JP2008093661A - 活性炭に基づく高性能吸着剤 - Google Patents
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Abstract
【解決手段】本願発明の高性能吸着剤は、特に球状形状の活性炭の個々の粒状の形において、少なくとも0.7cm3/gのグルビッチ合計細孔量であって、この合計細孔量の少なくとも70%が、20オングストローム以下の孔径を有するミクロ細孔によって形成されるもの;30オングストローム以下の中心傾向細孔径の寸法;及び少なくとも1500m2/gのBET表面積のパラメータによって特徴づけられる。
【選択図】 なし
Description
これは、炭化工程における揮発成分の分離及び活性化工程における焼失による重量損失が、認められる。さらなる詳細については、例えば非特許文献1に見られる活性炭の製造に関連する。
少なくとも0.7cm3/gのグルビッチ合計細孔量であって、この合計細孔量の少なくとも70%が、20オングストローム以下の孔径を有するミクロ細孔によって形成されるもの;
30オングストローム以下の中心傾向細孔径の寸法;及び
少なくとも1500m2/gのBET表面積。
多孔性における、内部表面積における且つ細孔量における増加と均等である物質の損失と関連して起こる。それゆえに、活性化は、選択的な又はより正確には管理された酸化状態において実行される。活性化は、700℃〜1300℃の温度、特に800℃〜1200℃の温度、好ましくは900℃〜1100℃の温度で実行される。
Claims (10)
- 特に球形状の活性炭の個々の粒状物の形の活性炭に基づく高性能吸着剤において、該高性能吸着剤が:
少なくとも0.7cm3/gのグルビッチ合計細孔量であって、この合計細孔量の少なくとも70%が、20オングストローム以下の孔径を有するミクロ細孔によって形成されるもの;
30オングストローム以下の中心傾向細孔径の寸法;及び
少なくとも1500m2/gのBET表面積;
というパラメータを具備することを特徴とする高性能吸着剤。 - 前記グルビッチ合計細孔量が、0.7〜1.8cm3/gの範囲内、特に0.8〜1.6cm3/gの範囲内、好ましくは0.9〜1.5cm3/gの範囲内であることを特徴とする請求項1記載の活性炭に基づく高性能吸着剤。
- 前記グルビッチ合計細孔量の少なくとも75%、特には少なくとも80%、好ましくは少なくとも85%、より好ましくは少なくとも90%が、20オングストローム以下の孔径を有するミクロ細孔によって形成されることを特徴とする請求項1又は2記載の活性炭に基づく高性能吸着剤。
- 前記グルビッチ合計細孔量の70%〜95%、特に75%〜90%、好ましくは75%〜85%が、20オングストローム以下の細孔径を有するミクロ細孔によって形成されることを特徴とする活性炭に基づく高性能吸着剤。
- 20オングストローム以下の孔径を有するミクロ細孔によって形成される高性能吸着剤の炭素ブラック法ミクロ細孔量は、0.5〜1.4cm3/gの範囲内、特には0.6〜1.2cm3/gの範囲内、好ましくは0.7〜1.1cm3/gの範囲内であることを特徴とする請求項1〜4のいずれか1つに記載の活性炭に基づく高性能吸着剤。
- 中心傾向細孔径は、26オングストローム以下であり、特には、25オングストローム以下であり、好ましくは24オングストローム以下であることを特徴とする請求項1〜5のいずれか1つに記載の活性炭に基づく高性能吸着剤。
- 少なくとも0.7cm3/gのグルビッチ合計細孔量であって、その合計細孔量の少なくとも70%が、20オングストローム以下の細孔径を有するミクロ細孔によって形成されているもの;
30オングストローム以下の中心傾向細孔径の寸法;
少なくとも1500m2/gのBET表面積;
少なくとも25%のブタン吸着量;
少なくとも1350mg/gのヨウ素価;
少なくとも10ニートンの活性炭粒子当たりの圧縮強さ又は破裂強さ及び/若しくは少なくとも95%の耐摩耗性;
というパラメータを具備することを特徴とする請求項1〜6のいずれか1つに記載の活性炭に基づく高性能吸着剤。 - ガス、特に空気を純化又は浄化するために、特にガス又は空気流から有毒物、有害物及び臭気を吸着するための、又は、特に防護衣類の製造における吸収フィルタ材料における使用のための請求項1〜7のいずれか1つに記載の活性炭に基づく高性能吸着剤の使用。
- ガス、特に水素のための吸収蓄積媒体としての請求項1〜8のいずれか1つに記載の活性炭に基づく高性能吸着剤の使用。
- 特に薬剤又は薬剤成分としての医学又は薬学領域における請求項1〜9のいずれか1つに記載の活性炭に基づく高性能吸着剤の使用。
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DE102006048790 | 2006-10-12 | ||
DE102006048790.7 | 2006-10-12 |
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JP2008093661A true JP2008093661A (ja) | 2008-04-24 |
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US (1) | US7737083B2 (ja) |
EP (1) | EP1918022B1 (ja) |
JP (1) | JP5013290B2 (ja) |
KR (1) | KR100958852B1 (ja) |
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Also Published As
Publication number | Publication date |
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US7737083B2 (en) | 2010-06-15 |
EP1918022B1 (de) | 2015-11-18 |
DE202006016898U1 (de) | 2007-11-22 |
EP1918022A1 (de) | 2008-05-07 |
JP5013290B2 (ja) | 2012-08-29 |
KR20080033129A (ko) | 2008-04-16 |
US20080107589A1 (en) | 2008-05-08 |
KR100958852B1 (ko) | 2010-05-20 |
RU2007137631A (ru) | 2009-04-20 |
RU2378046C2 (ru) | 2010-01-10 |
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