JP2013519000A - 炭素繊維糸およびその製造方法 - Google Patents
炭素繊維糸およびその製造方法 Download PDFInfo
- Publication number
- JP2013519000A JP2013519000A JP2012551693A JP2012551693A JP2013519000A JP 2013519000 A JP2013519000 A JP 2013519000A JP 2012551693 A JP2012551693 A JP 2012551693A JP 2012551693 A JP2012551693 A JP 2012551693A JP 2013519000 A JP2013519000 A JP 2013519000A
- Authority
- JP
- Japan
- Prior art keywords
- fibers
- carbon fiber
- spun yarn
- yarn
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 115
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 115
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000000835 fiber Substances 0.000 claims abstract description 93
- 239000002699 waste material Substances 0.000 claims abstract description 30
- 239000004744 fabric Substances 0.000 claims abstract description 29
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 206010011906 Death Diseases 0.000 claims abstract description 8
- 238000004804 winding Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 53
- 239000000463 material Substances 0.000 claims description 41
- 238000002156 mixing Methods 0.000 claims description 16
- 239000011159 matrix material Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 14
- 238000009987 spinning Methods 0.000 claims description 14
- 238000009960 carding Methods 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 11
- -1 polyethylene Polymers 0.000 claims description 9
- 229920001169 thermoplastic Polymers 0.000 claims description 9
- 239000004416 thermosoftening plastic Substances 0.000 claims description 9
- 238000005520 cutting process Methods 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 239000012783 reinforcing fiber Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920005992 thermoplastic resin Polymers 0.000 claims description 4
- 229920003235 aromatic polyamide Polymers 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 229920006253 high performance fiber Polymers 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000004753 textile Substances 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920000508 Vectran Polymers 0.000 claims description 2
- 239000004979 Vectran Substances 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- 238000010040 friction spinning Methods 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 238000007383 open-end spinning Methods 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 2
- 229920006393 polyether sulfone Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- 238000007378 ring spinning Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000009816 wet lamination Methods 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims 1
- 238000005304 joining Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 2
- 230000008569 process Effects 0.000 description 12
- 238000012545 processing Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 4
- 239000004918 carbon fiber reinforced polymer Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000239290 Araneae Species 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010036 direct spinning Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
- D01G11/00—Disintegrating fibre-containing articles to obtain fibres for re-use
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
- D01G1/00—Severing continuous filaments or long fibres, e.g. stapling
- D01G1/06—Converting tows to slivers or yarns, e.g. in direct spinning
- D01G1/10—Converting tows to slivers or yarns, e.g. in direct spinning by cutting
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
- D01G13/00—Mixing, e.g. blending, fibres; Mixing non-fibrous materials with fibres
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
- D01G15/00—Carding machines or accessories; Card clothing; Burr-crushing or removing arrangements associated with carding or other preliminary-treatment machines
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
- D01G15/00—Carding machines or accessories; Card clothing; Burr-crushing or removing arrangements associated with carding or other preliminary-treatment machines
- D01G15/84—Card clothing; Manufacture thereof not otherwise provided for
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
- D01G19/00—Combing machines
- D01G19/06—Details
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/06—Threads formed from strip material other than paper
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Nonwoven Fabrics (AREA)
- Processing Of Solid Wastes (AREA)
- Inorganic Fibers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1001868.7A GB2477531B (en) | 2010-02-05 | 2010-02-05 | Carbon fibre yarn and method for the production thereof |
| GB1001868.7 | 2010-02-05 | ||
| PCT/GB2011/050208 WO2011095826A2 (en) | 2010-02-05 | 2011-02-07 | Carbon fibre yarn and method for the production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013519000A true JP2013519000A (ja) | 2013-05-23 |
| JP2013519000A5 JP2013519000A5 (enExample) | 2014-03-27 |
Family
ID=42082503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012551693A Pending JP2013519000A (ja) | 2010-02-05 | 2011-02-07 | 炭素繊維糸およびその製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9404202B2 (enExample) |
| EP (1) | EP2531638A2 (enExample) |
| JP (1) | JP2013519000A (enExample) |
| CA (1) | CA2826613C (enExample) |
| GB (1) | GB2477531B (enExample) |
| WO (1) | WO2011095826A2 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160012429A (ko) * | 2014-07-24 | 2016-02-03 | 코오롱인더스트리 주식회사 | 탄소섬유 스테이플을 포함하는 방적사 및 그의 제조방법 |
| JP2018035492A (ja) * | 2016-08-29 | 2018-03-08 | ロッテ アドバンスト マテリアルズ カンパニー リミテッド | 炭素繊維ステープルを含む紡績糸及びその製造方法 |
| JP7140438B1 (ja) | 2022-04-15 | 2022-09-21 | 竹本油脂株式会社 | 炭素繊維紡績糸製造用処理剤、及び炭素繊維紡績糸 |
| JP2023020666A (ja) * | 2021-07-30 | 2023-02-09 | 帝人株式会社 | 再生炭素繊維及び熱可塑性樹脂繊維の混紡糸並びに炭素繊維強化熱可塑性樹脂ペレット |
| KR20240053439A (ko) * | 2022-10-17 | 2024-04-24 | 임수빈 | 탄소섬유 및 닥섬유를 이용한 도전사의 제조방법 |
| EP4435162A1 (en) | 2023-03-20 | 2024-09-25 | Kabushiki Kaisha Toyota Jidoshokki | Fiber structure and fiber-reinforced composite material |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010028433A1 (de) * | 2010-04-30 | 2011-11-03 | Deutsche Institute Für Textil- Und Faserforschung Denkendorf | Hybridgarn zur Herstellung von Formteilen |
| KR101494507B1 (ko) * | 2010-11-03 | 2015-02-17 | 에스지엘 오토모티브 카본 파이버스 게임베하 운트 코. 카게 | 보강된 부직포 |
| ITRM20110520A1 (it) * | 2011-10-04 | 2013-04-05 | Agenzia Naz Per Le Nuove Tecn Ologie L Ener | Metodo per la realizzazione di filati di fibre di carbonio di riciclo. |
| ITRM20120118A1 (it) * | 2012-03-26 | 2013-09-27 | Agenzia Naz Per Le Nuove Tecn Ologie L Ener | Metodo per la realizzazione di feltri da fibre di carbonio di riciclo. |
| DE102012206384B4 (de) * | 2012-04-18 | 2022-10-13 | Bayerische Motoren Werke Aktiengesellschaft | Faser-Flechtprofil |
| US8920932B2 (en) | 2012-07-19 | 2014-12-30 | Empire Technology Development Llc | Recycling carbon fibers from epoxy using solvent cracking |
| GB201215855D0 (en) * | 2012-09-05 | 2012-10-24 | Univ Ulster | Carbon fibre composites |
| DE102012025181A1 (de) * | 2012-12-26 | 2014-06-26 | Hubert Hergeth | Verfahren und Vorrichtung zum Trennen von Nähfäden und Karbonfasern |
| CN103571036A (zh) * | 2013-11-13 | 2014-02-12 | 上海交通大学 | 回收碳纤维增强聚丙烯复合材料及其制备方法 |
| CN103938307B (zh) * | 2014-03-27 | 2016-04-27 | 浙江中鼎纺织有限公司 | 一种半精纺梳毛工艺及其设备 |
| EP3015576A1 (de) | 2014-10-27 | 2016-05-04 | Basf Se | Verfahren und Vorrichtung zur Herstellung von Carbonfaserhalbzeugen |
| US11257047B2 (en) | 2015-03-28 | 2022-02-22 | Psil Holdings Llc | Method and system of processing waste fabrics to rejuvenated fibrous materials |
| CN105256426A (zh) * | 2015-09-16 | 2016-01-20 | 太仓市良鑫化纤有限公司 | 一种导电防静电混纺纤维 |
| US12051527B2 (en) * | 2016-01-20 | 2024-07-30 | Federal-Mogul Powertrain Llc | Abrasion resistant textile sleeve, improved multifilament yarn therefor and methods of construction thereof |
| DE202016001344U1 (de) | 2016-03-02 | 2016-03-16 | Plamen Kravaev | Vorlagematerialien für die Produktion von Halbzeugen aus aktivierten Kohlenstofffasern |
| JP6855503B2 (ja) | 2016-03-30 | 2021-04-07 | バルテガ インコーポレイテッドVartega Inc. | 繊維強化複合材からの強化用繊維の回収 |
| JP6334073B1 (ja) | 2016-08-25 | 2018-05-30 | ジャパンマテックス株式会社 | 撚糸、開繊糸、炭素繊維被覆撚糸、及びそれらの製造方法 |
| KR101993960B1 (ko) | 2016-10-31 | 2019-06-27 | 롯데첨단소재(주) | 탄소 섬유 강화 플라스틱용 직조물 및 이로부터 형성된 성형품 |
| WO2018123290A1 (ja) * | 2016-12-26 | 2018-07-05 | 共和レザー株式会社 | 合成皮革 |
| US10829611B1 (en) | 2017-09-06 | 2020-11-10 | Vartega, Inc. | Recovery of reinforcing fibers from continuous fiber-reinforced composites |
| US11135743B1 (en) | 2017-10-04 | 2021-10-05 | Vartega Inc. | Removal of sizing material from reinforcing fibers for recycling of reinforcing fibers |
| US10610911B1 (en) | 2017-10-04 | 2020-04-07 | Vartega Inc. | Cosolvent processing of reinforcing fiber-containing products for recycling reinforcing fibers |
| EP3725923A1 (en) * | 2019-04-16 | 2020-10-21 | Calik Denim Tekstil San. Ve Tic. A.S. | Composite yarn, fabric comprising the composite yarn, method for producing a composite yarn and arrangement for producing a composite yarn |
| US20220195633A1 (en) * | 2019-05-06 | 2022-06-23 | Avery Dennison Retail Information Services Llc | A fiber from waste material and methods of producing |
| US20250122651A1 (en) * | 2021-08-25 | 2025-04-17 | Mitsubishi Gas Chemical Company, Inc. | Strand, driving part, method for producing strand, and winding body |
| ES3015309B2 (es) * | 2023-10-27 | 2025-10-20 | Asociacion De Investig De La Industria Textil Aitex | Procedimiento de obtencion de un hilo hibrido continuo e hilo hibrido continuo obtenido por dicho procedimiento |
| US20250297476A1 (en) * | 2024-03-20 | 2025-09-25 | Saudi Arabian Oil Company | Suspended ceiling system and method |
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| JPH0327122A (ja) * | 1985-04-18 | 1991-02-05 | Dow Chem Co:The | 炭素質繊維の製造法 |
| JPH05193030A (ja) * | 1991-08-15 | 1993-08-03 | B F Goodrich Co:The | ブレード造形フィラメント構造体及びその製造方法 |
| JPH06298993A (ja) * | 1993-04-15 | 1994-10-25 | Kobe Steel Ltd | 炭素繊維強化複合材料の熱分解処理方法 |
| JP2005179809A (ja) * | 2003-12-17 | 2005-07-07 | Kureha Chem Ind Co Ltd | ピッチ系炭素繊維スライバー及び紡績糸の製造方法 |
| JP2008303872A (ja) * | 2007-05-07 | 2008-12-18 | Oishi Corporation:Kk | 空気除電用材 |
| JP3152748U (ja) * | 2009-05-31 | 2009-08-13 | エアテクス株式会社 | カーボン不織布 |
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| FR2446336A1 (fr) * | 1979-01-10 | 1980-08-08 | Payen & Cie L | Nouveau type de fil textile guipe et procede pour son obtention |
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- 2011-02-07 JP JP2012551693A patent/JP2013519000A/ja active Pending
- 2011-02-07 WO PCT/GB2011/050208 patent/WO2011095826A2/en not_active Ceased
- 2011-02-07 EP EP11704090A patent/EP2531638A2/en not_active Withdrawn
- 2011-02-07 CA CA2826613A patent/CA2826613C/en not_active Expired - Fee Related
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160012429A (ko) * | 2014-07-24 | 2016-02-03 | 코오롱인더스트리 주식회사 | 탄소섬유 스테이플을 포함하는 방적사 및 그의 제조방법 |
| KR102113535B1 (ko) * | 2014-07-24 | 2020-05-21 | 코오롱인더스트리 주식회사 | 탄소섬유 스테이플을 포함하는 방적사 및 그의 제조방법 |
| JP2018035492A (ja) * | 2016-08-29 | 2018-03-08 | ロッテ アドバンスト マテリアルズ カンパニー リミテッド | 炭素繊維ステープルを含む紡績糸及びその製造方法 |
| JP2023020666A (ja) * | 2021-07-30 | 2023-02-09 | 帝人株式会社 | 再生炭素繊維及び熱可塑性樹脂繊維の混紡糸並びに炭素繊維強化熱可塑性樹脂ペレット |
| JP7140438B1 (ja) | 2022-04-15 | 2022-09-21 | 竹本油脂株式会社 | 炭素繊維紡績糸製造用処理剤、及び炭素繊維紡績糸 |
| WO2023199879A1 (ja) * | 2022-04-15 | 2023-10-19 | 竹本油脂株式会社 | 炭素繊維紡績糸製造用処理剤、及び炭素繊維紡績糸 |
| JP2023157607A (ja) * | 2022-04-15 | 2023-10-26 | 竹本油脂株式会社 | 炭素繊維紡績糸製造用処理剤、及び炭素繊維紡績糸 |
| KR20240053439A (ko) * | 2022-10-17 | 2024-04-24 | 임수빈 | 탄소섬유 및 닥섬유를 이용한 도전사의 제조방법 |
| KR102736120B1 (ko) | 2022-10-17 | 2024-11-28 | 임수빈 | 탄소섬유 및 닥섬유를 이용한 도전사의 제조방법 |
| EP4435162A1 (en) | 2023-03-20 | 2024-09-25 | Kabushiki Kaisha Toyota Jidoshokki | Fiber structure and fiber-reinforced composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| US20130192189A1 (en) | 2013-08-01 |
| US9404202B2 (en) | 2016-08-02 |
| WO2011095826A2 (en) | 2011-08-11 |
| WO2011095826A3 (en) | 2011-10-06 |
| EP2531638A2 (en) | 2012-12-12 |
| GB201001868D0 (en) | 2010-03-24 |
| GB2477531B (en) | 2015-02-18 |
| CA2826613C (en) | 2019-01-15 |
| CA2826613A1 (en) | 2011-08-11 |
| GB2477531A (en) | 2011-08-10 |
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