ES2726098T3 - Fibra hueca con propiedades de gradiente y método de fabricación de la misma - Google Patents
Fibra hueca con propiedades de gradiente y método de fabricación de la misma Download PDFInfo
- Publication number
- ES2726098T3 ES2726098T3 ES12194048T ES12194048T ES2726098T3 ES 2726098 T3 ES2726098 T3 ES 2726098T3 ES 12194048 T ES12194048 T ES 12194048T ES 12194048 T ES12194048 T ES 12194048T ES 2726098 T3 ES2726098 T3 ES 2726098T3
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- Prior art keywords
- polymers
- hollow
- fiber
- hollow fiber
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052582 BN Inorganic materials 0.000 description 3
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- XWUCFAJNVTZRLE-UHFFFAOYSA-N 7-thiabicyclo[2.2.1]hepta-1,3,5-triene Chemical group C1=C(S2)C=CC2=C1 XWUCFAJNVTZRLE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
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- D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
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- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
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- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
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- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
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- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0046—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by coagulation, i.e. wet electro-spinning
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- D—TEXTILES; PAPER
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- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
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- D—TEXTILES; PAPER
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- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/145—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues
- D01F9/155—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues from petroleum pitch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/731—Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
- Y10T428/2975—Tubular or cellular
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- Engineering & Computer Science (AREA)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/316,506 US9683310B2 (en) | 2011-12-10 | 2011-12-10 | Hollow fiber with gradient properties and method of making the same |
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| Publication Number | Publication Date |
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| ES2726098T3 true ES2726098T3 (es) | 2019-10-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| ES12194048T Active ES2726098T3 (es) | 2011-12-10 | 2012-11-23 | Fibra hueca con propiedades de gradiente y método de fabricación de la misma |
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| US (3) | US9683310B2 (enExample) |
| EP (1) | EP2602363B1 (enExample) |
| JP (1) | JP6180105B2 (enExample) |
| CN (1) | CN103160941B (enExample) |
| BR (1) | BR102012031443B1 (enExample) |
| ES (1) | ES2726098T3 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015119676A2 (en) * | 2014-02-04 | 2015-08-13 | The Boeing Company | Fiber-reinforced resin composites and methods of making the same |
| US10629814B2 (en) * | 2017-02-07 | 2020-04-21 | University Of South Florida | Coaxial semiconductive organic nanofibers and electrospinning fabrication thereof |
| CN106894107B (zh) * | 2017-03-06 | 2022-03-04 | 东华大学 | 聚苯硫醚/改性埃洛石纳米管杂化复合纤维及其制备方法 |
| US10787755B2 (en) | 2017-06-05 | 2020-09-29 | The Boeing Company | Method and apparatus for manufacturing carbon fibers |
| KR102115600B1 (ko) * | 2017-07-13 | 2020-05-26 | 주식회사 엘지화학 | 구조체의 제조방법 |
| US10612163B2 (en) * | 2017-08-24 | 2020-04-07 | GM Global Technology Operations LLC | Modification of continuous carbon fibers during precursor formation for composites having enhanced moldability |
| US10941510B2 (en) | 2017-12-08 | 2021-03-09 | GM Global Technology Operations LLC | Equipment for perforated pre-impregnated reinforcement materials |
| US10533266B2 (en) * | 2018-05-11 | 2020-01-14 | The Boeing Company | Layered carbon fiber |
| CN110257937A (zh) * | 2019-06-24 | 2019-09-20 | 绍兴诚邦高新纤维科技有限公司 | 一种自卷曲复合长丝及其加工工艺 |
| US11498318B2 (en) | 2019-12-05 | 2022-11-15 | GM Global Technology Operations LLC | Class-A components comprising moldable carbon fiber |
| CN116034008A (zh) * | 2020-08-06 | 2023-04-28 | 昕诺飞控股有限公司 | 使用fdm的连续中空管打印 |
| EP4226993A4 (en) * | 2020-10-05 | 2024-10-23 | Toray Industries, Inc. | Gas separation membrane and gas separation membrane module |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3677705A (en) | 1970-03-09 | 1972-07-18 | Celanese Corp | Process for the carbonization of a stabilized acrylic fibrous material |
| US4208267A (en) | 1977-07-08 | 1980-06-17 | Exxon Research & Engineering Co. | Forming optically anisotropic pitches |
| US4277324A (en) | 1979-04-13 | 1981-07-07 | Exxon Research & Engineering Co. | Treatment of pitches in carbon artifact manufacture |
| US5156831A (en) | 1986-01-21 | 1992-10-20 | Clemson University | Method for producing high strength, melt spun carbon fibers |
| US5162074A (en) | 1987-10-02 | 1992-11-10 | Basf Corporation | Method of making plural component fibers |
| US5021497A (en) | 1988-06-17 | 1991-06-04 | Ube Industries, Ltd. | Polyarylene sulfide resin composition |
| US5032250A (en) | 1988-12-22 | 1991-07-16 | Conoco Inc. | Process for isolating mesophase pitch |
| EP0421944A3 (en) | 1989-08-31 | 1992-06-17 | Tanaka Kikinzoku Kogyo K.K. | Composite carbon fibre and process for preparing same |
| US5338605A (en) | 1990-01-31 | 1994-08-16 | Ketema, Inc. | Hollow carbon fibers |
| MY131716A (en) | 1993-11-10 | 2007-08-30 | Standard Oil Co | A process for making a polymer of acrylonitrile, methacrylonitrile and olefinically unsaturated monomers |
| US5618901A (en) | 1993-11-10 | 1997-04-08 | The Standard Oil Company | Process for making a high nitrile multipolymer prepared from acrylonitrile and olefinically unsaturated monomers |
| US5700573A (en) * | 1995-04-25 | 1997-12-23 | Mccullough; Francis Patrick | Flexible biregional carbonaceous fiber, articles made from biregional carbonaceous fibers, and method of manufacture |
| DK0891433T3 (da) | 1996-03-29 | 2003-08-25 | Fibervisions L P | Polypropylenfibre og genstande fremstillet deraf |
| JPH1088430A (ja) * | 1996-09-09 | 1998-04-07 | Toray Ind Inc | 炭素繊維、炭素繊維製造用プリカーサーおよびその製造方法 |
| US5902530A (en) | 1997-12-12 | 1999-05-11 | The Standard Oil Company | Process of making high nitrile composite filaments |
| JP3940546B2 (ja) | 1999-06-07 | 2007-07-04 | 株式会社東芝 | パターン形成方法およびパターン形成材料 |
| US6743500B2 (en) | 2001-08-03 | 2004-06-01 | Hitachi Chemical Company, Ltd. | Hollow carbon fiber and production method |
| US6764628B2 (en) | 2002-03-04 | 2004-07-20 | Honeywell International Inc. | Composite material comprising oriented carbon nanotubes in a carbon matrix and process for preparing same |
| US6852410B2 (en) | 2002-07-01 | 2005-02-08 | Georgia Tech Research Corporation | Macroscopic fiber comprising single-wall carbon nanotubes and acrylonitrile-based polymer and process for making the same |
| JP2004097918A (ja) * | 2002-09-09 | 2004-04-02 | Nok Corp | ポリエーテルイミド複合中空糸膜およびその製造法 |
| WO2006137893A2 (en) | 2004-10-01 | 2006-12-28 | Board Of Regents Of The University Of Texas System | Polymer-free carbon nanotube assemblies (fibers, ropes, ribbons, films) |
| JP2006137869A (ja) | 2004-11-12 | 2006-06-01 | Nissan Motor Co Ltd | 樹脂組成物 |
| JP4892910B2 (ja) | 2005-09-29 | 2012-03-07 | 東レ株式会社 | 導電性繊維およびそれを用いてなる繊維製品 |
| EP1935480B1 (en) * | 2005-10-13 | 2013-03-27 | Asahi Kasei Chemicals Corporation | Process for producing a porous multilayered hollow-fiber membrane |
| WO2007103422A1 (en) | 2006-03-07 | 2007-09-13 | Clemson University | Mesoporous carbon fiber with a hollow interior or a convoluted surface |
| JP2010530929A (ja) | 2007-01-30 | 2010-09-16 | ジョージア テック リサーチ コーポレイション | 炭素繊維および炭素膜、ならびにそれらの作製方法 |
| US8388795B2 (en) | 2007-05-17 | 2013-03-05 | The Boeing Company | Nanotube-enhanced interlayers for composite structures |
| EP2205364A4 (en) * | 2007-10-11 | 2012-07-11 | Georgia Tech Res Inst | CARBON FIBERS AND FILMS AND MANUFACTURING METHOD THEREFOR |
| JP2009185425A (ja) | 2008-02-08 | 2009-08-20 | Shinshu Univ | 中空炭素繊維 |
| US8187700B2 (en) * | 2008-11-12 | 2012-05-29 | The Boeing Company | Continuous, carbon-nanotube-reinforced polymer precursors and carbon fibers |
| US8337730B2 (en) | 2009-01-05 | 2012-12-25 | The Boeing Company | Process of making a continuous, multicellular, hollow carbon fiber |
| US7875802B2 (en) | 2009-01-05 | 2011-01-25 | The Boeing Company | Thermoplastic-based, carbon nanotube-enhanced, high-conductivity layered wire |
| US7897876B2 (en) | 2009-01-05 | 2011-03-01 | The Boeing Company | Carbon-nanotube/graphene-platelet-enhanced, high-conductivity wire |
| US7875801B2 (en) | 2009-01-05 | 2011-01-25 | The Boeing Company | Thermoplastic-based, carbon nanotube-enhanced, high-conductivity wire |
| KR101822349B1 (ko) * | 2009-03-16 | 2018-03-08 | 보르벡크 머터리얼스 코포레이션 | 중합체 섬유 및 이로부터 제조된 물품 |
| FR2946176A1 (fr) | 2009-05-27 | 2010-12-03 | Arkema France | Fibre conductrice multicouche et son procede d'obtention par co-extrusion. |
| CN102085457B (zh) * | 2009-12-07 | 2013-01-02 | 广州美能材料科技有限公司 | 一种制备复合多层多孔中空纤维膜的方法及其装置和产品 |
| CN101768791B (zh) | 2010-02-10 | 2011-11-09 | 北京化工大学 | 一种聚丙烯腈基中空碳纤维原丝的制备方法 |
| US9096955B2 (en) * | 2011-09-30 | 2015-08-04 | Ut-Battelle, Llc | Method for the preparation of carbon fiber from polyolefin fiber precursor, and carbon fibers made thereby |
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2011
- 2011-12-10 US US13/316,506 patent/US9683310B2/en active Active
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2012
- 2012-11-23 ES ES12194048T patent/ES2726098T3/es active Active
- 2012-11-23 EP EP12194048.0A patent/EP2602363B1/en active Active
- 2012-12-07 JP JP2012268032A patent/JP6180105B2/ja active Active
- 2012-12-10 BR BR102012031443A patent/BR102012031443B1/pt active IP Right Grant
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- 2017-02-23 US US15/441,174 patent/US10253433B2/en active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| US9683310B2 (en) | 2017-06-20 |
| US20130149523A1 (en) | 2013-06-13 |
| CN103160941B (zh) | 2017-04-05 |
| BR102012031443A2 (pt) | 2013-11-12 |
| US20170159210A1 (en) | 2017-06-08 |
| US10253433B2 (en) | 2019-04-09 |
| JP6180105B2 (ja) | 2017-08-16 |
| CN103160941A (zh) | 2013-06-19 |
| US10774447B2 (en) | 2020-09-15 |
| JP2013122105A (ja) | 2013-06-20 |
| BR102012031443B1 (pt) | 2020-02-04 |
| US20190233973A1 (en) | 2019-08-01 |
| EP2602363A1 (en) | 2013-06-12 |
| EP2602363B1 (en) | 2019-02-13 |
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