JP2007500277A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2007500277A5 JP2007500277A5 JP2006532987A JP2006532987A JP2007500277A5 JP 2007500277 A5 JP2007500277 A5 JP 2007500277A5 JP 2006532987 A JP2006532987 A JP 2006532987A JP 2006532987 A JP2006532987 A JP 2006532987A JP 2007500277 A5 JP2007500277 A5 JP 2007500277A5
- Authority
- JP
- Japan
- Prior art keywords
- olefin
- reaction mixture
- polyolefin resin
- group
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001336 alkenes Chemical class 0.000 claims description 75
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 73
- 238000000034 method Methods 0.000 claims description 34
- 239000011541 reaction mixture Substances 0.000 claims description 30
- 239000003054 catalyst Substances 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 27
- 229920005672 polyolefin resin Polymers 0.000 claims description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 16
- 239000005977 Ethylene Substances 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 229910052720 vanadium Inorganic materials 0.000 claims description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004711 α-olefin Substances 0.000 claims description 10
- 239000003085 diluting agent Substances 0.000 claims description 9
- 239000003607 modifier Substances 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- RWDBMHZWXLUGIB-UHFFFAOYSA-N [C].[Mg] Chemical compound [C].[Mg] RWDBMHZWXLUGIB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 150000003682 vanadium compounds Chemical class 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims 16
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims 16
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 16
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims 16
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 12
- 239000000203 mixture Substances 0.000 claims 9
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 6
- 238000006116 polymerization reaction Methods 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 230000015572 biosynthetic process Effects 0.000 claims 4
- 229920001903 high density polyethylene Polymers 0.000 claims 3
- 239000004700 high-density polyethylene Substances 0.000 claims 3
- 229920000092 linear low density polyethylene Polymers 0.000 claims 3
- 239000004707 linear low-density polyethylene Substances 0.000 claims 3
- 239000002952 polymeric resin Substances 0.000 claims 3
- 229920003002 synthetic resin Polymers 0.000 claims 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- -1 ethylene, propylene, 1-butene Chemical class 0.000 claims 2
- 230000000977 initiatory effect Effects 0.000 claims 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/457,769 US20040249093A1 (en) | 2003-06-09 | 2003-06-09 | Polyolefins with high levels of long chain branching |
| PCT/US2004/014850 WO2005000919A1 (en) | 2003-06-09 | 2004-05-12 | Polyolefins with high levels of long chain branching |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007500277A JP2007500277A (ja) | 2007-01-11 |
| JP2007500277A5 true JP2007500277A5 (enExample) | 2007-05-24 |
Family
ID=33490392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006532987A Pending JP2007500277A (ja) | 2003-06-09 | 2004-05-12 | 高レベルの長鎖分岐を有するポリオレフィン |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20040249093A1 (enExample) |
| EP (1) | EP1631600B1 (enExample) |
| JP (1) | JP2007500277A (enExample) |
| KR (1) | KR20060028687A (enExample) |
| CN (1) | CN100366641C (enExample) |
| AT (1) | ATE414111T1 (enExample) |
| CA (1) | CA2528502A1 (enExample) |
| DE (1) | DE602004017719D1 (enExample) |
| ES (1) | ES2317008T3 (enExample) |
| MX (1) | MXPA05013431A (enExample) |
| WO (1) | WO2005000919A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1754723A1 (en) * | 2005-07-07 | 2007-02-21 | Total Petrochemicals Research Feluy | Single site catalyst systems having a scorpion-like structure |
| EA016790B1 (ru) * | 2006-04-13 | 2012-07-30 | Тотал Петрокемикалс Рисерч Фелюй | Разветвленный сополимер этилена низкой и средней плотности, способ его получения и применение |
| US20090048402A1 (en) * | 2007-08-17 | 2009-02-19 | Lynch Michael W | Preparing multimodal polyethylene having controlled long chain branching distribution |
| US20090163666A1 (en) * | 2007-12-21 | 2009-06-25 | David John Lohse | Polymer compositions exhibiting enhanced flow-induced crystallization |
| WO2009114661A1 (en) | 2008-03-13 | 2009-09-17 | Dow Global Technologies Inc. | Long chain branched (lcb), block or interconnected copolymers of ethylene in combination with one other polymer |
| KR102247231B1 (ko) * | 2016-11-17 | 2021-04-30 | 주식회사 엘지화학 | 에틸렌 비닐아세테이트 공중합체 및 이로부터 제조된 성형품 |
| KR102242546B1 (ko) * | 2016-11-17 | 2021-04-19 | 주식회사 엘지화학 | 에틸렌 비닐아세테이트 공중합체 및 이로부터 제조된 성형품 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4999327A (en) * | 1988-12-30 | 1991-03-12 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst for regulating the molecular weight distribution of ethylene polymers |
| US5089460A (en) * | 1989-07-26 | 1992-02-18 | Academy Of Applied Science, Inc. | Vanadium catalyst systems for olefin polymerization |
| US5534472A (en) * | 1995-03-29 | 1996-07-09 | Quantum Chemical Corporation | Vanadium-containing catalyst system |
| US5670439A (en) * | 1995-03-29 | 1997-09-23 | Quantum Chemical Corporation | Vanadium-containing catalyst system |
| TR199601005A2 (tr) * | 1995-12-15 | 1997-07-21 | Union Carbide Chem Plastic | Uzun zincirli, dallanmis poliolefinlerin üretimi icin yöntem. |
| CA2241486A1 (en) * | 1998-06-24 | 1999-12-24 | Bayer Inc. | Olefin polymerwith long chain branching, and process and catalyst system therefor |
| US6583240B2 (en) * | 2001-05-23 | 2003-06-24 | Equistar Chemicals, Lp | Ethylene polymerization process |
| EP1424349A4 (en) * | 2001-08-17 | 2005-01-05 | Idemitsu Petrochemical Co | ETHYLENE COPOLYMER AND THIS INCLUDING FILM |
-
2003
- 2003-06-09 US US10/457,769 patent/US20040249093A1/en not_active Abandoned
-
2004
- 2004-05-12 MX MXPA05013431A patent/MXPA05013431A/es unknown
- 2004-05-12 DE DE602004017719T patent/DE602004017719D1/de not_active Expired - Fee Related
- 2004-05-12 EP EP04751994A patent/EP1631600B1/en not_active Expired - Lifetime
- 2004-05-12 CN CNB2004800161563A patent/CN100366641C/zh not_active Expired - Fee Related
- 2004-05-12 JP JP2006532987A patent/JP2007500277A/ja active Pending
- 2004-05-12 CA CA002528502A patent/CA2528502A1/en not_active Abandoned
- 2004-05-12 AT AT04751994T patent/ATE414111T1/de not_active IP Right Cessation
- 2004-05-12 WO PCT/US2004/014850 patent/WO2005000919A1/en not_active Ceased
- 2004-05-12 KR KR1020057023503A patent/KR20060028687A/ko not_active Ceased
- 2004-05-12 ES ES04751994T patent/ES2317008T3/es not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6991132B2 (ja) | 活性化剤－担体を有するチーグラー・ナッタ－メタロセン二元触媒系 | |
| EP0527221B1 (en) | Process for preparing polyolefins having a bimodal molecular weight distribution | |
| US20120123067A1 (en) | Bimodal polyethylene process and products | |
| CA2688217C (en) | Multi reactor process | |
| JP6466566B2 (ja) | 繊維製造用ポリオレフィン重合体の製造方法 | |
| JP2018532860A (ja) | 高圧フリーラジカル重合 | |
| UA79678C2 (en) | Coating composition, process for its producing and substrate coated therewith | |
| JP2007500277A5 (enExample) | ||
| JP3715595B2 (ja) | エチレン系重合体の製造方法 | |
| JP2007500277A (ja) | 高レベルの長鎖分岐を有するポリオレフィン | |
| JPH01217014A (ja) | プロピレン重合体の製造法 | |
| JP6698657B2 (ja) | 高モジュラスシングル−サイトｌｌｄｐｅ | |
| NL8204876A (nl) | Katalysator en polymerisatie van olefinen met die katalysator. | |
| JP6180517B2 (ja) | アルキル化フェノールを使用してエチレン系ポリマーを作製するためのフリーラジカルプロセス | |
| JP7640554B2 (ja) | アルファ置換アクリレートを調製するためのプロセス | |
| JP3172594B2 (ja) | オレフィン系重合体の製造方法 | |
| JP4078430B2 (ja) | オレフィンの重合方法 | |
| KR102018535B1 (ko) | 올레핀 중합 촉매 및 이를 이용하여 중합된 올레핀계 중합체 | |
| JPH1025323A (ja) | α−オレフィンのブロック共重合体の製造方法 | |
| EP4274834A1 (en) | Isohexane-soluble unsaturated alkyl anilinium tetrakis(perfluoroaryl)borate activators | |
| JPH04261413A (ja) | プロピレンエチレン共重合体 | |
| JPS6369807A (ja) | エチレン共重合体の製造方法 | |
| JPH0853508A (ja) | オレフィン系共重合体の製造方法 | |
| JPS6330507A (ja) | エチレン共重合体の製造方法 | |
| JPS59199709A (ja) | 共重合体の製法 |