JP2013527567A - 充電式金属空気電池のための可溶性酸素発生触媒 - Google Patents
充電式金属空気電池のための可溶性酸素発生触媒 Download PDFInfo
- Publication number
- JP2013527567A JP2013527567A JP2013506357A JP2013506357A JP2013527567A JP 2013527567 A JP2013527567 A JP 2013527567A JP 2013506357 A JP2013506357 A JP 2013506357A JP 2013506357 A JP2013506357 A JP 2013506357A JP 2013527567 A JP2013527567 A JP 2013527567A
- Authority
- JP
- Japan
- Prior art keywords
- battery
- group
- oxygen
- battery according
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 192
- 239000001301 oxygen Substances 0.000 title claims abstract description 153
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 131
- 239000003054 catalyst Substances 0.000 title claims abstract description 68
- 239000003792 electrolyte Substances 0.000 claims abstract description 70
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 57
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 57
- 239000007788 liquid Substances 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 27
- 230000001590 oxidative effect Effects 0.000 claims abstract description 22
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 16
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 14
- 239000011148 porous material Substances 0.000 claims abstract description 13
- 239000011263 electroactive material Substances 0.000 claims abstract description 5
- 150000002500 ions Chemical class 0.000 claims abstract description 5
- -1 or Te Inorganic materials 0.000 claims description 72
- 229910018071 Li 2 O 2 Inorganic materials 0.000 claims description 68
- 229910052717 sulfur Inorganic materials 0.000 claims description 50
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 45
- 125000005842 heteroatom Chemical group 0.000 claims description 45
- 125000003118 aryl group Chemical group 0.000 claims description 37
- 229910052711 selenium Inorganic materials 0.000 claims description 35
- 239000011669 selenium Substances 0.000 claims description 35
- 229910052736 halogen Inorganic materials 0.000 claims description 31
- 150000002367 halogens Chemical class 0.000 claims description 31
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 30
- 125000000623 heterocyclic group Chemical group 0.000 claims description 30
- 125000002837 carbocyclic group Chemical group 0.000 claims description 29
- 239000002904 solvent Substances 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 28
- 229910052714 tellurium Inorganic materials 0.000 claims description 23
- 230000007306 turnover Effects 0.000 claims description 23
- 229910052723 transition metal Inorganic materials 0.000 claims description 20
- 229910001416 lithium ion Inorganic materials 0.000 claims description 18
- 150000003624 transition metals Chemical class 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 17
- 150000001491 aromatic compounds Chemical class 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 229910052744 lithium Inorganic materials 0.000 claims description 10
- 150000001449 anionic compounds Chemical class 0.000 claims description 9
- 229910001412 inorganic anion Inorganic materials 0.000 claims description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 8
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 8
- 239000003880 polar aprotic solvent Substances 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- 150000004820 halides Chemical class 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 125000002577 pseudohalo group Chemical group 0.000 claims description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000007784 solid electrolyte Substances 0.000 claims description 4
- 125000005259 triarylamine group Chemical group 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- 229910001424 calcium ion Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000002241 glass-ceramic Substances 0.000 claims description 3
- 239000002608 ionic liquid Substances 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 125000001741 organic sulfur group Chemical group 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229950000688 phenothiazine Drugs 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 229910001415 sodium ion Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- UJOBWOGCFQCDNV-UHFFFAOYSA-N Carbazole Natural products C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 claims description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 2
- 125000000609 carbazolyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- 229910001512 metal fluoride Inorganic materials 0.000 claims description 2
- 229910052987 metal hydride Inorganic materials 0.000 claims description 2
- 150000004681 metal hydrides Chemical class 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 239000013460 polyoxometalate Substances 0.000 claims description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 2
- 150000005029 thianthrenes Chemical class 0.000 claims description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- 229910052976 metal sulfide Inorganic materials 0.000 claims 1
- 125000001484 phenothiazinyl group Chemical class C1(=CC=CC=2SC3=CC=CC=C3NC12)* 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 13
- 239000003570 air Substances 0.000 description 167
- 210000004027 cell Anatomy 0.000 description 84
- 239000000047 product Substances 0.000 description 81
- 230000003647 oxidation Effects 0.000 description 62
- 238000007254 oxidation reaction Methods 0.000 description 62
- 238000012360 testing method Methods 0.000 description 52
- 150000001875 compounds Chemical class 0.000 description 43
- 241000894007 species Species 0.000 description 37
- 238000002474 experimental method Methods 0.000 description 36
- 239000000203 mixture Substances 0.000 description 34
- QXBUYALKJGBACG-UHFFFAOYSA-N 10-methylphenothiazine Chemical compound C1=CC=C2N(C)C3=CC=CC=C3SC2=C1 QXBUYALKJGBACG-UHFFFAOYSA-N 0.000 description 32
- 239000012071 phase Substances 0.000 description 31
- 229910052739 hydrogen Inorganic materials 0.000 description 30
- 230000000670 limiting effect Effects 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 28
- 238000009792 diffusion process Methods 0.000 description 26
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 25
- 230000009467 reduction Effects 0.000 description 24
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 20
- 229910020366 ClO 4 Inorganic materials 0.000 description 17
- 229910052740 iodine Inorganic materials 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 239000000126 substance Substances 0.000 description 17
- 229910052801 chlorine Inorganic materials 0.000 description 16
- 229910052731 fluorine Inorganic materials 0.000 description 16
- 101710178035 Chorismate synthase 2 Proteins 0.000 description 15
- 101710152694 Cysteine synthase 2 Proteins 0.000 description 15
- 229910052789 astatine Inorganic materials 0.000 description 15
- 229910052794 bromium Inorganic materials 0.000 description 15
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 14
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 239000000843 powder Substances 0.000 description 11
- 239000011541 reaction mixture Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 9
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 9
- 230000002829 reductive effect Effects 0.000 description 9
- 235000019439 ethyl acetate Nutrition 0.000 description 8
- 230000006870 function Effects 0.000 description 8
- 238000004502 linear sweep voltammetry Methods 0.000 description 8
- CJAOGUFAAWZWNI-UHFFFAOYSA-N 1-n,1-n,4-n,4-n-tetramethylbenzene-1,4-diamine Chemical compound CN(C)C1=CC=C(N(C)C)C=C1 CJAOGUFAAWZWNI-UHFFFAOYSA-N 0.000 description 7
- 230000000875 corresponding effect Effects 0.000 description 7
- 238000002484 cyclic voltammetry Methods 0.000 description 7
- 239000004810 polytetrafluoroethylene Substances 0.000 description 7
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- FHCPAXDKURNIOZ-UHFFFAOYSA-N tetrathiafulvalene Chemical class S1C=CSC1=C1SC=CS1 FHCPAXDKURNIOZ-UHFFFAOYSA-N 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000012267 brine Substances 0.000 description 6
- 238000004440 column chromatography Methods 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 6
- 239000008151 electrolyte solution Substances 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000002638 heterogeneous catalyst Substances 0.000 description 6
- 239000007773 negative electrode material Substances 0.000 description 6
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 5
- 238000005160 1H NMR spectroscopy Methods 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 5
- 239000010411 electrocatalyst Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 238000006056 electrooxidation reaction Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000000543 intermediate Substances 0.000 description 4
- 230000002427 irreversible effect Effects 0.000 description 4
- 150000004053 quinones Chemical class 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000000741 silica gel Substances 0.000 description 4
- 229910002027 silica gel Inorganic materials 0.000 description 4
- HMPWFXQSDUNCMF-UHFFFAOYSA-N 1-(2-ethylphenyl)-n-[[(2-ethylphenyl)methylamino]disulfanyl]methanamine Chemical compound CCC1=CC=CC=C1CNSSNCC1=CC=CC=C1CC HMPWFXQSDUNCMF-UHFFFAOYSA-N 0.000 description 3
- HNQNFZRNOJJPFM-UHFFFAOYSA-N 3-ethyl-1,3-benzothiazole-2-thione Chemical compound C1=CC=C2SC(=S)N(CC)C2=C1 HNQNFZRNOJJPFM-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003480 eluent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- OAYLNYINCPYISS-UHFFFAOYSA-N ethyl acetate;hexane Chemical compound CCCCCC.CCOC(C)=O OAYLNYINCPYISS-UHFFFAOYSA-N 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- CYPYTURSJDMMMP-WVCUSYJESA-N (1e,4e)-1,5-diphenylpenta-1,4-dien-3-one;palladium Chemical compound [Pd].[Pd].C=1C=CC=CC=1\C=C\C(=O)\C=C\C1=CC=CC=C1.C=1C=CC=CC=1\C=C\C(=O)\C=C\C1=CC=CC=C1.C=1C=CC=CC=1\C=C\C(=O)\C=C\C1=CC=CC=C1 CYPYTURSJDMMMP-WVCUSYJESA-N 0.000 description 2
- REHUVSDWCKMIAO-UHFFFAOYSA-N 3,6-difluoro-1-n,1-n,2-n,2-n,4-n,4-n,5-n,5-n-octamethylbenzene-1,2,4,5-tetramine Chemical compound CN(C)C1=C(F)C(N(C)C)=C(N(C)C)C(F)=C1N(C)C REHUVSDWCKMIAO-UHFFFAOYSA-N 0.000 description 2
- PVXFCOPBOYHONF-UHFFFAOYSA-N 3-ethyl-1,3-benzothiazol-2-one Chemical compound C1=CC=C2SC(=O)N(CC)C2=C1 PVXFCOPBOYHONF-UHFFFAOYSA-N 0.000 description 2
- JLHIDOFPSLZSHM-UHFFFAOYSA-N 3-ethyl-2-methylsulfanyl-2h-1,3-benzothiazole Chemical compound C1=CC=C2N(CC)C(SC)SC2=C1 JLHIDOFPSLZSHM-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 101100317222 Borrelia hermsii vsp3 gene Proteins 0.000 description 2
- 229910003771 Gold(I) chloride Inorganic materials 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910000733 Li alloy Inorganic materials 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical compound [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910021397 glassy carbon Inorganic materials 0.000 description 2
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- ZQBFAOFFOQMSGJ-UHFFFAOYSA-N hexafluorobenzene Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1F ZQBFAOFFOQMSGJ-UHFFFAOYSA-N 0.000 description 2
- 238000012613 in situ experiment Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000001989 lithium alloy Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000013110 organic ligand Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 230000036647 reaction Effects 0.000 description 2
- 230000027756 respiratory electron transport chain Effects 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- MFRIHAYPQRLWNB-UHFFFAOYSA-N sodium tert-butoxide Chemical compound [Na+].CC(C)(C)[O-] MFRIHAYPQRLWNB-UHFFFAOYSA-N 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- VIPKQVRVQSOXGZ-UHFFFAOYSA-N 1,4-diethyl-2,3-dihydroquinoxaline Chemical compound C1=CC=C2N(CC)CCN(CC)C2=C1 VIPKQVRVQSOXGZ-UHFFFAOYSA-N 0.000 description 1
- NAMDIHYPBYVYAP-UHFFFAOYSA-N 1-methoxy-2-(2-methoxyethoxy)ethane Chemical compound COCCOCCOC.COCCOCCOC NAMDIHYPBYVYAP-UHFFFAOYSA-N 0.000 description 1
- YPUWDDMFYRNEFX-UHFFFAOYSA-N 1-methoxy-2-[2-(2-methoxyethoxy)ethoxy]ethane Chemical compound COCCOCCOCCOC.COCCOCCOCCOC YPUWDDMFYRNEFX-UHFFFAOYSA-N 0.000 description 1
- RTYCZCFQHXCMGC-UHFFFAOYSA-N 1-methoxy-2-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]ethane Chemical compound COCCOCCOCCOCCOC.COCCOCCOCCOCCOC RTYCZCFQHXCMGC-UHFFFAOYSA-N 0.000 description 1
- XABNHQJAAXYGOW-UHFFFAOYSA-N 10-(4-methoxyphenyl)phenothiazine Chemical compound C1=CC(OC)=CC=C1N1C2=CC=CC=C2SC2=CC=CC=C21 XABNHQJAAXYGOW-UHFFFAOYSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- YEDUAINPPJYDJZ-UHFFFAOYSA-N 2-hydroxybenzothiazole Chemical compound C1=CC=C2SC(O)=NC2=C1 YEDUAINPPJYDJZ-UHFFFAOYSA-N 0.000 description 1
- YRNWIFYIFSBPAU-UHFFFAOYSA-N 4-[4-(dimethylamino)phenyl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C1=CC=C(N(C)C)C=C1 YRNWIFYIFSBPAU-UHFFFAOYSA-N 0.000 description 1
- QJPJQTDYNZXKQF-UHFFFAOYSA-N 4-bromoanisole Chemical compound COC1=CC=C(Br)C=C1 QJPJQTDYNZXKQF-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 1
- 239000002000 Electrolyte additive Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910013188 LiBOB Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012230 colorless oil Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 239000000412 dendrimer Substances 0.000 description 1
- 229920000736 dendritic polymer Polymers 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 125000005331 diazinyl group Chemical class N1=NC(=CC=C1)* 0.000 description 1
- SQKZZFWTOOPCDQ-UHFFFAOYSA-N dichloromethane;ethyl acetate;hexane Chemical compound ClCCl.CCCCCC.CCOC(C)=O SQKZZFWTOOPCDQ-UHFFFAOYSA-N 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- CNXMDTWQWLGCPE-UHFFFAOYSA-N ditert-butyl-(2-phenylphenyl)phosphane Chemical compound CC(C)(C)P(C(C)(C)C)C1=CC=CC=C1C1=CC=CC=C1 CNXMDTWQWLGCPE-UHFFFAOYSA-N 0.000 description 1
- 238000000840 electrochemical analysis Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 150000002170 ethers Chemical group 0.000 description 1
- 239000002024 ethyl acetate extract Substances 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011245 gel electrolyte Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000004770 highest occupied molecular orbital Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 238000006713 insertion reaction Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002540 isothiocyanates Chemical class 0.000 description 1
- 150000003951 lactams Chemical group 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- YDGSUPBDGKOGQT-UHFFFAOYSA-N lithium;dimethylazanide Chemical compound [Li+].C[N-]C YDGSUPBDGKOGQT-UHFFFAOYSA-N 0.000 description 1
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 1
- 238000004768 lowest unoccupied molecular orbital Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004660 morphological change Effects 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000002990 phenothiazines Chemical class 0.000 description 1
- GJSGGHOYGKMUPT-UHFFFAOYSA-N phenoxathiine Chemical class C1=CC=C2OC3=CC=CC=C3SC2=C1 GJSGGHOYGKMUPT-UHFFFAOYSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000004151 quinonyl group Chemical group 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 229910021561 transition metal fluoride Inorganic materials 0.000 description 1
- 229910000045 transition metal hydride Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000001075 voltammogram Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8626—Porous electrodes characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9008—Organic or organo-metallic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/923—Compounds thereof with non-metallic elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Hybrid Cells (AREA)
- Inert Electrodes (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32730410P | 2010-04-23 | 2010-04-23 | |
| US61/327,304 | 2010-04-23 | ||
| US39201410P | 2010-10-11 | 2010-10-11 | |
| US61/392,014 | 2010-10-11 | ||
| PCT/US2011/033821 WO2011133982A1 (en) | 2010-04-23 | 2011-04-25 | Soluble oxygen evolving catalysts for rechargeable metal-air batteries |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013527567A true JP2013527567A (ja) | 2013-06-27 |
| JP2013527567A5 JP2013527567A5 (cg-RX-API-DMAC7.html) | 2014-10-02 |
Family
ID=44834547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013506357A Pending JP2013527567A (ja) | 2010-04-23 | 2011-04-25 | 充電式金属空気電池のための可溶性酸素発生触媒 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US20120028137A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2561573B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2013527567A (cg-RX-API-DMAC7.html) |
| KR (1) | KR20130103333A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2011133982A1 (cg-RX-API-DMAC7.html) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015022858A1 (ja) * | 2013-08-15 | 2015-02-19 | 国立大学法人 東京大学 | リチウム－空気電池用電解液 |
| WO2015133139A1 (en) * | 2014-03-06 | 2015-09-11 | Sharp Kabushiki Kaisha | Battery anode with preloaded metals |
| US9178254B2 (en) | 2010-12-07 | 2015-11-03 | Samsung Electronics Co., Ltd. | Lithium air battery |
| JP2016110699A (ja) * | 2014-12-02 | 2016-06-20 | 日本電信電話株式会社 | リチウム空気二次電池 |
| JP2017507472A (ja) * | 2012-03-28 | 2017-03-16 | シャープ株式会社 | 予め充填された金属を有する電池の負極 |
| JP2017054760A (ja) * | 2015-09-11 | 2017-03-16 | 日本電信電話株式会社 | リチウム空気二次電池 |
| CN106732766A (zh) * | 2015-11-20 | 2017-05-31 | 现代自动车株式会社 | 用于锂‑空气电池的可溶性催化剂 |
| JP2017103215A (ja) * | 2015-12-01 | 2017-06-08 | 株式会社デンソー | 非水型マグネシウム酸素電池 |
| JP2017107786A (ja) * | 2015-12-11 | 2017-06-15 | 日本電信電話株式会社 | リチウム空気二次電池およびリチウム空気二次電池用電解質 |
| JP2018198183A (ja) * | 2017-05-25 | 2018-12-13 | 日本電信電話株式会社 | リチウム空気二次電池 |
| JP2019003935A (ja) * | 2017-06-12 | 2019-01-10 | パナソニックＩｐマネジメント株式会社 | リチウム空気電池 |
| JP2019003940A (ja) * | 2017-06-12 | 2019-01-10 | パナソニックＩｐマネジメント株式会社 | 空気電池 |
| JP2019046784A (ja) * | 2017-08-31 | 2019-03-22 | パナソニックＩｐマネジメント株式会社 | リチウム空気電池 |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9761878B2 (en) | 2010-09-23 | 2017-09-12 | Robert Bosch Gmbh | Metal/oxygen battery with a clean surface for oxidizing redox additives |
| US9431660B2 (en) | 2010-09-23 | 2016-08-30 | Robert Bosch Gmbh | Lithium battery with charging redox couple |
| WO2013077863A1 (en) * | 2011-11-22 | 2013-05-30 | Robert Bosch Gmbh | Lithium battery with charging redox couple |
| KR101899483B1 (ko) * | 2011-11-30 | 2018-09-18 | 삼성전자주식회사 | 리튬 공기 전지 |
| KR101887534B1 (ko) * | 2012-04-03 | 2018-08-13 | 삼성전자주식회사 | 리튬 공기 전지의 충전 방법 |
| JP6187458B2 (ja) * | 2012-06-05 | 2017-08-30 | 日本電気株式会社 | リチウム二次電池 |
| JP5660086B2 (ja) * | 2012-08-08 | 2015-01-28 | 株式会社デンソー | マグネシウム二次電池 |
| EP2883269B1 (en) * | 2012-08-10 | 2019-05-08 | Robert Bosch GmbH | Controlling the location of product distribution and removal in a metal/oxygen cell |
| KR101571588B1 (ko) | 2012-09-11 | 2015-11-24 | 주식회사 두산 | 퀴녹살린계 유기발광 화합물 및 이를 이용한 유기 전계 발광 소자 |
| JP6252486B2 (ja) | 2012-11-20 | 2017-12-27 | 日本電気株式会社 | リチウムイオン二次電池 |
| US9450278B2 (en) | 2012-12-20 | 2016-09-20 | International Business Machines Corporation | Cathode material for lithium—oxygen battery |
| JP5854009B2 (ja) * | 2012-12-26 | 2016-02-09 | 株式会社デンソー | マグネシウム二次電池用負極の表面処理方法 |
| DE102013200585A1 (de) * | 2013-01-16 | 2014-07-31 | Siemens Aktiengesellschaft | Wiederaufladbarer elektrischer Energiespeicher |
| CN103474671B (zh) * | 2013-09-13 | 2015-10-28 | 深圳大学 | 一种锂空气电池用碳-过氧化锂正极及其制备方法 |
| KR101600141B1 (ko) | 2013-10-11 | 2016-03-04 | 서울대학교산학협력단 | 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지 |
| KR20150057260A (ko) * | 2013-11-19 | 2015-05-28 | 한양대학교 산학협력단 | 리튬 공기 전지용 양극 및 이를 포함하는 리튬 공기 전지 |
| CN103633308A (zh) * | 2013-11-28 | 2014-03-12 | 宁波金和新材料股份有限公司 | 一种富锂镍钴铝氧正极材料及其制备方法 |
| WO2015148357A1 (en) * | 2014-03-24 | 2015-10-01 | Cornell University | Symmetric redox flow battery containing organic redox active molecule |
| WO2015148358A1 (en) | 2014-03-24 | 2015-10-01 | Cornell University | Solar flow battery |
| US9343787B2 (en) | 2014-07-30 | 2016-05-17 | Toyota Motor Engineering & Manufacturing North America, Inc. | Lithium-air battery with sodium salt as mediator |
| US11050077B2 (en) | 2014-08-15 | 2021-06-29 | National University Of Singapore | Battery system |
| US9954222B2 (en) * | 2014-12-10 | 2018-04-24 | Basf Corporation | Metal hydride compositions and lithium ion batteries |
| CN106328964B (zh) * | 2015-06-25 | 2019-04-23 | 清华大学 | 金属空气电池正极及金属空气电池 |
| EP3116052A1 (en) | 2015-07-08 | 2017-01-11 | Basf Se | Rechargeable metal-oxygen cells |
| US10103402B2 (en) | 2015-12-01 | 2018-10-16 | University Of Kentucky Research Foundation | Liquid phenothiazine catholytes for non-aqueous redox flow batteries |
| JP2017022096A (ja) * | 2016-06-28 | 2017-01-26 | ロベルト・ボッシュ・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツングＲｏｂｅｒｔ Ｂｏｓｃｈ Ｇｍｂｈ | 電気化学セル |
| EP3267514B1 (en) * | 2016-07-06 | 2021-01-27 | LiCAP Technologies, Inc. | Lithium attached electrodes and method of making same |
| US10177427B2 (en) * | 2017-02-10 | 2019-01-08 | General Electric Company | Electrochemical cell for use in high temperature metal-air battery |
| US10826145B2 (en) | 2017-02-10 | 2020-11-03 | General Electric Company | Electrochemical cell for use in high temperature metal-air battery |
| US11515566B2 (en) | 2020-04-26 | 2022-11-29 | International Business Machines Corporation | Liquid cathode formulation for rechargeable metal halide battery |
| CN113976099B (zh) * | 2021-11-23 | 2023-06-27 | 山东交通学院 | 一种负载氧化钙的磁性多孔碱性碳材料、其制备方法及应用 |
| CN116207313B (zh) * | 2023-05-06 | 2023-07-11 | 苏州擎动动力科技有限公司 | 自增湿膜电极及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080096061A1 (en) * | 2006-06-12 | 2008-04-24 | Revolt Technology Ltd | Metal-Air Battery or Fuel Cell |
| JP2010033890A (ja) * | 2008-07-29 | 2010-02-12 | Toyota Central R&D Labs Inc | リチウム空気電池 |
| JP2010167390A (ja) * | 2009-01-26 | 2010-08-05 | Nec Corp | 酸素還元触媒、それを用いた燃料電池および空気電池、酸素還元触媒の製造方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3316126A (en) * | 1962-03-01 | 1967-04-25 | Pullman Inc | Fuel cell |
| US4255498A (en) * | 1979-10-26 | 1981-03-10 | Toshiba Ray-O-Vac Co., Ltd. | Button-type air cell |
| US6908710B2 (en) * | 2001-10-09 | 2005-06-21 | Valence Technology, Inc. | Lithiated molybdenum oxide active materials |
| US7645543B2 (en) * | 2002-10-15 | 2010-01-12 | Polyplus Battery Company | Active metal/aqueous electrochemical cells and systems |
| US6855453B2 (en) * | 2002-12-30 | 2005-02-15 | Utc Fuel Cells, Llc | Fuel cell having a corrosion resistant and protected cathode catalyst layer |
| JP2004319324A (ja) * | 2003-04-17 | 2004-11-11 | Matsushita Electric Ind Co Ltd | 電気化学デバイス |
| US7238440B2 (en) * | 2003-10-03 | 2007-07-03 | E. I. Du Pont De Nemours And Company | Membrane free fuel cell |
| US7282295B2 (en) * | 2004-02-06 | 2007-10-16 | Polyplus Battery Company | Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture |
| KR100570359B1 (ko) * | 2004-12-23 | 2006-04-12 | 비나텍주식회사 | 하이브리드 전지 |
| GB0505087D0 (en) * | 2005-03-12 | 2005-04-20 | Acal Energy Ltd | Fuel cells |
| CN101147286A (zh) * | 2005-08-25 | 2008-03-19 | 松下电器产业株式会社 | 氧还原用电极 |
| AU2006323993A1 (en) * | 2005-12-06 | 2007-06-14 | Revolt Technology Ltd | Bifunctional air electrode |
| US20110123877A1 (en) * | 2007-08-23 | 2011-05-26 | Nec Corporation | Catalyst for oxygen reduction electrode and oxygen reduction electrode |
| US20090053594A1 (en) * | 2007-08-23 | 2009-02-26 | Johnson Lonnie G | Rechargeable air battery and manufacturing method |
| JP5315831B2 (ja) * | 2008-03-24 | 2013-10-16 | 株式会社豊田中央研究所 | リチウム空気電池 |
| US7842637B2 (en) * | 2008-05-23 | 2010-11-30 | Lumimove, Inc. | Electroactivated film with polymer gel electrolyte |
| US20100266907A1 (en) * | 2008-11-04 | 2010-10-21 | Rachid Yazami | Metal air battery system |
| CN101960664B (zh) * | 2008-12-25 | 2014-06-04 | 丰田自动车株式会社 | 锂空气电池 |
| KR20120063163A (ko) * | 2010-12-07 | 2012-06-15 | 삼성전자주식회사 | 리튬 공기 전지 |
-
2011
- 2011-04-25 JP JP2013506357A patent/JP2013527567A/ja active Pending
- 2011-04-25 EP EP11772854.3A patent/EP2561573B1/en active Active
- 2011-04-25 US US13/093,759 patent/US20120028137A1/en not_active Abandoned
- 2011-04-25 KR KR1020127030602A patent/KR20130103333A/ko not_active Withdrawn
- 2011-04-25 WO PCT/US2011/033821 patent/WO2011133982A1/en not_active Ceased
-
2020
- 2020-09-11 US US17/018,965 patent/US20200411933A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080096061A1 (en) * | 2006-06-12 | 2008-04-24 | Revolt Technology Ltd | Metal-Air Battery or Fuel Cell |
| JP2010033890A (ja) * | 2008-07-29 | 2010-02-12 | Toyota Central R&D Labs Inc | リチウム空気電池 |
| JP2010167390A (ja) * | 2009-01-26 | 2010-08-05 | Nec Corp | 酸素還元触媒、それを用いた燃料電池および空気電池、酸素還元触媒の製造方法 |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9178254B2 (en) | 2010-12-07 | 2015-11-03 | Samsung Electronics Co., Ltd. | Lithium air battery |
| JP2017507472A (ja) * | 2012-03-28 | 2017-03-16 | シャープ株式会社 | 予め充填された金属を有する電池の負極 |
| WO2015022858A1 (ja) * | 2013-08-15 | 2015-02-19 | 国立大学法人 東京大学 | リチウム－空気電池用電解液 |
| WO2015133139A1 (en) * | 2014-03-06 | 2015-09-11 | Sharp Kabushiki Kaisha | Battery anode with preloaded metals |
| JP2016110699A (ja) * | 2014-12-02 | 2016-06-20 | 日本電信電話株式会社 | リチウム空気二次電池 |
| JP2017054760A (ja) * | 2015-09-11 | 2017-03-16 | 日本電信電話株式会社 | リチウム空気二次電池 |
| CN106732766B (zh) * | 2015-11-20 | 2021-04-27 | 现代自动车株式会社 | 用于锂-空气电池的可溶性催化剂 |
| CN106732766A (zh) * | 2015-11-20 | 2017-05-31 | 现代自动车株式会社 | 用于锂‑空气电池的可溶性催化剂 |
| JP2017098215A (ja) * | 2015-11-20 | 2017-06-01 | 現代自動車株式会社Ｈｙｕｎｄａｉ Ｍｏｔｏｒ Ｃｏｍｐａｎｙ | リチウム−空気電池用液相触媒 |
| JP2017103215A (ja) * | 2015-12-01 | 2017-06-08 | 株式会社デンソー | 非水型マグネシウム酸素電池 |
| JP2017107786A (ja) * | 2015-12-11 | 2017-06-15 | 日本電信電話株式会社 | リチウム空気二次電池およびリチウム空気二次電池用電解質 |
| JP2018198183A (ja) * | 2017-05-25 | 2018-12-13 | 日本電信電話株式会社 | リチウム空気二次電池 |
| JP2019003935A (ja) * | 2017-06-12 | 2019-01-10 | パナソニックＩｐマネジメント株式会社 | リチウム空気電池 |
| JP2019003940A (ja) * | 2017-06-12 | 2019-01-10 | パナソニックＩｐマネジメント株式会社 | 空気電池 |
| US10629970B2 (en) | 2017-06-12 | 2020-04-21 | Panasonic Intellectual Property Management Co., Ltd. | Lithium air battery including negative electrode, positive electrode, nonaqueous lithium ion conductor, and copper ion |
| US10665867B2 (en) | 2017-06-12 | 2020-05-26 | Panasonic Intellectual Property Management Co., Ltd. | Air battery including negative electrode, positive electrode, nonaqueous metal ion conductor, and oxygen evolving catalyst |
| JP2019046784A (ja) * | 2017-08-31 | 2019-03-22 | パナソニックＩｐマネジメント株式会社 | リチウム空気電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20200411933A1 (en) | 2020-12-31 |
| WO2011133982A1 (en) | 2011-10-27 |
| EP2561573A4 (en) | 2016-09-14 |
| US20120028137A1 (en) | 2012-02-02 |
| EP2561573A1 (en) | 2013-02-27 |
| EP2561573B1 (en) | 2020-03-25 |
| KR20130103333A (ko) | 2013-09-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20200411933A1 (en) | Soluble oxygen evolving catalysts for rechargeable metal-air batteries | |
| Shu et al. | Understanding the reaction chemistry during charging in aprotic lithium–oxygen batteries: existing problems and solutions | |
| Qin et al. | Superoxide-based K–O2 batteries: highly reversible oxygen redox solves challenges in air electrodes | |
| Yadegari et al. | Sodium‐oxygen batteries: a comparative review from chemical and electrochemical fundamentals to future perspective | |
| Kolek et al. | Mechanism of charge/discharge of poly (vinylphenothiazine)-based Li–organic batteries | |
| Bergner et al. | How to improve capacity and cycling stability for next generation Li–O2 batteries: approach with a solid electrolyte and elevated redox mediator concentrations | |
| JP3555097B2 (ja) | 電極材料及び二次電池 | |
| Kwon et al. | Stability of glyme solvate ionic liquid as an electrolyte for rechargeable Li− O2 batteries | |
| Lee et al. | Polyoxometalate as a Nature-Inspired Bifunctional Catalyst for Lithium–Oxygen Batteries | |
| Lyu et al. | A dicyanobenzoquinone based cathode material for rechargeable lithium and sodium ion batteries | |
| Trahan et al. | Solvent-coupled catalysis of the oxygen electrode reactions in lithium-air batteries | |
| JPH09153362A (ja) | 電極材料及び二次電池 | |
| Liu et al. | Prevention of Na corrosion and dendrite growth for long-life flexible Na–air batteries | |
| Gabaudan et al. | Electrochemical alloying of lead in potassium-ion batteries | |
| Wang et al. | Benzene-bridged anthraquinones as a high-rate and long-lifespan organic cathode for advanced Na-ion batteries | |
| CN103311602B (zh) | 一种锂空气电池用电解液及相应的电池产品 | |
| JP6716364B2 (ja) | リチウム−空気電池用液相触媒 | |
| US10727488B2 (en) | Redox mediators for metal-sulfur batteries | |
| Goodarzi et al. | Assessing the performance of cobalt phthalocyanine nanoflakes as molecular catalysts for Li-promoted oxalate formation in Li–CO2–oxalate batteries | |
| JP2012133918A (ja) | 蓄電デバイス及び電極活物質の製造方法 | |
| He et al. | The Key Role of Magnesium Polysulfides in the Development of Mg-S Batteries | |
| KR20210112341A (ko) | 비대칭형 전해질 염 및 이러한 염을 혼입한 배터리 | |
| Xing et al. | An efficient multifunctional soluble catalyst for Li-O2 batteries | |
| Lin et al. | A comprehensive overview of the electrochemical mechanisms in emerging alkali metal–carbon dioxide batteries | |
| Qu et al. | Anionic Chemistry Modulation Enabled Environmental Self‐Charging Aqueous Zinc Batteries: The Case of Carbonate Ions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140425 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140425 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20140606 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140704 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140626 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150128 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150303 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150602 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150703 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150801 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20151203 |