JP2009521587A5 - - Google Patents
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- Publication number
- JP2009521587A5 JP2009521587A5 JP2008547734A JP2008547734A JP2009521587A5 JP 2009521587 A5 JP2009521587 A5 JP 2009521587A5 JP 2008547734 A JP2008547734 A JP 2008547734A JP 2008547734 A JP2008547734 A JP 2008547734A JP 2009521587 A5 JP2009521587 A5 JP 2009521587A5
- Authority
- JP
- Japan
- Prior art keywords
- styrenic polymer
- iii
- feed
- anionic styrenic
- reaction mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 18
- 125000000129 anionic group Chemical group 0.000 claims 15
- 229920000642 polymer Polymers 0.000 claims 14
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 claims 8
- 239000011541 reaction mixture Substances 0.000 claims 8
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 6
- 239000003054 catalyst Substances 0.000 claims 6
- 238000006243 chemical reaction Methods 0.000 claims 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 5
- 229910052794 bromium Inorganic materials 0.000 claims 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims 3
- 239000007788 liquid Substances 0.000 claims 3
- 238000010791 quenching Methods 0.000 claims 3
- 230000000171 quenching effect Effects 0.000 claims 3
- 239000002904 solvent Substances 0.000 claims 3
- 239000004793 Polystyrene Substances 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- -1 aluminum halide Chemical class 0.000 claims 2
- 125000001246 bromo group Chemical group Br* 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 229920002223 polystyrene Polymers 0.000 claims 2
- 239000002002 slurry Substances 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical group [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 230000002730 additional effect Effects 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 230000031709 bromination Effects 0.000 claims 1
- 238000005893 bromination reaction Methods 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 238000011437 continuous method Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 150000004820 halides Chemical group 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 238000013112 stability test Methods 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75328505P | 2005-12-21 | 2005-12-21 | |
| US60/753,285 | 2005-12-21 | ||
| PCT/US2006/062321 WO2007076369A1 (en) | 2005-12-21 | 2006-12-19 | Brominated anionic styrenic polymers and their preparation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009521587A JP2009521587A (ja) | 2009-06-04 |
| JP2009521587A5 true JP2009521587A5 (https=) | 2010-02-04 |
| JP5261190B2 JP5261190B2 (ja) | 2013-08-14 |
Family
ID=36579945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008547734A Active JP5261190B2 (ja) | 2005-12-21 | 2006-12-19 | 臭素化アニオン性スチレン性ポリマー及びそれらの製造 |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US7638583B2 (https=) |
| EP (1) | EP1963377B1 (https=) |
| JP (1) | JP5261190B2 (https=) |
| KR (1) | KR101353883B1 (https=) |
| CN (1) | CN101341174B (https=) |
| BR (1) | BRPI0620898A2 (https=) |
| CA (1) | CA2629742C (https=) |
| ES (1) | ES2602097T3 (https=) |
| HU (1) | HUE030768T2 (https=) |
| IL (1) | IL192217A (https=) |
| JO (1) | JO3223B1 (https=) |
| PL (1) | PL1963377T3 (https=) |
| TW (1) | TWI406877B (https=) |
| WO (1) | WO2007076369A1 (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3739377B2 (ja) * | 2003-12-10 | 2006-01-25 | シャープ株式会社 | 洗濯乾燥機 |
| BRPI0418907A (pt) * | 2004-05-20 | 2007-11-27 | Albemarle Corp | aglomerados de polìmeros estirênicos aniÈnicos bromatadas inalterados e método de preparação |
| US7632893B2 (en) * | 2005-06-30 | 2009-12-15 | Albemarle Corporation | Brominated styrenic polymers and their preparation |
| ES2602097T3 (es) | 2005-12-21 | 2017-02-17 | Albemarle Corporation | Polímeros aniónicos estirénicos bromados y su preparación |
| ES2351618T3 (es) * | 2005-12-21 | 2011-02-08 | Albemarle Corporation | Preparación de polímeros o resinas estirénicas bromadas. |
| EP2044133B1 (en) | 2006-07-20 | 2015-01-28 | Albemarle Corporation | Process technology for recovering brominated styrenic polymers from reaction mixtures in which they are formed and/or converting such mixtures into pellets or into granules or pastilles |
| WO2008066970A1 (en) * | 2006-11-28 | 2008-06-05 | Albemarle Corporation | Converting brominated anionic styrenic polymer into harder and larger form for storage, shipment, and use |
| MX2009013127A (es) | 2007-06-07 | 2010-01-15 | Albemarle Corp | Polimeros bromados de bajo peso molecular y su uso en formulaciones termoplasticas. |
| US8993684B2 (en) | 2008-06-06 | 2015-03-31 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
| EP3470441A1 (en) * | 2008-06-06 | 2019-04-17 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
| JO3423B1 (ar) * | 2008-12-02 | 2019-10-20 | Albemarle Corp | مؤخرات لهب معالجة بالبروم و مواد مشتقه منها |
| US8642821B2 (en) | 2008-12-02 | 2014-02-04 | Albemarle Corporation | Bromination of telomer mixtures derived from toluene and styrene |
| KR20110100216A (ko) | 2008-12-02 | 2011-09-09 | 알베마를 코포레이션 | 분지형 또는 별모양 분지형 스티렌 폴리머, 텔로머, 및 부가물, 그의 합성, 그의 브롬화, 및 그의 용도 |
| CN102224122B (zh) | 2008-12-02 | 2014-09-03 | 雅宝公司 | 甲苯和苯乙烯衍生的调聚物分布物及由其制备的溴化阻燃剂 |
| US8753554B2 (en) | 2009-05-01 | 2014-06-17 | Albemarle Corporation | Pelletized low molecular weight brominated aromatic polymer compositions |
| JO3059B1 (ar) * | 2009-05-01 | 2017-03-15 | Albemarle Corp | معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض |
| CN101824113B (zh) * | 2010-04-14 | 2011-12-07 | 山东兄弟科技股份有限公司 | 一种可控分子量溴化聚苯乙烯的制备方法 |
| JP6609614B2 (ja) * | 2014-07-08 | 2019-11-20 | ブローミン コンパウンズ リミテッド | 臭素含有重合体の調製およびその難燃剤としての応用 |
| CN107092188A (zh) * | 2017-05-27 | 2017-08-25 | 南京邮电大学 | 一种连续搅拌釜式反应器系统的广义预测控制算法 |
| CN109293854B (zh) * | 2017-07-25 | 2021-01-29 | 中国石油天然气股份有限公司 | 高色度抗冲击聚苯乙烯及其制备方法和制备装置 |
| EP4556625A1 (en) * | 2018-04-09 | 2025-05-21 | Albemarle Corporation | Flame retardants for textile applications |
Family Cites Families (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3099644A (en) * | 1959-10-06 | 1963-07-30 | Exxon Research Engineering Co | Continuous chlorination and bromination of butyl rubber |
| US3598876A (en) * | 1967-11-13 | 1971-08-10 | Universal Oil Prod Co | Selective halogenation of hydrocarbons |
| DE2756375A1 (de) | 1977-12-17 | 1979-07-05 | Basf Ag | Flammschutzmittelkonzentrat fuer thermoplaste |
| FR2413409A1 (fr) | 1978-01-02 | 1979-07-27 | Huels Chemische Werke Ag | Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau |
| DE3006448A1 (de) | 1980-02-21 | 1981-08-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen |
| US4548995A (en) | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4513116A (en) | 1983-04-01 | 1985-04-23 | Exxon Research And Engineering Co. | Process for the manufacture of halogenated polymers |
| US4554326A (en) | 1983-04-01 | 1985-11-19 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4501859A (en) | 1983-04-01 | 1985-02-26 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4650832A (en) | 1984-09-17 | 1987-03-17 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| EP0201411A3 (en) | 1985-05-03 | 1989-02-08 | The Dow Chemical Company | Brominated polymers of alkenyl aromatic compounds |
| JPH02215807A (ja) | 1989-02-17 | 1990-08-28 | Nippon Kayaku Co Ltd | 臭素化ポリスチレンの製造方法 |
| US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
| US5055235A (en) * | 1990-12-12 | 1991-10-08 | Ethyl Corporation | Bromination process |
| US6518468B1 (en) | 1994-09-16 | 2003-02-11 | Albemarle Corporation | Bromination process |
| EP0784648B2 (en) * | 1994-10-05 | 2010-10-27 | Great Lakes Chemical Corporation | Continuous bromination process and products thereof |
| AU5369496A (en) * | 1995-04-06 | 1996-10-23 | Ferro Corporation | Brominated syndiotactic styrenic polymers and method for mak ing and using same |
| US5637650A (en) | 1996-06-14 | 1997-06-10 | Ferro Corporation | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
| US5723549A (en) | 1996-06-14 | 1998-03-03 | Ferro Corporation | Process for the preparation of brominated polystyrene having improved color characteristics |
| US5686538A (en) * | 1996-09-26 | 1997-11-11 | Albemarle Corporation | Process for brominating polystyrenic resins |
| US6521714B2 (en) * | 1996-09-26 | 2003-02-18 | Albemarle Corporation | Brominated polystyrenic resins |
| US6326439B1 (en) | 1996-09-26 | 2001-12-04 | Albemarle Corporation | Process for brominating polystyrenic resins |
| US6232408B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
| US5767203A (en) | 1996-09-26 | 1998-06-16 | Albemarle Corporation | Process for brominated styrenic polymers |
| US5677390A (en) | 1996-09-26 | 1997-10-14 | Albemarle Corporation | Process for brominating polystyrenic resins |
| US6232393B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
| CA2265642C (en) | 1996-09-26 | 2006-03-14 | Albemarle Corporation | Process for brominated styrenic polymers |
| US6235831B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
| US6133381A (en) | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
| US6235844B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
| DE69832912T2 (de) * | 1997-05-07 | 2006-09-21 | Albemarle Corp. | Verfahren zur Bromierung von Polystyrolharzen |
| TW491954B (en) | 1997-11-10 | 2002-06-21 | Hitachi Device Eng | Liquid crystal display device |
| WO2000014125A1 (en) | 1998-09-10 | 2000-03-16 | Albemarle Corporation | Improved brominated polystyrenic resins, and their use |
| CA2261367C (en) | 1999-02-08 | 2008-04-22 | Mold-Masters Limited | Injection molding valve member actuating mechanism |
| JP2000248021A (ja) * | 1999-03-01 | 2000-09-12 | Teijin Chem Ltd | 臭素化ポリスチレン |
| JP2000281800A (ja) | 1999-03-30 | 2000-10-10 | Teijin Chem Ltd | 臭素化ポリスチレン粉粒体の製造方法 |
| US6657028B1 (en) * | 2002-08-01 | 2003-12-02 | Albemarle Corporation | Anionic polymerization process |
| US7202296B2 (en) * | 2003-12-19 | 2007-04-10 | Albemarle Corporation | Flame retardant compositions and their use |
| US6992148B2 (en) | 2003-12-31 | 2006-01-31 | Albemarle Corporation | Recovery of antimony catalyst residues from bromination reaction mixtures |
| US20050159552A1 (en) * | 2004-01-21 | 2005-07-21 | Reed Jon S. | Flame retarded fibers and filaments and process of production therefor |
| US7666944B2 (en) | 2004-01-21 | 2010-02-23 | Albemarle Corporation | Flame retarded fibers and filaments and process of production therefor |
| WO2006019414A1 (en) | 2004-03-01 | 2006-02-23 | Albemarle Corporation | Flame retardant compositions and their use |
| BRPI0418907A (pt) * | 2004-05-20 | 2007-11-27 | Albemarle Corp | aglomerados de polìmeros estirênicos aniÈnicos bromatadas inalterados e método de preparação |
| US7632893B2 (en) * | 2005-06-30 | 2009-12-15 | Albemarle Corporation | Brominated styrenic polymers and their preparation |
| ES2602097T3 (es) * | 2005-12-21 | 2017-02-17 | Albemarle Corporation | Polímeros aniónicos estirénicos bromados y su preparación |
| ES2351618T3 (es) | 2005-12-21 | 2011-02-08 | Albemarle Corporation | Preparación de polímeros o resinas estirénicas bromadas. |
| EP2044133B1 (en) | 2006-07-20 | 2015-01-28 | Albemarle Corporation | Process technology for recovering brominated styrenic polymers from reaction mixtures in which they are formed and/or converting such mixtures into pellets or into granules or pastilles |
| TW200817447A (en) | 2006-08-22 | 2008-04-16 | Albemarle Corp | Terminating bromination of styrenic polymer in a bromination reaction mixture |
| WO2008066970A1 (en) | 2006-11-28 | 2008-06-05 | Albemarle Corporation | Converting brominated anionic styrenic polymer into harder and larger form for storage, shipment, and use |
| WO2008086362A1 (en) | 2007-01-10 | 2008-07-17 | Albemarle Corporation | Brominated styrenic polymer compositions and processes for producing same |
| TW200838919A (en) | 2007-01-10 | 2008-10-01 | Albemarle Corp | Brominated styrenic polymer compositions and processes for producing same |
-
2006
- 2006-12-19 ES ES06846694.5T patent/ES2602097T3/es active Active
- 2006-12-19 KR KR1020087015148A patent/KR101353883B1/ko active Active
- 2006-12-19 CA CA2629742A patent/CA2629742C/en active Active
- 2006-12-19 CN CN2006800481965A patent/CN101341174B/zh active Active
- 2006-12-19 BR BRPI0620898-3A patent/BRPI0620898A2/pt not_active Application Discontinuation
- 2006-12-19 PL PL06846694T patent/PL1963377T3/pl unknown
- 2006-12-19 WO PCT/US2006/062321 patent/WO2007076369A1/en not_active Ceased
- 2006-12-19 US US11/612,991 patent/US7638583B2/en active Active
- 2006-12-19 EP EP06846694.5A patent/EP1963377B1/en active Active
- 2006-12-19 JP JP2008547734A patent/JP5261190B2/ja active Active
- 2006-12-19 HU HUE06846694A patent/HUE030768T2/en unknown
- 2006-12-20 TW TW095147781A patent/TWI406877B/zh not_active IP Right Cessation
- 2006-12-21 JO JOP/2006/0491A patent/JO3223B1/ar active
-
2008
- 2008-06-16 IL IL192217A patent/IL192217A/en active IP Right Grant
-
2009
- 2009-12-11 US US12/636,250 patent/US8071688B2/en active Active
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