JP2007514821A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2007514821A5 JP2007514821A5 JP2006545381A JP2006545381A JP2007514821A5 JP 2007514821 A5 JP2007514821 A5 JP 2007514821A5 JP 2006545381 A JP2006545381 A JP 2006545381A JP 2006545381 A JP2006545381 A JP 2006545381A JP 2007514821 A5 JP2007514821 A5 JP 2007514821A5
- Authority
- JP
- Japan
- Prior art keywords
- crude
- column
- periodic table
- crude product
- metals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Description
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含み、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を、触媒の少なくとも1種はバナジウム、バナジウムの1種以上の化合物、又はそれらの混合物を含む1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, the total content of alkali metals and alkaline earth metals (as determined by ASTM method D1318) is the crude feed is at least 0.00001g per crude feed 1g, at least one vanadium, one or more compounds of vanadium catalyst Or a total product comprising a crude product that is a liquid mixture at 25 ° C. and 0.101 MPa, in contact with one or more catalysts comprising a mixture thereof, and an organic acid metal salt of the crude product Contact so that the total content of alkali metal and alkaline earth metal in the product is 90% or less of the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude oil Method for producing a crude product comprising the step of controlling the matter are also provided.
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油を、触媒の少なくとも1種は、中央値細孔径が90〜180Åの範囲であり、かつ全細孔数の60%以上が中央値細孔径の45Å以内の細孔径を有する細孔サイズ分布(ASTM法D4282で測定)を示す1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the crude total content of alkali metal Shoku及 beauty alkaline earth metals (as determined by ASTM method D1318) is not less than 0.00001g per crude feed 1g in, at least one catalyst, median pore diameter 90 In contact with one or more catalysts exhibiting a pore size distribution (measured by ASTM method D4282) having a pore size in the range of ~ 180% and having a pore diameter of not less than 45% of the median pore diameter, with more than 60% of the total pore number A process for producing a whole product including a crude product which is a liquid mixture at 25 ° C. and 0.101 MPa, and the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude product is crude oil Charges to be 90% or less relative to the total content of alkali metals and alkaline earth metals in metal salts of organic acids, method for producing a crude product comprising the step of controlling the contacting conditions are also provided.
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を、触媒の少なくとも1種は、中央値細孔径が180Å以上である細孔サイズ分布(ASTM法D4282で測定)を有し、該細孔サイズ分布の触媒は周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を含む1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals (as determined by ASTM method D1318) is the crude feed is at least 0.00001g per crude feed 1g in, at least one catalyst, median pore diameter It has a pore size distribution (measured by ASTM method D4282) of 180 mm or more, and the catalyst of the pore size distribution is one or more metals in the sixth column of the periodic table, one or more metals in the sixth column of the periodic table Producing a total product comprising a crude product which is a liquid mixture at 25 ° C. and 0.101 MPa by contacting with one or more catalysts comprising one or more compounds of Organic acid metal The step of controlling the contact conditions so that the total content of alkali metal and alkaline earth metal is 90% or less of the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude oil raw material A method for producing a crude product comprising
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を、触媒の少なくとも1種は、中央値細孔径が230Å以上である細孔サイズ分布(ASTM法D4282で測定)を有し、該細孔サイズ分布の触媒は周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を含む1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals (as determined by ASTM method D1318) is the crude feed is at least 0.00001g per crude feed 1g in, at least one catalyst, median pore diameter It has a pore size distribution (measured by ASTM method D4282) of 230 mm or more, and the catalyst of the pore size distribution is one or more metals in the sixth column of the periodic table, one or more metals in the sixth column of the periodic table Producing a total product comprising a crude product which is a liquid mixture at 25 ° C. and 0.101 MPa by contacting with one or more catalysts comprising one or more compounds of the formula: Organic acid metal The step of controlling the contact conditions so that the total content of alkali metal and alkaline earth metal is 90% or less of the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude oil raw material A method for producing a crude product comprising
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を、触媒の少なくとも1種は、中央値細孔径が90Å以上である細孔サイズ分布(ASTM法D4282で測定)を有し、該細孔サイズ分布の触媒は触媒1g当たりモリブデン、1種以上のモリブデン化合物又はそれらの混合物を、モリブデンの重量として計算して、0.0001〜0.3g含有する1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals (as determined by ASTM method D1318) is the crude feed is at least 0.00001g per crude feed 1g in, at least one catalyst, median pore diameter Having a pore size distribution (measured by ASTM method D4282) that is greater than or equal to 90 mm, the catalyst of the pore size distribution is calculated as molybdenum, one or more molybdenum compounds or mixtures thereof per gram of catalyst as the weight of molybdenum. To produce a total product including a crude product which is a liquid mixture at 25 ° C. and 0.101 MPa in contact with one or more catalysts containing 0.0001-0.3 g. The total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude product is 90% or less relative to the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude oil raw material. Also provided is a method for producing a crude product comprising a step of controlling contact conditions.
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を、触媒の少なくとも1種は、(a)周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物及び(b)周期表第10欄の1種以上の金属、周期表第10欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を合計第10欄金属対合計第6欄金属のモル比で1〜10の範囲で含む1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the alkali metal Shoku及 beauty total content of alkaline earth metals crude feed is above 0.00001g per crude feed 1 g (as determined by ASTM method D1318) in at least one catalyst, (a) the periodic table One or more metals in column 6, one or more compounds of one or more metals in column 6 of the periodic table, or mixtures thereof; and (b) one or more metals in column 10 of the periodic table, periodic table. Contact with one or more catalysts comprising one or more compounds of one or more metals in column 10 or mixtures thereof in a total column 10 metal to total column 6 metal molar ratio in the range of 1-10. Let it be a liquid mixture at 25 ° C. and 0.101 MPa A step of producing a total product including an oil product, and a total content of alkali metals and alkaline earth metals in the organic acid metal salt of the crude product is determined by the alkali metal and alkaline earth in the organic acid metal salt of the crude material There is also provided a method for producing a crude product including a step of controlling the contact conditions so that the total content of the similar metals is 90% or less.
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を、(a)周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を、第一触媒1g当たり、金属の重量として計算して、0.0001〜0.06g含有する第一触媒及び(b)周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を第二触媒1g当たり、金属の重量として計算して、0.02g以上含有する1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals in the crude feed is above 0.00001g per crude feed 1 g (as determined by ASTM method D1318), (a) 1 or more of the periodic table column 6 Of metal, one or more compounds of one or more metals in the sixth column of the periodic table, or a mixture thereof, calculated as the weight of the metal per 1 g of the first catalyst, and contained 0.0001 to 0.06 g The first catalyst and (b) one or more metals in the sixth column of the periodic table, one or more compounds of one or more metals in the sixth column of the periodic table, or a mixture thereof, One or more containing 0.02g or more, calculated as weight Contacting the catalyst to produce a total product comprising a crude product which is a liquid mixture at 25 ° C. and 0.101 MPa, and the sum of alkali metals and alkaline earth metals in the organic acid metal salt of the crude product There is also provided a method for producing a crude product including a step of controlling contact conditions so that the content is 90% or less with respect to the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude oil raw material. .
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を、触媒の少なくとも1種は、周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を触媒1g当たり、金属の重量として計算して、0.001g以上含有する1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び接触帯での液体の時間当たり空間速度が10h−1を超えると共に、原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals (as determined by ASTM method D1318) is the crude feed is at least 0.00001g per crude feed 1g in, at least one catalyst, periodic table 6 column One or more kinds of metals, one or more compounds of one or more kinds of metals in the sixth column of the periodic table, or a mixture thereof, calculated as the weight of the metal per gram of catalyst, one kind containing 0.001 g or more Contacting the above catalyst to produce a total product including a crude product which is a liquid mixture at 25 ° C. and 0.101 MPa, and the liquid hourly space velocity in the contact zone exceeds 10 h −1 Crude oil raw The total content of alkali metal and alkaline earth metal in the organic acid metal salt of the product is 90% or less with respect to the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude oil raw material. Also provided is a method for producing a crude product comprising a step of controlling contact conditions.
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上で残留物含有量(ASTM法D5307で測定)が原油原料1g当たり0.1g以上である原油原料を、触媒の少なくとも1種は、周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を含有する1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下で原油生成物の残留物含有量が原油原料の残留物含有量に対し70〜130%となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals in the residue content with (as measured ASTM method D1318) or more 0.00001g per crude feed 1g (as determined by ASTM method D5307) is crude feed 1g per 0 .1 g or more of crude feedstock, at least one of the catalysts is one or more metals in the sixth column of the periodic table, one or more compounds of one or more metals in the sixth column of the periodic table, or a mixture thereof Producing an overall product comprising a crude product that is a liquid mixture at 25 ° C. and 0.101 MPa, and an alkali metal in an organic acid metal salt of the crude product, in contact with one or more catalysts containing And Arca The total content of earth metals is 90% or less of the total content of alkali metals and alkaline earth metals in the organic acid metal salt of crude oil raw material, and the residual content of crude product is the residual content of crude oil raw material Further, a method for producing a crude product including a step of controlling the contact conditions so as to be 70 to 130% is also provided.
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.0001g以上で真空ガス油(VGO)含有量(ASTM法D5307で測定)が原油原料1g当たり0.1g以上である原油原料1g当たり0.00002g以上である原油原料を、触媒の少なくとも1種は、周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物を含有する1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下で原油生成物のVGO含有量が原油原料のVGO含有量に対し70〜130%となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals in the (ASTM method D1318 measured at) vacuum gas oil at least 0.0001g per crude feed 1 g (VGO) content (as determined by ASTM method D5307) of crude At least one kind of catalyst is one or more metals in column 6 of the periodic table, one kind of column in the sixth column of the periodic table, crude raw material that is 0.00002 g or more per gram of crude material that is 0.1 g or more A step of producing a total product including a crude product that is a liquid mixture at 25 ° C. and 0.101 MPa by contacting with one or more catalysts containing one or more compounds of the above metals, or a mixture thereof. And the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude product is 90% or less of the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude material. There is also provided a method for producing a crude product including a step of controlling contact conditions such that the VGO content of the product is 70 to 130% with respect to the VGO content of the crude raw material.
また本発明は、1種以上の有機酸の1種以上のアルカリ金属塩、1種以上の有機酸の1種以上のアルカリ土類金属塩、又はそれらの混合物を含有すると共に、有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量(ASTM法D1318で測定)が原油原料1g当たり0.00001g以上である原油原料を1種以上の触媒と接触させて、25℃、0.101MPaにおいて液体混合物である原油生成物を含む全生成物を製造する工程であって、触媒の少なくとも1種は支持体を、周期表第6欄の1種以上の金属、周期表第6欄の1種以上の金属の1種以上の化合物、又はそれらの混合物と組合わせて触媒前駆体とし、次いでこれを1種以上の硫黄含有化合物の存在下に400℃未満の温度で加熱して触媒を形成することにより得られる該工程、及び原油生成物の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量が原油原料の有機酸金属塩中のアルカリ金属及びアルカリ土類金属の合計含有量に対し90%以下となるように、接触条件を制御する工程を含む原油生成物の製造方法も提供する。 The present invention also includes one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, and an organic acid metal salt the total content of alkali metal Shoku及 beauty alkaline earth metals (as determined by ASTM method D1318) is in contact with one or more catalysts to crude feed is at least 0.00001g per crude feed 1g in, 25 ° C., A process for producing a total product comprising a crude product which is a liquid mixture at 0.101 MPa, wherein at least one of the catalysts is a support, one or more metals in column 6 of the periodic table, periodic table 6 Combining with one or more compounds of one or more metals in the column, or a mixture thereof to form a catalyst precursor, which is then heated at a temperature of less than 400 ° C. in the presence of one or more sulfur-containing compounds. By forming a catalyst The total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude product is 90% of the total content of alkali metal and alkaline earth metal in the organic acid metal salt of the crude raw material. Also provided is a method for producing a crude product comprising a step of controlling the contact conditions so as to be less than or equal to%.
また本発明は、それぞれ組成物1g当たり、硫黄を0.001g以上(ASTM法D4294で測定)、残留物を0.2g以上(ASTM法D5307で測定)含有すると共に、MCR含有量(ASTM法D4530で測定)対C5アスファルテン含有量(ASTM法D2007で測定)の重量比が1.5以上でTANが0.5以下(ASTM法D664で測定)である原油組成物も提供する。 Further, the present invention contains 0.001 g or more of sulfur (measured by ASTM method D4294) and 0.2 g or more of residue (measured by ASTM method D5307) per 1 g of the composition , and MCR content (ASTM method D4530). TAN is also provided crude composition is 0.5 or less (measured by ASTM method D664) in in measurement) the weight ratio of to-C 5 asphaltenes content (determined by ASTM method D2007) of 1.5 or more.
幾つかの実施態様では、本発明は、本発明方法又は組成物の1つ以上と組合わせて、原油原料を1種以上の触媒と接触させて、原油生成物を含む全生成物を製造する工程、及び接触条件を制御して、有機酸素含有化合物を低下させる工程であって、(a)原油生成物の酸素含有量が原油原料の酸素含有量の90%以下になるように、選択した有機酸素化合物の含有量を低下させ、(b)有機酸素含有化合物の少なくとも1種の化合物は、カルボン酸の金属塩を含有し、(c)有機酸素含有化合物の少なくとも1種の化合物は、カルボン酸のアルカリ金属塩を含有し、(d)有機酸素含有化合物の少なくとも1種の化合物は、カルボン酸のアルカリ土類金属塩を含有し、(e)有機酸素含有化合物の少なくとも1種の化合物は、カルボン酸の金属塩(但し、該金属は周期表第12欄の1種以上の金属を含む)を含有し、(f)原油生成物中のカルボキシル非含有有機化合物の含有量は、原油原料中のカルボキシル非含有有機化合物の含有量に対し90%以下であり、及び/又は(g)原油原料中の酸素含有化合物の少なくとも1種は、ナフテン酸又はカルボキシル非含有有機酸素化合物から生じる該制御工程を含む方法も提供する。 In some embodiments, the present invention combines a crude feed with one or more catalysts in combination with one or more of the methods or compositions of the present invention to produce a total product including a crude product. The step and the step of controlling the contact conditions to reduce the organic oxygen-containing compound were selected so that (a) the oxygen content of the crude product was 90% or less of the oxygen content of the crude feed. The content of the organic oxygen compound is reduced, (b) at least one compound of the organic oxygen-containing compound contains a metal salt of a carboxylic acid, and (c) at least one compound of the organic oxygen-containing compound is a carboxylic acid. An alkali metal salt of an acid; (d) at least one compound of an organic oxygen-containing compound contains an alkaline earth metal salt of a carboxylic acid; and (e) at least one compound of an organic oxygen-containing compound is Carboxylic acid gold Salt (provided that the metal contains one or more metals in column 12 of the periodic table), and (f) the content of the non-carboxylated organic compound in the crude product is the non-carboxyl content in the crude feed There is also a method comprising the control step of 90% or less with respect to the content of the organic compound and / or (g) at least one of the oxygen-containing compounds in the crude oil raw material is generated from a naphthenic acid or carboxyl-free organic oxygen compound provide.
接触帯は、1種以上(例えば2種)の触媒を含有してよい。幾つかの実施態様では、原油原料と2種の触媒の最初の触媒との接触で、原油原料のTANを低下できる。引き続き、TANが低下した原油原料と第二の触媒との接触で、ヘテロ原子の含有量は低下し、API比重は増大する。他の実施態様では、原油原料と1種以上の触媒との接触後、原油生成物のTAN、粘度、Ni/V/Fe含有量、ヘテロ原子含有量、残留物含有量、API比重、又はこれら特性の組合わせは、原油原料の同じ特性に比べて、10%以上変化する。
The contact zone may contain one or more (eg, two) catalysts. In some embodiments, contact of the crude feed with the first of the two catalysts can reduce the TAN of the crude feed . Subsequently, the heteroatom content is decreased and the API specific gravity is increased by the contact between the crude raw material having a reduced TAN and the second catalyst. In other embodiments, after contacting the crude feed with one or more catalysts, the crude product TAN, viscosity, Ni / V / Fe content, heteroatom content, residue content, API specific gravity, or these The combination of properties varies by more than 10% compared to the same properties of the crude feed.
Claims (21)
原油生成物のTANが原油原料のTANに対し90%以下で原油生成物の硫黄含有量が原油原料の硫黄含有量に対し70〜130%となるように、温度、圧力、水素源の流れ、原油原料流、又はそれらの組合わせからなる接触条件を制御する工程、
を含む原油生成物の製造方法。 A crude oil feedstock having a total acid number (TAN) (measured by ASTM method D664) of 0.3 or more and a sulfur content (measured by ASTM method D4294) of 0.0001 g or more of crude feedstock is used. It contains one or more metals in the sixth column of the periodic table, one or more compounds of one or more metals in the sixth column of the periodic table, or a mixture thereof, and the median pore diameter is in the range of 90 to 180 mm. Producing a total product, including a crude product that is a liquid mixture at 25 ° C. and 0.101 MPa, in contact with one or more catalysts having a pore size distribution (measured by ASTM method D4282); Temperature, pressure, flow of hydrogen source, crude oil feed so that the TAN of the product is 90% or less of the TAN of the crude feed and the sulfur content of the crude product is 70-130% of the sulfur content of the crude feed Flow Or controlling the contact conditions comprising a combination thereof,
A method for producing a crude product comprising:
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53150603P | 2003-12-19 | 2003-12-19 | |
US61889204P | 2004-10-14 | 2004-10-14 | |
PCT/US2004/042121 WO2005066303A2 (en) | 2003-12-19 | 2004-12-16 | Systems, methods, and catalysts for producing a crude product |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007514821A JP2007514821A (en) | 2007-06-07 |
JP2007514821A5 true JP2007514821A5 (en) | 2008-01-31 |
Family
ID=34713792
Family Applications (26)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006545528A Pending JP2007515523A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545420A Pending JP2007514830A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545526A Pending JP2007514849A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545524A Pending JP2007514847A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545472A Expired - Fee Related JP5306598B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545474A Pending JP2007514843A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545455A Expired - Fee Related JP4891090B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545421A Pending JP2007518847A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545520A Expired - Fee Related JP5179059B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545529A Pending JP2007514850A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545470A Pending JP2007514840A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545381A Pending JP2007514821A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545444A Pending JP2007514835A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545471A Pending JP2007514841A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545384A Pending JP2007514824A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545450A Pending JP2007517931A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545453A Pending JP2007514838A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545464A Pending JP2007522269A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545522A Pending JP2007514845A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545473A Expired - Fee Related JP5107580B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545425A Pending JP2007514831A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545445A Pending JP2007514836A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545389A Pending JP2007514826A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545390A Pending JP2007514827A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545449A Pending JP2007514837A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545369A Pending JP2007514820A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
Family Applications Before (11)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006545528A Pending JP2007515523A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545420A Pending JP2007514830A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545526A Pending JP2007514849A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545524A Pending JP2007514847A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545472A Expired - Fee Related JP5306598B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545474A Pending JP2007514843A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545455A Expired - Fee Related JP4891090B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545421A Pending JP2007518847A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545520A Expired - Fee Related JP5179059B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545529A Pending JP2007514850A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545470A Pending JP2007514840A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
Family Applications After (14)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006545444A Pending JP2007514835A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545471A Pending JP2007514841A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545384A Pending JP2007514824A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545450A Pending JP2007517931A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545453A Pending JP2007514838A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545464A Pending JP2007522269A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545522A Pending JP2007514845A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545473A Expired - Fee Related JP5107580B2 (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545425A Pending JP2007514831A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545445A Pending JP2007514836A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545389A Pending JP2007514826A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545390A Pending JP2007514827A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545449A Pending JP2007514837A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
JP2006545369A Pending JP2007514820A (en) | 2003-12-19 | 2004-12-16 | System, method and catalyst for producing crude product |
Country Status (11)
Country | Link |
---|---|
EP (26) | EP1702055A2 (en) |
JP (26) | JP2007515523A (en) |
KR (7) | KR20070032625A (en) |
AU (15) | AU2004312365A1 (en) |
BR (26) | BRPI0405568B1 (en) |
CA (26) | CA2549088C (en) |
MX (4) | MXPA06006806A (en) |
NL (23) | NL1027772C2 (en) |
SG (3) | SG138599A1 (en) |
TW (14) | TW200530388A (en) |
WO (26) | WO2005063931A2 (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7591941B2 (en) | 2003-12-19 | 2009-09-22 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
NL1027772C2 (en) * | 2003-12-19 | 2006-08-29 | Shell Int Research | Systems, methods and catalysts for producing a crude product. |
CA2604015C (en) * | 2005-04-11 | 2014-02-18 | Shell International Research Maatschappij B.V. | Systems, methods, and catalysts for producing a crude product |
CN101166808B (en) * | 2005-04-11 | 2013-03-27 | 国际壳牌研究有限公司 | Method and catalyst for producing a crude product having a reduced MCR content |
CN101405371B (en) * | 2006-04-04 | 2012-07-18 | 国际壳牌研究有限公司 | Method for reducing total acid number (TAN) of liquid hydrocarbon raw material |
US20080083650A1 (en) * | 2006-10-06 | 2008-04-10 | Bhan Opinder K | Methods for producing a crude product |
JP5346036B2 (en) * | 2007-11-28 | 2013-11-20 | サウジ アラビアン オイル カンパニー | Upgrade method for heavy and high waxy crude oil without hydrogen supply |
BRPI0704443B1 (en) | 2007-11-30 | 2018-09-11 | Petroleo Brasileiro S/A Petrobras | system and process for separating spent catalyst suspensions and hydrocarbons formed in a multi-reaction upstream fluid catalytic cracking unit |
US7862708B2 (en) | 2007-12-13 | 2011-01-04 | Exxonmobil Research And Engineering Company | Process for the desulfurization of heavy oils and bitumens |
KR100931036B1 (en) * | 2008-03-18 | 2009-12-10 | 한국화학연구원 | Catalyst for Hydrocracking of Crude Oil and Hydrocracking Method Using the Same |
US8114806B2 (en) * | 2008-04-10 | 2012-02-14 | Shell Oil Company | Catalysts having selected pore size distributions, method of making such catalysts, methods of producing a crude product, products obtained from such methods, and uses of products obtained |
JP5684107B2 (en) * | 2008-04-10 | 2015-03-11 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Method for converting catalyst systems and crude oil feeds with such catalyst systems |
EP2628780A1 (en) * | 2012-02-17 | 2013-08-21 | Reliance Industries Limited | A solvent extraction process for removal of naphthenic acids and calcium from low asphaltic crude oil |
JP2013057075A (en) * | 2012-11-19 | 2013-03-28 | Shell Internatl Research Maatschappij Bv | Lowering process of total acid number (tan) of liquid hydrocarbon quality feedstock |
US12025435B2 (en) | 2017-02-12 | 2024-07-02 | Magēmã Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
US20190233741A1 (en) | 2017-02-12 | 2019-08-01 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
Family Cites Families (119)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US587636A (en) * | 1897-08-03 | Blacking-brush and dauber | ||
US2850435A (en) * | 1956-02-06 | 1958-09-02 | Pure Oil Co | Method of removing high molecular weight naphthenic acids from hydrocarbon oils |
US2921023A (en) * | 1957-05-14 | 1960-01-12 | Pure Oil Co | Removal of naphthenic acids by hydrogenation with a molybdenum oxidesilica alumina catalyst |
US3025231A (en) * | 1959-06-03 | 1962-03-13 | Texaco Inc | Catalytic hydrogenation of heavy oils such as shale oil |
NL275200A (en) | 1961-07-31 | |||
GB1115122A (en) * | 1965-08-23 | 1968-05-29 | Universal Oil Prod Co | Hydrotreatment of alkyl aromatic hydrocarbons |
US3488716A (en) | 1967-10-03 | 1970-01-06 | Exxon Research Engineering Co | Process for the removal of naphthenic acids from petroleum distillate fractions |
US3547585A (en) * | 1968-11-26 | 1970-12-15 | Universal Oil Prod Co | Combination of a hydrocarbon conversion process with a waste water treating process |
US3576737A (en) * | 1969-03-25 | 1971-04-27 | Chevron Res | Vanadium removal from hydrocarbons |
GB1232173A (en) * | 1969-11-18 | 1971-05-19 | ||
US3696027A (en) * | 1970-01-12 | 1972-10-03 | Chevron Res | Multi-stage desulfurization |
GB1364238A (en) * | 1970-08-04 | 1974-08-21 | Topsoe H F A | Process for the hydrodesulphurisation of heavy hydrocarbon oils |
US3712861A (en) * | 1970-10-19 | 1973-01-23 | Mobil Oil Corp | Upgrading a hydrocarbon utilizing a catalyst of metal sulfides dispersed in alumina |
US3730876A (en) * | 1970-12-18 | 1973-05-01 | A Sequeira | Production of naphthenic oils |
US3766054A (en) * | 1970-12-23 | 1973-10-16 | Mobil Oil Corp | Demetalation of hydrocarbon charge stocks |
US3684688A (en) * | 1971-01-21 | 1972-08-15 | Chevron Res | Heavy oil conversion |
US3876532A (en) * | 1973-02-27 | 1975-04-08 | Gulf Research Development Co | Method for reducing the total acid number of a middle distillate oil |
US3948759A (en) | 1973-03-28 | 1976-04-06 | Exxon Research And Engineering Company | Visbreaking a heavy hydrocarbon feedstock in a regenerable molten medium in the presence of hydrogen |
US3902991A (en) * | 1973-04-27 | 1975-09-02 | Chevron Res | Hydrodesulfurization process for the production of low-sulfur hydrocarbon mixture |
IN142203B (en) * | 1973-04-30 | 1977-06-11 | Uop Inc | |
US3960712A (en) * | 1973-04-30 | 1976-06-01 | Universal Oil Products Company | Hydrodesulfurization of asphaltene-containing black oil with a gamma-alumina composite catalyst of specified particle density |
US3846288A (en) * | 1973-07-05 | 1974-11-05 | Gulf Research Development Co | Acid number reduction of hydrocarbon fractions using a solid catalyst and methanol |
US3891541A (en) * | 1973-08-29 | 1975-06-24 | Mobil Oil Corp | Process for demetalizing and desulfurizing residual oil with hydrogen and alumina-supported catalyst |
US3931052A (en) * | 1973-08-29 | 1976-01-06 | Mobil Oil Corporation | Alumina-supported catalyst for residua demetalation and desulfurization |
US3876523A (en) * | 1973-08-29 | 1975-04-08 | Mobil Oil Corp | Catalyst for residua demetalation and desulfurization |
US3920538A (en) * | 1973-11-30 | 1975-11-18 | Shell Oil Co | Demetallation with nickel-vanadium on silica in a hydrocarbon conversion process |
JPS51122105A (en) * | 1975-04-18 | 1976-10-26 | Toa Nenryo Kogyo Kk | Process for hydrofining of hydrocarbon oil |
US4062757A (en) * | 1975-07-18 | 1977-12-13 | Gulf Research & Development Company | Residue thermal cracking process in a packed bed reactor |
US4196102A (en) * | 1975-12-09 | 1980-04-01 | Chiyoda Chemical Engineering & Construction Co., Ltd. | Catalysts for demetallization treatment of _hydrocarbons supported on sepiolite |
US4048060A (en) * | 1975-12-29 | 1977-09-13 | Exxon Research And Engineering Company | Two-stage hydrodesulfurization of oil utilizing a narrow pore size distribution catalyst |
US4067799A (en) | 1976-07-02 | 1978-01-10 | Exxon Research And Engineering Company | Hydroconversion process |
US4127470A (en) * | 1977-08-01 | 1978-11-28 | Exxon Research & Engineering Company | Hydroconversion with group IA, IIA metal compounds |
US4225421A (en) * | 1979-03-13 | 1980-09-30 | Standard Oil Company (Indiana) | Process for hydrotreating heavy hydrocarbons |
US4446244A (en) * | 1979-09-26 | 1984-05-01 | Chevron Research Company | Hydrocarbons hydroprocessing with imogolite catalyst |
US4358361A (en) * | 1979-10-09 | 1982-11-09 | Mobil Oil Corporation | Demetalation and desulfurization of oil |
JPS595011B2 (en) * | 1979-11-27 | 1984-02-02 | 千代田化工建設株式会社 | Catalyst for hydrotreating heavy hydrocarbon oil and its production method |
US4301037A (en) * | 1980-04-01 | 1981-11-17 | W. R. Grace & Co. | Extruded alumina catalyst support having controlled distribution of pore sizes |
US4306964A (en) * | 1980-09-16 | 1981-12-22 | Mobil Oil Corporation | Multi-stage process for demetalation and desulfurization of petroleum oils |
US4411824A (en) * | 1981-05-12 | 1983-10-25 | Chevron Research Company | Method of making a catalyst suitable for hydrometalation of hydrocarbonaceous feedstocks |
AU547464B2 (en) * | 1981-06-17 | 1985-10-24 | Amoco Corporation | Catalyst for hydrotreating hydrocarbon feed |
US4456699A (en) * | 1981-06-17 | 1984-06-26 | Standard Oil Company (Indiana) | Catalyst and support, and their methods of preparation |
US4549957A (en) * | 1981-06-17 | 1985-10-29 | Amoco Corporation | Hydrotreating catalyst and process |
US4447314A (en) * | 1982-05-05 | 1984-05-08 | Mobil Oil Corporation | Demetalation, desulfurization, and decarbonization of petroleum oils by hydrotreatment in a dual bed system prior to cracking |
FR2528721B1 (en) * | 1982-06-17 | 1986-02-28 | Pro Catalyse Ste Fse Prod Cata | SUPPORTED CATALYST HAVING INCREASED RESISTANCE TO POISONS AND ITS USE IN PARTICULAR FOR THE HYDROTREATMENT OF OIL FRACTIONS CONTAINING METALS |
US4405441A (en) * | 1982-09-30 | 1983-09-20 | Shell Oil Company | Process for the preparation of hydrocarbon oil distillates |
JPS59150537A (en) * | 1982-12-06 | 1984-08-28 | アモコ コーポレーション | Hydrotreating catalyst and hydrotreating of hydrocarbon |
US4886594A (en) | 1982-12-06 | 1989-12-12 | Amoco Corporation | Hydrotreating catalyst and process |
US4450068A (en) * | 1982-12-20 | 1984-05-22 | Phillips Petroleum Company | Demetallization of hydrocarbon containing feed streams |
JPS59132945A (en) * | 1983-01-21 | 1984-07-31 | Shokubai Kasei Kogyo Kk | Hydro-demetalation catalyst and use thereof |
US4592827A (en) * | 1983-01-28 | 1986-06-03 | Intevep, S.A. | Hydroconversion of heavy crudes with high metal and asphaltene content in the presence of soluble metallic compounds and water |
US4525472A (en) * | 1983-02-23 | 1985-06-25 | Intevep, S.A. | Process for catalyst preparation for the hydrodemetallization of heavy crudes and residues |
JPS6065092A (en) * | 1983-09-21 | 1985-04-13 | Res Assoc Petroleum Alternat Dev<Rapad> | Removal of metal from oil sand oil and residual oil |
US4587012A (en) * | 1983-10-31 | 1986-05-06 | Chevron Research Company | Process for upgrading hydrocarbonaceous feedstocks |
US4520128A (en) * | 1983-12-19 | 1985-05-28 | Intevep, S.A. | Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same |
US4588709A (en) * | 1983-12-19 | 1986-05-13 | Intevep, S.A. | Catalyst for removing sulfur and metal contaminants from heavy crudes and residues |
US4572778A (en) * | 1984-01-19 | 1986-02-25 | Union Oil Company Of California | Hydroprocessing with a large pore catalyst |
US4844792A (en) * | 1984-08-07 | 1989-07-04 | Union Oil Company Of California | Hydroprocessing with a specific pore sized catalyst containing non-hydrolyzable halogen |
NL8402997A (en) * | 1984-10-01 | 1986-05-01 | Unilever Nv | CATALYST MATERIAL. |
GB2167430B (en) * | 1984-11-22 | 1988-11-30 | Intevep Sa | Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content |
US4600503A (en) * | 1984-12-28 | 1986-07-15 | Mobil Oil Corporation | Process for hydrotreating residual petroleum oil |
US4729826A (en) * | 1986-02-28 | 1988-03-08 | Union Oil Company Of California | Temperature controlled catalytic demetallization of hydrocarbons |
US4738884A (en) * | 1986-03-03 | 1988-04-19 | Owens-Corning Fiberglas Corporation | Asphalt adhesives superimposed on asphalt-based roofing sheet |
US4670134A (en) * | 1986-05-02 | 1987-06-02 | Phillips Petroleum Company | Catalytic hydrofining of oil |
US4830736A (en) * | 1986-07-28 | 1989-05-16 | Chevron Research Company | Graded catalyst system for removal of calcium and sodium from a hydrocarbon feedstock |
JP2631712B2 (en) * | 1988-08-18 | 1997-07-16 | コスモ石油株式会社 | Catalyst composition for hydrotreating heavy hydrocarbon oil and hydrotreating method using the same |
US4992157A (en) * | 1988-08-29 | 1991-02-12 | Uop | Process for improving the color and color stability of hydrocarbon fraction |
JP2609301B2 (en) * | 1988-08-31 | 1997-05-14 | 工業技術院長 | Method for producing hydrotreating catalyst |
EP0367021B1 (en) * | 1988-10-19 | 1993-12-29 | Research Association For Petroleum Alternatives Development | Process for hydrogenation of heavy oil |
US5124027A (en) | 1989-07-18 | 1992-06-23 | Amoco Corporation | Multi-stage process for deasphalting resid, removing catalyst fines from decanted oil and apparatus therefor |
US4992163A (en) | 1989-12-13 | 1991-02-12 | Exxon Research And Engineering Company | Cat cracking feed preparation |
US4988434A (en) * | 1989-12-13 | 1991-01-29 | Exxon Research And Engineering Company | Removal of metallic contaminants from a hydrocarbonaceous liquid |
JPH03292395A (en) * | 1989-12-28 | 1991-12-24 | Chevron Res & Technol Co | Removal of calcium from hydrocarbon supply material |
US5053117A (en) * | 1990-07-25 | 1991-10-01 | Mobil Oil Corporation | Catalytic dewaxing |
US5851381A (en) | 1990-12-07 | 1998-12-22 | Idemitsu Kosan Co., Ltd. | Method of refining crude oil |
US5200060A (en) * | 1991-04-26 | 1993-04-06 | Amoco Corporation | Hydrotreating process using carbides and nitrides of group VIB metals |
US5215954A (en) | 1991-07-30 | 1993-06-01 | Cri International, Inc. | Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst |
US5210061A (en) * | 1991-09-24 | 1993-05-11 | Union Oil Company Of California | Resid hydroprocessing catalyst |
US5215955A (en) * | 1991-10-02 | 1993-06-01 | Chevron Research And Technology Company | Resid catalyst with high metals capacity |
JP2966985B2 (en) * | 1991-10-09 | 1999-10-25 | 出光興産株式会社 | Catalytic hydrotreating method for heavy hydrocarbon oil |
US5399259A (en) * | 1992-04-20 | 1995-03-21 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
EP0569092A1 (en) | 1992-05-05 | 1993-11-10 | Shell Internationale Researchmaatschappij B.V. | Hydrotreating process |
US5322617A (en) * | 1992-08-07 | 1994-06-21 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Energy, Mines And Resources | Upgrading oil emulsions with carbon monoxide or synthesis gas |
JPH0753968A (en) * | 1993-08-09 | 1995-02-28 | Idemitsu Kosan Co Ltd | Hydrotreatment of heavy hydrocarbon oil |
US5928601A (en) * | 1994-02-28 | 1999-07-27 | Honda Giken Kogyo Kabushiki Kaisha | Method for producing silicon nitride reaction sintered body |
NO303837B1 (en) * | 1994-08-29 | 1998-09-07 | Norske Stats Oljeselskap | Process for removing substantially naphthenic acids from a hydrocarbon oil |
JP3504984B2 (en) * | 1994-09-19 | 2004-03-08 | 日本ケッチェン株式会社 | Hydrodesulfurization demetallization catalyst for heavy hydrocarbon oil |
US5635056A (en) * | 1995-05-02 | 1997-06-03 | Exxon Research And Engineering Company | Continuous in-situ process for upgrading heavy oil using aqueous base |
US5807469A (en) * | 1995-09-27 | 1998-09-15 | Intel Corporation | Flexible continuous cathode contact circuit for electrolytic plating of C4, tab microbumps, and ultra large scale interconnects |
JP3315314B2 (en) | 1996-05-30 | 2002-08-19 | 矢崎総業株式会社 | Low insertion force connector |
JPH1060456A (en) * | 1996-08-15 | 1998-03-03 | Catalysts & Chem Ind Co Ltd | Hydrogenation treatment of heavy oil and device for hydrogenation treatment |
FR2758278B1 (en) * | 1997-01-15 | 1999-02-19 | Inst Francais Du Petrole | CATALYST COMPRISING A MIXED SULFIDE AND USE IN HYDRO-REFINING AND HYDROCONVERSION OF HYDROCARBONS |
US5744025A (en) | 1997-02-28 | 1998-04-28 | Shell Oil Company | Process for hydrotreating metal-contaminated hydrocarbonaceous feedstock |
US6162350A (en) * | 1997-07-15 | 2000-12-19 | Exxon Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901) |
US5871636A (en) | 1997-08-29 | 1999-02-16 | Exxon Research And Engineering Company | Catalytic reduction of acidity of crude oils in the absence of hydrogen |
US5897769A (en) | 1997-08-29 | 1999-04-27 | Exxon Research And Engineering Co. | Process for selectively removing lower molecular weight naphthenic acids from acidic crudes |
US5914030A (en) | 1997-08-29 | 1999-06-22 | Exxon Research And Engineering. Co. | Process for reducing total acid number of crude oil |
DK1062302T3 (en) * | 1997-08-29 | 2002-04-02 | Exxonmobil Res & Eng Co | Process for reducing total acid number in crude oil |
US5910242A (en) * | 1997-08-29 | 1999-06-08 | Exxon Research And Engineering Company | Process for reduction of total acid number in crude oil |
US5928502A (en) | 1997-08-29 | 1999-07-27 | Exxon Research And Engineering Co. | Process for reducing total acid number of crude oil |
US5928501A (en) * | 1998-02-03 | 1999-07-27 | Texaco Inc. | Process for upgrading a hydrocarbon oil |
JP2000005609A (en) * | 1998-06-26 | 2000-01-11 | Idemitsu Kosan Co Ltd | Method for regeneration of hydrotreating catalyst |
US6096192A (en) | 1998-07-14 | 2000-08-01 | Exxon Research And Engineering Co. | Producing pipelinable bitumen |
US6258258B1 (en) * | 1998-10-06 | 2001-07-10 | Exxon Research And Engineering Company | Process for treatment of petroleum acids with ammonia |
FR2787040B1 (en) * | 1998-12-10 | 2001-01-19 | Inst Francais Du Petrole | HYDROTREATMENT OF HYDROCARBON CHARGES IN A BOILING BED REACTOR |
FR2787041B1 (en) * | 1998-12-10 | 2001-01-19 | Inst Francais Du Petrole | HYDROCARBON CHARGE HYDROTREATMENT CATALYST IN A FIXED BED REACTOR |
US6218333B1 (en) | 1999-02-15 | 2001-04-17 | Shell Oil Company | Preparation of a hydrotreating catalyst |
US6554994B1 (en) * | 1999-04-13 | 2003-04-29 | Chevron U.S.A. Inc. | Upflow reactor system with layered catalyst bed for hydrotreating heavy feedstocks |
JP3824464B2 (en) * | 1999-04-28 | 2006-09-20 | 財団法人石油産業活性化センター | Method for hydrocracking heavy oils |
FR2792851B1 (en) * | 1999-04-29 | 2002-04-05 | Inst Francais Du Petrole | LOW-DISPERSE NOBLE METAL-BASED CATALYST AND USE THEREOF FOR THE CONVERSION OF HYDROCARBON CHARGES |
JP2003171671A (en) * | 2000-06-08 | 2003-06-20 | Japan Energy Corp | Method for hydrogenation refining of heavy oil |
US20020056664A1 (en) * | 2000-09-07 | 2002-05-16 | Julie Chabot | Extension of catalyst cycle length in residuum desulfurization processes |
US6547957B1 (en) * | 2000-10-17 | 2003-04-15 | Texaco, Inc. | Process for upgrading a hydrocarbon oil |
US7384537B2 (en) * | 2000-10-24 | 2008-06-10 | Jgc Corporation | Refined oil and process for producing the same |
US20020112987A1 (en) * | 2000-12-15 | 2002-08-22 | Zhiguo Hou | Slurry hydroprocessing for heavy oil upgrading using supported slurry catalysts |
US6759364B2 (en) | 2001-12-17 | 2004-07-06 | Shell Oil Company | Arsenic removal catalyst and method for making same |
GB0209222D0 (en) | 2002-04-23 | 2002-06-05 | Bp Oil Int | Purification process |
JP2003181292A (en) * | 2002-12-25 | 2003-07-02 | Chevron Research & Technology Co | Highly active catalyst for treating residual oil |
NL1027772C2 (en) * | 2003-12-19 | 2006-08-29 | Shell Int Research | Systems, methods and catalysts for producing a crude product. |
US10535462B2 (en) | 2007-04-05 | 2020-01-14 | Hans Wennerstrom | Flat winding / equal coupling common mode inductor apparatus and method of use thereof |
-
2004
- 2004-12-15 NL NL1027772A patent/NL1027772C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405568-3A patent/BRPI0405568B1/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405589-6A patent/BRPI0405589B1/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405564-0A patent/BRPI0405564B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027757A patent/NL1027757C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405795-3A patent/BRPI0405795A/en not_active Application Discontinuation
- 2004-12-15 NL NL1027755A patent/NL1027755C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405588-8A patent/BRPI0405588A/en not_active Application Discontinuation
- 2004-12-15 BR BRPI0405535-7A patent/BRPI0405535B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027771A patent/NL1027771C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405566-7A patent/BRPI0405566A/en not_active IP Right Cessation
- 2004-12-15 NL NL1027761A patent/NL1027761C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405570-5A patent/BRPI0405570B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027769A patent/NL1027769C2/en not_active IP Right Cessation
- 2004-12-15 NL NL1027754A patent/NL1027754C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405565-9A patent/BRPI0405565A/en not_active IP Right Cessation
- 2004-12-15 NL NL1027760A patent/NL1027760C2/en not_active IP Right Cessation
- 2004-12-15 NL NL1027752A patent/NL1027752C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405586-1A patent/BRPI0405586A/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405739-2A patent/BRPI0405739B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027751A patent/NL1027751C2/en not_active IP Right Cessation
- 2004-12-15 NL NL1027762A patent/NL1027762C2/en not_active IP Right Cessation
- 2004-12-15 NL NL1027753A patent/NL1027753C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405537-3A patent/BRPI0405537B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027756A patent/NL1027756C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405572-1A patent/BRPI0405572A/en not_active Application Discontinuation
- 2004-12-15 NL NL1027768A patent/NL1027768C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405576-4A patent/BRPI0405576A/en not_active IP Right Cessation
- 2004-12-15 NL NL1027770A patent/NL1027770C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405843-7A patent/BRPI0405843B1/en not_active IP Right Cessation
- 2004-12-15 BR BR0405584-5A patent/BRPI0405584A/en not_active Application Discontinuation
- 2004-12-15 NL NL1027767A patent/NL1027767C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405567-5A patent/BRPI0405567B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027750A patent/NL1027750C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405579-9A patent/BRPI0405579A/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405720-1A patent/BRPI0405720B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027766A patent/NL1027766C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405578-0A patent/BRPI0405578B1/en not_active IP Right Cessation
- 2004-12-15 BR BR0405571-3A patent/BRPI0405571A/en not_active Application Discontinuation
- 2004-12-15 BR BRPI0405738-4A patent/BRPI0405738B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027764A patent/NL1027764C2/en not_active IP Right Cessation
- 2004-12-15 NL NL1027763A patent/NL1027763C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405722-8A patent/BRPI0405722A/en not_active IP Right Cessation
- 2004-12-15 NL NL1027758A patent/NL1027758C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405582-9A patent/BRPI0405582B1/en not_active IP Right Cessation
- 2004-12-15 NL NL1027765A patent/NL1027765C2/en not_active IP Right Cessation
- 2004-12-15 BR BR0405587-0A patent/BRPI0405587A/en not_active Application Discontinuation
- 2004-12-15 NL NL1027759A patent/NL1027759C2/en not_active IP Right Cessation
- 2004-12-15 BR BRPI0405577-2A patent/BRPI0405577B1/en not_active IP Right Cessation
- 2004-12-16 CA CA2549088A patent/CA2549088C/en not_active Expired - Fee Related
- 2004-12-16 CA CA002549246A patent/CA2549246A1/en not_active Abandoned
- 2004-12-16 EP EP04814412A patent/EP1702055A2/en not_active Withdrawn
- 2004-12-16 EP EP04820781A patent/EP1702037A2/en not_active Withdrawn
- 2004-12-16 JP JP2006545528A patent/JP2007515523A/en active Pending
- 2004-12-16 CA CA002551098A patent/CA2551098A1/en not_active Abandoned
- 2004-12-16 CA CA002549411A patent/CA2549411A1/en not_active Abandoned
- 2004-12-16 JP JP2006545420A patent/JP2007514830A/en active Pending
- 2004-12-16 AU AU2004312365A patent/AU2004312365A1/en not_active Abandoned
- 2004-12-16 JP JP2006545526A patent/JP2007514849A/en active Pending
- 2004-12-16 EP EP04814508A patent/EP1702033A2/en not_active Ceased
- 2004-12-16 TW TW093139067A patent/TW200530388A/en unknown
- 2004-12-16 EP EP04814783A patent/EP1709141A2/en not_active Withdrawn
- 2004-12-16 CA CA2549410A patent/CA2549410C/en not_active Expired - Fee Related
- 2004-12-16 CA CA2551101A patent/CA2551101C/en not_active Expired - Fee Related
- 2004-12-16 TW TW093139063A patent/TW200535226A/en unknown
- 2004-12-16 EP EP04814509A patent/EP1702040A2/en not_active Withdrawn
- 2004-12-16 JP JP2006545524A patent/JP2007514847A/en active Pending
- 2004-12-16 MX MXPA06006806A patent/MXPA06006806A/en unknown
- 2004-12-16 WO PCT/US2004/042432 patent/WO2005063931A2/en active Application Filing
- 2004-12-16 EP EP04814562A patent/EP1702022A2/en not_active Withdrawn
- 2004-12-16 JP JP2006545472A patent/JP5306598B2/en not_active Expired - Fee Related
- 2004-12-16 TW TW093139065A patent/TW200535228A/en unknown
- 2004-12-16 KR KR1020067014561A patent/KR20070032625A/en not_active Application Discontinuation
- 2004-12-16 WO PCT/US2004/042426 patent/WO2005061669A2/en active Application Filing
- 2004-12-16 EP EP04814796A patent/EP1702043A2/en not_active Withdrawn
- 2004-12-16 SG SG200717847-8A patent/SG138599A1/en unknown
- 2004-12-16 EP EP04814586A patent/EP1702034A2/en not_active Ceased
- 2004-12-16 WO PCT/US2004/042333 patent/WO2005063925A2/en active Application Filing
- 2004-12-16 EP EP04814413A patent/EP1704211A2/en not_active Withdrawn
- 2004-12-16 SG SG200809467-4A patent/SG149049A1/en unknown
- 2004-12-16 WO PCT/US2004/042139 patent/WO2005066307A2/en active Application Filing
- 2004-12-16 TW TW093139053A patent/TWI452127B/en not_active IP Right Cessation
- 2004-12-16 AU AU2004303873A patent/AU2004303873A1/en not_active Abandoned
- 2004-12-16 AU AU2004303874A patent/AU2004303874B2/en not_active Ceased
- 2004-12-16 KR KR1020067014549A patent/KR20060130114A/en not_active Application Discontinuation
- 2004-12-16 EP EP04817041A patent/EP1704205A2/en not_active Withdrawn
- 2004-12-16 KR KR1020067014558A patent/KR20060130119A/en not_active Application Discontinuation
- 2004-12-16 WO PCT/US2004/042343 patent/WO2005063927A2/en active Application Filing
- 2004-12-16 EP EP04814336A patent/EP1702039A2/en not_active Withdrawn
- 2004-12-16 JP JP2006545474A patent/JP2007514843A/en active Pending
- 2004-12-16 TW TW093139051A patent/TW200530386A/en unknown
- 2004-12-16 EP EP04814591A patent/EP1711583A2/en not_active Withdrawn
- 2004-12-16 WO PCT/US2004/042121 patent/WO2005066303A2/en active Application Filing
- 2004-12-16 MX MXPA06006794A patent/MXPA06006794A/en unknown
- 2004-12-16 EP EP04814588A patent/EP1711582A2/en not_active Withdrawn
- 2004-12-16 WO PCT/US2004/042309 patent/WO2005061666A2/en active Application Filing
- 2004-12-16 CA CA002549887A patent/CA2549887A1/en not_active Abandoned
- 2004-12-16 CA CA2552461A patent/CA2552461C/en not_active Expired - Fee Related
- 2004-12-16 MX MXPA06006788A patent/MXPA06006788A/en unknown
- 2004-12-16 JP JP2006545455A patent/JP4891090B2/en not_active Expired - Fee Related
- 2004-12-16 AU AU2004311743A patent/AU2004311743B2/en not_active Expired - Fee Related
- 2004-12-16 JP JP2006545421A patent/JP2007518847A/en active Pending
- 2004-12-16 WO PCT/US2004/042399 patent/WO2005063929A2/en active Search and Examination
- 2004-12-16 CA CA2549535A patent/CA2549535C/en not_active Expired - Fee Related
- 2004-12-16 JP JP2006545520A patent/JP5179059B2/en not_active Expired - Fee Related
- 2004-12-16 JP JP2006545529A patent/JP2007514850A/en active Pending
- 2004-12-16 TW TW093139054A patent/TW200535223A/en unknown
- 2004-12-16 TW TW093139059A patent/TW200535225A/en unknown
- 2004-12-16 WO PCT/US2004/042640 patent/WO2005063933A2/en active Application Filing
- 2004-12-16 JP JP2006545470A patent/JP2007514840A/en active Pending
- 2004-12-16 JP JP2006545381A patent/JP2007514821A/en active Pending
- 2004-12-16 CA CA2551091A patent/CA2551091C/en not_active Expired - Fee Related
- 2004-12-16 WO PCT/US2004/042225 patent/WO2005066311A2/en active Search and Examination
- 2004-12-16 EP EP04814797A patent/EP1702044A2/en not_active Ceased
- 2004-12-16 KR KR1020067014545A patent/KR20060130110A/en not_active Application Discontinuation
- 2004-12-16 EP EP04814488A patent/EP1713886A2/en not_active Withdrawn
- 2004-12-16 AU AU2004309334A patent/AU2004309334A1/en not_active Abandoned
- 2004-12-16 CA CA2549258A patent/CA2549258C/en not_active Expired - Fee Related
- 2004-12-16 WO PCT/US2004/042088 patent/WO2005066301A2/en active Application Filing
- 2004-12-16 WO PCT/US2004/042430 patent/WO2005063939A2/en active Search and Examination
- 2004-12-16 CA CA2549566A patent/CA2549566C/en not_active Expired - Fee Related
- 2004-12-16 CA CA002562759A patent/CA2562759A1/en not_active Abandoned
- 2004-12-16 EP EP04814519A patent/EP1704208A2/en not_active Withdrawn
- 2004-12-16 AU AU2004309330A patent/AU2004309330C1/en not_active Ceased
- 2004-12-16 CA CA2652088A patent/CA2652088C/en not_active Expired - Fee Related
- 2004-12-16 EP EP04814514A patent/EP1713887A2/en not_active Ceased
- 2004-12-16 JP JP2006545444A patent/JP2007514835A/en active Pending
- 2004-12-16 CA CA2549427A patent/CA2549427C/en not_active Expired - Fee Related
- 2004-12-16 WO PCT/US2004/042651 patent/WO2005063934A2/en active Application Filing
- 2004-12-16 WO PCT/US2004/042427 patent/WO2005063930A2/en active Application Filing
- 2004-12-16 CA CA002547360A patent/CA2547360A1/en not_active Abandoned
- 2004-12-16 WO PCT/US2004/042647 patent/WO2005061678A2/en active Application Filing
- 2004-12-16 WO PCT/US2004/042656 patent/WO2005063938A2/en active Application Filing
- 2004-12-16 WO PCT/US2004/042224 patent/WO2005066310A2/en active Application Filing
- 2004-12-16 SG SG200809503-6A patent/SG149055A1/en unknown
- 2004-12-16 AU AU2004312379A patent/AU2004312379A1/en not_active Abandoned
- 2004-12-16 TW TW093139056A patent/TW200533737A/en unknown
- 2004-12-16 JP JP2006545471A patent/JP2007514841A/en active Pending
- 2004-12-16 TW TW093139066A patent/TW200602481A/en unknown
- 2004-12-16 TW TW093139055A patent/TWI440707B/en not_active IP Right Cessation
- 2004-12-16 EP EP04814324A patent/EP1702031A2/en not_active Withdrawn
- 2004-12-16 EP EP04814585A patent/EP1702047A2/en not_active Ceased
- 2004-12-16 EP EP04814334A patent/EP1704206A2/en not_active Withdrawn
- 2004-12-16 JP JP2006545384A patent/JP2007514824A/en active Pending
- 2004-12-16 WO PCT/US2004/042310 patent/WO2005061667A2/en active Application Filing
- 2004-12-16 CA CA2549873A patent/CA2549873C/en not_active Expired - Fee Related
- 2004-12-16 EP EP04814589A patent/EP1702035A2/en not_active Ceased
- 2004-12-16 JP JP2006545450A patent/JP2007517931A/en active Pending
- 2004-12-16 CA CA2549255A patent/CA2549255C/en not_active Expired - Fee Related
- 2004-12-16 WO PCT/US2004/042125 patent/WO2005065189A2/en active Application Filing
- 2004-12-16 KR KR1020067014548A patent/KR20060130113A/en not_active Application Discontinuation
- 2004-12-16 JP JP2006545453A patent/JP2007514838A/en active Pending
- 2004-12-16 CA CA2552466A patent/CA2552466C/en not_active Expired - Fee Related
- 2004-12-16 JP JP2006545464A patent/JP2007522269A/en active Pending
- 2004-12-16 WO PCT/US2004/042137 patent/WO2005066306A2/en active Application Filing
- 2004-12-16 WO PCT/US2004/042653 patent/WO2005063935A2/en active Search and Examination
- 2004-12-16 EP EP04814292A patent/EP1702030A2/en not_active Ceased
- 2004-12-16 WO PCT/US2004/042241 patent/WO2005063924A2/en active Application Filing
- 2004-12-16 EP EP04814428A patent/EP1702032A2/en not_active Withdrawn
- 2004-12-16 TW TW093139062A patent/TW200530387A/en unknown
- 2004-12-16 CA CA2549251A patent/CA2549251C/en not_active Expired - Fee Related
- 2004-12-16 AU AU2004309335A patent/AU2004309335B2/en not_active Ceased
- 2004-12-16 WO PCT/US2004/042332 patent/WO2005061668A2/en active Application Filing
- 2004-12-16 CA CA2549886A patent/CA2549886C/en not_active Expired - Fee Related
- 2004-12-16 AU AU2004303869A patent/AU2004303869A1/en not_active Abandoned
- 2004-12-16 JP JP2006545522A patent/JP2007514845A/en active Pending
- 2004-12-16 TW TW093139064A patent/TW200535227A/en unknown
- 2004-12-16 CA CA2549875A patent/CA2549875C/en not_active Expired - Fee Related
- 2004-12-16 KR KR1020067014556A patent/KR20060130118A/en not_active Application Discontinuation
- 2004-12-16 JP JP2006545473A patent/JP5107580B2/en not_active Expired - Fee Related
- 2004-12-16 AU AU2004309354A patent/AU2004309354B2/en not_active Ceased
- 2004-12-16 JP JP2006545425A patent/JP2007514831A/en active Pending
- 2004-12-16 EP EP04814794A patent/EP1702042A2/en not_active Withdrawn
- 2004-12-16 AU AU2004312380A patent/AU2004312380A1/en not_active Abandoned
- 2004-12-16 WO PCT/US2004/042429 patent/WO2005061670A2/en active Application Filing
- 2004-12-16 AU AU2004303870A patent/AU2004303870A1/en not_active Abandoned
- 2004-12-16 JP JP2006545445A patent/JP2007514836A/en active Pending
- 2004-12-16 JP JP2006545389A patent/JP2007514826A/en active Pending
- 2004-12-16 EP EP04814792A patent/EP1702036A2/en not_active Withdrawn
- 2004-12-16 JP JP2006545390A patent/JP2007514827A/en active Pending
- 2004-12-16 WO PCT/US2004/042655 patent/WO2005063937A2/en active Application Filing
- 2004-12-16 CA CA2551096A patent/CA2551096C/en not_active Expired - Fee Related
- 2004-12-16 KR KR1020067014555A patent/KR101229770B1/en not_active IP Right Cessation
- 2004-12-16 CA CA2548914A patent/CA2548914C/en not_active Expired - Fee Related
- 2004-12-16 MX MXPA06006795A patent/MXPA06006795A/en active IP Right Grant
- 2004-12-16 AU AU2004309349A patent/AU2004309349B2/en not_active Ceased
- 2004-12-16 CA CA2549430A patent/CA2549430C/en not_active Expired - Fee Related
- 2004-12-16 TW TW093139049A patent/TW200535221A/en unknown
- 2004-12-16 AU AU2004312367A patent/AU2004312367A1/en not_active Abandoned
- 2004-12-16 TW TW093139061A patent/TW200532010A/en unknown
- 2004-12-16 CA CA2551105A patent/CA2551105C/en not_active Expired - Fee Related
- 2004-12-16 JP JP2006545449A patent/JP2007514837A/en active Pending
- 2004-12-16 EP EP04814320A patent/EP1704204A2/en not_active Withdrawn
- 2004-12-16 WO PCT/US2004/042338 patent/WO2005063926A2/en active Application Filing
- 2004-12-16 JP JP2006545369A patent/JP2007514820A/en active Pending
-
2009
- 2009-06-09 AU AU2009202290A patent/AU2009202290B2/en not_active Ceased