JP2013518981A - 省エネルギー型防食用金属塗膜組成物及びその製造方法 - Google Patents
省エネルギー型防食用金属塗膜組成物及びその製造方法 Download PDFInfo
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 72
- 239000002184 metal Substances 0.000 title claims abstract description 72
- 239000008199 coating composition Substances 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 58
- 239000011347 resin Substances 0.000 claims abstract description 58
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 28
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002245 particle Substances 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 13
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims abstract description 12
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 11
- QLNOVKKVHFRGMA-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical group [CH2]CC[Si](OC)(OC)OC QLNOVKKVHFRGMA-UHFFFAOYSA-N 0.000 claims abstract description 10
- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 claims abstract description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 239000011777 magnesium Substances 0.000 claims abstract description 6
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- 238000000034 method Methods 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 19
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 6
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052726 zirconium Inorganic materials 0.000 abstract description 2
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
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- 239000002518 antifoaming agent Substances 0.000 description 3
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- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
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- 238000011109 contamination Methods 0.000 description 1
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- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- -1 polyoxypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
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- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
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Abstract
【解決手段】本発明の省エネルギー型防食用金属塗膜組成物は、5〜10μmの粒子サイズを有し、アルミニウム、マグネシウム及びその合金よりなる群から選択される少なくとも一つの金属粉末と、ジルコニウムテトラ−n−ブタノラート、ジルコニウムブトキシド、イソプロピルチタネート、及びその混合物よりなる群から選択される第1ゾルゲル樹脂と、トリ−(3−(トリメトキシシリル)プロピル)イソシアヌレート、γ−メタクリルオキシプロピルトリメトキシシラン、n−フェニル−γ−アミノプロピルトリメトキシシラン、及びその混合物よりなる群から選ばれる第2ゾルゲル樹脂と、溶媒とを含んでなる。
【選択図】なし
Description
粒子サイズ8μmのアルミニウムマグネシウム合金90重量部及び粒子サイズ8μmのアルミニウム35重量部にアセトン70重量部を2時間常温で混合し、温度を15℃に調節した後、ジルコニウムテトラ−n−ブタノラート29重量部、ジルコニウムブトキシド15重量部、及びイソプロピルチタネート5重量部を添加して5時間、400rpmで攪拌し、その後に、温度を10℃、攪拌速度を100rpmにそれぞれ低下した後、トリ−(3−(トリメトキシシリル)プロピル)イソシアヌレート35重量部、γ−メタクリルオキシプロピルトリメトキシシラン60重量部、及びn−フェニル−γ−アミノプロピルトリメトキシシラン55重量部を添加して5時間攪拌し、防食用金属塗膜組成物を製造した。
ジルコニウムテトラ−n−ブタノラートを20重量部とし、他は実施例1と同一の配合にして、防食用金属塗膜組成物を製造した。
ジルコニウムブトキシドを10重量部とし、他は実施例1と同一の配合にして、防食用金属塗膜組成物を製造した。
金属粉末として、アルミニウムマグネシウム合金とアルミニウムの混合物を使用する代わりに、粒子サイズ8μmのアルミニウム125重量部のみを使用した以外は、実施例1と同様にして、防食用金属塗膜組成物を製造した。
第1ゾルゲル樹脂と第2ゾルゲル樹脂を順次入れる以外は、実施例1と同様の条件で混合及び攪拌して、防食用金属塗膜組成物を製造した。
アルミニウムマグネシウムとして粒子サイズ15μmのものを使用した以外は、実施例1と同様にして、防食用金属塗膜組成物を製造した。
アルミニウムマグネシウムとしてサイズ20μmのものを使用した以外は、実施例1と同様にして、防食用金属塗膜組成物を製造した。
ゾルゲル樹脂の代わりにエポキシを使用した以外は、実施例1と同様にして、防食用金属塗膜組成物を製造した。
鋼鉄の表面に、前記実施例及び比較例で製造された防食用金属塗膜組成物をスプレー法で塗布した後、乾く前に、韓国特許第10−0848671号(2008.7.28公告)の組成物であるシラン変性エポキシ樹脂系を用いてスプレーで塗布して厚さ20〜25μmの複合防食性塗膜を形成し、耐酸性、密着性、耐水密着性、耐食性及び金属層の這い上がり現象を測定した。その結果を表1に示す。前記防食性塗膜は、いずれも130℃の温度で約10分間硬化させたもので、具体的な方法は表1のとおりまとめた。
Claims (9)
- 5〜10μmの粒子サイズを有し、アルミニウム、マグネシウム及びその合金よりなる群から選ばれる少なくとも一つの金属粉末と、
ジルコニウムテトラ−n−ブタノラート、ジルコニウムブトキシド、イソプロピルチタネート、及びその混合物よりなる群から選択される第1ゾルゲル樹脂と、
トリ−(3−(トリメトキシシリル)プロピル)イソシアヌレート、γ−メタクリルオキシプロピルトリメトキシシラン、及びn−フェニル−γ−アミノプロピルトリメトキシシラン、及びその混合物よりなる群から選択される第2ゾルゲル樹脂と、
溶媒とを含んでなる、省エネルギー型防食用金属塗膜組成物。 - 前記金属粉末は100〜160重量部、前記第1ゾルゲル樹脂は35〜60重量部、前記第2ゾルゲル樹脂は165〜250重量部、前記溶媒は60〜90重量部である、請求項1に記載の省エネルギー型防食用金属塗膜組成物。
- 前記金属粉末は、アルミニウムマグネシウム合金70〜100重量部とアルミニウム30〜60重量部から構成される、請求項2に記載の省エネルギー型防食用金属塗膜組成物。
- 前記第1ゾルゲル樹脂は、ジルコニウムテトラ−n−ブタノラート20〜30重量部、ジルコニウムブトキシド10〜20重量部、及びイソプロピルチタネート5〜10重量部から構成される、請求項3に記載の省エネルギー型防食用金属塗膜組成物。
- 前記第2ゾルゲル樹脂は、トリ−(3−(トリメトキシシリル)プロピル)イソシアヌレート30〜50重量部、γ−メタクリルオキシプロピルトリメトキシシラン50〜70重量部、及びn−フェニル−γ−アミノプロピルトリメトキシシラン50〜70重量部から構成される、請求項4に記載の省エネルギー型防食用金属塗膜組成物。
- 前記溶媒はアセトンである、請求項5に記載の省エネルギー型防食用金属塗膜組成物。
- 5〜10μmの粒子サイズを有する、アルミニウム、マグネシウム、及びその合金よりなる群から選ばれる金属粉末を、溶媒に2〜3時間混合する金属粉末分散手順と、
前記金属粉末分散手順の混合物に、ジルコニウムテトラ−n−ブタノラート、ジルコニウムブトキシド、イソプロピルチタネート、及びその混合物よりなる群から選ばれる第1ゾルゲル樹脂を添加し、3〜5時間、300〜400rpmで攪拌する第1ゾルゲル樹脂混合及び攪拌手順と、
前記第1ゾルゲル樹脂混合及び攪拌手順の混合物に、トリ−(3−(トリメトキシシリル)プロピル)イソシアヌレート、γ−メタクリルオキシプロピルトリメトキシシラン、n−フェニル−γ−アミノプロピルトリメトキシシラン、及びその混合物よりなる群から選ばれる第2ゾルゲル樹脂を添加し、4〜7時間、100〜200rpmで攪拌する第2ゾルゲル樹脂混合及び攪拌手順とを含んでなる、省エネルギー型防食用金属塗膜組成物の製造方法。 - 前記第1ゾルゲル樹脂混合及び攪拌手順における温度は15〜20℃に維持する、請求項7に記載の省エネルギー型防食用金属塗膜組成物の製造方法。
- 前記第2ゾルゲル樹脂混合及び攪拌手順における温度は10〜15℃に維持する、請求項8に記載の省エネルギー型防食用金属塗膜組成物の製造方法。
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