JP2007321009A - 顆粒状板状チタン酸塩、その製造方法及び顆粒状板状チタン酸塩を含有する樹脂組成物 - Google Patents
顆粒状板状チタン酸塩、その製造方法及び顆粒状板状チタン酸塩を含有する樹脂組成物 Download PDFInfo
- Publication number
- JP2007321009A JP2007321009A JP2006150571A JP2006150571A JP2007321009A JP 2007321009 A JP2007321009 A JP 2007321009A JP 2006150571 A JP2006150571 A JP 2006150571A JP 2006150571 A JP2006150571 A JP 2006150571A JP 2007321009 A JP2007321009 A JP 2007321009A
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- JP
- Japan
- Prior art keywords
- titanate
- plate
- granular
- layered
- platy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000011342 resin composition Substances 0.000 title claims abstract description 11
- 241000276425 Xiphophorus maculatus Species 0.000 title abstract 9
- -1 titanate compound Chemical class 0.000 claims abstract description 56
- 239000011230 binding agent Substances 0.000 claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- 239000002131 composite material Substances 0.000 claims abstract description 10
- 238000000465 moulding Methods 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims description 6
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 4
- 230000007547 defect Effects 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 238000004898 kneading Methods 0.000 abstract description 9
- 150000003839 salts Chemical class 0.000 abstract description 3
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 abstract description 3
- 229910052700 potassium Inorganic materials 0.000 abstract description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 description 32
- 239000000203 mixture Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 14
- 238000003786 synthesis reaction Methods 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 10
- 239000004677 Nylon Substances 0.000 description 9
- 229920001778 nylon Polymers 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 238000005469 granulation Methods 0.000 description 7
- 230000003179 granulation Effects 0.000 description 7
- OBTSLRFPKIKXSZ-UHFFFAOYSA-N lithium potassium Chemical compound [Li].[K] OBTSLRFPKIKXSZ-UHFFFAOYSA-N 0.000 description 7
- SWHAQEYMVUEVNF-UHFFFAOYSA-N magnesium potassium Chemical compound [Mg].[K] SWHAQEYMVUEVNF-UHFFFAOYSA-N 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 229920002725 thermoplastic elastomer Polymers 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 238000010306 acid treatment Methods 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229920001643 poly(ether ketone) Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001955 polyphenylene ether Polymers 0.000 description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 description 2
- ZDHURYWHEBEGHO-UHFFFAOYSA-N potassiopotassium Chemical compound [K].[K] ZDHURYWHEBEGHO-UHFFFAOYSA-N 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 125000000101 thioether group Chemical group 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- QLAWAFBTLLCIIM-UHFFFAOYSA-N 1-naphthalen-1-ylsulfanylnaphthalene Chemical group C1=CC=C2C(SC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 QLAWAFBTLLCIIM-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- SOHCOYTZIXDCCO-UHFFFAOYSA-N 6-thiabicyclo[3.1.1]hepta-1(7),2,4-triene Chemical group C=1C2=CC=CC=1S2 SOHCOYTZIXDCCO-UHFFFAOYSA-N 0.000 description 1
- ODPYDILFQYARBK-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]hepta-1,3,5-triene Chemical group C1=CC=C2SC2=C1 ODPYDILFQYARBK-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 101000837805 Homo sapiens Testis-expressed protein 44 Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920000491 Polyphenylsulfone Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 102100028514 Testis-expressed protein 44 Human genes 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 229920013629 Torelina Polymers 0.000 description 1
- 239000004742 Torelina™ Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229920003233 aromatic nylon Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001652 poly(etherketoneketone) Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920000874 polytetramethylene terephthalate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229920006259 thermoplastic polyimide Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
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Abstract
【解決手段】板状チタン酸塩を、バインダーにより成形したことを特徴としており、板状チタン酸塩としては、層状チタン酸塩化合物、板状8チタン酸カリウム、及び複合板状チタン酸金属塩などを用いることができる。
【選択図】なし
Description
AxMy□Ti2−(y+z)O4 (1)
(式中A及びMは互いに異なる1〜3価の金属、□はTiの欠陥部位を示す。xは0<x<1.0を満たす正の実数であり、y及びzはそれぞれ0<y+z<1.0を満たす0または正の実数である。)
上記式(1)におけるAは、価数1〜3価の金属であり、好ましくは、K、Rb、及びCsから選ばれる少なくとも一種である。Mは、金属Aとは異なる価数1〜3価の金属であり、好ましくは、Li、Mg、Zn、Cu、Fe、Al、Ga、Mn、及びNiから選ばれる少なくとも一種である。
また、単重合体のほかに共重合体も用いることができる。例えば、その共重合体の構成単位としては、m−フェニレンサルファイド単位、o−フェニレンサルファイド単位、p、p’−ジフェニレンケトンサルファイド単位、p、p’−ジフェニレンスルホンサルファイド単位、p、p’−ビフェニレンサルファイド単位、p、p’−ジフェニレンメチレンサルファイド単位、p、p’−ジフェニレンクメニルサルファイド単位、ナチルサルファイド単位等を上げることができる。
また、単重合体のほかに共重合体も挙げることができる。例えば、ポリ(2,6−ジメチル−1,4−フェニレン)エーテル、ポリ(2,6−ジエチル−1,4−フェニレン)エーテル、ポリ(2,6−ジプロピル−1,4−フェニレン)エーテル、ポリ(2−メチル−6−プロピル−1,4−フェニレン)エーテル等を挙げることができる。
酸化チタン496.6g、炭酸カリウム213.7g、水酸化マグネシウム89.4gを常法により混合し、原料混合物を振動ミル(中央化工機社製、MB−1)に充填し、振動数1200cpm、振幅6.0mmの条件で30分間摩砕処理した。摩砕混合物に水48mLを加えて混合し、この摩砕混合物の15gを油圧プレス機にて圧力10MPaでペレット形状に成形した。このペレットを電気炉中にて1000℃で4時間焼成した後、冷却し、得られた焼成物を粉砕した。粉砕物の組成はK0.8Mg0.4Ti1.6O4であった。この粉砕物の10重量%水性スラリー1Lを調製し、ディスパミル(ホソカワミクロン社製)にて、15分間分散させ、この水性スラリーを吸引濾過し、分取したケーキ(固形分)を110℃で乾燥し、電気炉にて600℃で1時間焼成した後、冷却し、得られた焼成物を20メッシュの篩に通して、平均長径4μm、組成K0.6Mg0.4Ti1.6O3.9のチタン酸マグネシウムカリウムを得た。
酸化チタン542.0g、炭酸カリウム216.8g、炭酸リチウム41.2gを常法により混合し、合成例1と同様の方法にて、平均長径15μm、組成K0.6Li0.27Ti1.73O3.9のチタン酸リチウムカリウムを得た。
合成例2で得られたチタン酸リチウムカリウム154.6gを、70%硫酸1.57kgを水29.4Lに溶解させた溶液に分散させ、5%スラリーとした。攪拌羽根により約5時間攪拌を続けた後、濾過、水洗、乾燥して、板状チタン酸(H2Ti2O5)を得た。得られた板状チタン酸全量を、85%水酸化カリウム0.74kgを水11.2Lに溶解させた溶液に分散させ、10%スラリーとした。攪拌羽根により約5時間攪拌を続けた後、濾過、水洗し、110℃にて2時間乾燥した。次いで、このものを電気炉により500℃にて3時間焼成し、平均長径16μmの板状8チタン酸カリウムを得た。
炭酸カルシウムと塩化カルシウムをモル比7:3になるような配合割合で混合粉砕し、さらに、合成例2で得られたチタン酸リチウムカリウムをTi:Ca=1.11:1のモル比となるように配合して混合物とし、この混合物をミキサーにて十分混合した。この混合粉末をアルミナ坩堝に充填し、電気炉にて800℃で5時間焼成した。得られた焼成物を0.1N硝酸水溶液に浸漬し、可溶成分を溶解させた後、濾別分離し乾燥させ、平均長径14μm、組成比Ti:Ca=1.12:1、結晶質CaTiO389%、非晶質TiO211%が複合一体化した複合板状チタン酸カルシウムを得た。
合成例1で得られたチタン酸マグネシウムカリウムをヘンシェル型ミキサーにて攪拌しながら、アミノプロピルトリエトキシシラン10%水溶液をチタン酸マグネシウムカリウムに対して30重量%滴下し、5分間攪拌した。得られた顆粒状粒子を送風乾燥機にて110℃で一晩乾燥し、850μ目開きの篩を通して、通過した粒子である顆粒状板状チタン酸塩Aを得た。上段より250μm、150μm、75μmの篩を重ね、顆粒状板状チタン酸塩Aを通して各篩残分を測定したところ、250μm篩上34wt%、150μm篩上32wt%、75μm篩上33wt%、75μm篩通過1wt%であった。
合成例1〜4で得られた各種板状チタン酸塩を表1に示すように、単独あるいは所定配合比(重量%)で混合し、実施例1と同様の方法で顆粒状板状チタン酸塩B〜Jを得た。顆粒状板状チタン酸塩Aも合わせて表1に示す。
実施例1〜10で得られた顆粒状板状チタン酸塩A〜J各30重量%、PPS樹脂(トレリナL2120−60;東レ(株)製)70重量%をブレンダー混合し、二軸押出機(TEX44,(株)日本製鋼所製)に供給し、押出機へのフィード状況(ホッパーでの付着、詰まり)、および環境衛生性を下記方法にて評価した。評価結果を表4に示す。
目視にて表2に示す下記4段階で評価した。
押出機周囲の粉塵濃度を、ハイボリューム・エアサンプラーHVS―500−5型(柴田科学機器工業(株)製)にて測定し、表3に示す下記4段階で評価した。
合成例1〜4の各種板状酸化チタン酸塩を用い、実施例11〜20と同様の評価を行った。結果を表5に示す。
Claims (9)
- 板状チタン酸塩を、バインダーにより成形したことを特徴とする顆粒状板状チタン酸塩。
- 板状チタン酸塩が、層状チタン酸塩化合物、板状8チタン酸カリウム、及び複合板状チタン酸金属塩からなるグループより選ばれる少なくとも1種であることを特徴とする請求項1に記載の顆粒状板状チタン酸塩。
- 層状チタン酸塩化合物が、層状チタン酸塩化合物(A)を酸処理した後、焼成して得られる層状チタン酸塩化合物(B)であることを特徴とする請求項2に記載の顆粒状板状チタン酸塩。
- 層状チタン酸塩化合物(A)が、式(1)で表される層状チタン酸塩化合物であることを特徴とする請求項3に記載の顆粒状板状チタン酸塩。
AxMy□Ti2−(y+z)O4 (1)
(式中A及びMは互いに異なる1〜3価の金属、□はTiの欠陥部位を示す。xは0<x<1.0を満たす正の実数であり、y及びzはそれぞれ0<y+z<1.0を満たす0または正の実数である。) - 層状チタン酸塩化合物(A)が、K0.80Li0.27Ti1.73O4またはK0.8Mg0.4Ti1.6O4で表される層状チタン酸塩化合物であることを特徴とする請求項4に記載の顆粒状板状チタン酸塩。
- 層状チタン酸塩化合物(B)が、K0.5〜0.7Li0.27Ti1.73O3.85〜3.95またはK0.2〜0.7Mg0.4Ti1.6O3.7〜4で表される層状チタン酸塩化合物である請求項5に記載の顆粒状板状チタン酸塩。
- 複合板状チタン酸金属塩が、
MO・TiO2(式中、Mは二価金属を示す)
で表される複合板状チタン酸金属塩である請求項2に記載の顆粒状板状チタン酸塩。 - 板状チタン酸塩を、バインダーを用いて顆粒状に成形することを特徴とする顆粒状板状チタン酸塩の製造方法。
- 樹脂100重量部に対して、請求項1〜7のいずれか1項に記載の顆粒状板状チタン酸塩を1〜100重量部含有させたことを特徴とする樹脂組成物。
Priority Applications (7)
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JP2006150571A JP5284569B2 (ja) | 2006-05-30 | 2006-05-30 | 顆粒状板状チタン酸塩、その製造方法及び顆粒状板状チタン酸塩を含有する樹脂組成物 |
PCT/JP2007/060577 WO2007138967A1 (ja) | 2006-05-30 | 2007-05-24 | 顆粒状板状チタン酸塩、その製造方法及び顆粒状板状チタン酸塩を含有する樹脂組成物 |
CNA2007800202923A CN101490157A (zh) | 2006-05-30 | 2007-05-24 | 颗粒状板状钛酸盐、其制造方法和含有颗粒状板状钛酸盐的树脂组合物 |
AT07744011T ATE555159T1 (de) | 2006-05-30 | 2007-05-24 | Granulierte plättchenförmige titansäuresalze, herstellungsverfahren dafür, die salze enthaltende harzzusammensetzungen |
KR1020087029249A KR101353176B1 (ko) | 2006-05-30 | 2007-05-24 | 과립상 판상 티탄산염, 그의 제조 방법 및 과립상 판상 티탄산염을 함유하는 수지 조성물 |
US12/227,875 US20090264571A1 (en) | 2006-05-30 | 2007-05-24 | Granulated Flaky Titanic Acid Salts, Process for Production Thereof, Resin Compositions Containing the Salts |
EP07744011A EP2022821B1 (en) | 2006-05-30 | 2007-05-24 | Granulated flaky titanic acid salts, process for production thereof, resin compositions containing the salts |
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US20090264571A1 (en) | 2009-10-22 |
KR101353176B1 (ko) | 2014-01-17 |
KR20090013212A (ko) | 2009-02-04 |
EP2022821B1 (en) | 2012-04-25 |
EP2022821A1 (en) | 2009-02-11 |
CN101490157A (zh) | 2009-07-22 |
WO2007138967A1 (ja) | 2007-12-06 |
JP5284569B2 (ja) | 2013-09-11 |
EP2022821A4 (en) | 2010-08-04 |
ATE555159T1 (de) | 2012-05-15 |
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