JP2006504510A5 - - Google Patents
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- Publication number
- JP2006504510A5 JP2006504510A5 JP2004517758A JP2004517758A JP2006504510A5 JP 2006504510 A5 JP2006504510 A5 JP 2006504510A5 JP 2004517758 A JP2004517758 A JP 2004517758A JP 2004517758 A JP2004517758 A JP 2004517758A JP 2006504510 A5 JP2006504510 A5 JP 2006504510A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- support
- silver
- olefin
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims 16
- 238000000034 method Methods 0.000 claims 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 8
- 150000001336 alkenes Chemical class 0.000 claims 8
- 229910052709 silver Inorganic materials 0.000 claims 8
- 239000004332 silver Substances 0.000 claims 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 6
- 229910052760 oxygen Inorganic materials 0.000 claims 6
- 239000001301 oxygen Substances 0.000 claims 6
- 239000011148 porous material Substances 0.000 claims 5
- 229910052702 rhenium Inorganic materials 0.000 claims 5
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 5
- 150000000180 1,2-diols Chemical class 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 4
- 238000006735 epoxidation reaction Methods 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- 229910052750 molybdenum Inorganic materials 0.000 claims 4
- 239000011733 molybdenum Substances 0.000 claims 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 4
- 229910052721 tungsten Inorganic materials 0.000 claims 4
- 239000010937 tungsten Substances 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- 239000002019 doping agent Substances 0.000 claims 3
- 230000002708 enhancing effect Effects 0.000 claims 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 125000002091 cationic group Chemical group 0.000 claims 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 239000012876 carrier material Substances 0.000 claims 1
- 239000012018 catalyst precursor Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000002243 precursor Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- 229910052716 thallium Inorganic materials 0.000 claims 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39265702P | 2002-06-28 | 2002-06-28 | |
| PCT/US2003/019827 WO2004002954A2 (en) | 2002-06-28 | 2003-06-24 | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006504510A JP2006504510A (ja) | 2006-02-09 |
| JP2006504510A5 true JP2006504510A5 (enExample) | 2006-07-27 |
| JP4537848B2 JP4537848B2 (ja) | 2010-09-08 |
Family
ID=30000913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517758A Expired - Lifetime JP4537848B2 (ja) | 2002-06-28 | 2003-06-24 | 触媒の選択性を改善する方法及びオレフィンのエポキシ化方法 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7485597B2 (enExample) |
| EP (1) | EP1517751B2 (enExample) |
| JP (1) | JP4537848B2 (enExample) |
| KR (1) | KR100980123B1 (enExample) |
| CN (1) | CN100512966C (enExample) |
| AU (1) | AU2003243757A1 (enExample) |
| BR (1) | BR0312244B1 (enExample) |
| CA (1) | CA2491523C (enExample) |
| DE (1) | DE60332457D1 (enExample) |
| IN (2) | IN2004DE03867A (enExample) |
| MX (1) | MX256050B (enExample) |
| RU (1) | RU2314156C2 (enExample) |
| TW (1) | TWI317651B (enExample) |
| WO (1) | WO2004002954A2 (enExample) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2314156C2 (ru) | 2002-06-28 | 2008-01-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ улучшения селективности катализатора и способ эпоксидирования олефина |
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| US7521393B2 (en) * | 2004-07-27 | 2009-04-21 | Süd-Chemie Inc | Selective hydrogenation catalyst designed for raw gas feed streams |
| US7759284B2 (en) | 2005-05-09 | 2010-07-20 | Scientific Design Company, Inc. | Calcination in an inert gas in the presence of a small concentration of an oxidizing component |
| US20070151451A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the cooling, concentration or purification of ethylene oxide |
| US7750170B2 (en) | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
| US20070203352A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070197801A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process |
| US20070197808A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US7459589B2 (en) | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
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| US20070213545A1 (en) * | 2005-12-22 | 2007-09-13 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070154377A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the removal of combustible volatile contaminant materials from a process stream |
| BE1017793A3 (fr) * | 2005-12-22 | 2009-07-07 | Shell Int Research | Procede de preparation d'un oxyde d'olefine ou d'un produit chimique pouvant provenir d'un oxyde d'olefine. |
| EP1979092A2 (en) * | 2006-02-03 | 2008-10-15 | Shell Internationale Research Maatschappij B.V. | A process for treating a catalyst, the catalyst, and use of the catalyst |
| US7553795B2 (en) | 2006-03-21 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Activation of high selectivity ethylene oxide catalyst |
| WO2007116585A1 (ja) * | 2006-04-10 | 2007-10-18 | Mitsubishi Chemical Corporation | 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法 |
| CN101360562B (zh) * | 2006-04-10 | 2013-02-06 | 三菱化学株式会社 | 环氧乙烷制造用催化剂及其制造方法、以及环氧乙烷的制造方法 |
| US8097557B2 (en) * | 2006-08-08 | 2012-01-17 | Sd Lizenverwertungsgesellschaft Mbh & Co. Kg | Two-stage calcination for catalyst production |
| JP4267015B2 (ja) | 2006-09-29 | 2009-05-27 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| US8501664B2 (en) * | 2006-11-20 | 2013-08-06 | Shell Oil Company | Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst |
| US20080154052A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| US20080154051A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| TW200836828A (en) * | 2007-02-27 | 2008-09-16 | Nippon Catalytic Chem Ind | Catalyst for exhaust gas treatment and exhaust gas treatment method |
| WO2008141032A1 (en) * | 2007-05-09 | 2008-11-20 | Shell Oil Company | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| JP5507444B2 (ja) | 2007-05-09 | 2014-05-28 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 酸化オレフィン、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートまたはアルカノールアミンの製造方法 |
| EP2152411B1 (en) | 2007-05-09 | 2019-12-04 | Shell International Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| US7696368B2 (en) * | 2007-05-11 | 2010-04-13 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Start-up of high selectivity catalysts in olefin oxide plants |
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| CN102056909B (zh) | 2008-05-07 | 2014-03-05 | 国际壳牌研究有限公司 | 环氧化工艺的开车方法及环氧乙烷、1，2-二醇、1，2-二醇醚、1，2-碳酸酯或链烷醇胺的制备方法 |
| KR101629038B1 (ko) | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
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| JP5328452B2 (ja) * | 2009-03-31 | 2013-10-30 | 株式会社日本触媒 | 酸化エチレン製造用触媒の担体、酸化エチレン製造用触媒および酸化エチレンの製造方法 |
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2003
- 2003-06-24 RU RU2005102076/04A patent/RU2314156C2/ru not_active IP Right Cessation
- 2003-06-24 EP EP03761992.1A patent/EP1517751B2/en not_active Expired - Lifetime
- 2003-06-24 DE DE60332457T patent/DE60332457D1/de not_active Expired - Lifetime
- 2003-06-24 MX MXPA04012745 patent/MX256050B/es active IP Right Grant
- 2003-06-24 BR BRPI0312244-1B1A patent/BR0312244B1/pt active IP Right Grant
- 2003-06-24 WO PCT/US2003/019827 patent/WO2004002954A2/en not_active Ceased
- 2003-06-24 CA CA2491523A patent/CA2491523C/en not_active Expired - Lifetime
- 2003-06-24 AU AU2003243757A patent/AU2003243757A1/en not_active Abandoned
- 2003-06-24 KR KR1020047021330A patent/KR100980123B1/ko not_active Expired - Lifetime
- 2003-06-24 JP JP2004517758A patent/JP4537848B2/ja not_active Expired - Lifetime
- 2003-06-24 CN CNB038153084A patent/CN100512966C/zh not_active Expired - Lifetime
- 2003-06-26 US US10/606,440 patent/US7485597B2/en not_active Expired - Lifetime
- 2003-06-26 TW TW092117429A patent/TWI317651B/zh not_active IP Right Cessation
-
2004
- 2004-12-06 IN IN3867DE2004 patent/IN2004DE03867A/en unknown
- 2004-12-06 IN IN3876DE2004 patent/IN2004DE03876A/en unknown
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