JP2010242867A - Vacuum heat insulating material and apparatus having the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a vacuum heat insulating material having excellent heat insulating performance that can exceed the improvement limit of conventional heat insulating performance, and an apparatus having the vacuum heat insulating material. <P>SOLUTION: The vacuum heat insulating material 1 includes an external wrapping material 200, a core material 100 stored inside the external wrapping material 200, and an adsorbing material 400 stored inside the external wrapping material 200. The external wrapping material 200 has heat-welded parts 300 heat-welded by the mutual contact of the external wrapping materials 200. The heat-welded parts 300 are formed of material containing hydrocarbon. The adsorbing material 400 adsorbs hydrocarbon gas. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a vacuum heat insulating material and a device including the same.

  Refrigerator, cold box, heat box, etc. used for heating, cooling, and holding various foods, and dryers that blow dry air by blowing warm air on the object to be dried Conventionally, heat insulating materials having various structures and performances have been used. Among heat insulating materials, vacuum heat insulating materials are excellent in heat insulating performance, and are widely used in devices such as household refrigerators that require heat insulation. A vacuum heat insulating material is generally obtained by filling a core material made of an inorganic material into an outer packaging material, sealing the outer packaging material, and maintaining the inside of the outer packaging material in a reduced pressure state.

  In the vacuum heat insulating material, water vapor may be generated from the core material filled in the outer packaging material, or gas may enter the outer packaging material through the outer packaging material. When the internal pressure of the outer packaging material is increased by such water vapor or gas, the reduced pressure state is deteriorated and the heat insulation performance is lowered. Thus, some conventional vacuum heat insulating materials include a moisture adsorbent or the like inside the outer packaging material in order to prevent the internal pressure of the outer packaging material from increasing.

  For example, in the vacuum heat insulating material described in Japanese Patent Application Laid-Open No. 2002-161994 (Patent Document 1), a reactive moisture adsorbent is encased and sealed together with a core material together with a core material. Even when the internal pressure of the vacuum heat insulating material increases due to the release of water from the core material after the vacuum heat insulating material is produced, the reactive water adsorbent adsorbs and removes the water, thereby preventing the heat insulating performance from being deteriorated. In this vacuum heat insulating material, as the reactive moisture adsorbent, metal oxides such as calcium chloride, calcium oxide, lithium chloride and magnesium oxide, and physical adsorbents such as silica gel and zeolite are used.

  In addition, in the vacuum heat insulating material described in Japanese Patent Application Laid-Open No. 2002-48466 (Patent Document 2), the degree of vacuum of the vacuum heat insulating material deteriorates due to the gas generated from the core material or the gas that permeates and penetrates from the outside. In order to prevent the performance from deteriorating, an adsorbent is charged into the jacket material together with the core material. As the adsorbent, zeolite, activated carbon, metal oxides such as calcium chloride and magnesium oxide, hydroxides such as magnesium hydroxide and calcium hydroxide, alloys such as barium-lithium alloy, and the like are used.

In the vacuum heat insulating material described in Japanese Patent Application Laid-Open No. 2006-17169 (Patent Document 3), a core material made of glass wool made of glass fiber as an inorganic fiber laminated material is sealed under reduced pressure in a jacket material. In addition, the density of the core material in the vacuum heat insulating material is 200 to 270 kg / m ³ , and the core material after opening the outer cover material contains 75% or more of glass fibers having a fiber length of 100 μm or more.

Japanese Patent Laid-Open No. 2002-161994 JP 2002-48466 A JP 2006-17169 A

  However, an adsorbent adsorbs water, such as the vacuum heat insulating material described in JP 2002-161994 A (Patent Document 1) and the vacuum heat insulating material described in JP 2002-48466 A (Patent Document 2). By the conventional improvement method which suppresses the raise of the internal pressure of a vacuum heat insulating material by doing, there was a limit in the improvement of the heat insulation performance of a vacuum heat insulating material.

  Therefore, an object of the present invention is to provide a vacuum heat insulating material that can exceed the improvement limit of conventional heat insulating performance and has excellent heat insulating performance, and a device including the same.

  As a result of intensive studies in order to solve the problems of the conventional vacuum heat insulating material, the present inventors, as a result, when the heat-welded portion of the outer packaging material of the vacuum heat insulating material is formed of a material containing hydrocarbon, It has been found that the above object can be achieved by accommodating an adsorbent that adsorbs hydrocarbon gas inside the outer packaging material. Based on this knowledge, the vacuum heat insulating material according to the present invention has the following characteristics.

  The vacuum heat insulating material according to the present invention includes an outer packaging material, a core material accommodated in the outer packaging material, and an adsorbing material accommodated in the outer packaging material. The outer packaging material has a thermal welding part where the outer packaging materials come into contact with each other and are thermally welded. The heat welded portion is formed of a material containing hydrocarbons. The adsorbent is an adsorbent that adsorbs hydrocarbon gas.

  The inventors have conducted various verification experiments, and when the heat welded portion of the outer packaging material of the vacuum heat insulating material is formed of a material containing hydrocarbon, the vacuum heat insulating material is used when the heat welded portion is heat welded. It has been found that the heat insulation performance of is adversely affected.

  In the vacuum heat insulating material, the heat-welded portion of the outer packaging material is heat-welded and sealed, so that hydrocarbon gas generated from the heat-welded portion during heat welding not only diffuses outside the vacuum heat-insulating material, but also the vacuum heat-insulating material. It also diffuses inside the outer packaging material. The hydrocarbon gas diffused inside the outer packaging material of the vacuum heat insulating material is sealed as it is inside the outer packaging material.

  The vacuum heat insulating material is sealed by thermally welding the heat-sealed portion of the outer packaging material under a reduced pressure condition, so that when the hydrocarbon gas is diffused inside the outer packaging material, the degree of vacuum inside the outer packaging material is reduced. Becomes lower. The heat insulation of a vacuum heat insulating material falls by the vacuum degree inside an outer packaging material becoming low.

  Therefore, an adsorbent that adsorbs hydrocarbon gas is accommodated inside the outer packaging material, and the hydrocarbon gas that diffuses inside the outer packaging material is adsorbed by the adsorbent. By adsorbing the hydrocarbon gas to the adsorbent, it is possible to prevent the degree of vacuum from being lowered by the hydrocarbon gas.

  By doing in this way, the vacuum insulation material which can exceed the improvement limit of the conventional heat insulation performance and has the outstanding heat insulation performance can be provided.

  As a result of intensive studies to solve the problems of the core material that has been used in conventional vacuum heat insulating materials, the present inventors have produced a fiber constituting the core material for vacuum heat insulating material by a continuous filament method. It has been found that the above object can be achieved by including at least a plurality of inorganic fibers formed. Here, the continuous filament method is a fiber manufacturing method in which molten filaments are continuously drawn down through a bushing nozzle, drawn, and fiberized to produce continuous filaments. Based on this knowledge, the vacuum heat insulating material according to the present invention preferably has the following characteristics.

  In the vacuum heat insulating material according to the present invention, the core material is preferably configured by laminating a plurality of nonwoven fabrics. The nonwoven fabric preferably includes at least a plurality of inorganic fibers produced by a continuous filament method. In the nonwoven fabric, it is preferable that most of the plurality of inorganic fibers extend in a direction substantially parallel to the surface of the nonwoven fabric.

  According to the continuous filament method, a large number of fibers with extremely small variations in fiber diameter can be mass-produced. Moreover, the inorganic fiber manufactured by the continuous filament method has very high straightness of each fiber. For this reason, by cutting a large number of inorganic fibers manufactured by the continuous filament method into a substantially constant length, a straightness of a large number of inorganic fibers having substantially the same length and having a very small variation in fiber diameter can be obtained. It can be obtained in a very high state.

  The nonwoven fabric constituting the core material includes at least a plurality of inorganic fibers produced by the continuous filament method. Therefore, when forming a nonwoven fabric using such a plurality of inorganic fibers, each inorganic fiber is formed on the surface of the nonwoven fabric. When arranged in a parallel direction, a plurality of inorganic fibers can be easily aligned so that most of the inorganic fibers extend in a direction substantially parallel to the surface of the nonwoven fabric. At this time, most of the plurality of inorganic fibers extend in a direction substantially parallel to the surface of the nonwoven fabric, but are in close contact with each other and do not align with the parallel direction, and are in a random direction within the plane forming the surface of the nonwoven fabric. Align so that they face each other. As a result, the presence of inorganic fibers filling between the plurality of inorganic fibers constituting the core material can be minimized, and the presence of inorganic fibers entangled between the plurality of inorganic fibers can be minimized. Therefore, it is possible to prevent heat conduction between the inorganic fibers. For this reason, by preventing the occurrence of heat conduction along the thickness direction of the core material, the thermal conductivity of the core material can be reduced, and it becomes possible to exceed the improvement limit of the conventional heat insulation performance, It is possible to obtain a vacuum heat insulating material having high heat insulating performance.

  In the vacuum heat insulating material according to the present invention, it is preferable that the average fiber diameter of the inorganic fibers is 3 μm to 15 μm, and the average fiber length of the inorganic fibers is 3 mm to 15 mm. In this case, the heat conductivity of the core material can be reduced most, and a vacuum heat insulating material having the most excellent heat insulating performance can be obtained.

  In the vacuum heat insulating material according to the present invention, the inorganic fibers are preferably glass fibers. In this case, since the glass fiber has a lower thermal conductivity than other inorganic fibers, for example, ceramic fibers, the heat insulating performance of the core material can be further improved by reducing the thermal conductivity of the material itself.

  An apparatus according to the present invention includes an outer box, an inner box disposed inside the outer box, and a vacuum heat insulating material disposed between the outer box and the inner box. It is preferable that a vacuum heat insulating material is included.

  For example, a refrigerator efficiently cools food contained in an inner box. In addition, for example, the washing / drying machine efficiently blows warm air on an object to be dried such as clothes housed in the inner box and efficiently dries it. In these devices, in order to keep the temperature inside the inner box at a predetermined temperature lower or higher than the outside of the outer box, or to cool or heat the inner box efficiently, It is necessary to insulate the inside from the outside of the outer box. Therefore, a vacuum heat insulating material is disposed between the outer box and the inner box. If the heat insulation performance of the vacuum insulation material placed between the outer box and the inner box is excellent, the energy required to make the inside of the inner box lower or higher than the outside of the outer box will be reduced. Can save energy.

  Then, the vacuum heat insulating material arrange | positioned between an outer box and an inner box contains said vacuum heat insulating material, and can provide the apparatus excellent in heat insulation performance and energy saving.

  As described above, according to the present invention, it is possible to provide a vacuum heat insulating material that can exceed the improvement limit of conventional heat insulating performance and has excellent heat insulating performance, and a device including the same.

Front view (A) which shows the initial state of the vacuum heat insulating material used for the verification experiment 1, and sectional drawing (B) when the vacuum heat insulating material is seen from the direction shown by the BB line in FIG. They are a front view (C) showing a state when the second thermal welding is performed, and a front view (D) showing a state when the third thermal welding is performed. It is a figure which shows the change of the heat conductivity of the vacuum heat insulating material by the frequency | count of heat welding. It is a figure which shows the change of the heat conductivity of the vacuum heat insulating material by the length of a heat welding part. It is sectional drawing which shows typically the structure of a vacuum heat insulating material as 1st Embodiment of this invention. As one embodiment of this invention, it is a perspective view showing typically an arrangement (A) of a core material and an outer packaging material, and a state (B) inside a vacuum heat insulating material when the inside of the outer packaging material is decompressed. . It is a top view which shows typically the distribution state of the glass fiber which comprises the nonwoven fabric used for the core material of a vacuum heat insulating material as one embodiment of this invention. It is a scanning electron micrograph (magnification 100 times) which shows the distribution state before compression of the glass fiber which comprises the nonwoven fabric used for the core material of a vacuum heat insulating material as one embodiment of this invention. It is an electron micrograph (magnification 100 times) of the section which shows the distribution state before compression of the glass fiber which constitutes the nonwoven fabric used for the core material of a vacuum heat insulating material as one embodiment of the present invention. As 2nd Embodiment of this invention, it is a sectional side view (A) which shows the whole refrigerator, and a front view (B) which shows the exterior of a refrigerator. It is a sectional side view which shows the whole water heater as 3rd Embodiment of this invention. As 4th Embodiment of this invention, they are the front perspective view (A) which shows the whole rice cooker, the back perspective view (B), and the figure (C) which shows the member accommodated in the inside of a rice cooker. It is a perspective view which shows the whole washing-drying machine as 5th Embodiment of this invention. It is a top view which shows typically the distribution state of the glass fiber in the glass wool conventionally used as a core material of a vacuum heat insulating material. It is the electron microscope photograph (100 times of magnification) of the plane which shows the distribution state before compression of the glass fiber in the glass wool conventionally used as a core material of a vacuum heat insulating material. It is the electron micrograph (100-times multiplication factor) of the cross section which shows the distribution state before compression of the glass fiber in the glass wool conventionally used as a core material of a vacuum heat insulating material.

  As described above, the present inventors have conducted various verification experiments, and when the heat-welded portion of the outer packaging material of the vacuum heat insulating material is formed of a material containing hydrocarbon, the heat-welded portion is heat-welded. It was found that the heat insulation performance of the vacuum heat insulating material is adversely affected. The verification experiment conducted by the present inventors will be described below.

(Verification experiment 1)
In order to verify that the heat insulation performance of the vacuum insulation material decreases due to an increase in the amount of hydrocarbon gas inside the outer packaging material, the change in the heat insulation performance of the vacuum insulation material when the outer packaging material is thermally welded multiple times Was measured.

  FIG. 1 is a front view (A) showing an initial state of the vacuum heat insulating material used in the verification experiment 1, and a cross section when the vacuum heat insulating material is viewed from the direction indicated by the line BB in FIG. FIG. 4B is a front view showing a state when the second thermal welding is performed, and a front view showing the state when the third thermal welding is performed.

  As shown in FIGS. 1A and 1B, in the vacuum heat insulating material 2 used in the verification experiment 1, the core material 10 is accommodated in a gas barrier outer packaging material 20 formed in a bag shape. In the reduced pressure state, the outer packaging material 20 is thermally welded and sealed at the heat welded portion 30 and the heat welded portion 31.

  As the outer packaging material 20, nylon was used for the outermost layer 21, two layers of aluminum-deposited PET resin and aluminum foil were used for the intermediate layer 22, and two types of polyethylene resins were used for the innermost layer 23.

  The core material 10 is configured by laminating a plurality of nonwoven fabrics 11. Each nonwoven fabric 11 is produced by a papermaking method using glass fibers which are examples of inorganic fibers and a small amount of an organic binder. Specifically, the core material 10 was produced as follows.

  Glass chopped strands (manufactured by Owens Corning Corporation) having an average fiber diameter of 10 μm and an average fiber length of 10 mm were poured into water so that the concentration became 0.5% by mass, and Emanon ( (Registered trademark) 3199 (manufactured by Kao Corporation) was added to 1 part by mass with respect to 100 parts by mass of the glass chopped strands, and stirred to prepare a glass chopped strand slurry.

Using the obtained glass chopped strand slurry, paper was made by a wet paper making method to prepare a web. The obtained web was impregnated with a solution obtained by diluting an acrylic emulsion (GM-4, manufactured by Dainippon Ink & Chemicals, Inc.) with water so that the solid content concentration was 3.0% by mass, and the moisture content of the web Was adjusted by sucking moisture so as to be 0.7% by mass with respect to the glass fiber mass. Then, the nonwoven fabric 11 used for the core material 10 was produced by drying a web. The nonwoven fabric 11 used for the obtained core material 10 had a rice weight of 100 g / m ² . A plurality of nonwoven fabrics 11 were laminated to form the core material 10. The core material 10 had a long side of 435 mm, a short side of 400 mm, and a thickness of 9 mm.

  The outer packaging material 20 was sealed as follows. First, the three sides of the outer packaging material 20 were thermally welded at the heat welding portion 30, and then the core material 10 was filled therein. Next, the heat-welded portion 31 of the outer packaging material 20 filled with the core material 10 was heat-welded under reduced pressure in a vacuum chamber. Thus, the core material 10 was sealed in the outer packaging material 20, and the vacuum heat insulating material 2 was produced. The heat welding part 31 was heat-welded at a temperature of 170 to 220 ° C. when the Pirani gauge instruction value installed in the vacuum chamber reached 0.009 Torr. Thus, the heat conductivity of the vacuum heat insulating material 2 produced was measured.

  Next, heat welding was performed at the heat welding portion 32 inside the heat welding portion 31, and the thermal conductivity was measured in the same manner. Then, in the heat welding part 33 inside the heat welding part 32, further heat welding was performed and the thermal conductivity was measured. The heat welding of the heat welding parts 32 and 33 was performed at a temperature of 170 to 220 ° C. as with the heat welding part 31.

  In addition, the measurement of thermal conductivity is carried out by using a vacuum heat insulating material provided with an outer packaging material using HDPE (high density polyethylene) as a heat welding layer as a polyethylene resin of the innermost layer 23 of the outer packaging material 20, and LLDPE (linear low density). It carried out about two types of vacuum heat insulating materials provided with the outer packaging material which used polyethylene as a heat welding layer. The thermal conductivity was measured using a thermal conductivity measuring device (HC-074 / 600 manufactured by Eihiro Seiki Co., Ltd.). The average temperature of the vacuum heat insulating material at the time of measurement was 24 ° C.

  FIG. 2 is a diagram showing a change in the thermal conductivity of the vacuum heat insulating material depending on the number of times of thermal welding.

  As shown in FIG. 2, in the vacuum heat insulating material 2 using HDPE as the polyethylene resin of the innermost layer 23 of the outer packaging material 20 shown in FIG. 1, it was thermally welded at the time of creating the vacuum heat insulating material, that is, at the heat welding portion 31. The thermal conductivity at that time was 1.5. By performing heat welding also on the heat welding part 32, heat conductivity rose to 1.7 and the heat insulation performance fell. When heat welding was performed also on the heat welding part 33, the thermal conductivity was still 1.7.

  On the other hand, in the vacuum heat insulating material using LLDPE as the polyethylene resin of the innermost layer 23 of the outer packaging material 20, the thermal conductivity when the vacuum heat insulating material 2 is formed, that is, when heat-welded at the heat welding portion 31 is 1. 2. By performing heat welding also on the heat welding part 32, heat conductivity rose to 1.3 and the heat insulation performance fell. When heat welding was performed also on the heat welding part 33, the heat conductivity was still 1.3.

  After the thermal welding is performed in the thermal welding part 31, the polyethylene resin of the outer packaging material 20 is thermally decomposed by further thermal welding of the thermal welding part 32 and the thermal welding part 33 inside the thermal welding part 31. It is considered that the hydrocarbon gas thus diffused into the outer packaging material 20. Since the outermost heat welding portion 31 is thermally welded and the outer packaging material 20 is sealed, the hydrocarbon gas is confined inside the outer packaging material 20. Therefore, it is thought that the vacuum degree of the vacuum heat insulating material 2 fell and the heat conductivity fell.

(Verification experiment 2)
In order to further verify that the heat insulation performance of the vacuum heat insulating material is reduced by the hydrocarbon gas generated during the heat welding of the heat welded part, the heat insulating performance of the vacuum heat insulating material when the length of the heat welding of the outer packaging material is changed The change of was measured.

  As a vacuum heat insulating material, the vacuum heat insulating material 2 shown to (A) and (B) of FIG. 1 used for the above-mentioned verification experiment 1 was used. A material using HDPE as the polyethylene resin of the innermost layer 23 of the outer packaging material 20 was used.

  In the verification experiment 2, the entire length of the heat welded portion 31 of the vacuum heat insulating material 2 shown in FIG. The thermal conductivity of the vacuum heat insulating material 2 at this time was measured. Thereafter, 1/5 of the total length of the heat welding part 31 was opened, and the inside of the vacuum heat insulating material 2 was returned to atmospheric pressure. Next, the 1/5 portion opened in the heat welding part 31 was again heat welded under a reduced pressure condition. The thermal conductivity of the vacuum heat insulating material 2 at this time was measured. In this way, the thermal conductivity of the vacuum heat insulating material sealed by heat-sealing the outer packaging material 20 was measured in the same manner as in the verification experiment 1. The total length of the heat welding part 31 was 470 mm.

  By measuring the thermal conductivity of the two vacuum heat insulating materials 2, the influence of the hydrocarbon gas generated when only one-fifth of the total length of the heat welded portion 31 is heat welded is considered as the heat welded portion 31. This can be compared with the influence of the hydrocarbon gas generated when the entire length of is thermally welded.

  FIG. 3 is a diagram showing a change in the thermal conductivity of the vacuum heat insulating material depending on the length of the heat welded portion.

  As shown in FIG. 3, the thermal conductivity once heat-welded for the entire length of the heat-welded portion 31 was 1.5. On the other hand, after releasing 1/5 of the total length of the heat-welded portion 31, the heat conductivity when heat-welded again was 1.3.

  From the results of the verification experiment 1 and the verification experiment 2 described above, when sealing the outer packaging material by thermally welding the heat-welded portion formed of the material containing hydrocarbon, the thermal conductivity of the vacuum heat insulating material is the number of times of thermal welding. It has been found that the larger the amount, the larger, and the longer the length of the heat-welded portion that is heat-welded when the outer packaging material is finally sealed, the larger the length.

  From this, the hydrocarbon gas generated when heat-welding the heat-welded portion formed of a material containing hydrocarbons diffuses into the outer packaging material, thereby reducing the degree of vacuum inside the outer packaging material. It is thought that the heat insulation property of a heat insulating material falls.

  Therefore, an adsorbent that adsorbs hydrocarbon gas is accommodated inside the outer packaging material, and the hydrocarbon gas that diffuses inside the outer packaging material is adsorbed by the adsorbent. By adsorbing the hydrocarbon gas to the adsorbent, it is possible to prevent the degree of vacuum from being lowered by the hydrocarbon gas.

  As described above, when the heat-welded portion of the outer packaging material of the vacuum heat insulating material is formed of a material containing hydrocarbon, the present inventors have an adsorbent that adsorbs hydrocarbon gas inside the outer packaging material. It was found that a vacuum heat insulating material having excellent heat insulating performance can be obtained by being accommodated. Based on this knowledge, the vacuum heat insulating material according to the present invention has the following characteristics.

  The vacuum heat insulating material according to the present invention includes an outer packaging material, a core material accommodated in the outer packaging material, and an adsorbing material accommodated in the outer packaging material. The outer packaging material has a thermal welding part where the outer packaging materials come into contact with each other and are thermally welded. The heat welded portion is formed of a material containing hydrocarbons. The adsorbent is an adsorbent that adsorbs hydrocarbon gas.

  Hereinafter, embodiments of the present invention will be described with reference to the drawings.

(First embodiment)
FIG. 4 is a cross-sectional view schematically showing the configuration of the vacuum heat insulating material as the first embodiment of the present invention. 4A shows a state before the inside of the outer packaging material is decompressed, and FIG. 4B shows a state when the inside of the outer packaging material is decompressed.

  As shown in FIG. 4, in the vacuum heat insulating material 1, the core material 100 and the adsorbent material 400 are accommodated inside a gas barrier outer packaging material 200 formed in a rectangular parallelepiped bag shape. Before the core material 100 and the adsorbent 400 are filled in the outer packaging material 200, the outer packaging material 200 is thermally welded on three of the four sides. The remaining one-side heat welded portion 300 is heat-welded in a reduced pressure state after the core material 100 and the adsorbent 400 are filled, as will be described later. The adsorbent 400 is disposed in the vicinity of the heat welding portion 300 that is heat-welded after being in a reduced pressure state. The adsorbent 400 may be disposed at other positions inside the outer packaging material 200.

  As shown to (A) of FIG. 4, the core material 100 is comprised by the some nonwoven fabric 110 being laminated | stacked. Each nonwoven fabric 110 is produced by a papermaking method using glass fibers which are examples of inorganic fibers and a small amount of an organic binder. As the binder, it is possible to use an inorganic binder. However, when an inorganic binder is used, the flexibility of bending of the fiber assembly, that is, the nonwoven fabric 110 is inferior, and the cost when used as a product is lower than that of an organic binder. Since it becomes expensive compared with the case where it uses, it is preferable to use an organic binder. Also, the amount of binder should be kept as small as possible.

  As the adsorbent 400, for example, a material in which potassium permanganate is supported on a porous substrate such as activated alumina or zeolite, or a material in which bromine is attached to a porous member such as activated carbon is used. The adsorbent 400 only needs to adsorb hydrocarbon gas, and is not limited to these.

  As a specific example of the structure of the outer packaging material 200, the outermost layer 210 is made of polyethylene terephthalate (PET) resin, the intermediate layer 220 is made of an ethylene-vinyl alcohol copolymer resin having an aluminum vapor deposition layer, and the innermost layer 230 is made of Gas barrier film using low-density polyethylene resin such as high-density polyethylene resin or linear low-density polyethylene resin, nylon is used for outermost layer 210, and two layers of aluminum-deposited PET resin and aluminum foil are used for intermediate layer 220 Examples of the gas barrier film include a high-density polyethylene resin and a low-density polyethylene resin such as a linear low-density polyethylene resin. The heat welding part 300 is formed in a part of the innermost layer 230.

  Further, in order to maintain the initial heat insulation performance and the temporal heat insulation performance of the vacuum heat insulating material 1, it is possible to use an adsorbent such as a gas adsorbent or a moisture adsorbent in addition to the adsorbent 400 in the vacuum heat insulating material 1. preferable.

  After filling the core material 100 and the adsorbent material 400 into the outer packaging material 200, the core material 100 and the adsorbent material 400 are accommodated in a vacuum chamber. When the inside of the outer packaging material 200 is depressurized to a predetermined degree of vacuum, the outer packaging material 200 is thermally welded at the thermal welding portion 300. The heat welding temperature is preferably 170 to 220 ° C. as the heat welding temperature for maintaining the seal strength. As a heat welding method, a hot plate sealing method in which a heat plate is heated and conducted by a nichrome wire embedded in a hot plate made of brass or copper, and the heat welding portion 300 is overheated and sealed, or a heating element is used. There is an impulse welding method in which a heat welding part 300 is directly heated and sealed by a certain nichrome wire (ribbon heater). The heat welding part 300 may be welded by either method. Moreover, you may weld by another method. When the heat welding part 300 is heat welded, the outer packaging material 200 is sealed.

As shown in FIG. 4B, when the inside of the outer packaging material 200 is depressurized, the core material 100 is compressed by the atmospheric pressure outside the outer packaging material 200, and the nonwoven fabrics 110 constituting the core material 100 are pressed against each other. Touch as you can. The density of the core material 100 in a state where the inside of the outer packaging material 200 is decompressed is included in the range of 100 to 400 kg / m ³ .

  As described above, the nonwoven fabric 110 is configured, and the nonwoven fabric 110 is laminated to configure the core material 100. The core material 100 and the adsorbent material 400 are disposed inside the outer packaging material 200 and sealed under reduced pressure. 1 is constructed.

  FIG. 5 schematically shows an arrangement (A) of the core material and the outer packaging material and an internal state (B) of the vacuum heat insulating material when the inside of the outer packaging material is decompressed as one embodiment of the present invention. It is a perspective view. Only a part of each nonwoven fabric, core material, and outer packaging material is shown.

  As shown in FIG. 5A, a plurality of nonwoven fabrics 110 are laminated to form the core material 100. The core material 100 is covered with an outer packaging material 200. The outer packaging material 200 is gas barrier, is formed in a bag shape, and covers the entire core material 100.

  As shown in FIG. 5B, when the pressure inside the bag-shaped outer packaging material 200 is reduced, the core material 100 is compressed. When the core material 100 is compressed, the nonwoven fabrics 110 come into contact with each other so as to be pressed against each other.

  As the nonwoven fabric 110 of the core material 100, what is formed with the glass fiber manufactured by the continuous filament method, and what is formed with glass wool can be used.

  As a result of intensive studies in order to improve the heat insulating performance of the vacuum heat insulating material configured as described above, the present inventors have used as a core a non-woven fabric configured to contain inorganic fibers of specific conditions. It has been found that the heat insulating performance of the vacuum heat insulating material is remarkably improved by using it.

  Therefore, in this embodiment, as shown in FIG. 4, the nonwoven fabric 110 constituting the core material 100 used in the vacuum heat insulating material 1 of the present invention includes at least a plurality of inorganic fibers produced by the continuous filament method. Configured.

  Examples of inorganic fibers include glass fibers, ceramic fibers, rock wool fibers, etc., but small diameter fibers necessary for constituting the core material of the present invention are distributed at a relatively low price due to mass production, In view of the low thermal conductivity of the material itself, glass fibers are preferably used as the inorganic fibers.

  In one preferred embodiment of the present invention, a nonwoven fabric produced by a wet papermaking method using glass fibers cut to a certain length is used as a core material of a vacuum heat insulating material. Here, the glass fiber cut into a certain length is a glass fiber which is a filamentous continuous filament having a uniform thickness, formed by drawing molten glass from a number of nozzles by a continuous filament method. Thousands are bundled and wound into a strand, and the strand is cut to a predetermined length with a guillotine cutter or the like. What cut | disconnected the strand of glass fiber in this way is called glass chopped strand.

  The glass fiber thus obtained is a continuous filament cut into a predetermined length to obtain a predetermined length. Therefore, the glass fiber is extremely straight and highly rigid, and is a substantially uniform fiber. It has a diameter and a substantially circular cross section. That is, according to the continuous filament method, a large number of fibers with extremely small variation in fiber diameter can be produced. Moreover, the inorganic fiber manufactured by the continuous filament method has very high straightness of each fiber. For this reason, by cutting a large number of inorganic fibers manufactured by the continuous filament method into a substantially constant length, a straightness of a large number of inorganic fibers having substantially the same length and having a very small variation in fiber diameter can be obtained. It can be obtained in a very high state.

  For this reason, when a nonwoven fabric is produced by wet papermaking using this glass fiber, the fiber extends in a direction substantially parallel to the surface of the nonwoven fabric, but faces in a random direction within the plane forming the surface of the nonwoven fabric. Nonwoven fabrics arranged to be dispersed can be obtained.

  FIG. 6 is a plan view schematically showing the distribution state of the glass fibers constituting the nonwoven fabric used for the core material of the vacuum heat insulating material as one embodiment of the present invention. FIG. 6 shows a nonwoven fabric composed of two glass fiber layers. FIG. 7 is a plane electron micrograph (magnification 100 times) showing the distribution state before compression of the glass fibers constituting the nonwoven fabric used for the core material of the vacuum heat insulating material as one embodiment of the present invention, FIG. Is an electron micrograph (magnification 100 times) of a cross section showing a similar distribution state.

  As shown in FIG. 6, the plurality of glass fibers 111 forming the upper layer and the glass fibers 112 forming the lower layer extend in a direction substantially parallel to the surface of the nonwoven fabric 110, but in close contact with each other in the parallel direction. They are not aligned, but are aligned so as to be distributed in a random direction within a plane forming the surface of the nonwoven fabric 110. Moreover, as shown in FIGS. 7 and 8, it can be seen that the straightness of each fiber is extremely high. In addition, it can be seen that most of the fibers extend in a direction substantially parallel to the surface of the nonwoven fabric, but are aligned so as to be dispersed in a random direction within a plane forming the surface of the nonwoven fabric.

  Thus, since the nonwoven fabric 110 which comprises the core material of this invention contains at least the glass fiber which is an example of the some inorganic fiber manufactured by the continuous filament method, the nonwoven fabric 110 is used using such a some glass fiber. When the glass fibers are arranged in a direction parallel to the surface of the nonwoven fabric 110, a plurality of glass fibers 111 and 112 are arranged so as to extend in a direction substantially parallel to the surface of the nonwoven fabric. Glass fibers can be easily aligned. At this time, most of the plurality of glass fibers 111 and 112 extend in a direction substantially parallel to the surface of the nonwoven fabric 110, but do not align with each other in close contact with each other and form a surface of the nonwoven fabric 110. To be distributed in a random direction. As a result, the presence of glass fibers filling between the plurality of glass fibers constituting the core material can be minimized, and the presence of glass fibers entangled between the plurality of glass fibers can be minimized. Therefore, it is possible to prevent heat conduction from occurring between the glass fibers. For this reason, by preventing the occurrence of heat conduction along the thickness direction of the core material, the thermal conductivity of the core material can be reduced, and it becomes possible to exceed the improvement limit of the conventional heat insulation performance, The core material for vacuum heat insulating materials which has the heat insulation performance and the vacuum heat insulating material provided with the core material can be obtained.

  The glass fiber composition is not particularly limited, and C glass, D glass, E glass, and the like can be used, but E glass (aluminoborosilicate glass) is preferably employed because of its availability.

  As described above, the inorganic fiber forming the nonwoven fabric 110 as the core material of this embodiment is a glass fiber having a predetermined length obtained by cutting a continuous filament into a predetermined length, and has an extremely high straightness and a substantially circular shape. It has a cross section. For this reason, unless a plurality of glass fibers dispersed in a random direction are aligned and aligned in parallel, the glass fibers are in contact with each other at a point, so that heat conduction between the glass fibers is remarkably suppressed.

  Although other materials may be used instead of glass fibers, in general, inorganic fiber materials such as alumina chopped strands using alumina fibers are preferable because they are more expensive than glass fibers and have high thermal conductivity. Absent.

  Organic materials generally have lower thermal conductivity than inorganic materials, but do not have rigidity. For this reason, an organic fiber material deform | transforms a fiber by the external pressure in the location where a fiber cross | intersects, and causes the reduction | decrease in the surface contact of fibers and a vacuum space ratio. As a result, a vacuum heat insulating material using an organic fiber as a core material is not preferable because of its high thermal conductivity.

  As a manufacturing method of the core material 100, first, the nonwoven fabric 110 is manufactured by a wet papermaking method using at least glass fibers which are an example of a plurality of inorganic fibers manufactured by a continuous filament method. Thereby, most glass fibers 111 and 112 are made to extend in the direction substantially parallel to the surface of the manufactured nonwoven fabric 110 among several glass fibers. Further, a plurality of nonwoven fabrics 110 are laminated.

  Moreover, in one embodiment of the manufacturing method of the vacuum heat insulating material 1 of this invention, the nonwoven fabric 110 is first manufactured by the wet papermaking method using the several glass fiber manufactured by the continuous filament method at least. Thereby, most glass fibers 111 and 112 are made to extend in the direction substantially parallel to the surface of the manufactured nonwoven fabric 110 among several glass fibers. Further, a plurality of nonwoven fabrics 110 are laminated. Thereafter, the laminated nonwoven fabrics 110 are accommodated in the outer packaging material 200, and the interior of the outer packaging material 200 is kept in a reduced pressure state.

  In one embodiment of the manufacturing method of the vacuum heat insulating material 1, at least a plurality of glass fibers manufactured by a continuous filament method are used. When the non-woven fabric 110 is manufactured by the wet papermaking method using such a plurality of glass fibers, when the glass fibers are arranged in a direction parallel to the surface of the non-woven fabric 110, most of the glass fibers 111 and 112 are used. A plurality of glass fibers can be easily aligned so as to extend in a direction substantially parallel to the surface of the nonwoven fabric 110. At this time, most of the plurality of glass fibers 111 and 112 extend in a direction substantially parallel to the surface of the nonwoven fabric 110, but do not align with each other in close contact with each other and form a surface of the nonwoven fabric 110. To be distributed in a random direction. Thereby, even if a plurality of non-woven fabrics 110 are laminated to constitute the core material 100, the presence of glass fibers that fill between the plurality of glass fibers can be minimized, and between the plurality of glass fibers. Since the presence of the glass fiber entangled with the glass fiber can be eliminated as much as possible, it is possible to prevent heat conduction from occurring between the glass fibers. And the vacuum heat insulating material 1 can be manufactured by accommodating the some nonwoven fabric 110 laminated | stacked inside the outer packaging material 200, and keeping the inside of the outer packaging material 200 in a pressure-reduced state. Thus, by preventing heat conduction from occurring along the thickness direction of the core material 100, the thermal conductivity of the core material 100 can be lowered, and the improvement limit of the conventional heat insulation performance may be exceeded. It becomes possible and the core material 100 which has the outstanding heat insulation performance and the vacuum heat insulating material 1 provided with the core material 100 can be obtained.

  The nonwoven fabric 110 made of glass fibers used in the present invention is manufactured by a wet papermaking method. In the wet papermaking method, by adding an appropriate dispersant, glass chopped strands obtained by cutting glass fibers into a certain length are monofilamentized and dispersed and arranged in layers, and the nonwoven fabric 110 made of glass fibers with very little binding is formed. Obtainable. For this reason, the number of glass fibers arranged in parallel is very small, and most glass fibers 111 and 112 are in contact with each other between adjacent fibers. In this way, the nonwoven fabric 110 having a high compressive strength and a very low thermal conductivity in the thickness direction can be produced. Therefore, such a nonwoven fabric 110 is suitable as the core material 100 of the vacuum heat insulating material 1. .

  Fabrication of the nonwoven fabric 110 by the wet papermaking method employed in the method of manufacturing the vacuum heat insulating material 1 can be performed by using a known papermaking machine such as a long net papermaking machine, a short netting papermaking machine, or an inclined wire type papermaking machine.

  Usually, the nonwoven fabric which consists of glass fibers is used as a heat insulating material which has heat resistance, a heat insulating material which has fire resistance, or an electrical insulator. For this reason, the nonwoven fabric is required to have a fabric strength that can withstand tearing and breaking, and often requires entanglement of fibers. Nonwoven fabrics made of glass fibers used for such applications are often manufactured by a papermaking method using a long net paper machine or a short net paper machine.

  On the other hand, since the nonwoven fabric 110 made of glass fibers used for the vacuum heat insulating material 1 is accommodated in the outer packaging material 200 as the core material 100, the strength as a cloth is not so required. In addition, the papermaking method in which the fiber directions are easily aligned increases the contact area between the fibers, and thus is not preferable for producing the nonwoven fabric 110 made of glass fibers used in the present invention. On the other hand, in order to improve the heat insulation performance in the thickness direction, it is desirable that the fibers are less entangled.

  Therefore, as the paper machine for making the nonwoven fabric 110 made of glass fiber used for the vacuum heat insulating material 1, an inclined wire type paper machine capable of making paper at a low inlet concentration is suitable, but is not limited to this. Absent.

  As for the glass chopped strand which is an example of the inorganic fiber used for the vacuum heat insulating agent 1, it is preferable that the structural ratio of the glass fiber of fiber diameter 3-15micrometer and fiber length 3-15mm is 99% or more.

  A glass chopped strand having a fiber diameter of less than 3 μm or a fiber length of less than 3 mm is predicted to be unsuitable for use in the nonwoven fabric 110 constituting the core material 100 of the vacuum heat insulating material 1 as described below.

  Glass fibers having a fiber diameter of less than 3 μm have low fiber rigidity. Therefore, when a nonwoven fabric is produced by a wet papermaking method, the fibers are bent, entanglement between the fibers occurs, and the contact area between the fibers increases. . Thereby, since heat conduction becomes large and the heat insulation performance of the core material is deteriorated, glass fibers having a fiber diameter of less than 3 μm are not preferable.

  The glass fiber having a fiber length of less than 3 mm is produced by dispersing the fiber located in the upper layer on the fiber located in the lower layer already dispersed when the nonwoven fabric is produced by the wet papermaking method. The upper layer fibers are more likely to be supported on the lower layer fibers at one point, for example, one end of the upper layer fibers hang down to the lower layer and the other in the thickness direction. It is expected to be positioned in a protruding form. As described above, when a certain fiber is bridged in the thickness direction between a plurality of fibers, heat conduction in the length direction of the fiber occurs, and the contact area between the fibers increases. Thereby, heat conduction becomes large and the heat insulating performance of the core material is deteriorated, so that glass fibers having a fiber length of less than 3 mm are not preferable.

  When glass fibers having a fiber diameter of 15 μm or more are used to form a nonwoven fabric and a core material is formed by laminating a plurality of nonwoven fabrics, the number of fiber layers in the thickness direction of the core material is reduced, and the heat transfer path in the thickness direction Becomes shorter and the pore diameter becomes larger when the nonwoven fabric is formed. Accordingly, glass fibers having a fiber diameter of 15 μm or more are not preferable because they are affected by the thermal conductivity of the gas and reduce the heat insulating performance of the core material.

  When a glass fiber having a fiber length of 15 mm or more is used, the fiber length increases with respect to the fiber diameter, so that the rigidity of the fiber is lowered and the fiber is easily bent, entanglement between the fibers occurs, and the contact area between the fibers is increased. To increase. Thereby, since heat conduction becomes large and the heat insulation performance of the core material is deteriorated, glass fibers having a fiber length of 15 mm or more are not preferable.

  The nonwoven fabric made of glass fibers used as the core material of the vacuum heat insulating material of the present invention has no bonding force between the fibers. For this reason, it is necessary to use an organic binder in the paper making process in order to prevent the glass fibers from falling off in the manufacturing process of the nonwoven fabric and to prevent mold deformation in the subsequent processing process. However, since the nonwoven fabric is finally encapsulated in the outer packaging material as the core material of the vacuum heat insulating material, it is necessary to minimize the amount of the organic binder used. The binder content in the nonwoven fabric made of glass fibers is preferably 15% by mass or less.

  As an organic binder, it is common to spray liquid binders, such as resin emulsion and resin aqueous solution, by spray etc., and add to glass fiber.

The basis weight of the nonwoven fabric made of glass fibers used as the core material of the vacuum heat insulating material of the present invention is preferably 30 to 600 g / m ² . If the nonwoven fabric has a rice basis weight of less than 30 g / m ² , the influence of the thermal conductivity of the gas increases due to the increase in the diameter of the voids present in the nonwoven fabric. Thereby, since the heat insulation performance of a core material falls and the intensity | strength of a core material becomes weak, it is unpreferable if the rice basis weight of a nonwoven fabric is less than 30 g / m < ² >. On the other hand, when the basis weight of the nonwoven fabric exceeds 600 g / m ² , the drying efficiency when the nonwoven fabric is produced from the glass fiber is lowered, and the productivity is lowered.

  Here, the US basis weight is generally a unit of measurement of the thickness of paper, and represents the mass of paper per square meter, and is also referred to as metric basis weight. Here, rice tsubo is used as a unit for measuring the thickness of a nonwoven fabric made of glass fibers produced by a wet papermaking method.

  Incidentally, for example, JP-A-2006-17169 (Patent Document 3) describes that the average diameter of inorganic fibers such as glass wool constituting the core material of the vacuum heat insulating material is preferably 1 to 5 μm. . And when the average diameter of the inorganic fiber exceeds 5 μm, it is described that the heat insulation performance of the finally obtained vacuum heat insulating material itself is lowered. Certainly, the heat insulation performance of the vacuum heat insulating material increases as the diameter of the inorganic fibers constituting the core material is smaller. On the other hand, fine inorganic fibers are expensive and have the disadvantages of reducing the dewatering efficiency and reducing the productivity when producing nonwoven fabrics by wet papermaking. On the other hand, as an example of inorganic fibers, by selecting the optimum conditions for improving the heat insulation performance for the fiber parameters such as fiber diameter and fiber length of the inorganic fibers and the adhesion status between the fibers, the fiber diameter is relatively Even if a glass chopped strand having a large size is used, a vacuum heat insulating material that can obtain much higher heat insulating performance than a conventional vacuum heat insulating material can be realized.

  Moreover, even if a glass chopped strand with a fiber diameter thinner than 6 μm is used, the improvement width of the heat insulating performance of the finally obtained vacuum heat insulating material is almost the same as when using a glass chopped strand with a fiber diameter of 10 μm. It is negligible. Therefore, if the aspects of productivity, price, and performance are taken into consideration, the preferred fiber diameter of the glass chopped strand is 6 to 15 μm. When the glass fiber of this range is used, the vacuum heat insulating material which has heat insulation performance higher than the conventional vacuum heat insulating material can be obtained with a suitable manufacturing cost.

  The vacuum heat insulating material of this invention can be manufactured by a known method using the core material provided with the characteristics mentioned above. As a typical method, in the configuration of the vacuum heat insulating material 1 shown in FIG. 4, the core material 100 and the adsorbent material 400 are accommodated in a gas barrier outer packaging material 200 formed in a bag shape. The outer packaging material 200 for storing the core material 100 in a decompressed state has a high gas barrier property and a protective layer against heat-sealing layers, scratches, etc., and can keep the inner packaging material 200 in a decompressed state for a long period of time. Use something. Further, a plurality of films having such characteristics may be laminated to form the outer packaging material 200.

  The heat insulating performance can be further improved by removing or reducing the organic binder of the core material before the vacuum sealing. When a thermosetting resin binder such as an acrylic resin is used as the binder, the binder can be removed by using a thermal decomposition method.

  That is, before encapsulating the core material in the outer packaging material, only the binder can be removed by thermal decomposition by treating at a temperature higher than the thermal decomposition temperature of the binder and lower than the melting point of the glass fiber. When a water-soluble resin binder such as PVA is used as the binder, the binder can be removed or reduced by washing with warm water or the like in addition to the above method.

  As described above, the vacuum heat insulating material 1 according to the present invention includes the outer packaging material 200, the core material 100 accommodated in the outer packaging material 200, and the adsorbent 400 accommodated in the outer packaging material 200. . The outer packaging material 200 has a heat welding part 300 in which the outer packaging materials 200 come into contact with each other and are thermally welded. The heat welding part 300 is formed of a material containing hydrocarbons. The adsorbent 400 is an adsorbent 400 that adsorbs hydrocarbon gas.

  When the heat welding part 300 of the outer packaging material 200 of the vacuum heat insulating material 1 is formed of a material containing hydrocarbon, hydrocarbon gas is generated when the heat welding part 300 is heat welded. In the vacuum heat insulating material 1, since the heat welding part 300 of the outer packaging material 200 is heat welded and sealed, the hydrocarbon gas generated from the heat welding part 300 at the time of heat welding not only diffuses outside the vacuum heat insulating material 1. Also, it diffuses inside the outer packaging material 200 of the vacuum heat insulating material 1. The hydrocarbon gas diffused inside the outer packaging material 200 of the vacuum heat insulating material 1 is sealed inside the outer packaging material 200 as it is.

  In the vacuum heat insulating material 1, the heat-sealed portion 300 of the outer packaging material 200 is thermally welded and sealed in a reduced pressure state. Therefore, when the hydrocarbon gas is diffused inside the outer packaging material 200, the outer packaging material 200 The degree of vacuum inside becomes low. When the degree of vacuum inside the outer packaging material 200 is lowered, the heat insulating property of the vacuum heat insulating material 1 is lowered.

  Therefore, the adsorbent 400 that adsorbs hydrocarbon gas is accommodated inside the outer packaging material 200, and the hydrocarbon gas that diffuses inside the outer packaging material 200 is adsorbed by the adsorbent 400. By adsorbing the hydrocarbon gas to the adsorbent 400, it is possible to prevent the degree of vacuum from being lowered by the hydrocarbon gas.

  By doing in this way, the vacuum insulation 1 which can exceed the improvement limit of the conventional heat insulation performance and has the outstanding heat insulation performance can be provided.

(Second Embodiment)
FIG. 9 is a side sectional view (A) showing the entire refrigerator and a front view (B) showing the exterior of the refrigerator as a second embodiment of the present invention.

  As shown in FIG. 9A, the refrigerator 3 includes an outer box 301, an inner box 302, a door 303, a partition plate 304, a machine room 306 in which the compressor 305 is disposed, a cooling unit 307, The vacuum heat insulating material 320 is provided. The outer box 301 and the inner box 302 form an exterior 308 of the refrigerator 3. The exterior 308 is formed in a substantially rectangular parallelepiped shape with one surface opened. The opening of the exterior 308 is opened and closed by a door 303. The interior of the exterior 308 is divided into a plurality of chambers by a partition plate 304. In this embodiment, the interior of the exterior 308 is divided into, for example, a refrigerating room 311, an ice making room 312, an ice storage room 313, a freezing room 314, and a vegetable room 315.

  A vacuum heat insulating material 320 is disposed between the outer box 301 and the inner box 302. A vacuum heat insulating material 320 is also disposed inside the door 303. At least a part of the vacuum heat insulating material 320 shown in FIG. 9 is formed by the vacuum heat insulating material of the first embodiment.

  Some conventional refrigerators use hard foamed urethane as a heat insulating material. In such a conventional refrigerator, a heat insulating material is filled by injecting a foamed urethane material into a space formed by an inner box and an outer box and foaming it by a chemical reaction.

  In the conventional refrigerator, by replacing at least a part of the portion where the hard foamed urethane is used as the heat insulating material with the vacuum heat insulating material of the first embodiment having a good heat insulating performance, the heat insulating material The thickness can be reduced. If the thickness of the heat insulating material can be reduced, the internal volume can be increased without increasing the size of the refrigerator. In addition, energy saving can be achieved. Furthermore, since the amount of hard foam urethane used can be reduced, recycling at the time of disposal of the refrigerator becomes easy.

  The arrangement position of the vacuum heat insulating material 320 shown in FIG. 9 is an example. The vacuum heat insulating material 320 may be disposed at other positions.

  As described above, the refrigerator 3 according to the present invention includes the outer box 301, the inner box 302 disposed inside the outer box 301, and the vacuum heat insulating material disposed between the outer box 301 and the inner box 302. 320, the vacuum heat insulating material 320 includes the vacuum heat insulating material of the first embodiment.

  In the refrigerator 3, the food stored in the inner box 302 is cooled. Therefore, in the refrigerator 3, it is necessary to keep the temperature inside the inner box 302 at a lower temperature than the outside of the outer box 301 or to efficiently cool the inside of the inner box 302. Therefore, the vacuum heat insulating material 320 is disposed between the outer box 301 and the inner box 302. If the heat insulation performance of the vacuum heat insulating material 320 disposed between the outer box 301 and the inner box 302 is excellent, it is necessary to make the inside of the inner box 302 cooler or hotter than the outside of the outer box 301. Energy can be reduced, thus saving energy.

  Then, the vacuum heat insulating material 320 arrange | positioned between the outer box 301 and the inner box 302 contains the vacuum heat insulating material of 1st Embodiment, and can provide the refrigerator 3 excellent in heat insulation performance and energy saving.

(Third embodiment)
FIG. 10 is a side sectional view showing the entirety of a water heater as a third embodiment of the present invention.

  As shown in FIG. 10, a vacuum heat insulating material 430 is disposed inside the lid 410 of the water heater (pot) 4 and between the hot water storage container 422 and the outer container 421. The vacuum heat insulating material 430 is the vacuum heat insulating material of the first embodiment. The member forming the upper surface 411 of the lid 410 and the outer container 421 are examples of an outer box, and the member forming the lower surface 412 of the lid 410 and the hot water storage container 422 are an example of an inner box. Moreover, the arrangement | positioning position of the vacuum heat insulating material 430 is an example, and the vacuum heat insulating material 430 may be arrange | positioned in another position.

  In the water heater 4, water is stored in the hot water storage container 422, and this water is heated by the resistance heating heater 440 or the like. Further, the water stored in the hot water storage container 422 can be kept warm.

  Thus, by using the vacuum heat insulating material of the first embodiment outside the hot water storage container 422 for warming water with the resistance heating heater 440 or the like, the thickness of the heat insulating material can be made thinner than before. Thus, the internal volume of the water heater 4 can be increased while saving space. Moreover, energy saving can be achieved while improving the heat retaining performance of the water heater 4. Further, for example, the heat insulating material can be recycled more easily than in the case where urethane foam is used as the heat insulating material.

(Embodiment 4)
FIG. 11: is a front perspective view (A) which shows the whole rice cooker as a 4th Embodiment of this invention, a rear perspective view (B), and a figure (C) which shows the member accommodated in the inside of a rice cooker. It is.

  As shown in FIG. 11, the rice cooker 5 includes a housing 501 and an upper lid 502 for opening and closing an opening at the top of the housing 501. Inside the housing 501, as shown in FIG. 11C, there are an inner hook 504, a heater 505 disposed at the bottom of the inner hook 504, an inner hook 504 and an outer hook 503 that covers the heater 505. Be placed. A vacuum heat insulating material 510 is disposed inside the upper lid 502 of the rice cooker 5 and between the outer pot 503 and the housing 501. The vacuum heat insulating material 510 is disposed so as to be wound around the outer peripheral surface of the outer hook 503 so as to cover the outer peripheral face of the outer hook 503. The vacuum heat insulating material 510 is the vacuum heat insulating material of the first embodiment.

  The housing 501 is an example of an outer box, and the outer hook 503 is an example of an inner box. The upper surface of the upper lid 502 is an example of an outer box, and the lower surface of the upper lid 502 is an example of an inner box. Moreover, the arrangement | positioning position of the vacuum heat insulating material 510 is an example, and the vacuum heat insulating material 510 may be arrange | positioned in another position.

  By arranging the vacuum heat insulating material 510 on the outer periphery of the outer pot 503 for storing the inner pot 504 that is the rice cooking unit, the thickness of the heat insulating material can be reduced more than the conventional one while obtaining the same heat insulating performance as the conventional heat insulating material. Can be thinned. In this way, space saving and energy saving can be achieved, and a large-capacity rice cooker 5 can be obtained.

  Further, by disposing the vacuum heat insulating material 510 on the outer periphery of the outer hook 503, the temperature of the inner hook 504 is distributed isothermally along the height direction from the bottom where the heater 505 is arranged. The convection can be generated evenly in

(Fifth embodiment)
FIG. 12 is a perspective view showing the entirety of a washing / drying machine as a fifth embodiment of the present invention.

  As shown in FIG. 12, the washing / drying machine 6 includes an exterior 601, a lid 602 for opening and closing an opening of the exterior 601, a washing / drying tank storage 603 accommodated inside the exterior 601, and a washing / drying tank. A washing / drying tank (not shown) housed in the housing portion 603; A vacuum heat insulating material 610 is disposed between the exterior 601 and the washing / drying tank storage 603. The vacuum heat insulating material 610 is the vacuum heat insulating material of the first embodiment. The washing / drying machine 6 is a washing machine with a drying function. The arrangement position of the vacuum heat insulating material 610 is an example, and the vacuum heat insulating material 610 may be arranged at another position.

  The washing / drying tank is supported inside the washing / drying tank storage 603 so as to be rotatable. The user puts an object such as clothes in the washing / drying tank and operates the operation unit arranged on the lid 602 to wash or dry the object. At the time of washing the object, water is stored in the washing / drying tank, detergent is added, and the object is washed by rotating the washing / drying tank. When the object is dried, the object is dried by circulating and supplying warm air to the inside of the washing and drying tank.

  By winding the vacuum heat insulating material 610 around the outer peripheral surface of the washing / drying tank storage unit 603, the temperature of the hot air circulated in the washing / drying tank can be made difficult to decrease, so that it can be efficiently dried.

  As one of the effects of the vacuum heat insulating material of the present invention, there is an effect that excellent heat insulating performance can be obtained. The heat conductivity of the vacuum heat insulating material produced by changing the types of the outer packaging material, the core material, and the adsorbent was measured, and the heat insulating performance was compared.

  In the vacuum heat insulating material used in this example, the core material and the adsorbent were accommodated in the gas barrier outer packaging material formed in a bag shape, similarly to the vacuum heat insulating material of the first embodiment. After heat-welding the three sides of the substantially rectangular parallelepiped outer packaging material at the heat-welded portion, the core material and the adsorbent were filled inside. The heat-welded portion of the outer packaging material filled with the core material and the adsorbent material was heat-welded under reduced pressure in a vacuum chamber. Thus, the core material was sealed in the outer packaging material, and the vacuum heat insulating material was produced. The heat welded portion was heat welded at a temperature of 170 to 220 ° C. when the Pirani gauge indication value installed in the vacuum chamber reached 0.009 Torr.

  As the outer packaging material, a gas barrier film using nylon as the outermost layer, two layers of aluminum vapor-deposited PET resin and aluminum foil as the intermediate layer, and polyethylene resin as the innermost layer was used. LLDPE or HDPE was used as the innermost layer of the outer packaging material.

  The core material is configured by laminating a plurality of nonwoven fabrics. As the core material, a wet papermaking core material or a glass wool core material was used. Specifically, each of the wet papermaking core material and the glass wool core material was produced as follows.

(1) Wet papermaking core material In a wet papermaking core material, each nonwoven fabric is produced by a papermaking method using glass fibers which are examples of inorganic fibers and a small amount of an organic binder.

  Glass chopped strands (manufactured by Owens Corning Corporation) having an average fiber diameter of 10 μm and an average fiber length of 10 mm were poured into water so that the concentration became 0.5% by mass, and Emanon ( (Registered trademark) 3199 (manufactured by Kao Corporation) was added to 1 part by mass with respect to 100 parts by mass of the glass chopped strands, and stirred to prepare a glass chopped strand slurry.

Using the obtained glass chopped strand slurry, paper was made by a wet paper making method to prepare a web. The obtained web was impregnated with a solution obtained by diluting an acrylic emulsion (GM-4, manufactured by Dainippon Ink & Chemicals, Inc.) with water so that the solid content concentration was 3.0% by mass, and the moisture content of the web Was adjusted by sucking moisture so as to be 0.7% by mass with respect to the glass fiber mass. Then, the nonwoven fabric used for a wet papermaking core material was produced by drying a web. The nonwoven fabric used for the obtained wet papermaking core material had a basis weight of 100 g / m ² . A plurality of non-woven fabrics were laminated to form a wet papermaking core material. As for the size of the wet papermaking core, the long side was 435 mm, the short side was 400 mm, and the thickness was 9 mm.

(2) Glass Wool Core Material Glass wool having an average fiber diameter of 3.5 μm was laminated as an aggregate of glass fibers and formed into a predetermined density by hot pressing to prepare a core material in a board shape. The glass wool core material had a long side of 435 mm, a short side of 400 mm, and a thickness of 8 mm.

  FIG. 13 is a plan view schematically showing a distribution state of glass fibers in glass wool that has been conventionally used as a core material of a vacuum heat insulating material. FIG. 14 is a planar electron micrograph (magnification 100 times) showing a distribution state before compression of glass fibers in glass wool conventionally used as a core material of a vacuum heat insulating material, and FIG. 15 shows a similar distribution state. It is an electron micrograph (magnification 100 times) of a section.

  As shown in FIG. 13, in the glass wool 800, it can be seen that a large number of glass fibers 810 having various fiber lengths extend in various directions and are randomly distributed. Further, as shown in FIGS. 14 and 15, in glass wool manufactured by a flame method or a centrifugal method, a short fiber having a fiber length of 1 mm or less or a fine fiber having a fiber diameter of 1 μm or less with respect to the main fiber. It is in a state in which various fibers are mixed. Such short fibers and fine fibers are filled between the main fibers or entangled between the main fibers, and heat conduction occurs between the fibers, along the thickness direction of the core material. It is considered that the heat insulation performance is lowered by causing heat conduction. Moreover, in such glass wool, it turns out that the main fiber also includes many fibers that are bent or twisted.

  As the adsorbent, the following three types were used alone or in combination.

(1) Calcium oxide (CaO), 10g
(2) As hydrocarbon gas adsorbent A, Purafile Select (manufactured by JMS Co., Ltd.), 2.5 g, containing alumina and potassium permanganate as main components
(3) As hydrocarbon gas adsorbent B, SAES Getter (SG-CONBO3 manufactured by Saes getters), 10 g. The hydrocarbon gas adsorbent B contains calcium oxide (50 to 100%), cobalt oxide (10 to 25%), barium (2.5% or less), and lithium (2.5% or less).

  The potassium permanganate of the hydrocarbon gas adsorbent A adsorbs ethylene, which is a hydrocarbon gas. Moreover, the cobalt oxide of the hydrocarbon gas adsorbent B adsorbs the hydrocarbon gas. On the other hand, calcium oxide does not adsorb hydrocarbon gas but adsorbs water.

  Eight types of vacuum heat insulating materials were produced by combining the outer packaging material, the core material, and the adsorbent material as shown in the following (1) to (8).

  (1) The outer packaging material in which the innermost layer was formed of LLDPE was used. A wet papermaking core was used as the core. Calcium oxide (CaO) was used as the adsorbent.

  (2) The outer packaging material in which the innermost layer was formed of LLDPE was used. A wet papermaking core was used as the core. As the adsorbent, calcium oxide (CaO) and hydrocarbon gas adsorbent A were used.

  (3) The outer packaging material in which the innermost layer was formed of LLDPE was used. A wet papermaking core was used as the core. As the adsorbent, hydrocarbon gas adsorbent B was used.

  (4) The outer packaging material in which the innermost layer was formed of HDPE was used. A wet papermaking core was used as the core. Calcium oxide (CaO) was used as the adsorbent.

  (5) The outer packaging material in which the innermost layer was formed of HDPE was used. A wet papermaking core was used as the core. As the adsorbent, calcium oxide (CaO) and hydrocarbon gas adsorbent A were used.

  (6) An outer packaging material in which the innermost layer was formed of HDPE was used. A wet papermaking core was used as the core. As the adsorbent, hydrocarbon gas adsorbent B was used.

  (7) The outer packaging material in which the innermost layer was formed of HDPE was used. As a core material, a glass wool core material was used. Calcium oxide (CaO) was used as the adsorbent.

  (8) An outer packaging material in which the innermost layer was formed of HDPE was used. As a core material, a glass wool core material was used. As the adsorbent, calcium oxide (CaO) and hydrocarbon gas adsorbent A were used.

  The thermal conductivity of the eight types of vacuum heat insulating materials (1) to (8) was measured. The thermal conductivity was measured using a thermal conductivity measuring device (HC-074 / 600 manufactured by Eihiro Seiki Co., Ltd.). The average temperature of the vacuum heat insulating material at the time of measurement was 24 ° C.

  The obtained thermal conductivity is shown in Table 1.

  As shown in Table 1, the outermost layer is made of LLDPE, and the core material is oxidized as an adsorbent when compared with vacuum heat insulating materials (1) to (3) using wet papermaking core materials. Compared with (1) using calcium (CaO), the thermal conductivity of (2) using calcium oxide and hydrocarbon gas adsorbent A and (3) using hydrocarbon gas adsorbent B is lower. It was.

  Moreover, when using the outer packaging material in which the innermost layer is formed of HDPE and comparing the vacuum heat insulating materials (4) to (6) using the wet papermaking core material as the core material, calcium oxide (CaO) is used as the adsorbent material. The thermal conductivity of (5) using calcium oxide and hydrocarbon gas adsorbent A and (6) using hydrocarbon gas adsorbent B were lower than (4) used.

  In addition, when the outermost layer formed of HDPE is used as the innermost layer and the vacuum heat insulating materials (7) and (8) using the glass wool core material are compared as the core material, calcium oxide (CaO) is used as the adsorbent material. Compared with (7), the thermal conductivity of (8) using calcium oxide and hydrocarbon gas adsorbent A was lower.

  As described above, the vacuum heat insulating materials (2), (3), (5), (6), and (8) provided with the hydrocarbon gas adsorbent A and the hydrocarbon gas adsorbent B adsorb the hydrocarbon gas. As compared with the vacuum heat insulating materials (1), (4), and (7) that do not include the adsorbing material, the thermal conductivity is small, and it can be seen that the heat insulating performance is superior to the improvement limit of the conventional heat insulating performance.

  Therefore, by using the vacuum heat insulating material according to the present invention, it becomes possible to provide a device such as a refrigerator excellent in heat insulating performance and energy saving.

  When (5) and (8) using calcium oxide and hydrocarbon gas adsorbent A as the adsorbent are compared using the outer packaging material in which the innermost layer is formed of HDPE, glass wool core is used as the core. Compared with (8), the thermal conductivity of (5) using the wet papermaking core was lower. Thus, heat insulation performance can be improved more by using the wet papermaking core material like the core material of the vacuum heat insulating material of 1st Embodiment.

  It should be considered that the embodiments and examples disclosed above are illustrative and non-restrictive in every respect. The scope of the present invention is shown not by the above embodiments and examples but by the scope of the claims, and includes all modifications and variations within the meaning and scope equivalent to the scope of the claims.

  1: vacuum heat insulating material, 100: core material, 110: non-woven fabric, 200: outer packaging material, 230: innermost layer, 300: heat welding part, 400: adsorbent, 3: refrigerator, 301: outer box, 302: inner box, 320: Vacuum heat insulating material, 4: Water heater, 411: Upper surface, 412: Lower surface, 421: Outer container, 422: Hot water storage container, 430: Vacuum heat insulating material, 5: Rice cooker, 501: Housing, 503: Outer pot, 510: Vacuum heat insulating material, 6: Washing / drying machine, 601: Exterior, 603: Washing / drying tank storage, 610: Vacuum heat insulating material.

Claims (5)

Outer packaging materials,
A core material housed in the outer packaging material;
An adsorbent housed inside the outer packaging material,
The outer packaging material has a heat welding portion where the outer packaging materials are in contact with each other and thermally welded,
The thermally welded portion is formed of a material containing hydrocarbons,
The said adsorbent is a vacuum heat insulating material which is an adsorbent which adsorbs hydrocarbon gas. The core material is configured by laminating a plurality of nonwoven fabrics,
The non-woven fabric includes at least a plurality of inorganic fibers manufactured by a continuous filament method, and in the non-woven fabric, most of the inorganic fibers extend in a direction substantially parallel to the surface of the non-woven fabric. The vacuum heat insulating material according to claim 1.   The vacuum heat insulating material of Claim 2 whose average fiber diameter of the said inorganic fiber is 3 micrometers or more and 15 micrometers or less, and whose average fiber length of the said inorganic fiber is 3 mm or more and 15 mm or less.   The vacuum heat insulating material according to claim 2 or 3, wherein the inorganic fibers are glass fibers. An outer box,
An inner box disposed inside the outer box;
A vacuum heat insulating material disposed between the outer box and the inner box;
The said vacuum heat insulating material is an apparatus containing the vacuum heat insulating material of any one of Claim 1- Claim 4.