JP2012530790A - 燃料流を脱硫するための脱硫システム及び方法 - Google Patents
燃料流を脱硫するための脱硫システム及び方法 Download PDFInfo
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Abstract
【選択図】図2
Description
本発明の一実施形態の操作を例示するために、発明者らは、銅交換Y型ゼオライト及びそれに続く酸化銅を含む選択的硫黄吸着剤を順番に有する第一の硫黄吸着剤システム(実施例1)の性能を、カルシウムイオンで交換されたカルシウム交換X型ゼオライト及び同じ選択的硫黄吸着剤を同じ割合で有する第二の硫黄吸着剤システム(実施例2)と比較した。各システムにおいて、吸着剤の容量は10cm3とした。
実施例1及び2において用いたものと同じ天然ガス供給流を用いて、他の実施例が行われる。供給流の温度は常温に維持され、圧力は1.3barである。他の全ての条件は、同じである。その結果を図2に示す。
実施例4及び5は、実施例1及び2において用いたものと同様の天然ガス供給流を用いて行われる。ただし、実施例4では、供給流は、20ppmのエチルメルカプタンを含む。実施例5では、供給流は、実施例1及び2と同様の天然ガス中に10ppmのテトラヒドロチオフェンを含む。各供給流の温度は38℃に維持され、圧力は15psig(1.0bar)である。ガス空間密度(GHSV)は10,000hr−1である。実施例1についての試験成績をエチルメルカプタンのppmで示したものを図3に示す。供給流がテトラヒドロチオフェンを含む実施例5の結果を図4に示す。
Claims (15)
- 硫黄化合物により汚染された炭化水素供給流を供給する工程と、
前記硫黄汚染供給流を、Y型ゼオライト吸着剤及び選択的硫黄吸着剤中を通過させ、ここで前記供給流が実質的に脱硫される工程と
を有する炭化水素供給流の脱硫方法。 - 前記Y型ゼオライト吸着剤が、Cu、Ag、Mn、Mg、Fe、Ca、Ce、La、Sr、Pr、Nd、及びその混合物からなる群より選択されるカチオンとイオン交換されたY型ゼオライト(好ましくは銅交換Y型ゼオライト)を含む請求項1に記載の方法。
- 前記Y型ゼオライト吸着剤が、さらに、亜鉛、カドミウム、コバルト、ニッケル、銅、鉄、マンガン、銀、金、スカンジウム、リチウム、セリウム、ランタン、マグネシウム、及びその組み合わせからなる群より選択される金属イオンと交換された銅交換Y型ゼオライトである請求項1に記載の方法。
- 前記選択的硫黄吸収剤が、酸化銅と、1つ又はそれより多いマンガン化合物を含む請求項1に記載の方法。
- 前記選択的硫黄吸収剤が、1つ又はそれより多いマンガン化合物と、鉄化合物(好ましくは酸化鉄)を含む請求項1に記載の方法。
- 前記選択的硫黄吸収剤が、酸化銅と、鉄化合物と、1つ又はそれより多いマンガン化合物を含む請求項1に記載の方法。
- 前記Y型ゼオライト吸着剤及び前記選択的硫黄吸着剤の温度を100℃未満(好ましくは60℃未満)に維持する工程をさらに有する請求項1に記載の方法。
- 前記供給流を、水和アルミナ吸着剤上を通過させる工程をさらに有する請求項1に記載の方法。
- 前記硫黄汚染炭化水素供給流が、さらに水を含む請求項1に記載の方法。
- 前記炭化水素供給流が、少なくとも50ppbの量で、ジメチルスルフィド、ターシャリーブチルメルカプタン、又はこれらの混合物を含む硫黄化合物により汚染されている場合、前記硫黄汚染供給流を、最初に前記選択的硫黄吸着剤中を通過させ、次いで、前記供給流を、前記Y型ゼオライト吸着剤中を通過させる請求項1に記載の炭化水素供給流の脱硫方法。
- 前記炭化水素供給流が、少なくとも50ppbの量で、テトラヒドロチオフェン、エチルメルカプタン、又はこれらの混合物を含む硫黄化合物により汚染されている場合、前記硫黄汚染供給流を、最初に前記Y型ゼオライト吸着剤中を通過させ、次いで、前記供給流を、前記選択的硫黄吸着剤中を通過させる請求項1に記載の炭化水素供給流の脱硫方法。
- 前記Y型ゼオライト吸着剤が、Cu、Ag、Mn、Mg、Fe、Ca、Ce、La、Sr、Pr、Nd、及びその混合物からなる群より選択されるカチオンとイオン交換されたY型ゼオライト(好ましくは銅交換Y型ゼオライト)を含む請求項10又は11に記載の方法。
- 前記選択的硫黄吸着剤が、酸化銅と1つ又はそれより多いマンガン化合物;1つ又はそれより多いマンガン化合物と鉄化合物(好ましくは酸化鉄);酸化銅と鉄化合物(好ましくは酸化鉄)と1つ又はそれより多いマンガン化合物;及びその混合物からなる群より選択される請求項10〜12に記載の方法。
- 燃料電池駆動装置において水素を発生させるための、請求項1に記載の方法で得られた実質的に脱硫された炭化水素供給流の使用。
- 前記燃料電池駆動装置が、請求項1に記載の脱硫システムを有している請求項14に記載の使用。
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PCT/US2010/037415 WO2010141825A2 (en) | 2009-06-05 | 2010-06-04 | A desulfurization system and method for desulfurizing a fuel stream |
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JP2019527619A (ja) * | 2016-07-26 | 2019-10-03 | サウジ アラビアン オイル カンパニーSaudi Arabian Oil Company | 気相酸化的脱硫触媒のための添加剤 |
JP7014770B2 (ja) | 2016-07-26 | 2022-02-01 | サウジ アラビアン オイル カンパニー | 気相酸化的脱硫触媒のための添加剤 |
JPWO2018221633A1 (ja) * | 2017-05-31 | 2019-06-27 | 日揮触媒化成株式会社 | 耐水性硫黄化合物吸着剤 |
US10625238B2 (en) | 2017-05-31 | 2020-04-21 | Jgc Catalysts And Chemicals Ltd. | Water-resistant sulfur compound adsorbent |
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EP2438145B1 (en) | 2017-05-10 |
US8323603B2 (en) | 2012-12-04 |
US20130078540A1 (en) | 2013-03-28 |
EP2438145A2 (en) | 2012-04-11 |
KR101688252B1 (ko) | 2016-12-20 |
US20090272675A1 (en) | 2009-11-05 |
PL2438145T3 (pl) | 2017-09-29 |
US8658321B2 (en) | 2014-02-25 |
KR20120036943A (ko) | 2012-04-18 |
JP5770170B2 (ja) | 2015-08-26 |
DK2438145T3 (en) | 2017-08-28 |
WO2010141825A2 (en) | 2010-12-09 |
WO2010141825A3 (en) | 2013-04-25 |
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