JP2009514172A - セリウム塩添加物を有する高い耐久性の燃料電池構成要素 - Google Patents

セリウム塩添加物を有する高い耐久性の燃料電池構成要素 Download PDF

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JP2009514172A
JP2009514172A JP2008537882A JP2008537882A JP2009514172A JP 2009514172 A JP2009514172 A JP 2009514172A JP 2008537882 A JP2008537882 A JP 2008537882A JP 2008537882 A JP2008537882 A JP 2008537882A JP 2009514172 A JP2009514172 A JP 2009514172A
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polymer
polymer electrolyte
electrolyte membrane
cation
electrode assembly
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JP2009514172A5 (enExample
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エイチ． フレイ，マシュー
エム． ピアポント，ダニエル
ジェイ． ハムロック，スティーブン
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3M Innovative Properties Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0091—Composites in the form of mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
JP2008537882A 2005-10-28 2006-10-24 セリウム塩添加物を有する高い耐久性の燃料電池構成要素 Pending JP2009514172A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/262,268 US8628871B2 (en) 2005-10-28 2005-10-28 High durability fuel cell components with cerium salt additives
PCT/US2006/041493 WO2007120189A2 (en) 2005-10-28 2006-10-24 High durability fuel cell components with cerium salt additives

Publications (2)

Publication Number Publication Date
JP2009514172A true JP2009514172A (ja) 2009-04-02
JP2009514172A5 JP2009514172A5 (enExample) 2009-10-01

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JP2008537882A Pending JP2009514172A (ja) 2005-10-28 2006-10-24 セリウム塩添加物を有する高い耐久性の燃料電池構成要素

Country Status (5)

Country Link
US (2) US8628871B2 (enExample)
JP (1) JP2009514172A (enExample)
CN (1) CN101297430B (enExample)
DE (1) DE112006003025T5 (enExample)
WO (1) WO2007120189A2 (enExample)

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US9849227B2 (en) 2008-06-05 2017-12-26 Fresenius Medical Care Deutschland Gmbh Organizer for releasably accommodating components of blood tube sets, and methods for manufacturing and preparing it
KR20210052820A (ko) * 2019-11-01 2021-05-11 현대자동차주식회사 내구성 및 수소 이온 전도성이 우수한 막-전극 접합체 및 이의 제조방법

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EP1772919B2 (en) 2004-06-22 2016-11-30 Asahi Glass Company, Limited Electrolyte membrane for solid polymer fuel cell, method for producing same and membrane electrode assembly for solid polymer fuel cell
US7943249B2 (en) 2004-06-22 2011-05-17 Asahi Glass Company, Limited Liquid composition, process for its production and process for producing membrane-electrode assembly for polymer electrolyte fuel cells
US7572534B2 (en) 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
US8101317B2 (en) * 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US8722569B2 (en) 2006-03-13 2014-05-13 E I Du Pont De Nemours And Company Peroxide decomposition catalyst particles
US8663866B2 (en) 2006-03-13 2014-03-04 E I Du Pont De Nemours And Company Stable proton exchange membranes and membrane electrode assemblies
US20080107945A1 (en) * 2006-11-08 2008-05-08 Gm Global Technology Operations, Inc. Fuel cell substrate with an overcoat
US7593823B2 (en) * 2006-11-21 2009-09-22 The Furukawa Electric Co., Ltd Method and device for determining state of battery, and battery power supply system therewith
JP4765908B2 (ja) * 2006-11-22 2011-09-07 旭硝子株式会社 固体高分子電解質膜及び固体高分子型燃料電池用膜電極接合体
EP2127008B1 (en) * 2006-12-29 2013-06-05 3M Innovative Properties Company Method of making durable polymer electrolyte membranes
US8206874B2 (en) * 2007-11-09 2012-06-26 3M Innovative Properties Company Polymer electrolytes including heteropolyacids
US7989115B2 (en) * 2007-12-14 2011-08-02 Gore Enterprise Holdings, Inc. Highly stable fuel cell membranes and methods of making them
CN101953013B (zh) * 2007-12-27 2013-07-17 3M创新有限公司 含聚结溶剂的电极墨水
CN101953012B (zh) * 2007-12-27 2014-05-07 3M创新有限公司 具有组合添加剂的耐久性燃料电池膜电极组件
CN102077401A (zh) * 2008-06-24 2011-05-25 Utc电力公司 具有来自部分离子交换的提高的耐久性的膜
US9419300B2 (en) 2010-04-16 2016-08-16 3M Innovative Properties Company Proton conducting materials
WO2011149732A2 (en) 2010-05-25 2011-12-01 3M Innovative Properties Company Reinforced electrolyte membrane
US9711816B2 (en) * 2011-08-04 2017-07-18 3M Innovative Properties Company Low equivalent weight polymers
US11155661B2 (en) 2015-09-23 2021-10-26 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups
WO2019055791A1 (en) 2017-09-14 2019-03-21 3M Innovative Properties Company FLUORINATED COPOLYMER HAVING SULFONYL PENDANT GROUPS AND COMPOSITIONS AND ARTICLES COMPRISING SAID FLUORINATED COPOLYMER
KR102791509B1 (ko) * 2018-12-20 2025-04-03 현대자동차주식회사 화학적으로 내구성이 향상된 막-전극 접합체의 전해질막 및 이의 제조방법
WO2020183306A1 (en) 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
CN114761445B (zh) 2019-12-02 2024-08-30 3M创新有限公司 全氟磺酸离聚物的可分散颗粒
KR20220119048A (ko) 2019-12-20 2022-08-26 쓰리엠 이노베이티브 프로퍼티즈 컴파니 플루오르화 공중합체 및 이를 포함하는 조성물 및 물품
US12286387B2 (en) 2019-12-23 2025-04-29 3M Innovative Properties Company Process of making fluoroolefins by thermal decomposition of fluorinated ionomers
CN115667332B (zh) 2020-03-30 2024-08-16 3M创新有限公司 包含具有离子双(磺酰基)酰亚胺部分和全氟醚末端基团的侧基的含氟聚合物
US20230090482A1 (en) 2020-04-09 2023-03-23 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
US20230279192A1 (en) 2020-06-08 2023-09-07 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer
KR102855297B1 (ko) 2020-11-24 2025-09-03 현대자동차주식회사 연료전지의 촉매용 지지체의 제조방법
WO2022256669A1 (en) 2021-06-04 2022-12-08 3M Innovative Properties Company Fluorinated ionomers, polymer electrolyte membranes, fuel cells, and methods
US12341227B2 (en) 2021-06-04 2025-06-24 3M Innovative Properties Company Perfluorosulfonyl monomers suitable for fluoropolymers and fuel cell membrane articles
US20250239638A1 (en) 2021-10-07 2025-07-24 3M Innovative Properties Company Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
WO2023111750A1 (en) 2021-12-13 2023-06-22 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer
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