JP2007508457A - 金属表面をリン酸塩処理するための電解法及びそれによりリン酸塩処理された金属層 - Google Patents
金属表面をリン酸塩処理するための電解法及びそれによりリン酸塩処理された金属層 Download PDFInfo
- Publication number
- JP2007508457A JP2007508457A JP2006534745A JP2006534745A JP2007508457A JP 2007508457 A JP2007508457 A JP 2007508457A JP 2006534745 A JP2006534745 A JP 2006534745A JP 2006534745 A JP2006534745 A JP 2006534745A JP 2007508457 A JP2007508457 A JP 2007508457A
- Authority
- JP
- Japan
- Prior art keywords
- zinc
- ions
- layer
- range
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 238000000034 method Methods 0.000 title claims abstract description 40
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 24
- 239000002184 metal Substances 0.000 title claims abstract description 24
- 239000011701 zinc Substances 0.000 claims abstract description 29
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 24
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003792 electrolyte Substances 0.000 claims abstract description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 8
- 238000000151 deposition Methods 0.000 claims abstract description 6
- 230000008021 deposition Effects 0.000 claims abstract description 6
- 230000002378 acidificating effect Effects 0.000 claims abstract description 5
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- 238000004070 electrodeposition Methods 0.000 claims abstract description 3
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 14
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 13
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 9
- 238000005868 electrolysis reaction Methods 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 150000002500 ions Chemical class 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- -1 nitro, peroxy compound Chemical class 0.000 claims description 4
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 229910000906 Bronze Inorganic materials 0.000 claims description 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims description 2
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims description 2
- 239000010974 bronze Substances 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 239000002105 nanoparticle Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 25
- 238000005260 corrosion Methods 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 12
- 229940077935 zinc phosphate Drugs 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000010953 base metal Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000000576 coating method Methods 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229910000851 Alloy steel Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000005536 corrosion prevention Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DHCLVCXQIBBOPH-UHFFFAOYSA-N Glycerol 2-phosphate Chemical compound OCC(CO)OP(O)(O)=O DHCLVCXQIBBOPH-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 229940046257 glyceryl phosphate Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- SPDJAIKMJHJYAV-UHFFFAOYSA-H trizinc;diphosphate;tetrahydrate Chemical compound O.O.O.O.[Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O SPDJAIKMJHJYAV-UHFFFAOYSA-H 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/36—Phosphatising
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemical Treatment Of Metals (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10348251A DE10348251A1 (de) | 2003-10-16 | 2003-10-16 | Elektrolytisches Verfahren zum Phosphatieren von Metalloberflächen und damit phosphatierte Metallschicht |
| PCT/EP2004/052269 WO2005038095A2 (de) | 2003-10-16 | 2004-09-22 | Elektrolytisches verfahren zum phosphatieren von metalloberflächen und damit phosphatierte metallschicht |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2007508457A true JP2007508457A (ja) | 2007-04-05 |
Family
ID=34428451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006534745A Withdrawn JP2007508457A (ja) | 2003-10-16 | 2004-09-22 | 金属表面をリン酸塩処理するための電解法及びそれによりリン酸塩処理された金属層 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20070295608A1 (zh) |
| EP (1) | EP1675975A2 (zh) |
| JP (1) | JP2007508457A (zh) |
| CN (1) | CN1867704B (zh) |
| BR (1) | BRPI0415520A (zh) |
| DE (1) | DE10348251A1 (zh) |
| TR (1) | TR200601814T1 (zh) |
| WO (1) | WO2005038095A2 (zh) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006035974A1 (de) * | 2006-08-02 | 2008-02-07 | Robert Bosch Gmbh | Verfahren zur Phosphatierung einer Metallschicht |
| WO2009154753A2 (en) * | 2008-06-18 | 2009-12-23 | Massachusetts Institute Of Technology | Catalytic materials, electrodes, and systems for water electrolysis and other electrochemical techniques |
| CN101643928B (zh) * | 2009-09-09 | 2011-01-05 | 重庆科技学院 | 镁合金表面阴极电沉积磷酸盐/金属复合膜的方法 |
| DE102010030465B4 (de) | 2010-06-24 | 2023-12-07 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Herstellen eines Blechformteils aus einem höherfesten Stahlblechmaterial mit einer elektrolytisch aufgebrachten Zink-Nickel-Beschichtung |
| DE102011100974A1 (de) * | 2011-05-09 | 2012-11-15 | Knorr-Bremse Systeme für Schienenfahrzeuge GmbH | Schienenrad und Verfahren zur Herstellung eines Schienenrades |
| CN102212864A (zh) * | 2011-06-10 | 2011-10-12 | 沈阳理工大学 | 修饰电解磷化膜的方法 |
| US9393759B2 (en) * | 2013-10-24 | 2016-07-19 | General Electric Company | Metal laminate structures with systems and methods for treating |
| DE102016100245A1 (de) | 2016-01-08 | 2017-07-13 | Staku Anlagenbau Gmbh | Selbstschmierende elektrolytisch abgeschiedene Phosphatierungsbeschichtung |
| CN105951155B (zh) * | 2016-06-01 | 2017-12-29 | 中钢集团郑州金属制品研究院有限公司 | 一种钢丝在线双磷化方法及其连续生产设备 |
| CN107630243B (zh) * | 2017-10-16 | 2019-07-02 | 浙江五源科技股份有限公司 | 一种复合磷化膜的电解制备方法 |
| CN114824263B (zh) * | 2021-01-29 | 2024-03-19 | 中南大学 | 一种Zn@Zn-E复合负极及其制备和在水系锌离子电池中的应用 |
| CN114883560B (zh) * | 2021-02-05 | 2024-03-19 | 中南大学 | 一种三维集流体/Zn/Zn-E复合负极及其制备和在水系锌离子电池中的应用 |
| CN114737179B (zh) * | 2022-05-05 | 2024-05-24 | 东南大学 | 一种高温合金耐热磷化膜、其制备方法及应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2540314A (en) * | 1947-07-24 | 1951-02-06 | Parker Rust Proof Co | Process and compositions for applying phosphate coatings |
| GB1041761A (en) * | 1964-08-13 | 1966-09-07 | Pyrene Co Ltd | Improvements in the coating of metals |
| US3449229A (en) * | 1966-08-08 | 1969-06-10 | Hooker Chemical Corp | Electrophoretic deposition on zinc enriched metal surface |
| JP2534280B2 (ja) * | 1987-02-05 | 1996-09-11 | 日本パーカライジング株式会社 | 亜鉛系複合めっき金属材料およびめっき方法 |
| US5232523A (en) * | 1989-03-02 | 1993-08-03 | Nippon Paint Co., Ltd. | Phosphate coatings for metal surfaces |
| JPH0336296A (ja) * | 1989-06-29 | 1991-02-15 | Nippon Parkerizing Co Ltd | ステンレス鋼の表面処理方法 |
| JPH0436498A (ja) * | 1990-06-01 | 1992-02-06 | Nippon Parkerizing Co Ltd | 鉄鋼線材の表面処理方法 |
| US5645706A (en) * | 1992-04-30 | 1997-07-08 | Nippondenso Co., Ltd. | Phosphate chemical treatment method |
| JP2000144494A (ja) * | 1998-09-11 | 2000-05-26 | Nippon Parkerizing Co Ltd | 冷間圧造用の潤滑皮膜を形成する方法 |
| JP2000160394A (ja) * | 1998-12-01 | 2000-06-13 | Nippon Parkerizing Co Ltd | 鉄系金属材料の短時間りん酸塩処理方法 |
| JP4870872B2 (ja) * | 2001-02-23 | 2012-02-08 | 株式会社キリウ | 車両用ブレーキ装置の回転ブレーキ部材およびその防錆処理方法 |
-
2003
- 2003-10-16 DE DE10348251A patent/DE10348251A1/de not_active Withdrawn
-
2004
- 2004-09-22 EP EP04787187A patent/EP1675975A2/de not_active Withdrawn
- 2004-09-22 BR BRPI0415520-3A patent/BRPI0415520A/pt not_active Application Discontinuation
- 2004-09-22 WO PCT/EP2004/052269 patent/WO2005038095A2/de active Application Filing
- 2004-09-22 JP JP2006534745A patent/JP2007508457A/ja not_active Withdrawn
- 2004-09-22 TR TR2006/01814T patent/TR200601814T1/xx unknown
- 2004-09-22 CN CN200480030171.3A patent/CN1867704B/zh not_active Expired - Fee Related
- 2004-09-22 US US10/575,907 patent/US20070295608A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0415520A (pt) | 2006-12-26 |
| WO2005038095A2 (de) | 2005-04-28 |
| CN1867704B (zh) | 2012-03-14 |
| DE10348251A1 (de) | 2005-05-12 |
| TR200601814T1 (tr) | 2007-01-22 |
| CN1867704A (zh) | 2006-11-22 |
| EP1675975A2 (de) | 2006-07-05 |
| WO2005038095A3 (de) | 2005-07-14 |
| US20070295608A1 (en) | 2007-12-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20080318 |