JP2007246668A - プリプレグ用エポキシ樹脂硬化性組成物 - Google Patents
プリプレグ用エポキシ樹脂硬化性組成物 Download PDFInfo
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- JP2007246668A JP2007246668A JP2006071417A JP2006071417A JP2007246668A JP 2007246668 A JP2007246668 A JP 2007246668A JP 2006071417 A JP2006071417 A JP 2006071417A JP 2006071417 A JP2006071417 A JP 2006071417A JP 2007246668 A JP2007246668 A JP 2007246668A
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- carbon atoms
- epoxy resin
- hydroxyl group
- prepreg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000004984 aromatic diamines Chemical class 0.000 claims abstract description 17
- 125000003277 amino group Chemical group 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 68
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 51
- 125000001118 alkylidene group Chemical group 0.000 claims description 23
- 125000000732 arylene group Chemical group 0.000 claims description 23
- 125000005843 halogen group Chemical group 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 125000002947 alkylene group Chemical group 0.000 claims description 11
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 8
- 230000009477 glass transition Effects 0.000 abstract description 7
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- 229920000049 Carbon (fiber) Polymers 0.000 description 3
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- 125000002723 alicyclic group Chemical group 0.000 description 3
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- 150000001408 amides Chemical class 0.000 description 3
- 229920006231 aramid fiber Polymers 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
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- 238000010438 heat treatment Methods 0.000 description 3
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- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 2
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- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 2
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- CDOWNLMZVKJRSC-UHFFFAOYSA-N 2-hydroxyterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(O)=C1 CDOWNLMZVKJRSC-UHFFFAOYSA-N 0.000 description 2
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- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N 4-methylimidazole Chemical compound CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 2
- QNVNLUSHGRBCLO-UHFFFAOYSA-N 5-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC(O)=CC(C(O)=O)=C1 QNVNLUSHGRBCLO-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 2
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- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
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- 229910052711 selenium Inorganic materials 0.000 description 1
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- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
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- 239000003549 soybean oil Substances 0.000 description 1
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- 239000000758 substrate Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
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- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- 125000006836 terphenylene group Chemical group 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- CVNKFOIOZXAFBO-UHFFFAOYSA-J tin(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Sn+4] CVNKFOIOZXAFBO-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- NLSXASIDNWDYMI-UHFFFAOYSA-N triphenylsilanol Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(O)C1=CC=CC=C1 NLSXASIDNWDYMI-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
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- 229910052725 zinc Inorganic materials 0.000 description 1
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- 229910000859 α-Fe Inorganic materials 0.000 description 1
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- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/44—Amides
- C08G59/46—Amides together with other curing agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/246—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using polymer based synthetic fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
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- H05K1/032—Organic insulating material consisting of one material
- H05K1/0326—Organic insulating material consisting of one material containing O
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Inorganic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
【解決手段】下記の(A)〜(E)成分を含有するプリプレグ用エポキシ樹脂硬化性組成物。
(A):フェノール性水酸基をアミノ基と隣接する位置に有する、フェノール性水酸基含有芳香族ジアミン由来の構造を有するポリアミド化合物
(B):エポキシ樹脂
(C):エポキシ樹脂硬化剤
(D):充填剤
(E):溶剤
【選択図】なし
Description
(A):フェノール性水酸基をアミノ基と隣接する位置に有する、フェノール性水酸基含有芳香族ジアミン由来の構造を有するポリアミド化合物
(B):エポキシ樹脂
(C):エポキシ樹脂硬化剤
(D):充填剤
(E):溶剤
まず本発明の(A)成分について説明する。
本発明の(A)成分は、フェノール性水酸基をアミノ基と隣接する位置に有する、フェノール性水酸基含有芳香族ジアミン由来の構造を有するポリアミド化合物である。本発明でいうフェノール性水酸基をアミノ基と隣接する位置に有する、フェノール性水酸基含有芳香族ジアミンとは、その塩も含む。すなわちポリアミド中に、フェノール性水酸基をアミノ基と隣接する位置に有する、フェノール性水酸基含有芳香族ジアミンまたはその塩を由来とする構造が存在する。
前記(B)成分のエポキシ樹脂としては、特に制限されず、公知の芳香族エポキシ化合物、脂環族エポキシ化合物、脂肪族エポキシ化合物などが用いられる。芳香族エポキシ化合物としては、例えば、ハイドロキノン、レゾルシノール、ビスフェノールA、ビスフェノールF、4,4’−ジヒドロキシビフェニル、ノボラック、テトラブロモビスフェノールA、2,2−ビス(4−ヒドロキシフェニル)−1,1,1,3,3,3−ヘキサフルオロプロパン、1,6−ジヒドロキシナフタレンなどの多価フェノールのグリシジルエーテル化合物が挙げられる。脂環族エポキシ化合物としては、少なくとも1個以上の脂環族環を有する多価アルコールのポリグリシジルエーテルまたはシクロヘキセンやシクロペンテン環含有化合物を酸化剤でエポキシ化することによって得られるシクロヘキセンオキサイドやシクロペンテンオキサイド含有化合物が挙げられる。例えば、水素添加ビスフェノールAジグリシジルエーテル、3,4−エポキシシクロヘキシルメチル−3,4−エポキシシクロヘキシルカルボキシレート、3,4−エポキシ−1−メチルシクロヘキシル−3,4−エポキシ−1−メチルヘキサンカルボキシレート、6−メチル−3,4−エポキシシクロヘキシメチル−6−メチル−3,4−エポキシシクロヘキサンカルボキシレート、3,4−エポキシ−3−メチルシクロヘキシルメチル−3,4−エポキシ−3−メチルシクロヘキサンカルボキシレート、3,4−エポキシ−5−メチルシクロヘキシルメチル−3,4−エポキシ−5−メチルシクロヘキサンカルボキシレート、ビス(3,4−エポキシシクロヘキシルメチル)アジペート、メチレンビス(3,4−エポキシシクロヘキサン)、2,2−ビス(3,4−エポキシシクロヘキシル)プロパン、ジシクロペンタジエンジエポキサイド、エチレンビス(3,4−エポキシシクロヘキサンカルボキシレート)、エポキシヘキサヒドロフタル酸ジオクチル、エポキシヘキサヒドロフタル酸ジ−2−エチルへキシルなどが挙げられる。脂肪族エポキシ化合物としては、脂肪族多価アルコールまたはそのアルキレンオキサイド付加物のポリグリシジルエーテル、脂肪族長鎖多塩基酸のポリグリシジルエステル、グリシジルアクリレートまたはグリシジルメタクリレートのビニル重合により合成したホモポリマー、グリシジルアクリレートまたはグリシジルメタクリレートとその他のビニルモノマーとのビニル重合により合成したコポリマー等が挙げられる。代表的な化合物として、1,4−ブタンジオールジグリシジルエーテル、1,6−ヘキサンジオールジグリシジルエーテル、グリセリンのトリグリシジルエーテル、トリメチロールプロパンのトリグリシジルエーテル、ソルビトールのテトラグリシジルエーテル、ジペンタエリスリトールのヘキサグリシジルエーテル、ポリエチレングリコールのジグリシジルエーテル、ポリプロピレングリコールのジグリシジルエーテル等の多価アルコールのグリシジルエーテル、またプロピレングリコール、トリメチロールプロパン、グリセリン等の脂肪族多価アルコールに1種または2種以上のアルキレンオキサイドを付加することにより得られるポリエーテルポリオールのポリグリシジルエーテル、脂肪族長鎖二塩基酸のジグリシジルエステルが挙げられる。さらに、脂肪族高級アルコールのモノグリシジルエーテルやフェノール、クレゾール、ブチルフェノール、また、これらにアルキレンオキサイドを付加することによって得られるポリエーテルアルコールのモノグリシジルエーテル、高級脂肪酸のグリシジルエステル、エポキシ化大豆油、エポキシステアリン酸オクチル、エポキシステアリン酸ブチル、エポキシ化ポリブタジエン等が挙げられる。
前記(C)成分のエポキシ樹脂硬化剤としては、潜在性硬化剤、ポリアミン化合物、ポリフェノール化合物およびカチオン系光開始剤などが挙げられ、また硬化促進剤といわれるものも含まれる。
潜在性硬化剤としては、ジシアンジアミド、ヒドラジド、イミダゾール化合物、アミンアダクト、スルホニウム塩、オニウム塩、ケチミン、酸無水物、三級アミンなどが挙げられる。これら潜在性硬化剤は、一液型の硬化性組成物を与え、取り扱いが容易なので好ましい。
[A]m+[B]m-
で表される陽イオンと陰イオンの塩を挙げることができる。
[(R1 )a Q]m+
で表すことができる。
[LXb ]m-
で表すことができる。
[LXb-1 (OH)]m-
で表される構造のものも好ましく用いることができる。L、X、bは上記と同様である。また、その他用いることができる陰イオンとしては、過塩素酸イオン(ClO4 )- 、トリフルオロメチル亜硫酸イオン(CF3 SO3 )- 、フルオロスルホン酸イオン(FSO3 )- 、トルエンスルホン酸陰イオン、トリニトロベンゼンスルホン酸陰イオン等が挙げられる。
これらの光開始剤は安息香酸系または第三級アミン系などの公知の光重合促進剤の1種または2種以上と組み合わせて用いても良い。
前記(D)成分の充填剤(フィラー)としては、従来公知のものが使用でき特に限定されないが、ガラス繊維、ホウ酸アルミニウムウィスカー、窒化ホウ素ウィスカー、チタン酸カリウムウィスカー、酸化チタンウィスカーなどの繊維状充填剤や、シリカ、溶融シリカ、アルミナなどの球状充填剤を用いることが好ましく、特に、硬化物の物性(低線膨張係数)の点から球状シリカまたは球状の溶融シリカが好ましい。もちろん、繊維状、球状の形態に限らず、シリカ(溶融シリカ、結晶性シリカ)、アルミナ、ホウ酸アルミ、窒化アルミ、窒化ケイ素、窒化ホウ素、チタン酸カリウム、酸化チタン等も用いることもでき、その他、充填剤として、タルク、マイカ、炭酸カルシウム、ガラスフレーク、ガラスビーズ、ガラスバルーン、ケイ酸カルシウム、水酸化アルミニウム、硫酸バリウム、マグネシア、フェライト、各種金属微粒子、黒鉛、カーボンや、炭素繊維、ボロン繊維、シリコンカーバイト繊維、アルミナ繊維、シリカアルミナ繊維などの無機系繊維、アラミド繊維、ポリエステル繊維、セルロース繊維、炭素繊維などの有機系繊維などが挙げられる。
前記(E)成分の溶剤としては、例えばγ−ブチロラクトン類、N−メチルピロリドン(NMP)、N,N−ジメチルホルムアミド(DMF)、N,N−ジメチルアセトアミド、N,N−ジメチルイミダゾリジノン等のアミド系溶剤、テトラメチレンスルフォン等のスルフォン類、ジエチレングリコールジメチルエーテル、ジエチレングリコールジエチルエーテル、プロピレングリコール、プロピレングリコールモノメチルエーテル、プロピレングリコールモノメチルエーテルモノアセテート、プロピレングリコールモノブチルエーテル等のエーテル系溶剤、メチルエチルケトン、メチルイソブチルケトン、シクロペンタノン、シクロヘキサノン等のケトン系溶剤、トルエン、キシレンなどの芳香族系溶剤が挙げられる。なかでも、溶解性と、乾燥の容易さから、ジエチレングリコールジメチルエーテル、ジエチレングリコールジエチルエーテル、プロピレングリコール、プロピレングリコールモノメチルエーテル、プロピレングリコールモノメチルエーテルモノアセテート、プロピレングリコールモノブチルエーテル等のエーテル系溶剤が好ましい。
任意成分としては、例えば、天然ワックス類、合成ワックス類および長鎖脂肪族酸の金属塩類等の可塑剤、酸アミド類、エステル類、パラフィン類などの離型剤、ニトリルゴム、ブタジエンゴム等の応力緩和剤、三酸化アンチモン、五酸化アンチモン、酸化錫、水酸化錫、酸化モリブデン、硼酸亜鉛、メタ硼酸バリウム、赤燐、水酸化アルミニウム、水酸化マグネシウム、アルミン酸カルシウム等の無機難燃剤、テトラブロモビスフェノールA、テトラブロモ無水フタル酸、ヘキサブロモベンゼン、ブロム化フェノールノボラック等の臭素系難燃剤、リン酸エステル系難燃剤、リン酸アミド系難燃剤、シラン系カップリング剤、チタネート系カップリング剤、アルミニウム系カップリング剤等のカップリング剤、染料や顔料等の着色剤、酸化安定剤、光安定剤、耐湿性向上剤、チキソトロピー付与剤、希釈剤、消泡剤、他の各種の樹脂、粘着付与剤、帯電防止剤、滑剤、紫外線吸収剤等が挙げられる。
2,2−ビス(3−アミノ−4−ヒドロキシフェニル)ヘキサフルオロプロパン16.48g(0.045モル)をN−メチルピロリドン(NMP)40g及びピリジン15.33gの混合物に溶かした溶液に、イソフタロイルクロライド10.05g(0.0495モル)をNMP40gに溶かした溶液を−15〜0℃で滴下した。−15〜0℃を保持したまま2時間反応し、さらに室温で2時間反応した。約2リットルのイオン交換水で再沈後、ろ過して150℃で3時間減圧乾燥して白色粉末17.9g(収率80.1%)(下記の実施ポリマー1)を得た。
得られた白色粉末の化合物は、赤外吸収スペクトルよりアミド結合の形成を確認し、ゲルパーミエーションクロマトグラフにより重量平均分子量の20000のポリマーであることを確認した。また、分析により粘度は50cps(25℃、30重量%NMP溶液) でOH当量は250g/eqであった。
合成例1と同様にして下記の実施ポリマー2〜20を合成した。得られた実施ポリマーの重量平均分子量、粘度、OH当量を下記に示す。
前記合成例で得られた実施ポリマー又は後記の比較ポリマーを用いて表1〜表5に記載の配合によりプリプレグ用エポキシ樹脂硬化性組成物をそれぞれ調製した。これらのエポキシ樹脂硬化性組成物と表1〜表5に記載の基材を用いてプリプレグを作成し、このプリプレグを4枚積層して表面に5μmの銅箔を張り合わせ、真空下180℃、50kg/cm2 で90分プレスしたものについて、ガラス転移温度と線膨張係数を測定した。その結果を表1〜表5に示す。
線膨張係数は、幅3mm長さ10mmの短冊状に切り出したサンプルを用いてTMAにて測定した。
*3:二酸化チタンウィスカー
*4:イミダゾール系硬化剤 2−フェニル−4, 5−ジヒドロキシメチルイミダゾール
*5:PGM プロピレングリコールモノメチルエーテル
Claims (5)
- 下記の(A)〜(E)成分を含有するプリプレグ用エポキシ樹脂硬化性組成物。
(A):フェノール性水酸基をアミノ基と隣接する位置に有する、フェノール性水酸基含有芳香族ジアミン由来の構造を有するポリアミド化合物
(B):エポキシ樹脂
(C):エポキシ樹脂硬化剤
(D):充填剤
(E):溶剤 - 前記(A)成分のポリアミド化合物が、その繰り返し単位中に、下記の一般式(I)又は一般式(II)で表されるフェノール性水酸基を有する構造を有する請求項1記載のプリプレグ用エポキシ樹脂硬化性組成物。
- 前記(A)成分のポリアミド化合物が、下記の一般式(III) 又は一般式(IV)で表されるフェノール性水酸基を有する構造である請求項1記載のプリプレグ用エポキシ樹脂硬化性組成物。
- 請求項1〜3のいずれかに記載のプリプレグ用エポキシ樹脂硬化性組成物から得られるプリプレグ。
- 請求項4記載のプリプレグから得られるプリント配線板。
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JP2006071417A JP5004483B2 (ja) | 2006-03-15 | 2006-03-15 | プリプレグ用エポキシ樹脂硬化性組成物 |
CN200780004453XA CN101379118B (zh) | 2006-03-15 | 2007-02-08 | 预成型料用环氧树脂固化性组合物 |
EP20070708197 EP1995271B1 (en) | 2006-03-15 | 2007-02-08 | Epoxy resin curable composition for prepreg |
US12/278,176 US7906213B2 (en) | 2006-03-15 | 2007-02-08 | Epoxy resin curable composition for prepreg |
PCT/JP2007/052173 WO2007108242A1 (ja) | 2006-03-15 | 2007-02-08 | プリプレグ用エポキシ樹脂硬化性組成物 |
KR1020087019058A KR101328015B1 (ko) | 2006-03-15 | 2007-02-08 | 프리프레그용 에폭시수지 경화성 조성물 |
TW96105606A TWI394769B (zh) | 2006-03-15 | 2007-02-15 | Epoxy resin hardening composition for prepreg |
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KR20140042738A (ko) | 2012-09-28 | 2014-04-07 | 파나소닉 주식회사 | 프리프레그, 금속 클래드 적층판, 프린트 배선판, 다층 프린트 배선판 |
JP2017149933A (ja) * | 2016-02-24 | 2017-08-31 | 東洋紡株式会社 | フェノール性水酸基含有ポリアミド樹脂、およびその組成物 |
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JP2017171878A (ja) * | 2016-03-16 | 2017-09-28 | 東洋紡株式会社 | 金属化合物を含有するフェノール性水酸基含有ポリアミド樹脂組成物 |
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2006
- 2006-03-15 JP JP2006071417A patent/JP5004483B2/ja not_active Expired - Fee Related
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2007
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- 2007-02-08 CN CN200780004453XA patent/CN101379118B/zh not_active Expired - Fee Related
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US9718986B2 (en) | 2009-04-01 | 2017-08-01 | Taiwan Union Technology Corporation | Epoxy resin blend |
US20100255740A1 (en) * | 2009-04-01 | 2010-10-07 | Taiwan Union Technology Corporation | Epoxy resin blend |
WO2013081060A1 (ja) * | 2011-11-29 | 2013-06-06 | 三菱レイヨン株式会社 | エポキシ樹脂組成物、プリプレグ、繊維強化複合材料とその製造方法 |
WO2013081058A1 (ja) * | 2011-11-29 | 2013-06-06 | 三菱レイヨン株式会社 | プリプレグ、繊維強化複合材料とその製造方法、エポキシ樹脂組成物 |
US10227476B2 (en) | 2011-11-29 | 2019-03-12 | Mitsubishi Chemical Corporation | Prepreg, fiber-reinforced composite material, method for producing same, and epoxy resin composition |
CN103958560A (zh) * | 2011-11-29 | 2014-07-30 | 三菱丽阳株式会社 | 环氧树脂组合物、预浸料、纤维强化复合材料及其制造方法 |
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JPWO2013081060A1 (ja) * | 2011-11-29 | 2015-04-27 | 三菱レイヨン株式会社 | エポキシ樹脂組成物、プリプレグ、繊維強化複合材料とその製造方法 |
JPWO2013081058A1 (ja) * | 2011-11-29 | 2015-04-27 | 三菱レイヨン株式会社 | プリプレグ、繊維強化複合材料とその製造方法、エポキシ樹脂組成物 |
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KR101683662B1 (ko) | 2012-09-28 | 2016-12-07 | 파나소닉 아이피 매니지먼트 가부시키가이샤 | 프리프레그, 금속 클래드 적층판, 프린트 배선판, 다층 프린트 배선판 |
KR20140042738A (ko) | 2012-09-28 | 2014-04-07 | 파나소닉 주식회사 | 프리프레그, 금속 클래드 적층판, 프린트 배선판, 다층 프린트 배선판 |
JP2017149933A (ja) * | 2016-02-24 | 2017-08-31 | 東洋紡株式会社 | フェノール性水酸基含有ポリアミド樹脂、およびその組成物 |
JP2017165940A (ja) * | 2016-03-09 | 2017-09-21 | 東洋紡株式会社 | 縮合環式有機化合物を含有するフェノール性水酸基含有ポリアミド樹脂組成物 |
JP2017165861A (ja) * | 2016-03-16 | 2017-09-21 | 東洋紡株式会社 | 縮合環式有機化合物および金属化合物を含有するフェノール性水酸基含有ポリアミド樹脂組成物 |
JP2017171878A (ja) * | 2016-03-16 | 2017-09-28 | 東洋紡株式会社 | 金属化合物を含有するフェノール性水酸基含有ポリアミド樹脂組成物 |
JP2020200431A (ja) * | 2019-06-13 | 2020-12-17 | 帝人株式会社 | 繊維強化半芳香族ポリアミド樹脂組成物及びその成形品 |
JP7343312B2 (ja) | 2019-06-13 | 2023-09-12 | 帝人株式会社 | 繊維強化半芳香族ポリアミド樹脂組成物及びその成形品 |
Also Published As
Publication number | Publication date |
---|---|
TWI394769B (zh) | 2013-05-01 |
EP1995271A1 (en) | 2008-11-26 |
TW200745198A (en) | 2007-12-16 |
US7906213B2 (en) | 2011-03-15 |
KR20080106172A (ko) | 2008-12-04 |
CN101379118B (zh) | 2012-07-04 |
EP1995271B1 (en) | 2013-07-24 |
EP1995271A4 (en) | 2012-03-28 |
CN101379118A (zh) | 2009-03-04 |
JP5004483B2 (ja) | 2012-08-22 |
WO2007108242A1 (ja) | 2007-09-27 |
US20090030147A1 (en) | 2009-01-29 |
KR101328015B1 (ko) | 2013-11-13 |
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