JP2013122105A5 - - Google Patents
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- JP2013122105A5 JP2013122105A5 JP2012268032A JP2012268032A JP2013122105A5 JP 2013122105 A5 JP2013122105 A5 JP 2013122105A5 JP 2012268032 A JP2012268032 A JP 2012268032A JP 2012268032 A JP2012268032 A JP 2012268032A JP 2013122105 A5 JP2013122105 A5 JP 2013122105A5
- Authority
- JP
- Japan
- Prior art keywords
- hollow
- fiber
- hollow fiber
- polymers
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920000642 polymer Polymers 0.000 claims description 197
- 239000012510 hollow fiber Substances 0.000 claims description 148
- 239000000835 fiber Substances 0.000 claims description 121
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 65
- 239000002086 nanomaterial Substances 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 52
- 239000002243 precursor Substances 0.000 claims description 33
- 239000011159 matrix material Substances 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 29
- 239000002071 nanotube Substances 0.000 claims description 26
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 22
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 22
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 20
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 20
- 238000009987 spinning Methods 0.000 claims description 19
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 229920000297 Rayon Polymers 0.000 claims description 8
- 208000013201 Stress fracture Diseases 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 8
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 8
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims description 6
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 4
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 claims description 4
- 229920001634 Copolyester Polymers 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000004626 polylactic acid Substances 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920001897 terpolymer Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- RENMDAKOXSCIGH-UHFFFAOYSA-N Chloroacetonitrile Chemical compound ClCC#N RENMDAKOXSCIGH-UHFFFAOYSA-N 0.000 claims description 2
- KKUKTXOBAWVSHC-UHFFFAOYSA-N Dimethylphosphate Chemical compound COP(O)(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-N 0.000 claims description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- 238000010276 construction Methods 0.000 claims description 2
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 230000006378 damage Effects 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 75
- 239000002041 carbon nanotube Substances 0.000 description 52
- 229910021393 carbon nanotube Inorganic materials 0.000 description 52
- 229920000049 Carbon (fiber) Polymers 0.000 description 40
- 239000004917 carbon fiber Substances 0.000 description 40
- 239000002131 composite material Substances 0.000 description 37
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 21
- 239000011295 pitch Substances 0.000 description 21
- 229910052799 carbon Inorganic materials 0.000 description 17
- 238000010586 diagram Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 239000002717 carbon nanostructure Substances 0.000 description 7
- 239000011258 core-shell material Substances 0.000 description 6
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 239000002105 nanoparticle Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000002074 melt spinning Methods 0.000 description 4
- 239000011302 mesophase pitch Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000002787 reinforcement Effects 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 229910052621 halloysite Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 239000002109 single walled nanotube Substances 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000004815 dispersion polymer Substances 0.000 description 2
- 238000000578 dry spinning Methods 0.000 description 2
- 238000001523 electrospinning Methods 0.000 description 2
- 238000010035 extrusion spinning Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000001891 gel spinning Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- XWUCFAJNVTZRLE-UHFFFAOYSA-N 7-thiabicyclo[2.2.1]hepta-1,3,5-triene Chemical group C1=C(S2)C=CC2=C1 XWUCFAJNVTZRLE-UHFFFAOYSA-N 0.000 description 1
- 229920001824 Barex® Polymers 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000015842 Hesperis Nutrition 0.000 description 1
- 235000012633 Iberis amara Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- -1 but not limited to Polymers 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000002134 carbon nanofiber Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000412 polyarylene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/316,506 | 2011-12-10 | ||
| US13/316,506 US9683310B2 (en) | 2011-12-10 | 2011-12-10 | Hollow fiber with gradient properties and method of making the same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013122105A JP2013122105A (ja) | 2013-06-20 |
| JP2013122105A5 true JP2013122105A5 (enExample) | 2017-01-26 |
| JP6180105B2 JP6180105B2 (ja) | 2017-08-16 |
Family
ID=47227668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012268032A Active JP6180105B2 (ja) | 2011-12-10 | 2012-12-07 | 勾配性質を有する中空繊維とその作製方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US9683310B2 (enExample) |
| EP (1) | EP2602363B1 (enExample) |
| JP (1) | JP6180105B2 (enExample) |
| CN (1) | CN103160941B (enExample) |
| BR (1) | BR102012031443B1 (enExample) |
| ES (1) | ES2726098T3 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6581114B2 (ja) * | 2014-02-04 | 2019-09-25 | ザ・ボーイング・カンパニーＴｈｅ Ｂｏｅｉｎｇ Ｃｏｍｐａｎｙ | 繊維強化樹脂複合体及びその製作方法 |
| US10629814B2 (en) * | 2017-02-07 | 2020-04-21 | University Of South Florida | Coaxial semiconductive organic nanofibers and electrospinning fabrication thereof |
| CN106894107B (zh) * | 2017-03-06 | 2022-03-04 | 东华大学 | 聚苯硫醚/改性埃洛石纳米管杂化复合纤维及其制备方法 |
| US10787755B2 (en) | 2017-06-05 | 2020-09-29 | The Boeing Company | Method and apparatus for manufacturing carbon fibers |
| KR102115600B1 (ko) * | 2017-07-13 | 2020-05-26 | 주식회사 엘지화학 | 구조체의 제조방법 |
| US10612163B2 (en) * | 2017-08-24 | 2020-04-07 | GM Global Technology Operations LLC | Modification of continuous carbon fibers during precursor formation for composites having enhanced moldability |
| US10941510B2 (en) | 2017-12-08 | 2021-03-09 | GM Global Technology Operations LLC | Equipment for perforated pre-impregnated reinforcement materials |
| US10533266B2 (en) * | 2018-05-11 | 2020-01-14 | The Boeing Company | Layered carbon fiber |
| CN110257937A (zh) * | 2019-06-24 | 2019-09-20 | 绍兴诚邦高新纤维科技有限公司 | 一种自卷曲复合长丝及其加工工艺 |
| US11498318B2 (en) | 2019-12-05 | 2022-11-15 | GM Global Technology Operations LLC | Class-A components comprising moldable carbon fiber |
| CN116034008A (zh) * | 2020-08-06 | 2023-04-28 | 昕诺飞控股有限公司 | 使用fdm的连续中空管打印 |
| JPWO2022075115A1 (enExample) | 2020-10-05 | 2022-04-14 |
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| CN101768791B (zh) | 2010-02-10 | 2011-11-09 | 北京化工大学 | 一种聚丙烯腈基中空碳纤维原丝的制备方法 |
| US9096955B2 (en) * | 2011-09-30 | 2015-08-04 | Ut-Battelle, Llc | Method for the preparation of carbon fiber from polyolefin fiber precursor, and carbon fibers made thereby |
-
2011
- 2011-12-10 US US13/316,506 patent/US9683310B2/en active Active
-
2012
- 2012-11-23 EP EP12194048.0A patent/EP2602363B1/en active Active
- 2012-11-23 ES ES12194048T patent/ES2726098T3/es active Active
- 2012-12-07 JP JP2012268032A patent/JP6180105B2/ja active Active
- 2012-12-10 CN CN201210530067.7A patent/CN103160941B/zh active Active
- 2012-12-10 BR BR102012031443A patent/BR102012031443B1/pt active IP Right Grant
-
2017
- 2017-02-23 US US15/441,174 patent/US10253433B2/en active Active
-
2019
- 2019-04-08 US US16/377,257 patent/US10774447B2/en active Active
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