A JP2013522123 A JP 2013522123A JP 2013534218 A JP2013534218 A JP 2013534218A
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- JP
- Japan
- Prior art keywords
- group
- inci
- propyl
- methyl
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title description 39
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 106
- 150000001875 compounds Chemical class 0.000 claims abstract description 104
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 96
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 77
- 239000000126 substance Substances 0.000 claims abstract description 46
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 239000000825 pharmaceutical preparation Substances 0.000 claims abstract description 5
- 229940127557 pharmaceutical product Drugs 0.000 claims abstract description 4
- -1 2-propylheptyl Chemical group 0.000 claims description 624
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 172
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 39
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- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 28
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 23
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- 239000004094 surface-active agent Substances 0.000 description 23
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 18
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- 150000003839 salts Chemical class 0.000 description 18
- 239000002253 acid Substances 0.000 description 17
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 17
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- HEAHZSUCFKFERC-IWGRKNQJSA-N [(2e)-2-[[4-[(e)-[7,7-dimethyl-3-oxo-4-(sulfomethyl)-2-bicyclo[2.2.1]heptanylidene]methyl]phenyl]methylidene]-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonic acid Chemical group CC1(C)C2CCC1(CS(O)(=O)=O)C(=O)\C2=C\C(C=C1)=CC=C1\C=C/1C(=O)C2(CS(O)(=O)=O)CCC\1C2(C)C HEAHZSUCFKFERC-IWGRKNQJSA-N 0.000 description 9
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- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
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- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
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- IIBWEWUPWKQJAW-UHFFFAOYSA-N 4-(2-propylheptoxymethyl)nonane Chemical compound CCCCCC(CCC)COCC(CCC)CCCCC IIBWEWUPWKQJAW-UHFFFAOYSA-N 0.000 description 7
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 7
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- 150000002170 ethers Chemical class 0.000 description 7
- UBHWBODXJBSFLH-UHFFFAOYSA-N hexadecan-1-ol;octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO.CCCCCCCCCCCCCCCCCCO UBHWBODXJBSFLH-UHFFFAOYSA-N 0.000 description 7
- 229920001223 polyethylene glycol Polymers 0.000 description 7
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- 125000002252 acyl group Chemical group 0.000 description 6
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- 125000002091 cationic group Chemical group 0.000 description 6
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- 238000006243 chemical reaction Methods 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
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- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 5
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- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 5
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 5
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 5
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- 210000004209 hair Anatomy 0.000 description 5
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 5
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
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- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 description 4
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- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 description 4
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- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- ZCIHMQAPACOQHT-ZGMPDRQDSA-N trans-isorenieratene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/c1c(C)ccc(C)c1C)C=CC=C(/C)C=Cc2c(C)ccc(C)c2C ZCIHMQAPACOQHT-ZGMPDRQDSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UYERRXOXXRNFHC-UHFFFAOYSA-N tridodecyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCC)CC(=O)OCCCCCCCCCCCC UYERRXOXXRNFHC-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- FAGMGMRSURYROS-UHFFFAOYSA-M trihexadecyl(methyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCC FAGMGMRSURYROS-UHFFFAOYSA-M 0.000 description 1
- 229940118576 triisostearyl citrate Drugs 0.000 description 1
- 229940072029 trilaureth-4 phosphate Drugs 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- UKBHVNMEMHTWQO-UHFFFAOYSA-N trioctadecyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCCCCCCCC)CC(=O)OCCCCCCCCCCCCCCCCCC UKBHVNMEMHTWQO-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- ICWQKCGSIHTZNI-UHFFFAOYSA-N tris(16-methylheptadecyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCCCCCC(C)C)CC(=O)OCCCCCCCCCCCCCCCC(C)C ICWQKCGSIHTZNI-UHFFFAOYSA-N 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 235000002374 tyrosine Nutrition 0.000 description 1
- 229940040064 ubiquinol Drugs 0.000 description 1
- QNTNKSLOFHEFPK-UPTCCGCDSA-N ubiquinol-10 Chemical compound COC1=C(O)C(C)=C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)C(O)=C1OC QNTNKSLOFHEFPK-UPTCCGCDSA-N 0.000 description 1
- 229940035936 ubiquinone Drugs 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005314 unsaturated fatty acid group Chemical group 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 235000019386 wax ester Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Abstract
Description
R1−O−R2
〔式中、
− R1は、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数10〜22の分枝アルキル(アルキレン)基を表し、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕
で示される化合物に関する。
基R1は、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数10〜22の分枝アルキル(アルキレン)基を表す。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数10の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数11の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数12の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数13の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数14の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数15の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数16の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数17の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数18の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数19の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数20の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数21の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
本発明の一実施態様は、R1が、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数22の分枝アルキル(アルキレン)基を表す、式(I)の化合物に関する。
基R2は、炭素数1〜14の直鎖または分枝アルキル(アルキレン)基を表す。
基R1またはR2がキラル炭素原子を有している場合、ラセミ化合物のエーテルおよび各エナンチオマーのエーテルのいずれもが含まれる。
R1−O−R2
〔式中、
− R1は、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数10の分枝アルキル(アルキレン)基を表し、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕
で示される化合物に関する。
2−プロピル−ヘプチル−O−R2
〔式中、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕。
驚くべきことに、本発明の化合物は、化粧品および/または医薬品調製物に好適であり、特に皮膚における「軽い」感触が重要となる調製物にとって好適である。本発明の化合物は、様々な処方に非常に良好に配合することができる。本発明の化合物は、揮発性シリコーン(例えば、シクロメチコン)の感覚特性と同等の感覚特性を有している。本発明の化合物は、公知のジアルキルエーテルに比べて改善された皮膚適合性を示す。
R1−O−R2
〔式中、
− R1は、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数10〜22の分枝アルキル(アルキレン)基を表し、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕
で示される1つ以上の化合物の、化粧品および/または医薬品における使用、またはその製造における使用、特に化粧品および/または医薬品における油性物質としての、および/または可溶化剤としての、および/または分散剤としての使用に関する。好ましくは、先の段落で記載した化合物若しくはその混合物を使用する。特に好ましくは、R1が、2−プロピルヘプチル基である式(I)の化合物、またはこれらの2−プロピルヘプチルエーテルを含む一般式(I)のエーテルの混合物を使用する。
(a)少なくとも1つの請求項1〜5のいずれかに記載の化合物、
(b)少なくとも1つの表面活性物質(b−1)および/またはワックス成分(b−2)および/またはポリマー(b−3)および/または他の油性物質(b−4)
を含んでなる化粧品および/または医薬品に関する。
(a)少なくとも1つの請求項1〜5のいずれかに記載の化合物、
(b)少なくとも1つのUV光保護フィルター
を含んでなる化粧品および/または医薬品に関する。
(a)一般式(I):
R1−O−R2
〔式中、
− R1は、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数10の分枝アルキル(アルキレン)基を表し、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕
で示される1つ以上の化合物、
(b)少なくとも1つの表面活性物質(b−1)および/またはワックス成分(b−2)および/またはポリマー(b−3)および/または他の油性物質(b−4)
を含む。
(a)一般式(I):
R1−O−R2
〔式中、
− R1は、2−プロピルヘプチル基、3−メチル−2−プロピル−へキシル基、4−メチル−2−プロピル−へキシル基、5−メチル−2−プロピル−へキシル基、トリメチルヘプチル基、3,5−ジメチルオクチル基、2,2−ジメチルオクチル基、1−エチル−オクチル基、2−エチル−オクチル基、3−エチル−オクチル基、4−エチル−オクチル基、1−プロピル−ヘプチル基、3−プロピル−ヘプチル基および4−プロピル−ヘプチル基からなる群から選択される分枝アルキル(アルキレン)基を表し、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕
で示される1つ以上の化合物、
(b)少なくとも1つの乳化剤(b−1)および/または界面活性剤(b−2)および/またはワックス成分(b−3)および/またはポリマー(b−4)および/または他の油性物質(b−5)
を含んでなる化粧品および/または医薬品に関する。
R1−O−R2
〔式中、
− R1は、2−プロピルヘプチル基であり、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕
で示される1つ以上の化合物、
(b)少なくとも1つの乳化剤(b−1)および/または界面活性剤(b−2)および/またはワックス成分(b−3)および/またはポリマー(b−4)および/または他の油性物質(b−5)
を含んでなる化粧品および/または医薬品が特に好ましい。
(a)0.1〜95重量%の、特に0.2〜80重量%の、とりわけ0.1〜70重量%の、好ましくは0.1〜60重量%の、特に0.1〜50重量%の、好ましくは0.1〜40重量%の、少なくとも1つの請求項1に従う化合物、
(b)0.1〜20重量%の表面活性物質(b−1)および/またはワックス成分(b−2)および/またはポリマー(b−3)、0.1〜40重量%の他の油性物質(b−4)、および
(c)0〜98重量%の水
を含んでなる化粧品および/または医薬品に関する。
本発明の一実施態様において、本発明の調製物は、少なくとも1つの界面活性物質を含む。本発明の調製物は、調製物の総重量に基づいて、0〜80重量%、特に0〜40重量%、好ましくは0.1〜20重量%、好ましくは0.1〜15重量%、とりわけ0.1〜10重量%の量の表面活性物質を含む。
非イオン性乳化剤のグループは、例えば以下のものを含む。
(1)8〜40個の炭素原子を有する直鎖脂肪アルコール、12〜40個の炭素原子を有する脂肪酸、アルキル基に8〜15個の炭素原子を有するアルキルフェノールへの、2〜50molのエチレンオキシドおよび/または1〜20molのプロピレンオキシドの付加生成物。
(2)グリセロールへの、1〜50molのエチレンオキシドの付加生成物のC12〜C18脂肪酸モノ−およびジエステル。
(3)6〜22個の炭素原子を有する飽和および不飽和脂肪酸のソルビタンモノ−およびジエステル、およびそれらのエチレンオキシド付加生成物。
(4)アルキル基に8〜22個の炭素原子を有するアルキルモノ−およびオリゴグリコシド、およびそれらのエトキシル化類似体。
(5)ヒマシ油および/または硬化ヒマシ油への7〜60molのエチレンオキシドの付加生成物。
(6)ポリオール、特にポリグリセロールエステル、例えばポリオールポリ−12−ヒドロキシステアレート、ポリグリセロールポリリシノレエート、ポリグリセロール−4−ラウレート、ポリグリセロールジイソステアレートまたはポリグリセロールダイメレート。これらの物質類のいくつかの化合物の混合物、例えばポリグリセロール−4ジイソステアレート/ポリヒドロキシステアレート/セバケートなどの混合物も適している。
(7)ヒマシ油および/または硬化ヒマシ油への2〜15molのエチレンオキシドの付加生成物。
(8)直鎖、分枝、不飽和または飽和C6〜C22脂肪酸、リシノール酸および12−ヒドロキシステアリン酸および、ポリグリセロール、ペンタエリスリトール、ジペンタエリスリトール、糖アルコール(例えばソルビトール)、アルキルグルコシド(例えばメチルグルコシド、ブチルグルコシド、ラウリルグルコシド)、およびポリグルコシド(例えばセルロース)に基づく部分エステル、または混合エステル、スクロースポリステアレート(Emulgade(登録商標)SUCRO、Cognis GmbH製)。
(9)ポリシロキサン−ポリアルキル−ポリエーテル共重合体および対応する誘導体。
(10)ペンタエリスリトール、脂肪酸、クエン酸および脂肪アルコールの混合エステルおよび/または6〜22個の炭素原子を有する脂肪酸の混合エステル、メチルグルコースおよびポリオール、好ましくはグリセロールまたはポリグリセロール。
で示される化合物の群から選択することができる。
本発明の一実施態様において、本発明の調製物は、表面活性物質として少なくとも1種の界面活性剤を含有する。界面活性剤としては、アニオン性、非イオン性、カチオン性および/または両性若しくは双性イオン性界面活性剤が含まれ得る。表面活性剤含有化粧品(例えばシャワージェル、フォームバス、シャンプーなど)は、好ましくは少なくとも1種のアニオン性界面活性剤を含有する。
本発明の一実施態様において、本発明の調製物は、少なくとも1つのワックス成分を含む。本発明の調製物は、調製物の総重量に基づいて、0〜40重量%、特に0〜20重量%、好ましくは0.1〜15重量%、とりわけ0.1〜10重量%の量のワックス成分を含む。
本発明の一実施態様において、本発明の調製物は少なくとも1つのポリマーを含む。本発明の調製物は、調製物の総重量に基づいて、0〜20重量%、好ましくは0.05〜18重量%、好ましくは0.05〜15重量%、特に0.05〜10重量%、とりわけ0.1〜1重量%の量のポリマーを含む。本発明の好ましい実施態様において、本発明の調製物は、調製物の総重量に基づいて、0.1〜5重量%、特に0.1〜3重量%、とりわけ0.1〜2重量%の量でポリマーを含む。
クリーム、ボディーオイル、ローションおよびミルクのようなボディーケア製品は、通常、感触特性をさらに最適化することに寄与する多数の他の油性物質およびエモリエントを含む。油性物質(本発明の化合物および他の油性物質)は、通常、合計0.1〜80重量%、特に0.5〜70重量%、好ましくは1〜60重量%、特に1〜50重量%、特に1〜40重量%、好ましくは5〜25重量%、とりわけ5〜15重量%の量で存在する。他の油性物質は、通常、0.1〜40重量%の量で含まれる。
・3−ベンジリデンカンファーまたは3−ベンジリデンノルカンファー(Mexoryl(登録商標)SDS 20)およびその誘導体、例えば、EP0693471B1に記載されるような3−(4−メチルベンジリデン)カンファー;
・3−(4’−トリメチルアンモニウム)ベンジリデン−ボルナン−2−オン−メチルスルフェート(Mexoryl SO);
・3,3’−(1,4−フェニレンジメチン)−ビス(7,7−ジメチル−2−オキソビシクロ−[2.2.1]ヘプタン−1−メタスルホン酸)および塩(Mexoryl SX);
・3−(4’−スルホ)−ベンジリデン−ボルナン−2−オンおよび塩(Mexryl SL);
・N−{(2および4)−[2−オキソボルン−3−イリデン]メチル}ベンジル}アクリルアミドのポリマー(Mexoryl SW);
・2−(2H−ベンゾトリアゾ−ル−2−イル)−4−メチル−6−(2−メチル−3−(1,3,3,3−テトラメチル−1−(トリメチルシリルオキシ)ジシロキサニル)プロピル)フェノ−ル(Mexoryl SL);
・4−アミノ安息香酸誘導体、好ましくは4−(ジメチルアミノ)安息香酸2−エチルヘキシル、4−(ジメチルアミノ)安息香酸−2−オクチルおよび4−(ジメチルアミノ)安息香酸アミル;
・ケイ皮酸のエステル、好ましくは4−メトキシケイ皮酸2−エチルヘキシル、4−メトキシケイ皮酸プロピル、4−メトキシケイ皮酸イソアミル、2−シアノ−3,3−フェニルケイ皮酸2−エチルヘキシル(Octocrylene);
・サリチル酸のエステル、好ましくはサリチル酸2−エチルヘキシル、サリチル酸4−イソプロピルベンジル、サリチル酸ホモメンチル;
・ベンゾフェノンの誘導体、好ましくは2−ヒドロキシ−4−メトキシベンゾフェノン、2−ヒドロキシ−4−メトキシ−4’−メチルベンゾフェノン、2,2’−ジヒドロキシ−4−メトキシベンゾフェノン;
・ベンザルマロン酸のエステル、好ましくは4−メトキシベンズマロン酸ジ−2−エチルヘキシル;
・トリアジンの誘導体、例えば、EP0818450A1に記載されるような2,4,6−トリアニリノ−(p−カルボ−2’−エチル−1’−ヘキシルオキシ)−1,3,5−トリアジンおよび2,4,6−トリス[p−(2−エチルヘキシル−オキシカルボニル)アニリノ]−1,3,5−トリアジン(Uvinul T 150)または4,4’−[(6−[4−((1,1−ジメチルエチル)アミノ−カルボニル)フェニルアミノ]−1,3,5−トリアジン−2,4−ジイル)ジイミノ]ビス(安息香酸2−エチルヘキシル)(Uvasorb(登録商標)HEB);
・2,2−(メチレン−ビス(6−(2H−ベンゾトリアゾール−2−イル)−4−(1,1,3,3−テトラメチルブチル)フェノール)(Tinosorb M);
・2,4−ビス[4−(2−エチルヘキシルオキシ)−2−ヒドロキシフェニル]−6−(4−メトキシフェニル)−1,3,5−トリアジン(Tinosorb S);
・プロパン−1,3−ジオン、例えば1−(4−tert−ブチルフェニル)−3−(4’−メトキシフェニル)プロパン−1,3−ジオン;
・EP0694521B1に記載されるようなケトトリシクロ(5.2.1.0)デカン誘導体;
・ジメチコジエチルベンザルマロネート(Parsol SLX)。
・2−フェニルベンズイミダゾール−5−スルホン酸、ならびに、そのアルカリ、アルカリ土類、アンモニウム、アルキルアンモニウム、アルカノールアンモニウムおよびグルクアンモニウム塩;
・2,2(−(1,4−フェニレン)ビス(1H−ベンズイミダゾール−4,6−ジスルホン酸、モノナトリウム塩)(Neo Heliopan AP);
・ベンゾフェノンのスルホン酸誘導体、好ましくは2−ヒドロキシ−4−メトキシベンゾフェノン−5−スルホン酸およびその塩;
・3−ベンジリデンカンファーのスルホン酸誘導体、例えば4−(2−オキソ−3−ボルニリデンメチル)ベンゼンスルホン酸および2−メチル−5−(2−オキソ−3−ボルニリデン)スルホン酸およびその塩。
NeoHeliopan(登録商標)MBC(INCI:4−メチルベンジリデンカンファー、Symrise製);NeoHeliopan(登録商標)BB(INCI:ベンゾフェノン−3、Symrise製);Parsol(登録商標)1789(INCI:ブチルメトキシジベンゾイルメタン、Hoffmann−La Roche (Givaudan)製);Tinosorb(登録商標)S(INCI:ビス−エチルヘキシルオキシフェノールメトキシフェニルトリアジン);Tinosorb(登録商標)M(INCI:メチレンビス−ベンゾトリアゾリルテトラメチルブチルフェノール、Ciba Specialty Chemicals Corporation製);Uvasorb(登録商標)HEB(INCI:ジエチルヘキシルブタミドトリアゾン、3V Inc.製);Uvinul(登録商標)T150(INCI:エチルヘキシルトリアゾン、BASF AG製);Uvinul(登録商標)A plus(INCI:ジエチルアミノヒドロキシベンゾイルヘキシルベンゾエート、BASF AG製);Mexoryl(登録商標)SO:3−(4’−トリメチルアンモニウム)ベンジリデンボルナン−2−オン−メチルスルフェート、INCI:カンファーベンザルコニウムメトスルフェート;Mexoryl(登録商標)SX:3,3’−(1,4−フェニレンジメチン)−ビス(7,7−ジメチル−2−オキソビシクロ[2.2.1]ヘプタン−1−メタンスルホン酸)、CTFA:INCIテレフタルイリデンジカンファースルホン酸;Mexoryl(登録商標)SL:3−(4’−スルホ)ベンジリデン−ボルナン−2−オン、INCIベンジリデンカンファースルホン酸;Mexoryl(登録商標)SW:N−{(2および4)−[2−オキソボルン−3−イリデン)メチル}ベンジル]アクリルアミドのポリマー、INCIポリアクリルアミドメチルベンジリデンカンファー;Mexoryl(登録商標)SL:2−(2H−ベンゾトリアゾール−2−イル)−4−メチル−6−(2−メチル−3−(1,3,3,3−テトラメチル−1−(トリメチルシリルオキシ)ジシロキサニル)プロピル)フェノール;INCI:ドロメトリゾールトリシロキサン;Parsol(登録商標)SLX:ジメチコジエチルベンザルマロネート、INCIポリシリコン−15。本発明の調製物は、調製物に対して、0.5〜30重量%、好ましくは2.5〜20重量%、特に好ましくは5〜15重量%の量でUV光保護フィルターを含むことができる。
適当な増粘剤は、例えば、Aerosilタイプ(親水性ケイ酸)、カルボキシメチルセルロースおよびヒドロキシエチルセルロースおよびヒドロキシプロピルセルロース、ポリビニルアルコール、ポリビニルピロリドンおよび例えばBentone(登録商標)Gel VS−5PC(Rhoex)のようなベントナイトである。
適当な増粘剤は、例えば、Cosmedia(登録商標)Gel CC(INCI名:ジカプリリルカーボネート、ステアラルコニウムヘクトライトおよびプロピレンカーボネート)の商品名のもと入手し得る製品である。
生体活性成分としては、例えば、トコフェロール、酢酸トコフェロール、パルミチン酸トコフェロール、アスコルビン酸、(デオキシ)リボ核酸およびそれらの断片化生成物、β−グルカン、レチノール、ビサボロール、アラントイン、フィタントリオール、パンテノール、AHA酸、アミノ酸、セラミド、疑似セラミド、精油、例えばプルーン抽出物、バンバラナッツ抽出物のような植物抽出物ならびにビタミン複合体が挙げられる。
脱臭物質/制汗剤は、体臭を抑制し、マスキングし、または除去する。体臭は、不快臭のある分解生成物が形成されるアポクリン汗での皮膚細菌の作用によって生じる。従って、とりわけ、抗菌剤、酵素阻害剤、臭気吸収剤または臭気マスキング剤が脱臭物質として適している。
防虫剤としては、例えば、N,N−ジエチル−m−トルアミド、1,2−ペンタンジオールまたは、Insect Repellent(登録商標)3535の名称のもとMerck KGaAにより販売されているエチル3−(N−n−ブチル−N−アセチルアミノ)プロピオン酸およびブチルアセチルアミノプロピオネートが挙げられる。
適当なセルフタンニング剤は、ジヒドロキシアセトンまたはエリスルロースである。メラニンの生成を抑制し、脱色素組成物における用途が見い出されているチロシン阻害剤には、例えば、アルブチン、フェルラ酸、コウジ酸、クマリン酸およびアスコルビン酸(ビタミンC)が含まれる。
適当な防腐剤は、例えば、フェノキシエタノール、ホルムアルデヒド溶液、パラベン、ペンタンジオール、クロルフェネシン、カプリリルグリコール、エチルへキシルグリコールまたはソルビン酸であり、また、Surfacine(登録商標)の名称のもと既知である銀錯体および化粧品条例の別表6、パートAおよびBに記載された分類の他の物質である。
香油として、天然および合成香料の混合物が挙げられる。天然香料は、花、茎および葉、果実、果皮、根、木、ハーブおよび草、針葉および枝、樹脂およびバルサムの抽出物である。また、例えばシベットおよび海狸香のような動物性原料、ならびにエステル、エーテル、アルデヒド、ケトン、アルコールおよび炭化水素の合成香料化合物も考慮され得る。
例えば下記物質を、特に界面活性処方における使用に適する真珠光沢ワックスまたは真珠光沢化合物として例示し得る:アルキレングリコールエステル、特にエチレングリコールジステアレート;脂肪酸アルカノールアミド、特にヤシ脂肪酸ジエタノールアミド;部分グリセリド、特にステアリン酸モノグリセリド;任意でヒドロキシ置換したカルボン酸と6〜22個の炭素原子を有する脂肪アルコールとの多価エステル、特に酒石酸の長鎖エステル;脂肪物質、例えば、脂肪アルコール、脂肪ケトン、脂肪アルデヒド、脂肪エーテルおよび脂肪カーボネート(少なくとも24個の炭素原子を有する)、特にラウロンおよびジステアリルエーテル;クエン酸ステアリル、シクロデキストリン、ステアリン酸、ヒドロキシステアリン酸またはベヘン酸のような脂肪酸、12〜22個の炭素原子を有するオレフィンエポキシドと12〜22個の炭素原子を有する脂肪アルコールおよび/または2〜15個の炭素原子および2〜10個のヒドロキシ基を有するポリオールとの開環生成物、およびそれらの混合物。
使用し得る過脂肪剤は、例えば、ラノリンおよびレシチン、およびポリエトキシル化またはアシル化したラノリンおよびレシチン誘導体、ポリオール脂肪酸エステル、モノグリセリドおよび脂肪酸アルカノールアミドのような物質であり、後者は同時に気泡安定剤としてもはたらく。適当な過脂肪剤は、例えばココグルコシドとオレイン酸グリセリルの混合物(Cognis GmbHからLamesoft(登録商標)PO65のもと入荷能)である。
本発明の別の主題は、一般式R1−OHおよび/またはR2−OH〔R1およびR2は前記と同じ意味を有する〕のアルコールを触媒の存在下で縮合させる、一般式(I)の化合物の製造方法に関する。
製造例1:プロピルヘプチル−メチルエーテル
949.8gのプロピルヘプタノール(6mol)と320.0gのNaOH(50%)(4mol)を、水分離器で220℃で10時間加熱した。得られた粘性アルコラートに596.4gのヨウ化メチル(4mol)を加えて、80℃でさらに10時間加熱した。はじめに形成されたヨウ化メチルを生成物からろ過により取り除き、次いで充填カラムを用いて生成物を蒸留した。低粘度の透明な油として生成物が得られた。
600gのプロピルヘプタノール(3.8mol)、12gのトリフルオロメタンスルホン酸(50%、0.04mol)および12gの次亜リン酸(0.09mol)を、デフレグメーターでゆっくりと160℃まで加熱し、この温度を6時間保持した。冷却後、25gの水酸化ナトリウム溶液(50%、313mmol)で中和し、その後充填カラムで生成物を蒸留した。生成物を0.001barで120℃まで加熱し、透明な油を得た。
密閉表皮24時間パッチテストにより、製造例2に従って得られたジ(2−プロピルヘプチル)エーテルを、市販のジ−n−オクチルエーテルと比較した。この試験について、22人の被験者の背中にそれぞれ75μlの被験物質を貼り付けた〔パッチテスト系:Scanpor(登録商標)の密閉フィルター容器を有するフィンチャンバー(登録商標)〕。ブランクコントロールとして水を、ポジティブコントロールとしてSDS0.5%溶液を用いた。24時間後に張り付けたパッチを剥がし、さらに6時間後に最初の視覚的評価を行い、さらにパッチを剥がしてから24時間後、48時間後および72時間後に評価を行った。
下記の化粧品調製物を、本発明の製造例1に従うエーテル(プロピルヘプチル−メチルエーテル)と本発明の製造例2に従うエーテル(ジ(2−プロピルヘプチル)エーテル)の両方で調製した。すべてのデータは、調製物の総重量に対する重量パーセントで表す。
AMP− 95;INCI:アミノメチルプロパノール,Dow Chemical Co;
Abil(登録商標)EM 90;INCI:セチルジメチコンコポリオール;Tego Cosmetics (Goldschmidt);
Allianz(登録商標)OPT;INCI:アクリレート/C12−22アルキルメタクリレートコポリマー;Rohm and Haas;
Amphisol(登録商標)K;INCI:セチルリン酸カリウム;Hoffmann La Roche;
Admul(登録商標)WOL 1403;INCI:ポリグリセロールのポリリシノレート,Quest;
Antaron(登録商標)V 220;INCI:PVP/エイコセンコポリマー; GAF General Aniline Firm Corp. (IPS−Global);
Antaron(登録商標)V 216;INCI:PVP/ヘキサデカンコポリマー:GAF General Aniline Firm Corp. (IPS−Global);
Arlacel(登録商標)83;INCI:セスキオレイン酸ソルビタン,Uniqema(ICI Surfacants);
Arlacel(登録商標)P 135,INCI:PEG−30ジポリヒドロキシステアレート,Uniqema(ICI Surfacants);
Bentone(登録商標)38,INCI:クオタニウム−18ヘクトライト,Rheox(Elementis Specialties);
Carbopol(登録商標)980,INCI:カルボマー,Goodrich;
Carbopol(登録商標)2984,INCI:カルボマー,Noveon,Inc.;
Carbopol(登録商標)ETD 2001,INCI:カルボマー,Noveon,Inc.;
Carbopol(登録商標)Ultrez 10,INCI:カルボマー;Noveon, Inc.;
Cegesoft(登録商標)C 17,乳酸ミリスチル,Cognis GmbH;
Cegesoft(登録商標)PFO,INCI:Passiflora Incarnata(EU);Cognis GmbH;
Cegesoft(登録商標)PS 6,INCI:オラス,Cognis GmbH;
Cegesoft(登録商標)SH,INCI:Shorea Stenoptera Seed Butter,Cognis GmbH;
Ceraphyl(登録商標)45,INCI:リンゴ酸ジエチルヘキシル,International Specialty Products;
Cetiol(登録商標)868,INCI:ステアリン酸エチルへキシル,Manufacturer:Cognis GmbH;
Cetiol(登録商標)A,INCI:ラウリン酸へキシル,Cognis GmbH;
Cetiol(登録商標)B,INCI:アジピン酸ジブチル,Cognis GmbH;
Cetiol(登録商標)CC,INCI:ジカプリリルカーボネート;Cognis GmbH;
Cetiol(登録商標)J 600,INCI:エルカ酸オレイル,Cognis GmbH;
Cetiol(登録商標)LC,INCI:ヤシ脂肪酸−カプリレート/カプレート,Cognis GmbH;
Cetiol(登録商標)MM,INCI:ミリスチン酸ミリステート,Cognis GmbH;
Cetiol(登録商標)OE,INCI:ジカプリリルエーテル,Cognis GmbH;
Cetiol(登録商標)PGL,INCI:ヘキシルデカノール、ラウリン酸ヘキシルデシル,Cognis GmbH;
Cetiol(登録商標)S,INCI:ジエチルヘキシルシクロヘキサン,Cognis GmbH;
Cetiol(登録商標)SB 45,INCI:シアバター Butyrospermum Parkii (Linne),Cognis GmbH;
Cetiol(登録商標)SN,INCI:イソノナン酸セテアリル,Cognis GmbH;
Copherol(登録商標)F 1300 C,INCI:トコフェロール,Cognis GmbH;
Copherol 1250 C,INCI:酢酸トコフェロール,Cognis GmbH;
Cosmedia(登録商標)DC,INCI:水素化ダイマージリノレイル/ジメチルカーボネートコポリマー;Cognis GmbH;
Cosmedia(登録商標)SP,INCI:ポリアクリル酸ナトリウム;Cognis GmbH;
Cutina(登録商標)E 24,INCI:PEG−20ステアリン酸グリセリル;Cognis GmbH;
Cutina(登録商標)HR,INCI:硬化ヒマシ油,Cognis GmbH;
Cutina(登録商標)MD,INCI:ステアリン酸グリセリル,Cognis GmbH;
Cutina(登録商標)PES,INCI:ジステアリン酸ペンタエリスリチル,Cognis GmbH;
Cutina(登録商標)FS−45,INCI:パルミシン酸、ステアリン酸,Cognis GmbH;
Cutina(登録商標)GMS−SE,INCI:ステアリン酸グリセリルSE,Cognis GmbH;
Cutina(登録商標)LM conc,INCI:ポリグリセリル−2ジポリヒドロキシステアレート、オクチルドデカノール、Copernicia Cerifera(カルナウバ)ワックス、Euphorbia Cerifera(キャンデリラ)ワックス、ミツロウ、セテアリルグルコシド、セテアリルアルコール,Cognis GmbH;
Dehymuls(登録商標)FCE,INCI:ジココイルペンタエリスリチルジステアリルシトレート,Cognis GmbH;
Dehymuls(登録商標)HRE 7,INCI:PEG−7硬化ヒマシ油,Cognis GmbH;
Dehymuls(登録商標)PGPH,INCI:ポリグリセリル−2ジポリヒドロキシステアレート,Cognis GmbH;
Crodesta(登録商標)F−50,INCI:スクロースジステアレート,Croda;
Dehymuls(登録商標)LE,INCI:PEG−30ジポリヒドロキシステアレート,Cognis GmbH;
Dow Corning(登録商標)244 Fluid,INCI:シクロメチコン,Dow Corning;
Dow Corning(登録商標)246 Fluid,シクロペンタシロキサン,Dow Corning;
Dow Corning(登録商標)2502,INCI:セチルジメチコン,Dow Corning;
Dow Corning DC(登録商標)245,INCI:シクロペンタシロキサン,Dow Corning;
Dehyquart(登録商標)C 4046,INCI:セテアリルアルコール、ジパルミトイルエチルヒドロキシエチルモニウムメトスルフェート、セテアレス−20,Cognis GmbH;
Dry(登録商標)Flo Plus,INCI:アルミニウムデンプンオクテニルスクシネート,National Starch;
Dry(登録商標)Flo PC,INCI:アルミニウムデンプンオクテニルスクシネート,Akzo Nobel;
Elfacos(登録商標)ST 37,INCI:PEG−22ドデシルグリコシルコポリマー,Akzo−Nobel;
Elfacos(登録商標)ST 9,INCI:PEG−45ドデシルグリコシルコポリマー,Akzo−Nobel;
Emery(登録商標)1780,INCI:ラノリンアルコール,Cognis Corp.;
Emulgade(登録商標)CM,INCI:イソノナン酸セテアリルおよびセテアレス−20およびセテアリルアルコールおよびステアリン酸グリセリルおよびグリセリンおよびセテアレス−12およびパルミチン酸セチル,Cognis GmbH;
Emulgade(登録商標)PL 68/50,INCI:セテアリルグルコシド、セテアリルアルコール,Cognis GmbH;
Emulgade(登録商標)SE−PF,INCI:ステアリン酸グリセリル(および)セテアレス−20(および)セテアレス−12(および)セテアリルアルコール(および)パルミチン酸セチル;Cognis GmbH;
Emulgade(登録商標)SUCRO,INCI:スクロースポリステアレート(および)水素化ポリイソブテン,Cognis GmbH;
Eumulgin(登録商標)B1,INCI:セテアレス−12,Cognis GmbH;
Eumulgin(登録商標)B2,INCI:セテアレス−20,Cognis GmbH;
Eumulgin(登録商標)HRE 40,INCI:PEG−40硬化ヒマシ油,Cognis GmbH;
Eumulgin(登録商標)Prisma,INCI:セテアリルスルホコハク酸二ナトリウム;
Eumulgin(登録商標)SG,INCI:ステアロイルグルタミン酸ナトリウム,Cognis GmbH;
Eumulgin(登録商標)VL 75,INCI:ラウリルグルコシド(および)ポリグリセリル−2ジポリヒドロキシステアレート(および)グリセリン;Cognis GmbH;
Eusolex(登録商標)OCR,INCI:オクトクリレン,Merck;
Eusolex(登録商標)T 2000,INCI:二酸化チタン、アルミナ、シメチコン,Merck;
Eusolex(登録商標)T AQUA,INCI:水および二酸化チタンおよびアルミナおよびメタリン酸ナトリウムおよびフェノキシエタノールおよびメチルパラベンナトリウム,Merck;
Eutanol(登録商標)G,INCI:オクチルドデカノール,Cognis GmbH;
Eutanol(登録商標)G 16,INCI:ヘキシルデカノール,Cognis GmbH;
Eutanol(登録商標)G 16 S,INCI:ヘキシルデシルステアレート,Cognis GmbH;
Finsolv(登録商標)TN,INCI:C12/15アルキルベンゾエート,Findex(Nordmann/Rassmann);
Fitoderm(登録商標),INCI:スクアラン,Cognis GmbH;
Generol(登録商標)R,INCI:Brassica Campestris (菜種)ステロール,Cognis GmbH;
Glucate(登録商標)DO,INCI:メチルグルコースジオレエート,NRC Nordmann/Rassmann;
Hispagel(登録商標)200,INCI:グリセリン,グリセリルポリカプリレート,Cognis GmbH;
Hostaphat(登録商標)KL 340 N,INCI:トリラウレス−4リン酸塩,Clariant;
Hydagen(登録商標)C.A.T.,INCI:クエン酸トリエチル,Cognis GmbH;
Hydagen(登録商標)DCMF,INCI:キトサン,Cognis GmbH;
Insect Repellent(登録商標)3535,INCI:エチルブチルアセチルアミノプロピオネート,EMD Chemicals Inc;
lsolan(登録商標)PDI,INCI:ジイソステアロイルポリグリセリル−3ジイソステアレート,Goldschmidt AG;
Isolan(登録商標)GPS,INCI:ポリグリセリル−4ジイソステアレート/ポリヒドロキシステアレート/セバケート,Evonik Goldschmidt;
Isolan(登録商標)Gl 34,INCI:ポリグリセリル−4イソステアレート,Evonik Goldschmidt;
Irwinol(登録商標)LS 9319,INCI:オクチルデカノール,Irvingia Gabonensis Kernel Butter,水素化ココグリセリド,
Keltrol(登録商標)T,INCI:キサンタンガム,CP Kelco;
Lameform(登録商標)TGI,INCI:ポリグリセリル−3ジイソステアレート,Cognis GmbH;
Lanette(登録商標)14,INCI:ミリスチルアルコール,Cognis GmbH;
Lanette(登録商標)18,INCI:ステアリルアルコール,Cognis GmbH;
Lanette(登録商標)22,INCI:ベヘニルアルコール,Cognis GmbH;
Lanette(登録商標)E,INCI:セテアリル硫酸ナトリウム,Cognis GmbH;
Lanette(登録商標)O,INCI:セテアリルアルコール,Cognis GmbH;
Locron(登録商標)L,INCI:アルミニウムクロルハイドレート,Clariant;
Lucentite(登録商標)SAN,INCI:クオタニウム−18ヘクトライト,Co−Op Chemical Co.,Ltd.;
Microna(登録商標)Matte White(INCI:二酸化チタン,酸化亜鉛);
Microna(登録商標)Matte Black(INCI:酸化鉄、マイカ);
Microna(登録商標)Matte Yellow(INCI:酸化鉄、マイカ);
Microna(登録商標)Matte Red(INCI:酸化鉄、マイカ),
コスメティックホワイト C47056(INCI:二酸化チタン、マイカ);
FDC イエロー6 Alレーキ C705270(INCI:カラーインデックス 15985);
DC レッド7 Caレーキ C 19003(INCI:カラーインデックス 15850);
Irodin 100 シルバーパール,(INCI:マイカ,二酸化チタン);
Colophane Claire type Y(INCI:コロフォニウム);
Monomuls(登録商標)90−O 18,INCI:オレイン酸グリセリル,Cognis GmbH;
Monomuls(登録商標)90 L 12,INCI:ラウリン酸グリセリル,Cognis GmbH;
Myrj(登録商標)51,INCI:PEG−30−ステアレート,Uniqema;
Myritol(登録商標)312,INCI:カプリル酸/カプリン酸トリグリセリド,Cognis GmbH;
Myritol(登録商標)331,INCI:ココグリセリド,Cognis GmbH;
Myritol(登録商標)PC,INCI:プロピレングリコールジカプリレート/ジカプレート,Cognis GmbH;
Neo Heliopan(登録商標)303,INCI:オクトクリレン,Symrise;
Neo Heliopan(登録商標)AP,INCI:フェニルジベンゾイミダゾールテトラスルホン酸エステル二ナトリウム,Symrise;
Neo Heliopa(登録商標)AV,INCI:エチルへキシルメトキシシンナメート,Symrise;
Neo Heliopan(登録商標)BB,INCI:ベンゾフェノン−3,Symrise;
Neo Heliopan(登録商標)E 1000,INCI:イソアミル−p−メトキシシンナメート,Symrise;
Neo Heliopan(登録商標)Hydro,INCI:フェニルベンズイミダゾールスルホン酸,Symrise;
Neo Heliopan(登録商標)MBC,INCI:4−メチルベンジリデンカンファー,Symrise;
Neo Heliopan(登録商標)OS,INCI:サリチル酸エチルへキシル,Symrise;
Novata(登録商標)AB,INCI:ココグリセリド,Cognis GmbH;
Parsol(登録商標)1789,INCI:ブチルメトキシジベンゾイルメタン,Hoffmann−La Roche(Givaudan);
Pemulen(登録商標)TR−2 ポリマー,INCI:アクリレート/C10−30アルキルアクリレートクロスポリマー,Noveon,Inc.;
Photonyl(登録商標)LS,INCI:アルギニン,アデノシン三リン酸二ナトリウム、マンニトール、ピリドキシン HCL、フェニルアラニン、チロシン,Laboratoires Serobiologiques(Cognis);
Prisorine(登録商標)3505,INCI:イソステアリン酸;Uniqema;
Prisorine(登録商標)3758,INCI:水素化ポリイソブテン,Uniqema;
Rezal 36G,INCI:アルミニウムジルコニウムテトラクロロハイドレックス GLY,Reheis,Inc;
Rheocare(登録商標)C Plus,INCI:カルボマー,Cognis GmbH;
Ronasphere(登録商標)LDP,INCI:シリカ、二酸化チタン、酸化鉄;
Squatol(登録商標)S,INCI:水素化ポリイソブテン,BASF Corp.;
Poloxamer(登録商標)101,INCI:ポロキサマー,BASF SE;
SFE(登録商標)839,INCI:シクロペンタシロキサンおよびジメチコン/ビニルジメチコンクロスポリマー,GE Silicones;
シリコーン油 Wacker AK(登録商標)350,INCI:ジメチコン,Wacker;
Tego(登録商標)Care 450,INCI:ポリグリセリル−3メチルグルコースジステアレート,Goldschmidt;
Tego(登録商標)Care CG 90,INCI:セテアリルグルコシド,Goldschmidt;
Tegosoft(登録商標)DEC,INCI:ジエチルヘキシルカーボネート,Goldschmidt;
Tinosorb(登録商標)S,INCI:ビス−エチルヘキシルオキシフェノールメトキシフェニルトリアジン;Ciba Specialty Chemicals Corporation;
Tinosorb(登録商標)M,INCI:メチレンビス−ベンゾトリアゾリルテトラメチルブチルフェノール,Ciba Specialty Chemicals Corporation;
Tween(登録商標)60,INCI:ポリソルベート60,Uniqema(ICI Surfactants);
Uvasorb(登録商標)HEB,INCI:ジエチルヘキシルブタミドトリアゾン,3V Inc.;
Unirep(登録商標)U−18,INCI:フタル酸ジメチルおよびジエチルトルアミドおよびエチルヘキサンジオール,Induchem AG;
Uvinul(登録商標)T 150,INCI:エチルヘキシルトリアゾン,BASF;
Uvinul(登録商標)A plus,INCI:ジエチルアミノヒドロキシベンゾイルヘキシルベンゾエート,BASF;
Veegum(登録商標)Ultra,INCI:マグネシウムアルミニウムシリケート,R.T.Vanderbilt Company,Inc;
Veegum(登録商標)Plus,INCI:マグネシウムアルミニウムシリケートおよびセルロースガム,R.T.Vanderbilt Company,Inc;
Z−Cote(登録商標)HP 1,INCI:酸化亜鉛およびトリエトキシカプリリルシラン,BASF,
酸化亜鉛 NDM,INCI:酸化亜鉛,Symrise
Claims (11)
- 一般式(I):
R1−O−R2
〔式中、
− R1は、少なくとも1つの分枝が酸素原子に対して1位、2位、3位または4位に位置する、炭素数10〜22の分枝アルキル(アルキレン)基を表し、
− R2は、炭素数1〜13の直鎖または分枝アルキル(アルキレン)基を表し、かつ、
− R1およびR2は、式(I)中の炭素原子の総数が11〜23になるよう選択される〕
で示される化合物。 - R1が、少なくとも1つの分枝が酸素原子に対して2位に位置する、分枝アルキル(アルキレン)基を表す、請求項1に記載の化合物。
- 式(I)の化合物において、R1およびR2が、式(I)中の炭素原子の総数が14〜23になるよう選択される、請求項1または2に記載の化合物。
- R1が、2−プロピルヘプチル、3−メチル−2−プロピル−へキシル、4−メチル−2−プロピル−へキシルおよび5−メチル−2−プロピル−へキシル、トリメチルヘプチル、3,5−ジメチルオクチル、2,2−ジメチルオクチル、1−エチル−オクチル、2−エチル−オクチル、3−エチル−オクチル、4−エチル−オクチル、1−プロピル−ヘプチル、3−プロピル−ヘプチルおよび4−プロピル−ヘプチルからなる群から選択される、請求項1〜3のいずれかに記載の化合物。
- R1が、2−プロピルヘプチル、3−メチル−2−プロピル−へキシル、4−メチル−2−プロピル−へキシルおよび5−メチル−2−プロピル−へキシルからなる群から選択される、請求項1〜4のいずれかに記載の化合物。
- R1が、2−プロピルヘプチル基である、請求項1〜5のいずれかに記載の化合物。
- R1およびR2が同一である、請求項1〜6のいずれかに記載の化合物。
- R1およびR2が、2−プロピルヘプチル基である請求項1〜7のいずれかに記載の化合物。
- 化粧品および/または医薬品における、またはその製造における、請求項1〜8のいずれかに記載の化合物の使用。
- 油性物質としての請求項9に記載の使用。
- 化粧品および/または医薬品適合性媒体中に、0.1〜95重量%の1つ以上の請求項1〜8のいずれかに記載の化合物を含む化粧品および/または医薬品。
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JP2015147740A (ja) * | 2014-02-05 | 2015-08-20 | 株式会社コーセー | ゲル状口唇化粧料 |
JP2017516861A (ja) * | 2014-05-29 | 2017-06-22 | エバレデイ バツテリ カンパニー インコーポレーテツド | 改善された皮膚外観のための色持ちが向上した化粧品組成物 |
US11857658B2 (en) | 2014-05-29 | 2024-01-02 | Edgewell Personal Care Brands, Llc | Cosmetic compositions with enhanced color retention for improved skin appearance |
JP2017538761A (ja) * | 2014-12-23 | 2017-12-28 | ロレアル | ケラチン繊維をコンディショニングするための組成物 |
US11351109B2 (en) | 2014-12-23 | 2022-06-07 | L'oreal | Composition for conditioning keratin fibers |
JP2021020920A (ja) * | 2015-06-18 | 2021-02-18 | カストロール リミテッド | エーテル化合物ならびに関連の組成物および方法 |
JP2018537429A (ja) * | 2015-12-18 | 2018-12-20 | ロレアル | 改善された輝度効果を有する組成物 |
JP2021104970A (ja) * | 2019-12-26 | 2021-07-26 | ライオン株式会社 | 固形制汗剤組成物 |
JP7378292B2 (ja) | 2019-12-26 | 2023-11-13 | ライオン株式会社 | 固形制汗剤組成物 |
Also Published As
Publication number | Publication date |
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BR112013002631B1 (pt) | 2023-10-31 |
CA2807386A1 (en) | 2012-02-09 |
WO2012016642A1 (de) | 2012-02-09 |
EP2601166A1 (de) | 2013-06-12 |
JP5851504B2 (ja) | 2016-02-03 |
CN103068786A (zh) | 2013-04-24 |
US8940943B2 (en) | 2015-01-27 |
KR20130105597A (ko) | 2013-09-25 |
AU2011287985A1 (en) | 2013-02-21 |
US20130131188A1 (en) | 2013-05-23 |
CN103068786B (zh) | 2016-01-20 |
EP2426101A1 (de) | 2012-03-07 |
ES2622520T3 (es) | 2017-07-06 |
BR112013002631A2 (pt) | 2016-06-07 |
KR101881727B1 (ko) | 2018-07-25 |
EP2601166B1 (de) | 2017-01-18 |
MX2013001346A (es) | 2013-03-08 |
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