JP2007512681A - 有機半導体のn‐ドーピング - Google Patents
有機半導体のn‐ドーピング Download PDFInfo
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- JP2007512681A JP2007512681A JP2006529630A JP2006529630A JP2007512681A JP 2007512681 A JP2007512681 A JP 2007512681A JP 2006529630 A JP2006529630 A JP 2006529630A JP 2006529630 A JP2006529630 A JP 2006529630A JP 2007512681 A JP2007512681 A JP 2007512681A
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/341—Transition metal complexes, e.g. Ru(II)polypyridine complexes
- H10K85/344—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/30—Doping active layers, e.g. electron transporting layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
- H10K85/211—Fullerenes, e.g. C60
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/311—Phthalocyanine
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- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Theoretical Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mathematical Physics (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Photovoltaic Devices (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Electroluminescent Light Sources (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (22)
- ドーピング剤でドープすることによる高い電荷キャリア密度および有効な電荷キャリア移動度を有したドープド有機半導体材料の製造方法であって、
ドーピング剤が第一ステップで実質的に電気結晶化により製造され、該ドーピング剤が低い酸化電位を有する有機化合物の群から選択され、有機半導体材料が第二ステップにおいて該ドーピング剤でドープされる方法。 - 有機ドーピング剤の塩が電気結晶化用の遊離体として用いられる、請求項1に記載の方法。
- 一または多荷電カチオンが有機ドーピング剤の遊離体塩で用いられる、請求項2に記載の方法。
- 未荷電有機化合物がドーピング剤として用いられる、請求項1〜3のいずれか一項に記載の方法。
- ドーピング剤が作用電極で晶出され、その後に作用電極で回収される、請求項1〜4のいずれか一項に記載の方法。
- ドーピング剤が、電気結晶化に際して作用電極で回収後に、中間ステップで精製される、請求項5に記載の方法。
- NHEに対して0V未満の酸化電位を有する化合物が、ドーピング剤として用いられる、請求項1〜6のいずれか一項に記載の方法。
- NHEに対して−0.5V〜NHEに対して−2.5Vの範囲内で酸化電位を有する化合物が、ドーピング剤として用いられる、請求項7に記載の方法。
- ビス(2,2′‐ターピリジン)ルテニウムがドーピング剤として用いられる、請求項1〜8のいずれか一項に記載の方法。
- トリス(4,4′,5,5′‐テトラメチル‐2,2′‐ビピリジン)クロムがドーピング剤として用いられる、請求項1〜8のいずれか一項に記載の方法。
- 請求項1〜10に記載された方法により製造された、高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料。
- 半導体材料がビス(2,2′‐ターピリジン)ルテニウムでドープされている、請求項11に記載の高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料。
- 半導体材料がトリス(4,4′,5,5′‐テトラメチル‐2,2′‐ビピリジン)クロムでドープされている、請求項11に記載の高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料。
- 半導体材料のマトリックスがフラーレンを含有している、請求項11〜13のいずれか一項に記載の高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料。
- 半導体材料のマトリックスがフタロシアニン亜鉛を含有している、請求項11〜14のいずれか一項に記載の高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料。
- 半導体材料が室温で約10−1S/cmの導電率を有し、半導体材料のマトリックスがフラーレンを含有し、半導体材料がビス(2,2′‐ターピリジン)ルテニウムでドープされている、請求項11に記載の高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料。
- 半導体材料が室温で約10−6S/cmの導電率を有し、半導体材料のマトリックスがフタロシアニン亜鉛を含有し、半導体材料がビス(2,2′‐ターピリジン)ルテニウムでドープされている、請求項11に記載の高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料。
- ダイオードが請求項11〜17のいずれか一項に記載されたドープド有機半導体材料を含んでなる、高い電荷キャリア密度および有効な電荷キャリア移動度を有するドープド有機半導体材料からなるダイオード。
- ダイオードが金属‐アイソレーター‐n‐ドープド半導体(min)である、請求項18に記載のダイオード。
- ダイオードがp‐ドープド半導体‐アイソレーター‐n‐ドープド半導体(pin)である、請求項19に記載のダイオード。
- ダイオードが少くとも105の整流比を有している、請求項18〜20のいずれか一項に記載のダイオード。
- ダイオードが約0.8Vの内部電圧を有している、請求項18〜21のいずれか一項に記載のダイオード。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10347856A DE10347856B8 (de) | 2003-10-10 | 2003-10-10 | Halbleiterdotierung |
DE10347856.6 | 2003-10-10 | ||
PCT/DE2004/002247 WO2005036667A1 (de) | 2003-10-10 | 2004-10-08 | N- dotierung von organischen halbleitern |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007512681A true JP2007512681A (ja) | 2007-05-17 |
JP5089983B2 JP5089983B2 (ja) | 2012-12-05 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2006529630A Active JP5089983B2 (ja) | 2003-10-10 | 2004-10-08 | 有機半導体のn‐ドーピング |
Country Status (5)
Country | Link |
---|---|
US (1) | US20070278479A1 (ja) |
JP (1) | JP5089983B2 (ja) |
DE (1) | DE10347856B8 (ja) |
TW (1) | TWI265649B (ja) |
WO (1) | WO2005036667A1 (ja) |
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JP2010530626A (ja) * | 2007-06-20 | 2010-09-09 | シーメンス アクチエンゲゼルシヤフト | 半導体材料及び有機整流ダイオード |
JP2014053383A (ja) * | 2012-09-05 | 2014-03-20 | Konica Minolta Inc | タンデム型の有機光電変換素子およびこれを用いた太陽電池 |
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JP2008509565A (ja) | 2004-08-13 | 2008-03-27 | ノヴァレッド・アクチエンゲゼルシャフト | 発光成分用積層体 |
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ATE381117T1 (de) | 2005-04-13 | 2007-12-15 | Novaled Ag | Anordnung für eine organische leuchtdiode vom pin-typ und verfahren zum herstellen |
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EP1804308B1 (en) * | 2005-12-23 | 2012-04-04 | Novaled AG | An organic light emitting device with a plurality of organic electroluminescent units stacked upon each other |
DE602006001930D1 (de) | 2005-12-23 | 2008-09-04 | Novaled Ag | tur von organischen Schichten |
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EP2008318B1 (en) | 2006-03-21 | 2013-02-13 | Novaled AG | Method for preparing doped organic semiconductor materials |
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DE102007028238A1 (de) * | 2007-06-20 | 2008-12-24 | Osram Opto Semiconductors Gmbh | Verwendung eines Metallkomplexes als p-Dotand für ein organisches halbleitendes Matrixmaterial, organisches Halbleitermaterial und organische Leuchtdiode |
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DE102007037905B4 (de) * | 2007-08-10 | 2011-02-24 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Dotiertes Halbleitermaterial und dessen Verwendung |
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JP2002043063A (ja) * | 2000-06-30 | 2002-02-08 | Xerox Corp | 有機発光素子 |
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AU2002323418A1 (en) * | 2002-04-08 | 2003-10-27 | The University Of Southern California | Doped organic carrier transport materials |
-
2003
- 2003-10-10 DE DE10347856A patent/DE10347856B8/de not_active Expired - Lifetime
-
2004
- 2004-10-08 US US10/595,319 patent/US20070278479A1/en not_active Abandoned
- 2004-10-08 JP JP2006529630A patent/JP5089983B2/ja active Active
- 2004-10-08 WO PCT/DE2004/002247 patent/WO2005036667A1/de active Application Filing
- 2004-10-08 TW TW093130645A patent/TWI265649B/zh active
Patent Citations (2)
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JP2001006878A (ja) * | 1999-06-22 | 2001-01-12 | Matsushita Electric Ind Co Ltd | 薄膜el素子およびその駆動方法 |
JP2002043063A (ja) * | 2000-06-30 | 2002-02-08 | Xerox Corp | 有機発光素子 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010530626A (ja) * | 2007-06-20 | 2010-09-09 | シーメンス アクチエンゲゼルシヤフト | 半導体材料及び有機整流ダイオード |
KR101507372B1 (ko) | 2007-06-20 | 2015-03-31 | 지멘스 악티엔게젤샤프트 | 반도체 물질 및 유기 정류기 다이오드 |
TWI483440B (zh) * | 2007-06-20 | 2015-05-01 | Siemens Ag | 半導體材料及有機整流二極體 |
JP2014053383A (ja) * | 2012-09-05 | 2014-03-20 | Konica Minolta Inc | タンデム型の有機光電変換素子およびこれを用いた太陽電池 |
Also Published As
Publication number | Publication date |
---|---|
DE10347856B8 (de) | 2006-10-19 |
WO2005036667A1 (de) | 2005-04-21 |
TW200514289A (en) | 2005-04-16 |
JP5089983B2 (ja) | 2012-12-05 |
DE10347856B4 (de) | 2006-07-06 |
US20070278479A1 (en) | 2007-12-06 |
DE10347856A1 (de) | 2005-06-02 |
TWI265649B (en) | 2006-11-01 |
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