JP2009046681A - 遷移金属錯体触媒存在下におけるニトリルゴムのメタセシス - Google Patents
遷移金属錯体触媒存在下におけるニトリルゴムのメタセシス Download PDFInfo
- Publication number
- JP2009046681A JP2009046681A JP2008212060A JP2008212060A JP2009046681A JP 2009046681 A JP2009046681 A JP 2009046681A JP 2008212060 A JP2008212060 A JP 2008212060A JP 2008212060 A JP2008212060 A JP 2008212060A JP 2009046681 A JP2009046681 A JP 2009046681A
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- JP
- Japan
- Prior art keywords
- alkyl
- aryl
- alkoxy
- group
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 0 *C1=C(*)N(*)CN1* Chemical compound *C1=C(*)N(*)CN1* 0.000 description 2
- BBKUZGLUVZZPJQ-UHFFFAOYSA-N [CH+]=Cc1ccccc1 Chemical compound [CH+]=Cc1ccccc1 BBKUZGLUVZZPJQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/08—Depolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07114656A EP2028194B1 (en) | 2007-08-21 | 2007-08-21 | Metathesis of nitrile rubbers in the presence of transition metal complex catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009046681A true JP2009046681A (ja) | 2009-03-05 |
| JP2009046681A5 JP2009046681A5 (enExample) | 2011-08-04 |
Family
ID=39111430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008212060A Pending JP2009046681A (ja) | 2007-08-21 | 2008-08-20 | 遷移金属錯体触媒存在下におけるニトリルゴムのメタセシス |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8362154B2 (enExample) |
| EP (2) | EP2028194B1 (enExample) |
| JP (1) | JP2009046681A (enExample) |
| CN (1) | CN101372518B (enExample) |
| AT (1) | ATE467644T1 (enExample) |
| BR (1) | BRPI0804882A2 (enExample) |
| DE (1) | DE602007006480D1 (enExample) |
| MX (1) | MX2008010686A (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013503223A (ja) * | 2009-08-31 | 2013-01-31 | ランクセス・ドイチュランド・ゲーエムベーハー | 遷移金属触媒の存在下におけるニトリルゴムのメタセシス |
| JP2013503228A (ja) * | 2009-08-31 | 2013-01-31 | ランクセス・ドイチュランド・ゲーエムベーハー | 水素化ニトリルゴムの製造方法 |
| JP2013503226A (ja) * | 2009-08-31 | 2013-01-31 | ランクセス・ドイチュランド・ゲーエムベーハー | 場合により水素化された低分子量ニトリルゴムを含有する加硫性ポリマー組成物 |
| KR101478474B1 (ko) * | 2010-08-09 | 2014-12-31 | 란세스 도이치란트 게엠베하 | 부분 수소화 니트릴 고무 |
| US9346908B1 (en) | 2014-12-25 | 2016-05-24 | Industrial Technology Research Institute | Olefin-metathesis catalysts and method for preparing low-molecular-weight nitrile butadiene rubber |
| US11549084B2 (en) | 2017-10-31 | 2023-01-10 | Lg Chem, Ltd. | Cleaning liquid composition and method for cleaning polymerization apparatus using same |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8895667B2 (en) | 2009-07-17 | 2014-11-25 | Tyco Electronics Corporation | Methods of making reversible crosslinked polymers and related methods |
| EP2484700B1 (de) | 2011-02-04 | 2013-10-09 | LANXESS Deutschland GmbH | Funktionalisierte Nitrilkautschuke und ihre Herstellung |
| WO2013056400A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| WO2013056461A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| WO2013056463A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| WO2013056459A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| CN104271607B (zh) * | 2012-04-28 | 2017-05-24 | 阿朗新科德国有限责任公司 | 丁腈橡胶的氢化 |
| CN103030716B (zh) * | 2012-12-28 | 2015-06-17 | 苏州大学 | 一种改性二烯基聚合物的制备方法 |
| EP3063592B1 (en) | 2013-10-30 | 2021-04-07 | California Institute of Technology | Direct photopatterning of robust and diverse materials |
| CN106349409B (zh) * | 2015-07-20 | 2018-02-13 | 中国石油化工股份有限公司 | 一种降低聚合物分子量的方法 |
| JP7248677B2 (ja) | 2017-12-08 | 2023-03-29 | アランセオ・ドイチュランド・ゲーエムベーハー | ルテニウム錯体触媒を使用してニトリルゴムを製造するためのプロセス |
| WO2019207096A1 (en) | 2018-04-27 | 2019-10-31 | Arlanxeo Deutschland Gmbh | Use of ruthenium and osmium catalysts for the metathesis of nitrile rubber |
| JP7417554B2 (ja) | 2018-07-23 | 2024-01-18 | アランセオ・ドイチュランド・ゲーエムベーハー | ニトリルゴムをメタセシスするための触媒の使用 |
| CN113559939B (zh) * | 2019-04-22 | 2023-06-23 | 郑州大学 | 一种腈的α烷基化反应催化剂及其制备方法 |
| KR102536751B1 (ko) * | 2020-04-07 | 2023-05-24 | 주식회사 엘지화학 | 촉매 조성물, 이를 포함하는 세척액 조성물 및 이를 이용한 중합장치의 세척방법 |
| BR102021025716B1 (pt) * | 2021-12-20 | 2022-12-06 | Bernardo Barreto Alvarez | Processo para reciclagem de elastômeros, elastômeros reciclados, e, uso dos elastômeros reciclados |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003176294A (ja) * | 2001-08-24 | 2003-06-24 | California Inst Of Technol | 6配位ルテニウムまたはオスミウム金属カルベンメタセシス触媒 |
| JP2004300444A (ja) * | 2001-06-12 | 2004-10-28 | Bayer Inc | 水素化ニトリルゴムの製造方法 |
| WO2006127483A1 (en) * | 2005-05-20 | 2006-11-30 | Bridgestone Corporation | Method for preparing low molecular weight polymers |
| JP2007500766A (ja) * | 2003-07-28 | 2007-01-18 | ファイヤーストーン ポリマーズ エルエルシー | エラストマー製造に用いた重合装置からゲル化不飽和エラストマーの除去 |
| JP2007077394A (ja) * | 2005-08-30 | 2007-03-29 | Lanxess Deutschland Gmbh | ニトリルゴムをメタセシスにより分解するための触媒の使用 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3700637A (en) | 1970-05-08 | 1972-10-24 | Shell Oil Co | Diene-nitrile rubbers |
| DE2539132C2 (de) | 1975-09-03 | 1987-04-09 | Bayer Ag, 5090 Leverkusen | Verwendung hydrierter Dien-Copolymere als temperaturbeständige Materialien auf dem Dichtungssektor |
| CA1203047A (en) | 1982-12-08 | 1986-04-08 | Hormoz Azizian | Polymer hydrogenation process |
| CA1220300A (en) | 1982-12-08 | 1987-04-07 | Polysar Limited | Polymer hydrogenation process |
| DE3329974A1 (de) | 1983-08-19 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | Herstellung von hydrierten nitrilkautschuken |
| DE3433392A1 (de) | 1984-09-12 | 1986-03-20 | Bayer Ag, 5090 Leverkusen | Hydrierung nitrilgruppenhaltiger ungesaettigter polymerer |
| DE3529252A1 (de) | 1985-08-16 | 1987-02-19 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| DE3540918A1 (de) | 1985-11-19 | 1987-05-21 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| DE3541689A1 (de) | 1985-11-26 | 1987-05-27 | Bayer Ag | Verfahren zur selektiven hydrierung nitrilgruppenhaltiger ungesaettigter polymerer |
| US4812528A (en) | 1987-07-06 | 1989-03-14 | University Of Waterloo | Polymer hydrogenation process |
| US4816525A (en) | 1987-07-06 | 1989-03-28 | University Of Waterloo | Polymer hydrogenation process |
| DE3932019C1 (enExample) | 1989-09-26 | 1991-05-08 | Bayer Ag, 5090 Leverkusen, De | |
| DE4025781A1 (de) | 1990-08-15 | 1992-02-20 | Bayer Ag | Hydrierte butadien/isopren/(meth-)acrylnitril- copolymerisate |
| EP0773948A4 (en) | 1992-04-03 | 1998-09-02 | California Inst Of Techn | HIGHLY ACTIVE RUTHENIUM OR OSMIUM METAL CARBEN COMPLEXES FOR OLEFIN METHETHESE REACTIONS AND THEIR SYNTHESIS |
| US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
| CN1213032C (zh) | 1999-05-24 | 2005-08-03 | 加州理工学院 | 咪唑烷基金属卡宾易位催化剂 |
| US7329758B1 (en) | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
| WO2002020535A1 (en) | 2000-09-05 | 2002-03-14 | California Institute Of Technology | Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors |
| CA2329844A1 (en) | 2000-12-28 | 2002-06-28 | Bayer Inc. | Esbo enhanced hydrogenation |
| TW593386B (en) | 2001-06-12 | 2004-06-21 | Bayer Inc | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| US6841623B2 (en) | 2001-06-29 | 2005-01-11 | Bayer Inc. | Low molecular weight nitrile rubber |
| US6818586B2 (en) * | 2001-08-01 | 2004-11-16 | Cymetech, Llp | Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts |
| CN1265882C (zh) | 2001-08-01 | 2006-07-26 | 加州理工学院 | 六配位钌或锇金属卡宾易位催化剂 |
| US7598330B2 (en) | 2002-04-05 | 2009-10-06 | California Institute Of Technology | Cross-metathesis of olefins directly substituted with an electron-withdrawing group using transition metal carbene catalysts |
| CA2409434A1 (en) | 2002-10-17 | 2004-04-17 | Bayer Inc. | Polymer blends comprising low molecular weight nitrile rubber |
| CA2409436A1 (en) * | 2002-10-17 | 2004-04-17 | Bayer Inc. | Polymer composites comprising low molecular weight nitrile rubber |
| CA2409429A1 (en) | 2002-10-17 | 2004-04-17 | Bayer Inc. | Hydrogenated nitrile rubber composites with improved proccesability |
| CA2413607A1 (en) | 2002-12-05 | 2004-06-05 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| CA2462011A1 (en) * | 2004-02-23 | 2005-08-23 | Bayer Inc. | Process for the preparation of low molecular weight nitrile rubber |
| EP1743918B1 (en) * | 2005-07-14 | 2008-05-14 | Lanxess Deutschland GmbH | Low mooney nitrile rubber thermoplastic elastomer composition with improved processability |
| EP1757623A1 (en) * | 2005-07-14 | 2007-02-28 | Lanxess Inc. | Process for the preparation of low mooney nitrile terpolymers |
-
2007
- 2007-08-21 AT AT07114656T patent/ATE467644T1/de not_active IP Right Cessation
- 2007-08-21 EP EP07114656A patent/EP2028194B1/en active Active
- 2007-08-21 DE DE602007006480T patent/DE602007006480D1/de active Active
-
2008
- 2008-08-08 EP EP08162052A patent/EP2028195A1/en not_active Withdrawn
- 2008-08-13 US US12/190,840 patent/US8362154B2/en active Active
- 2008-08-19 BR BRPI0804882-7A patent/BRPI0804882A2/pt not_active IP Right Cessation
- 2008-08-20 CN CN200810210863.6A patent/CN101372518B/zh active Active
- 2008-08-20 JP JP2008212060A patent/JP2009046681A/ja active Pending
- 2008-08-20 MX MX2008010686A patent/MX2008010686A/es active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004300444A (ja) * | 2001-06-12 | 2004-10-28 | Bayer Inc | 水素化ニトリルゴムの製造方法 |
| JP2003176294A (ja) * | 2001-08-24 | 2003-06-24 | California Inst Of Technol | 6配位ルテニウムまたはオスミウム金属カルベンメタセシス触媒 |
| JP2007500766A (ja) * | 2003-07-28 | 2007-01-18 | ファイヤーストーン ポリマーズ エルエルシー | エラストマー製造に用いた重合装置からゲル化不飽和エラストマーの除去 |
| WO2006127483A1 (en) * | 2005-05-20 | 2006-11-30 | Bridgestone Corporation | Method for preparing low molecular weight polymers |
| JP2007077394A (ja) * | 2005-08-30 | 2007-03-29 | Lanxess Deutschland Gmbh | ニトリルゴムをメタセシスにより分解するための触媒の使用 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013503223A (ja) * | 2009-08-31 | 2013-01-31 | ランクセス・ドイチュランド・ゲーエムベーハー | 遷移金属触媒の存在下におけるニトリルゴムのメタセシス |
| JP2013503228A (ja) * | 2009-08-31 | 2013-01-31 | ランクセス・ドイチュランド・ゲーエムベーハー | 水素化ニトリルゴムの製造方法 |
| JP2013503226A (ja) * | 2009-08-31 | 2013-01-31 | ランクセス・ドイチュランド・ゲーエムベーハー | 場合により水素化された低分子量ニトリルゴムを含有する加硫性ポリマー組成物 |
| KR101405744B1 (ko) * | 2009-08-31 | 2014-06-10 | 란세스 도이치란트 게엠베하 | 저분자량의 임의로 수소화된 니트릴 고무를 포함하는 가황성 중합체 조성물 |
| KR101411751B1 (ko) * | 2009-08-31 | 2014-06-25 | 란세스 도이치란트 게엠베하 | 수소화 니트릴 고무의 제조 방법 |
| KR101478474B1 (ko) * | 2010-08-09 | 2014-12-31 | 란세스 도이치란트 게엠베하 | 부분 수소화 니트릴 고무 |
| US9346908B1 (en) | 2014-12-25 | 2016-05-24 | Industrial Technology Research Institute | Olefin-metathesis catalysts and method for preparing low-molecular-weight nitrile butadiene rubber |
| US11549084B2 (en) | 2017-10-31 | 2023-01-10 | Lg Chem, Ltd. | Cleaning liquid composition and method for cleaning polymerization apparatus using same |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2028195A1 (en) | 2009-02-25 |
| EP2028194B1 (en) | 2010-05-12 |
| CN101372518B (zh) | 2013-03-20 |
| DE602007006480D1 (de) | 2010-06-24 |
| US20090054597A1 (en) | 2009-02-26 |
| CN101372518A (zh) | 2009-02-25 |
| ATE467644T1 (de) | 2010-05-15 |
| BRPI0804882A2 (pt) | 2010-06-15 |
| EP2028194A1 (en) | 2009-02-25 |
| US8362154B2 (en) | 2013-01-29 |
| MX2008010686A (es) | 2009-03-05 |
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