JP2013512306A5 - - Google Patents
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- Publication number
- JP2013512306A5 JP2013512306A5 JP2012541070A JP2012541070A JP2013512306A5 JP 2013512306 A5 JP2013512306 A5 JP 2013512306A5 JP 2012541070 A JP2012541070 A JP 2012541070A JP 2012541070 A JP2012541070 A JP 2012541070A JP 2013512306 A5 JP2013512306 A5 JP 2013512306A5
- Authority
- JP
- Japan
- Prior art keywords
- coated
- composition
- containing chalcogenide
- chalcogenide nanoparticles
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000004770 chalcogenides Chemical class 0.000 claims description 41
- 239000002105 nanoparticle Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 26
- 239000010949 copper Substances 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 18
- 239000011701 zinc Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 150000004771 selenides Chemical class 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 125000000101 thioether group Chemical group 0.000 claims description 9
- 238000000151 deposition Methods 0.000 claims description 6
- 239000010408 film Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 239000011669 selenium Substances 0.000 description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 6
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229920000388 Polyphosphate Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 150000001356 alkyl thiols Chemical class 0.000 description 3
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 3
- 235000018417 cysteine Nutrition 0.000 description 3
- 125000000487 histidyl group Chemical group [H]N([H])C(C(=O)O*)C([H])([H])C1=C([H])N([H])C([H])=N1 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000001205 polyphosphate Substances 0.000 description 3
- 235000011176 polyphosphates Nutrition 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 108090000765 processed proteins & peptides Proteins 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical group 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26436209P | 2009-11-25 | 2009-11-25 | |
| US61/264,362 | 2009-11-25 | ||
| PCT/US2010/035792 WO2011065994A2 (en) | 2009-11-25 | 2010-05-21 | CZTS/Se PRECURSOR INKS AND METHODS FOR PREPARING CZTS/Se THIN FILMS AND CZTS/Se-BASED PHOTOVOLTAIC CELLS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013512306A JP2013512306A (ja) | 2013-04-11 |
| JP2013512306A5 true JP2013512306A5 (enExample) | 2013-05-30 |
Family
ID=44067159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012541070A Pending JP2013512306A (ja) | 2009-11-25 | 2010-05-21 | ＣＺＴＳ／Ｓｅ前駆体インクとＣＺＴＳ／Ｓｅ薄フィルムおよびＣＺＴＳ／Ｓｅ系光電池の製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20120220066A1 (enExample) |
| EP (1) | EP2504854A2 (enExample) |
| JP (1) | JP2013512306A (enExample) |
| KR (1) | KR20120085331A (enExample) |
| CN (1) | CN102668021A (enExample) |
| WO (1) | WO2011065994A2 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100330367A1 (en) * | 2009-02-03 | 2010-12-30 | Ut-Battelle, Llc | Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles |
| US8366975B2 (en) * | 2010-05-21 | 2013-02-05 | E I Du Pont De Nemours And Company | Atypical kesterite compositions |
| US8778724B2 (en) * | 2010-09-24 | 2014-07-15 | Ut-Battelle, Llc | High volume method of making low-cost, lightweight solar materials |
| US8771555B2 (en) | 2011-05-06 | 2014-07-08 | Neo Solar Power Corp. | Ink composition |
| CN102344166B (zh) * | 2011-07-04 | 2013-06-05 | 东华大学 | 一种Cu2ZnSnS4太阳能吸收层材料的制备方法 |
| US20130074911A1 (en) * | 2011-09-23 | 2013-03-28 | Yueh-Chun Liao | Photovoltaic Device Including a CZTS Absorber Layer and Method of Manufacturing the Same |
| EP2786419B1 (en) * | 2011-11-30 | 2020-02-12 | Konica Minolta Laboratory U.S.A., Inc. | Method of manufacturing a photovoltaic device |
| KR101300791B1 (ko) * | 2011-12-15 | 2013-08-29 | 한국생산기술연구원 | 전자빔 조사를 이용한 몰리브덴 박막의 전도도 향상 방법 |
| WO2013091114A1 (en) * | 2011-12-22 | 2013-06-27 | The University Of Western Ontario | Copper-containing nanocrystals and methods of preparation therefor |
| US8673260B2 (en) * | 2012-01-04 | 2014-03-18 | Franklin And Marshall College | Development of earth-abundant mixed-metal sulfide nanoparticles for use in solar energy conversion |
| CN102614897A (zh) * | 2012-03-12 | 2012-08-01 | 中国科学院福建物质结构研究所 | 一种提高硫化锌材料光催化活性的退火处理方法 |
| EP2647675A2 (en) * | 2012-04-02 | 2013-10-09 | Neo Solar Power Corp. | Method for forming an ink |
| EP2647595A2 (en) * | 2012-04-03 | 2013-10-09 | Neo Solar Power Corp. | Ink composition, chalcogenide semiconductor film, photovoltaic device and methods for forming the same |
| US20150118144A1 (en) * | 2012-05-14 | 2015-04-30 | E I Du Pont Nemours And Company | Dispersible metal chalcogenide nanoparticles |
| US8598560B1 (en) | 2012-07-12 | 2013-12-03 | Micron Technology, Inc. | Resistive memory elements exhibiting increased interfacial adhesion strength, methods of forming the same, and related resistive memory cells and memory devices |
| CN102856398A (zh) * | 2012-07-25 | 2013-01-02 | 中国科学技术大学 | 铜锌锡硒太阳能电池及其制造方法 |
| FR2993792B1 (fr) * | 2012-07-26 | 2017-09-15 | Imra Europe Sas | Film de chalcogenure(s) metallique(s) cristallise(s) a gros grains, solution colloidale de particules amorphes et procedes de preparation. |
| KR101388451B1 (ko) * | 2012-08-10 | 2014-04-24 | 한국에너지기술연구원 | 탄소층이 감소한 ｃｉ(ｇ)ｓ계 박막의 제조방법, 이에 의해 제조된 박막 및 이를 포함하는 태양전지 |
| US8741386B2 (en) | 2012-09-28 | 2014-06-03 | Uchicago Argonne, Llc | Atomic layer deposition of quaternary chalcogenides |
| US20140117293A1 (en) * | 2012-10-29 | 2014-05-01 | Tokyo Ohka Kogyo Co., Ltd. | Coating solution for forming light-absorbing layer, and method of producing coating solution for forming light-absorbing layer |
| FR3001467B1 (fr) * | 2013-01-29 | 2016-05-13 | Imra Europe Sas | Procede de preparation de couche mince d'absorbeur a base de sulfure(s) de cuivre, zinc et etain, couche mince recuite et dispositif photovoltaique obtenu |
| JP6138288B2 (ja) * | 2013-03-15 | 2017-05-31 | ナノコ テクノロジーズ リミテッド | Ｃｕ２ＺｎＳｎＳ４ナノ粒子 |
| KR101449576B1 (ko) * | 2013-04-04 | 2014-10-16 | 한국에너지기술연구원 | 비진공 방식에 의한 ｃｚｔｓ계 광흡수층 제조방법 |
| CN103194739B (zh) * | 2013-04-22 | 2015-04-22 | 青岛科技大学 | 一种铜锌锡硫薄膜的水热合成制备方法 |
| CN103346201B (zh) * | 2013-05-24 | 2016-11-23 | 徐东 | 掺锗的铜锌锡硫硒薄膜制备方法、薄膜及太阳能电池 |
| CN103337551B (zh) * | 2013-05-28 | 2015-12-23 | 湘潭大学 | 一种不含碳层的CZTS或者CZTSe薄膜的非真空制备方法 |
| ES2772177T3 (es) * | 2013-08-01 | 2020-07-07 | Lg Chemical Ltd | Nanopartículas de calcogenuro metálico para preparar una capa de absorción de luz de una célula solar, y método de preparación para esto |
| JP6194108B2 (ja) * | 2013-08-01 | 2017-09-06 | エルジー・ケム・リミテッド | 太陽電池の光吸収層製造用インク組成物及びこれを使用した薄膜の製造方法 |
| KR101619933B1 (ko) | 2013-08-01 | 2016-05-11 | 주식회사 엘지화학 | 태양전지 광흡수층 제조용 3층 코어-쉘 나노 입자 및 이의 제조 방법 |
| KR101650049B1 (ko) | 2013-09-12 | 2016-08-22 | 주식회사 엘지화학 | 태양전지 광흡수층 제조용 금속 칼코게나이드 나노 입자 및 이의 제조방법 |
| US9893220B2 (en) | 2013-10-15 | 2018-02-13 | Nanoco Technologies Ltd. | CIGS nanoparticle ink formulation having a high crack-free limit |
| KR101583026B1 (ko) * | 2013-10-31 | 2016-01-08 | 재단법인대구경북과학기술원 | Ｃｚｔｓ계 태양전지용 박막의 제조방법 |
| FR3014909B1 (fr) * | 2013-12-12 | 2016-01-29 | Electricite De France | Bain a morpholine et procede pour le depot chimique d'une couche. |
| CN103714973B (zh) * | 2013-12-26 | 2016-08-31 | 中国矿业大学 | 一种光电化学太阳能电池用Cu3SnS4/Cu2SnSe3复合光阴极及其制备方法 |
| CN104761956B (zh) * | 2014-01-03 | 2017-07-18 | 中国科学院苏州纳米技术与纳米仿生研究所 | 纳米硒化铜导电墨水、其制备方法及应用 |
| KR101632631B1 (ko) | 2014-05-20 | 2016-06-23 | 재단법인대구경북과학기술원 | Zn(O, S) 버퍼층 CZTS계 박막 태양전지의 제조방법 |
| US10319589B2 (en) * | 2014-09-12 | 2019-06-11 | The Regents Of The University Of California | High performance thin films from solution processible two-dimensional nanoplates |
| KR101869138B1 (ko) * | 2015-05-13 | 2018-06-19 | 주식회사 엘지화학 | 태양전지 광흡수층 제조용 전구체 및 이의 제조방법 |
| WO2016072654A2 (ko) * | 2014-11-05 | 2016-05-12 | 주식회사 엘지화학 | 태양전지 광흡수층 제조용 전구체 및 이의 제조방법 |
| CN104451597B (zh) * | 2014-11-19 | 2017-08-11 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种固体润滑ZnS薄膜的制备方法 |
| CN105039937A (zh) * | 2015-06-02 | 2015-11-11 | 南昌大学 | 一种基于水溶剂制备铜锌锡硫硒薄膜的方法 |
| US10217888B2 (en) | 2016-10-06 | 2019-02-26 | International Business Machines Corporation | Solution-phase inclusion of silver into chalcogenide semiconductor inks |
| CN109148625A (zh) * | 2018-05-17 | 2019-01-04 | 中国科学院物理研究所 | 铜锌锡硫硒薄膜太阳能电池及其制备方法 |
| CN109678123A (zh) * | 2018-11-30 | 2019-04-26 | 中国科学院物理研究所 | 铜锌锡硫硒薄膜太阳能电池及其前驱体溶液制备方法 |
| CN109659356B (zh) * | 2018-12-18 | 2021-08-27 | 河南师范大学 | 基于硒化铜单层的具有负微分电阻和开关作用的纳米器件 |
| CN110639555A (zh) * | 2019-10-09 | 2020-01-03 | 长春工业大学 | 一种可见光响应的CdS/CdIn2S4复合纳米结构光催化剂的制备方法及应用 |
| CN114388660A (zh) * | 2022-01-13 | 2022-04-22 | 黑龙江工业学院 | 一种降低CZTSSe薄膜中小晶粒层的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7306823B2 (en) * | 2004-09-18 | 2007-12-11 | Nanosolar, Inc. | Coated nanoparticles and quantum dots for solution-based fabrication of photovoltaic cells |
| US7253226B1 (en) * | 2005-08-11 | 2007-08-07 | Aps Laboratory | Tractable silica sols and nanocomposites therefrom |
| US7605062B2 (en) * | 2007-02-26 | 2009-10-20 | Eastman Kodak Company | Doped nanoparticle-based semiconductor junction |
| EP2232576A2 (en) * | 2007-12-06 | 2010-09-29 | Craig Leidholm | Methods and devices for processing a precursor layer in a group via environment |
| US20100055440A1 (en) * | 2008-08-27 | 2010-03-04 | Seoul National University Industry Foundation | Composite nanoparticles |
| US9028723B2 (en) * | 2009-02-27 | 2015-05-12 | National University Corporation Nagoya University | Semiconductor nanoparticles and method for producing same |
| WO2010138636A2 (en) * | 2009-05-26 | 2010-12-02 | Purdue Research Foundation | Synthesis of multinary chalcogenide nanoparticles comprising cu, zn, sn, s, and se |
| US20110094557A1 (en) * | 2009-10-27 | 2011-04-28 | International Business Machines Corporation | Method of forming semiconductor film and photovoltaic device including the film |
-
2010
- 2010-05-21 CN CN2010800521013A patent/CN102668021A/zh active Pending
- 2010-05-21 JP JP2012541070A patent/JP2013512306A/ja active Pending
- 2010-05-21 KR KR1020127016242A patent/KR20120085331A/ko not_active Withdrawn
- 2010-05-21 EP EP10724615A patent/EP2504854A2/en not_active Withdrawn
- 2010-05-21 WO PCT/US2010/035792 patent/WO2011065994A2/en not_active Ceased
- 2010-05-21 US US13/505,841 patent/US20120220066A1/en not_active Abandoned
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