JP2012142270A - 発光装置、照明装置 - Google Patents
発光装置、照明装置 Download PDFInfo
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- JP2012142270A JP2012142270A JP2011273245A JP2011273245A JP2012142270A JP 2012142270 A JP2012142270 A JP 2012142270A JP 2011273245 A JP2011273245 A JP 2011273245A JP 2011273245 A JP2011273245 A JP 2011273245A JP 2012142270 A JP2012142270 A JP 2012142270A
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- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 150000003553 thiiranes Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- QGJSAGBHFTXOTM-UHFFFAOYSA-K trifluoroerbium Chemical compound F[Er](F)F QGJSAGBHFTXOTM-UHFFFAOYSA-K 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
- CJGUQZGGEUNPFQ-UHFFFAOYSA-L zinc;2-(1,3-benzothiazol-2-yl)phenolate Chemical compound [Zn+2].[O-]C1=CC=CC=C1C1=NC2=CC=CC=C2S1.[O-]C1=CC=CC=C1C1=NC2=CC=CC=C2S1 CJGUQZGGEUNPFQ-UHFFFAOYSA-L 0.000 description 1
- GWDUZCIBPDVBJM-UHFFFAOYSA-L zinc;2-(2-hydroxyphenyl)-3h-1,3-benzothiazole-2-carboxylate Chemical compound [Zn+2].OC1=CC=CC=C1C1(C([O-])=O)SC2=CC=CC=C2N1.OC1=CC=CC=C1C1(C([O-])=O)SC2=CC=CC=C2N1 GWDUZCIBPDVBJM-UHFFFAOYSA-L 0.000 description 1
- QEPMORHSGFRDLW-UHFFFAOYSA-L zinc;2-(2-hydroxyphenyl)-3h-1,3-benzoxazole-2-carboxylate Chemical compound [Zn+2].OC1=CC=CC=C1C1(C([O-])=O)OC2=CC=CC=C2N1.OC1=CC=CC=C1C1(C([O-])=O)OC2=CC=CC=C2N1 QEPMORHSGFRDLW-UHFFFAOYSA-L 0.000 description 1
- HTPBWAPZAJWXKY-UHFFFAOYSA-L zinc;quinolin-8-olate Chemical compound [Zn+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 HTPBWAPZAJWXKY-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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Abstract
【解決手段】第1の有機樹脂層と、第1の有機樹脂層上の、第1の有機樹脂層の一方の面に接する第1のガラス層と、発光素子上の第2のガラス層と、第2のガラス層上の、第2のガラス層の一方の面と接する第2の有機樹脂層と、を備え、第1の有機樹脂層及び第1のガラス層が、可視光に対する透光性を有し、第1のガラス層及び第2のガラス層は、それぞれ独立に、25μm以上100μm以下の厚さであり、発光素子が、第1のガラス層側から、可視光に対する透光性を有する第1の電極と、発光性の有機化合物を含む層と、第2の電極と、を有する発光装置を提供する。
【選択図】図1
Description
本実施の形態では、本発明の一態様の発光装置について図1乃至図5を用いて説明する。
図2(A)に、ボトムエミッション構造の発光装置の一例を示す。図2(A)は、図1のA−B間の断面図に相当する。
図3に、ボトムエミッション構造の発光装置の別の例を示す。図3は、図1のA−B間の断面図に相当する。
図4に、デュアルエミッション構造の発光装置の一例を示す。図4は、図1のA−B間の断面図に相当する。
図5(A)に、デュアルエミッション構造の発光装置の別の例を示す。図5(A)は、図1のA−B間の断面図に相当する。
第1の有機樹脂層100a及び第2の有機樹脂層100bの材料としては、例えば、ポリエチレンテレフタレート(PET)、ポリエチレンナフタレート(PEN)等のポリエステル樹脂、ポリアクリルニトリル樹脂、ポリイミド樹脂、ポリメチルメタクリレート樹脂、ポリカーボネート(PC)樹脂、ポリエーテルスルフォン(PES)樹脂、ポリアミド樹脂、シクロオレフィン樹脂、ポリスチレン樹脂、ポリアミドイミド樹脂、またはポリ塩化ビニル樹脂などを用いることができる。また、ガラス繊維に樹脂を含浸した基板や、無機フィラーを有機樹脂に混ぜた基板を使用することもできる。
第1のガラス層101a及び第2のガラス層101bの材料としては、25μm以上100μm以下の厚さのガラスを用いることができる。
構成例1、2は、ボトムエミッション構造の発光装置である。したがって、第1の電極103は透光性を有する。また、構成例3、4はデュアルエミッション構造の発光装置である。したがって、第1の電極103及び第2の電極107は透光性を有する。
封止層110は、第1のガラス層101aと接し、発光素子を覆う。封止層110は必ずしも設ける必要は無いが、設けることで、水分又は不純物等が発光素子の外部から発光素子に含まれる有機化合物や金属材料に侵入することをさらに抑制することができる。封止層110の材料としては、例えば、窒化ケイ素、酸化ケイ素、アルミナ等を用いることができる。
シール材としては公知の材料を用いることができる。例えば、熱硬化型の材料、紫外線硬化型の材料を用いても良い。シール材114には、ガラス同士を接着することができる材料、シール材116には、有機樹脂同士を接着することができる材料を用いる。これらの材料はできるだけ水分や酸素を透過しない材料であることが望ましい。また、乾燥剤入りのシール材を用いることもできる。
凹凸の構造118a及び凹凸の構造118bは、ストライプ状であっても効果を奏するが、マトリクス状であることが好ましい。凹凸のパターンは、特に限定されず、例えば、半球状や、円錐、角錐(三角錐、四角錐等)、傘状などの頂点を有する形状とすることができる。
本実施の形態では、実施の形態1で示した本発明の一態様の発光装置の作製方法について、図7及び図8を用いて説明する。
<構成例1>
構成例1(図2(A)参照)の作製方法の一例について、図7を用いて説明する。
構成例1の作製工程の後に、第1の有機樹脂層100aの大気と接する面に凹凸の構造118aを設けることで、構成例2(図3参照)を作製することができる(図7(E))。第1の有機樹脂層100aに凹凸の構造118aを形成する時期に限定は無い。発光素子等を形成する工程中や搬送中に凹凸の構造118aが壊れることを防ぐことができるため、第1の有機樹脂層100a上に発光素子等を形成した後(又は封止した後)に凹凸の構造118aを形成することが好ましい。
上記構成例1の作製工程において、透光性を有する材料を用いて第2の電極を形成することで、構成例3(図4参照)を作製することができる。その他の層は、構成例1と同様の作製方法を適用することができる。
構成例3の作製工程の後に、第1の有機樹脂層100aの大気と接する面に凹凸の構造118aを設けることで、図5(A)に示す構成例4を作製することができる。さらに、第2の有機樹脂層100bの大気と接する面に凹凸の構造118bを設けることで、図5(B)に示す構成例4を作製することができる。
<構成例1>
構成例1(図2(A)参照)の作製方法の別の例について、図8を用いて説明する。
構成例1の作製工程の後に、第1の有機樹脂層100aの大気と接する面に凹凸の構造118aを設けることで、構成例2(図3参照)を作製することができる(図8(D))。または、凹凸の構造118aが設けられた第1の有機樹脂層100aを、シール材116を用いて第2の有機樹脂層100bと貼り合わせても良い。
上記構成例1の作製工程において、透光性を有する材料を用いて第2の電極を形成することで、構成例3(図4参照)を作製することができる。その他の層は、構成例1と同様の作製方法を適用することができる。
構成例3の作製工程の後に、第1の有機樹脂層100aの大気と接する面に凹凸の構造118aを設けることで、図5(A)に示す構成例4を作製することができる。さらに、第2の有機樹脂層100bの大気と接する面に凹凸の構造118bを設けることで、図5(B)に示す構成例4を作製することができる。
本実施の形態では、実施の形態1で示した構成とは異なる本発明の一態様の発光装置について図1及び図6を用いて説明する。
図6(A)にボトムエミッション構造の発光装置の一例を示す。
図6(B)にデュアルエミッション構造の発光装置の一例を示す。
第1の樹脂層124a及び第2の樹脂層124bの材料としては、高屈折率の液体や樹脂等が挙げられる。第1の樹脂層124a及び第2の樹脂層124bは透光性を有する。高屈折率の樹脂としては、臭素が含まれる樹脂、硫黄が含まれる樹脂などが挙げられ、例えば、含硫黄ポリイミド樹脂、エピスルフィド樹脂、チオウレタン樹脂、又は臭素化芳香族樹脂などを用いることができる。また、PET(ポリエチレンテレフタラート)、TAC(トリアセチルセルロース)なども用いることができる。高屈折率の液体としては、硫黄及びヨウ化メチレンを含む接触液(屈折液)などを用いることができる。成膜方法としては、材料にあった種々の方法を適用すれば良い。例えば、前述の樹脂を、スピンコート法を用いて成膜し、熱または光によって硬化させることで形成することができる。接着強度や加工のしやすさなどを考慮し適宜選択することができる。
第1の保護層120a及び第2の保護層120bとしては、例えば、窒化ケイ素膜、窒化酸化ケイ素膜、窒化アルミニウム膜等を用いることができる。第1の保護層120a及び第2の保護層120bは、必ずしも設ける必要はないが、第1の樹脂層124a及び第2の樹脂層124bからEL層102に水分が侵入することを防ぐことができ、発光装置の寿命の低下を抑制することができる。
凹凸の構造体は、ガラス層の表面に、半球レンズ、マイクロレンズアレイや、凹凸構造が施されたフィルム、光拡散フィルム等を、公知の接着剤等を用いて接着することで形成することができる。
本実施の形態では、実施の形態3で示した本発明の一態様の発光装置の作製方法について、図9及び図10を用いて説明する。
構成例5(図6(A)参照)の作製方法の一例について、図9を用いて説明する。
構成例6(図6(B)参照)の作製方法の一例について、図9及び図10を用いて説明する。
本実施の形態では、先の実施の形態で示した構成とは異なる本発明の一態様の発光装置について説明する。
図11にボトムエミッション構造の発光装置の一例を示す。図11は、図1のA−B間の断面図に相当する。
本実施の形態では、実施の形態1で示した本発明の一態様の発光装置の変形例について説明する。
図12(D)に示す曲面を有する発光装置は、第1の有機樹脂層100a、第1のガラス層101a、発光素子(第1の電極103、EL層102、及び第2の電極108)、封止層110、第2のガラス層101b、及び第2の有機樹脂層100bを有する。
本実施の形態では、本発明の一態様の発光装置にコンバータを内蔵する構成について、図14を用いて説明する。なお、以下の説明において、上記の実施の形態と同一の部分については説明を省略する。
本実施の形態では、本発明の一態様に適用できるEL層の一例について、図15を用いて説明する。
本実施の形態では、本発明の一態様の発光装置を用いて完成させた照明装置の一例について、図21を用いて説明する。
まず、本実施例で作製したGZO膜について説明する。本実施例で作製したGZO膜は表1に示す3種類である。
次に、構成例1乃至構成例3の屈折率をそれぞれ測定した。本実施例では、エリプソメトリ法を用いて屈折率を求めた。
次に、構成例1乃至構成例3の透過率をそれぞれ測定した。本実施例では、分光光度計を用いて透過率の値を得た。
まず、本実施例で作製したGZO膜について説明する。本実施例で作製したGZO膜は表2に示す12種類である。
次に、構成例A−1乃至構成例A−4、構成例B−1乃至構成例B−4、及び構成例C−1乃至構成例C−4の屈折率をそれぞれ測定した。
100b 第2の有機樹脂層
101a 第1のガラス層
101b 第2のガラス層
102 EL層
103 第1の電極
107 第2の電極
108 第2の電極
110 封止層
112 空間
114 シール材
115 充填材
116 シール材
118a 凹凸の構造
118b 凹凸の構造
120a 第1の保護層
120b 第2の保護層
122a 凹凸の構造体
122b 凹凸の構造体
124a 第1の樹脂層
124b 第2の樹脂層
130a 第1の回路素子
130b 第2の回路素子
130c 第3の回路素子
135 接続配線
138 絶縁膜
140 プリント基板
150 コンバータ
151 封止樹脂
410a 取り出し電極
410b 取り出し電極
411 接続電極
411a 接続電極
411b 接続電極
701 正孔注入層
702 正孔輸送層
703 発光性の有機化合物を含む層
704 電子輸送層
705 電子注入層
706 電子注入バッファー層
707 電子リレー層
708 複合材料層
800 第1のEL層
801 第2のEL層
803 電荷発生層
901 照明装置
902 照明装置
903 卓上照明器具
9501 照明部
9503 支柱
9505 支持台
Claims (15)
- 第1の有機樹脂層と、
前記第1の有機樹脂層上の、前記第1の有機樹脂層の一方の面に接する第1のガラス層と、
前記第1のガラス層上の発光素子と、
前記発光素子上の第2のガラス層と、
前記第2のガラス層上の、前記第2のガラス層の一方の面と接する第2の有機樹脂層と、を備え、
前記第1の有機樹脂層及び前記第1のガラス層が、可視光に対する透光性を有し、
前記第1のガラス層及び前記第2のガラス層は、それぞれ独立に、25μm以上100μm以下の厚さであり、
前記発光素子が、前記第1のガラス層側から、可視光に対する透光性を有する第1の電極と、発光性の有機化合物を含む層と、第2の電極と、を有する発光装置。 - 請求項1において、
前記第1の有機樹脂層と前記第2の有機樹脂層は、同じ材料からなる発光装置。 - 請求項1又は請求項2において、
前記第1のガラス層と接し、前記発光素子を覆う封止層を備える発光装置。 - 請求項1乃至請求項3のいずれか一項において、
前記第1の有機樹脂層が、他方の面に凹凸の構造を有する発光装置。 - 請求項4において、
前記第1のガラス層上に凹凸の構造体と、
前記凹凸の構造体上に第1の樹脂層と、
前記第1の樹脂層上に前記第1の電極と、を有し、
前記第1の樹脂層の屈折率が、前記発光性の有機化合物を含む層の屈折率以上である発光装置。 - 請求項4において、
前記第1のガラス層上に凹凸の構造体と、
前記凹凸の構造体上に第1の樹脂層と、
前記第1の樹脂層上に前記第1の電極と、を有し、
前記第1の樹脂層の屈折率が、前記第1の電極の屈折率以上である発光装置。 - 請求項5又は請求項6において、
前記第1の樹脂層及び第1の電極の間に接して設けられた第1の保護層を有し、
前記第1の保護層の屈折率が、前記第1の樹脂層の屈折率以上である発光装置。 - 請求項1乃至請求項7のいずれか一項において、
前記第2の有機樹脂層、前記第2のガラス層、及び前記第2の電極が、可視光に対する透光性を有する発光装置。 - 請求項8において、
前記第2の有機樹脂層が、前記第2のガラス層と接しない面に凹凸の構造を有する発光装置。 - 請求項8又は請求項9のいずれか一項において、
前記第2の電極上の第2の樹脂層と、
前記第2の樹脂層上の凹凸の構造体と、
前記凹凸の構造体上の前記第2のガラス層と、を有し、
前記第2の樹脂層の屈折率が、前記発光性の有機化合物を含む層の屈折率以上である発光装置。 - 請求項8又は請求項9のいずれか一項において、
前記第2の電極上の第2の樹脂層と、
前記第2の樹脂層上の凹凸の構造体と、
前記凹凸の構造体上の前記第2のガラス層と、を有し、
前記第2の樹脂層の屈折率が、前記第2の電極の屈折率以上である発光装置。 - 請求項10又は請求項11において、
前記第2の電極及び第2の樹脂層の間に接して設けられた第2の保護層を有し、
前記第2の保護層の屈折率が、前記第2の樹脂層の屈折率以上である発光装置。 - 可撓性を有する、請求項1乃至請求項12のいずれか一項に記載の発光装置。
- コンバータを備える、請求項1乃至請求項13のいずれか一項に記載の発光装置。
- 請求項1乃至請求項14のいずれか一項に記載の発光装置を発光部に備える照明装置。
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TW201705576A (zh) | 2017-02-01 |
JP2017130462A (ja) | 2017-07-27 |
JP2024100926A (ja) | 2024-07-26 |
JP2023022295A (ja) | 2023-02-14 |
JP6118020B2 (ja) | 2017-04-19 |
US9502690B2 (en) | 2016-11-22 |
JP6921176B2 (ja) | 2021-08-18 |
TWI562422B (en) | 2016-12-11 |
US20120153333A1 (en) | 2012-06-21 |
JP2019050212A (ja) | 2019-03-28 |
KR101802409B1 (ko) | 2017-11-28 |
JP2021170552A (ja) | 2021-10-28 |
JP6637579B2 (ja) | 2020-01-29 |
JP2020064867A (ja) | 2020-04-23 |
US20170077444A1 (en) | 2017-03-16 |
JP7193589B2 (ja) | 2022-12-20 |
JP6442544B2 (ja) | 2018-12-19 |
TW201240180A (en) | 2012-10-01 |
US9882165B2 (en) | 2018-01-30 |
KR20120067959A (ko) | 2012-06-26 |
TWI591871B (zh) | 2017-07-11 |
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