JP2010510945A - 広い表面積接触用途のための高度に接触可能なナノチューブ電極 - Google Patents
広い表面積接触用途のための高度に接触可能なナノチューブ電極 Download PDFInfo
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- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
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- H—ELECTRICITY
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Abstract
Description
1.HFで溶解されたシリカナノ粒子。
2.酸で溶解された金属ナノ粒子、例えば、HClで溶解された亜鉛ナノ粒子。
3.天井温度効果を用いてポリマー粒子の脱重合。
Claims (20)
- 多孔質カーボンナノチューブまたはナノワイヤーフィルムを形成する方法であって、
カーボンナノチューブまたはナノワイヤーおよび犠牲ナノ粒子または微粒子を含むコンポジットフィルムを形成すること、および
少なくとも一部の該ナノ粒子または微粒子を該フィルムから除去し、高多孔質ナノチューブまたはナノワイヤーフィルムを形成することを特徴とする、方法。 - 形成工程が、該カーボンナノチューブまたはナノワイヤーおよび該微粒子または該ナノ粒子の共析出を含むことを特徴とする、請求項1記載の方法。
- 形成工程が、該カーボンナノチューブまたはナノワイヤーの析出および該微粒子または該ナノ粒子の析出を交互に行うことを含むことを特徴とする、請求項1記載の方法。
- 形成工程が、
多孔質フィルムを得ること;
複数の該ナノチューブまたはナノワイヤーおよび微粒子または該ナノ粒子を該ナノチューブまたはナノワイヤーを懸濁液からの凝集から阻止するための少なくとも1種の表面安定剤を含む、溶液中に分散させること;
該溶液を該フィルムに適用すること、および
該溶液を除去することを特徴とし、ここで、該ナノチューブまたはナノワイヤーおよび微粒子または該ナノ粒子が、該多孔質フィルムの表面上に強要され、該フィルム上に位置する該コンポジットフィルムを形成する、請求項1記載の方法。 - 25℃の該多孔質フィルムの電気抵抗が、6x10−3Ω・cm未満であることを特徴とする、請求項1記載の方法。
- 該ナノチューブまたはナノワイヤーが、95%より大きい単層カーボンナノチューブ(SWNT)を含むことを特徴とする、請求項1記載の方法。
- 該形成工程が、噴霧析出方法を含むことを特徴とする、請求項1記載の方法。
- 該形成工程が、電着方法を含むことを特徴とする、請求項1記載の方法。
- 該形成工程が、ラングミュア−ブロジェット析出方法を含むことを特徴とする、請求項1記載の方法。
- 該ナノ粒子または微粒子が、均一な大きさを有することを特徴とする、請求項1記載の方法。
- 該ナノ粒子または微粒子が、種々の大きさを有することを特徴とする、請求項1記載の方法。
- 該ナノ粒子または微粒子の表面上の該ナノチューブまたはナノワイヤーのアセンブリーを強化する該形成工程前にナノチューブまたはナノワイヤーに対する特異的アフィニティーを有する種で該ナノ粒子または微粒子の表面を機能化することをさらに特徴とする、請求項1記載の方法。
- 該機能化工程が、一定期間、該ナノ粒子または微粒子を該ナノチューブまたはナノワイヤーで混合およびインキュベートすることを含むことを特徴とする、請求項12記載の方法。
- 該機能化工程前に、該ナノ粒子または微粒子の相分離を該ナノチューブまたはナノワイヤーで阻止する添加物である、該表面安定剤以外の添加物を該懸濁液に加えることをさらに特徴とする、請求項4記載の方法。
- 該添加物が、強酸を含むことを特徴とする、請求項14記載の方法。
- 該ナノ粒子または微粒子が、液体に関与する方法で除去されることを特徴とし、該フィルムが、後で用いる次の処理のために浸され続ける、請求項1記載の方法。
- 複数のカーボンナノチューブ、ナノワイヤー、または両方の組み合わせを特徴とする、伝導性高多孔質フィルムであって、25℃で0.1Ω・cm未満の電気抵抗および0.05〜0.70g/cm3の密度を提供するところの、フィルム。
- 該密度が、0.50〜0.85g/cm3であり、該電気抵抗が、25℃で6x10−3Ω・cm未満であることを特徴とする、請求項17記載のフィルム。
- 該ナノチューブまたはナノワイヤーが、95%より大きい単層カーボンナノチューブ(SWNT)を含むことを特徴とする、請求項17記載のフィルム。
- 該フィルムが本質的に該ナノチューブからなることを特徴とする、請求項17記載のフィルム。
Applications Claiming Priority (3)
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US84393906P | 2006-09-12 | 2006-09-12 | |
US60/843,939 | 2006-09-12 | ||
PCT/US2007/078230 WO2008033889A2 (en) | 2006-09-12 | 2007-09-12 | Highly accessible, nanotube electrodes for large surface area contact applications |
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JP2010510945A true JP2010510945A (ja) | 2010-04-08 |
JP5663164B2 JP5663164B2 (ja) | 2015-02-04 |
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US (2) | US7704479B2 (ja) |
EP (1) | EP2062275A2 (ja) |
JP (1) | JP5663164B2 (ja) |
KR (1) | KR101434694B1 (ja) |
CN (1) | CN101529542B (ja) |
CA (1) | CA2663281A1 (ja) |
SG (1) | SG174798A1 (ja) |
WO (1) | WO2008033889A2 (ja) |
Cited By (1)
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CA2698093A1 (en) | 2007-08-29 | 2009-03-12 | Northwestern University | Transparent electrical conductors prepared from sorted carbon nanotubes and methods of preparing same |
CN101659789B (zh) * | 2008-08-29 | 2012-07-18 | 清华大学 | 碳纳米管/导电聚合物复合材料的制备方法 |
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WO2008033889A2 (en) | 2008-03-20 |
US7704479B2 (en) | 2010-04-27 |
EP2062275A2 (en) | 2009-05-27 |
JP5663164B2 (ja) | 2015-02-04 |
KR101434694B1 (ko) | 2014-08-26 |
US9368291B2 (en) | 2016-06-14 |
CN101529542A (zh) | 2009-09-09 |
WO2008033889A3 (en) | 2009-01-29 |
US20100207074A1 (en) | 2010-08-19 |
SG174798A1 (en) | 2011-10-28 |
US20080299030A1 (en) | 2008-12-04 |
CN101529542B (zh) | 2012-06-13 |
CA2663281A1 (en) | 2008-03-20 |
KR20090060344A (ko) | 2009-06-11 |
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