JP2012102061A - 固形粉末化粧料 - Google Patents
固形粉末化粧料 Download PDFInfo
- Publication number
- JP2012102061A JP2012102061A JP2010253517A JP2010253517A JP2012102061A JP 2012102061 A JP2012102061 A JP 2012102061A JP 2010253517 A JP2010253517 A JP 2010253517A JP 2010253517 A JP2010253517 A JP 2010253517A JP 2012102061 A JP2012102061 A JP 2012102061A
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- JP
- Japan
- Prior art keywords
- iob
- less
- mass
- oil agent
- solid powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000576 coating method Methods 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
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- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
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- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 1
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- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 description 1
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- 229910000271 hectorite Inorganic materials 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
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- 229910052742 iron Inorganic materials 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- JCDAAXRCMMPNBO-UHFFFAOYSA-N iron(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Fe+3].[Fe+3] JCDAAXRCMMPNBO-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical compound [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
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- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
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- 239000012463 white pigment Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
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Abstract
【解決手段】(a)比表面積が100m2/g以上で平均粒子径0.1〜20μmの架橋型アクリル系樹脂粉末0.01〜10質量%、(b)25℃で液体であるIOB値0.1以下の低極性油剤及び/又は非極性油剤20〜70質量%、並びに(c)IOB値0.1を超える極性油剤15質量%以下を含有することを特徴とする固形粉末化粧料。
【選択図】なし
Description
従って、本発明の課題は、滑らかな塗擦感を有し、皮膚を平滑にし、毛穴やシワ等の皮膚形態を補正し、且つ化粧持続性に優れた固形粉末化粧料を提供することにある。
当該架橋アクリル系樹脂粉末の比表面積は、皮脂や汗を選択的に吸着し、高い化粧持続性を得る点から100m2/g以上であり、さらに150m2/g以上であるのが特に好ましい。また、比表面積の上限は特に限定されないが、300m2/g以下が好ましい。また、当該架橋アクリル系樹脂粉末の平均粒子径は、皮脂や汗を選択的に吸着し、高い化粧持続性を得る点及び皮膚形態の補正効果、皮膚の平滑性、塗擦感の点から、0.1〜20μmが好ましく、1〜10μmがより好ましい。また、当該架橋アクリル系樹脂粉末の形状は、球状又は略球状であるのが、皮膚の平滑性、塗擦感の点から好ましい。このような架橋アクリル系樹脂粉末の市販品としては、比表面積が170m2/g、平均粒子径が8μmであるMAKIBEADS(大東化成工業社製)等を用いることができる。
尚、IOB値とは、Inorganic/Organic Balance(無機性/有機性比)の略であって、無機性値の有機性値に対する比率を表す値であり、有機化合物の極性の度合いを示す指標となるものである。IOB値は、具体的には、IOB値=無機性値/有機性値として表される。「無機性値」、「有機性値」のそれぞれについては、例えば、分子中の炭素原子1個について「有機性値」が20、同水酸基1個について「無機性値」が100といったように、各種原子又は官能基に応じた「無機性値」、「有機性値」が設定されており、有機化合物中の全ての原子及び官能基の「無機性値」、「有機性値」を積算することによって、当該有機化合物のIOB値を算出することができる(例えば、甲田善生著、「有機概念図−基礎と応用−」p11〜17、三共出版、1984年発行参照)。
下記油剤10gと、粉体A〜C5gとをガラス瓶に充填し、ボルテックス(MS1 Minishaker、IKA(登録商標)Japan K.K.)にて1分間分散させた後(2500/min)、1日静置し、その外観を下記の評価基準により判定した。
粉体A:メタクリル酸メチルクロスポリマー(MAKIBEADS 150、大東化成工業社製)
粉体B:ポリメタクリル酸メチル(マイクロスフェアーM、松本油脂製薬社製)
粉体C:メタクリル酸メチルクロスポリマー(GMP−0800、ガンツ化成社製)
○:油剤と粉体が2層に分離
△:ペースト状
×:塊状又は粉状
したがって本発明で用いる比表面積が100m2/g以上であるメタクリル酸メチルクロスポリマーとIOB値0.1以下の低極性油剤又は非極性油剤とを組み合わせて配合した固形粉末化粧料は、その製剤中においては油剤を吸着せず、皮膚に塗布されたとき、高極性油剤と類似する皮脂や汗を選択的に吸着することが可能となる。
次に下記の処方にて油性ファンデーションを調製し、その官能評価を行った。評価は、専門パネラーを評価項目ごとに20名ずつ用意し(但し、項目によりパネラーが重複する場合もある)、「塗布感(滑らかさ)」、「補正効果」、「化粧持続性」の評価項目に関し、下記に示す絶対評価基準に従って5段階評価を行い、全パネラーの合計点数を算出した。そしてその平均値を算出し、下記4段階判定基準により判定した。
基準点数:
効果が高く感じられる :5
効果が感じられる :4
効果はやや感じられる :3
効果はわずかしか感じられない :2
効果が感じられない :1
判定評点の平均点:
◎:4点を超える
○:3点を超え、4点以下
△:2点を超え、3点以下
×:2点以下
デカメチルシクロペンタシロキサン(b成分) 35.0
ジメチルポリシロキサン(6cs)(b成分) 10.0
水添ポリイソブテン(b成分) 3.0
イソノナン酸イソノニル(c成分) 7.0
アクリル酸アルキルコポリマー 5.0
パラフィン 5.0
ポリメチルシルセスキオキサン 5.0
(ジメチコン・ビニルメチコン)クロスポリマー 4.0
シリカ 3.0
マイクロクリスタリンワックス 1.5
トリメチルシロキシケイ酸 1.5
メタクリル酸メチルクロスポリマー(a成分) 1.0
(比表面積:170m2/g、平均粒子径8μm)
カオリン 8.99
ベンガラ/酸化アルミニウム/酸化チタン被覆マイカ 0.01
雲母チタン 10.0
デカメチルシクロペンタシロキサン(b成分) 45.0
ジメチルポリシロキサン(6cs)(b成分) 5.0
流動パラフィン(b成分) 2.0
イソノナン酸イソノニル(c成分) 5.0
オクチルドデカノール(c成分) 3.0
(ジメチコン・ビニルメチコン)クロスポリマー 12.0
ポリメチルシルセスキオキサン 10.0
パラフィン 6.0
シリカ 3.0
トリメチルシロキシケイ酸 2.0
メタクリル酸メチルクロスポリマー(a成分) 2.0
(比表面積:170m2/g、平均粒子径8μm)
マイクロクリスタリンワックス 2.0
酸化チタン 2.9
アルミナ/酸化鉄/酸化チタン/マイカ 0.1
Claims (4)
- (a)比表面積が100m2/g以上で平均粒子径0.1〜20μmの架橋型アクリル系樹脂粉末0.01〜10質量%、(b)25℃で液体であるIOB値0.1以下の低極性油剤及び/又は非極性油剤20〜70質量%、並びに(c)IOB値0.1を超える極性油剤15質量%以下を含有することを特徴とする固形粉末化粧料。
- 架橋型アクリル系樹脂粉末が、アクリル酸エステル、メタクリル酸エステル、アクリルアミド及びメタクリルアミドから選ばれるアクリル系モノマーを構成単位として含む重合体又は共重合体の架橋体である請求項1記載の固形粉末化粧料。
- 架橋型アクリル系樹脂粉末が、球状又は略球状である請求項1又は2記載の固形粉末化粧料。
- (b)25℃で液体であるIOB値0.1以下の低極性油剤及び/又は非極性油が、IOB値0.1以下のエステル油、シリコーン油及び炭化水素系油剤から選ばれる1種又は2種以上である請求項1〜3のいずれか1項記載の固形粉末化粧料。
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JP2014193834A (ja) * | 2013-03-29 | 2014-10-09 | Kose Corp | カロテノイド含有組成物、カロテノイド劣化抑制剤、及び、カロテノイドの劣化抑制方法 |
JP2016147821A (ja) * | 2015-02-10 | 2016-08-18 | 紀伊産業株式会社 | 固形化粧料 |
WO2019111831A1 (ja) * | 2017-12-04 | 2019-06-13 | 花王株式会社 | 油中水型乳化化粧料 |
JP2019099510A (ja) * | 2017-12-04 | 2019-06-24 | 花王株式会社 | 油中水型乳化化粧料 |
JP2019099509A (ja) * | 2017-12-04 | 2019-06-24 | 花王株式会社 | 油中水型乳化化粧料 |
WO2021172351A1 (ja) * | 2020-02-28 | 2021-09-02 | 株式会社 資生堂 | 粉末固形化粧料 |
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JP2014193834A (ja) * | 2013-03-29 | 2014-10-09 | Kose Corp | カロテノイド含有組成物、カロテノイド劣化抑制剤、及び、カロテノイドの劣化抑制方法 |
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JP7272783B2 (ja) | 2017-12-04 | 2023-05-12 | 花王株式会社 | 油中水型乳化化粧料 |
WO2021172351A1 (ja) * | 2020-02-28 | 2021-09-02 | 株式会社 資生堂 | 粉末固形化粧料 |
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