JP2006126365A - 感放射線性樹脂組成物 - Google Patents
感放射線性樹脂組成物 Download PDFInfo
- Publication number
- JP2006126365A JP2006126365A JP2004312826A JP2004312826A JP2006126365A JP 2006126365 A JP2006126365 A JP 2006126365A JP 2004312826 A JP2004312826 A JP 2004312826A JP 2004312826 A JP2004312826 A JP 2004312826A JP 2006126365 A JP2006126365 A JP 2006126365A
- Authority
- JP
- Japan
- Prior art keywords
- group
- carbon atoms
- radiation
- meth
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000005855 radiation Effects 0.000 title claims abstract description 70
- 239000011342 resin composition Substances 0.000 title claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 65
- 239000011347 resin Substances 0.000 claims abstract description 65
- 239000002253 acid Substances 0.000 claims abstract description 48
- 125000004432 carbon atom Chemical group C* 0.000 claims description 50
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 125000002723 alicyclic group Chemical group 0.000 claims description 14
- 239000003513 alkali Substances 0.000 claims description 14
- 238000009792 diffusion process Methods 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 230000009471 action Effects 0.000 claims description 9
- 125000001424 substituent group Chemical group 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 230000000704 physical effect Effects 0.000 abstract description 2
- -1 1,2-butylene group Chemical group 0.000 description 79
- 150000001875 compounds Chemical class 0.000 description 52
- 238000006116 polymerization reaction Methods 0.000 description 38
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
- 239000000243 solution Substances 0.000 description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 24
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 23
- 239000000178 monomer Substances 0.000 description 23
- 229910052757 nitrogen Inorganic materials 0.000 description 20
- 239000000843 powder Substances 0.000 description 19
- 239000002904 solvent Substances 0.000 description 18
- 239000000203 mixture Substances 0.000 description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000012986 chain transfer agent Substances 0.000 description 10
- 150000002430 hydrocarbons Chemical group 0.000 description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- 238000011161 development Methods 0.000 description 9
- 238000001914 filtration Methods 0.000 description 9
- 230000035945 sensitivity Effects 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000004090 dissolution Methods 0.000 description 8
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000005227 gel permeation chromatography Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000010926 purge Methods 0.000 description 7
- 239000007870 radical polymerization initiator Substances 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
- 229920006026 co-polymeric resin Polymers 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000001312 dry etching Methods 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000003849 aromatic solvent Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 3
- MWMWRSCIFDZZGW-UHFFFAOYSA-N (2-oxooxolan-3-yl) prop-2-enoate Chemical compound C=CC(=O)OC1CCOC1=O MWMWRSCIFDZZGW-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
- OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- DWYHDSLIWMUSOO-UHFFFAOYSA-N 2-phenyl-1h-benzimidazole Chemical compound C1=CC=CC=C1C1=NC2=CC=CC=C2N1 DWYHDSLIWMUSOO-UHFFFAOYSA-N 0.000 description 2
- JJYPMNFTHPTTDI-UHFFFAOYSA-N 3-methylaniline Chemical compound CC1=CC=CC(N)=C1 JJYPMNFTHPTTDI-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 description 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N 4-methylimidazole Chemical compound CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 2
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 2
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical class C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003759 ester based solvent Substances 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000004210 ether based solvent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 125000004494 ethyl ester group Chemical group 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 150000003903 lactic acid esters Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical compound C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000004528 spin coating Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229960002317 succinimide Drugs 0.000 description 2
- XKXIQBVKMABYQJ-UHFFFAOYSA-N tert-butyl hydrogen carbonate Chemical group CC(C)(C)OC(O)=O XKXIQBVKMABYQJ-UHFFFAOYSA-N 0.000 description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- WLOQLWBIJZDHET-UHFFFAOYSA-N triphenylsulfonium Chemical compound C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 WLOQLWBIJZDHET-UHFFFAOYSA-N 0.000 description 2
- 239000012953 triphenylsulfonium Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- FKWURGDTWUGDQB-UHFFFAOYSA-N (1-ethylcyclohexyl) prop-2-enoate Chemical compound C=CC(=O)OC1(CC)CCCCC1 FKWURGDTWUGDQB-UHFFFAOYSA-N 0.000 description 1
- FDOANYJWOYTZAP-UHFFFAOYSA-N (1-ethylcyclopentyl) prop-2-enoate Chemical compound C=CC(=O)OC1(CC)CCCC1 FDOANYJWOYTZAP-UHFFFAOYSA-N 0.000 description 1
- GGHSJKUBBRSPMP-UHFFFAOYSA-N (1-hydroxy-2-methyl-2-adamantyl) prop-2-enoate Chemical compound C1C(C2)CC3CC1C(C)(OC(=O)C=C)C2(O)C3 GGHSJKUBBRSPMP-UHFFFAOYSA-N 0.000 description 1
- CJCGDEYGAIPAEN-UHFFFAOYSA-N (1-methylcyclohexyl) prop-2-enoate Chemical compound C=CC(=O)OC1(C)CCCCC1 CJCGDEYGAIPAEN-UHFFFAOYSA-N 0.000 description 1
- QOTUZLQBNYANGA-UHFFFAOYSA-N (1-methylcyclopentyl) prop-2-enoate Chemical compound C=CC(=O)OC1(C)CCCC1 QOTUZLQBNYANGA-UHFFFAOYSA-N 0.000 description 1
- RQLZWQDFQKUWDY-UHFFFAOYSA-N (2,2-dimethyl-5-oxooxolan-3-yl) prop-2-enoate Chemical compound CC1(C)OC(=O)CC1OC(=O)C=C RQLZWQDFQKUWDY-UHFFFAOYSA-N 0.000 description 1
- OKRLWHAZMUFONP-UHFFFAOYSA-N (2,5-dioxopyrrolidin-1-yl) trifluoromethanesulfonate Chemical compound FC(F)(F)S(=O)(=O)ON1C(=O)CCC1=O OKRLWHAZMUFONP-UHFFFAOYSA-N 0.000 description 1
- NLNVUFXLNHSIQH-UHFFFAOYSA-N (2-ethyl-2-adamantyl) prop-2-enoate Chemical compound C1C(C2)CC3CC1C(CC)(OC(=O)C=C)C2C3 NLNVUFXLNHSIQH-UHFFFAOYSA-N 0.000 description 1
- YRPLSAWATHBYFB-UHFFFAOYSA-N (2-methyl-2-adamantyl) prop-2-enoate Chemical compound C1C(C2)CC3CC1C(C)(OC(=O)C=C)C2C3 YRPLSAWATHBYFB-UHFFFAOYSA-N 0.000 description 1
- MSPUYPFBNZVALC-UHFFFAOYSA-N (2-oxo-4-propyloxan-4-yl) prop-2-enoate Chemical compound C=CC(=O)OC1(CCC)CCOC(=O)C1 MSPUYPFBNZVALC-UHFFFAOYSA-N 0.000 description 1
- DUVDEQGMXBXFEV-UHFFFAOYSA-N (2-oxooxan-4-yl) prop-2-enoate Chemical compound C=CC(=O)OC1CCOC(=O)C1 DUVDEQGMXBXFEV-UHFFFAOYSA-N 0.000 description 1
- OFHHPVYGGQKWQL-UHFFFAOYSA-N (3,3-dimethyl-5-oxooxolan-2-yl)methyl prop-2-enoate Chemical compound CC1(C)CC(=O)OC1COC(=O)C=C OFHHPVYGGQKWQL-UHFFFAOYSA-N 0.000 description 1
- RNWQNJSIQVREPH-UHFFFAOYSA-N (3-ethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2C(CC)(OC(=O)C=C)CC1C2 RNWQNJSIQVREPH-UHFFFAOYSA-N 0.000 description 1
- DKDKCSYKDZNMMA-UHFFFAOYSA-N (3-hydroxy-1-adamantyl) prop-2-enoate Chemical compound C1C(C2)CC3CC1(O)CC2(OC(=O)C=C)C3 DKDKCSYKDZNMMA-UHFFFAOYSA-N 0.000 description 1
- RYNQKSJRFHJZTK-UHFFFAOYSA-N (3-methoxy-3-methylbutyl) acetate Chemical compound COC(C)(C)CCOC(C)=O RYNQKSJRFHJZTK-UHFFFAOYSA-N 0.000 description 1
- VKOQDQSVHAOFJL-UHFFFAOYSA-N (3-methoxy-3-methylbutyl) butanoate Chemical compound CCCC(=O)OCCC(C)(C)OC VKOQDQSVHAOFJL-UHFFFAOYSA-N 0.000 description 1
- VNYGZQZFJDADCT-UHFFFAOYSA-N (3-methyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2C(C)(OC(=O)C=C)CC1C2 VNYGZQZFJDADCT-UHFFFAOYSA-N 0.000 description 1
- ICMBTQSRUNSRKI-UHFFFAOYSA-N (4,4-dimethyl-2-oxooxolan-3-yl) prop-2-enoate Chemical compound CC1(C)COC(=O)C1OC(=O)C=C ICMBTQSRUNSRKI-UHFFFAOYSA-N 0.000 description 1
- YOQPDIXNIJUCFJ-UHFFFAOYSA-N (4,4-dimethyl-5-oxooxolan-3-yl) prop-2-enoate Chemical compound CC1(C)C(OC(=O)C=C)COC1=O YOQPDIXNIJUCFJ-UHFFFAOYSA-N 0.000 description 1
- JARBFWCCCQIDRE-UHFFFAOYSA-N (4-ethyl-2-oxooxan-4-yl) prop-2-enoate Chemical compound C=CC(=O)OC1(CC)CCOC(=O)C1 JARBFWCCCQIDRE-UHFFFAOYSA-N 0.000 description 1
- NYJFKKATAUTNIQ-UHFFFAOYSA-N (4-methyl-2-oxooxan-4-yl) prop-2-enoate Chemical compound C=CC(=O)OC1(C)CCOC(=O)C1 NYJFKKATAUTNIQ-UHFFFAOYSA-N 0.000 description 1
- WTTYZFMBIUWKKQ-UHFFFAOYSA-N (5,5-dimethyl-2-oxooxolan-3-yl) prop-2-enoate Chemical compound CC1(C)CC(OC(=O)C=C)C(=O)O1 WTTYZFMBIUWKKQ-UHFFFAOYSA-N 0.000 description 1
- GKMCOMBDUTZHID-UHFFFAOYSA-N (5-oxooxolan-2-yl)methyl prop-2-enoate Chemical compound C=CC(=O)OCC1CCC(=O)O1 GKMCOMBDUTZHID-UHFFFAOYSA-N 0.000 description 1
- NLFBWKWLKNHTDC-UHFFFAOYSA-N (5-oxooxolan-3-yl) prop-2-enoate Chemical compound C=CC(=O)OC1COC(=O)C1 NLFBWKWLKNHTDC-UHFFFAOYSA-N 0.000 description 1
- FJALTVCJBKZXKY-UHFFFAOYSA-M (7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonate;triphenylsulfanium Chemical compound C1CC2(CS([O-])(=O)=O)C(=O)CC1C2(C)C.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 FJALTVCJBKZXKY-UHFFFAOYSA-M 0.000 description 1
- WKVQNVXAPOFSPQ-UHFFFAOYSA-N (7,7-dimethyl-4-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(OC(=O)C=C)CCC1C2(C)C WKVQNVXAPOFSPQ-UHFFFAOYSA-N 0.000 description 1
- OEPCINZNIXWOPJ-UHFFFAOYSA-N (7-oxo-6-oxabicyclo[3.2.1]octan-4-yl) prop-2-enoate Chemical compound C=CC(=O)OC1CCC2C(=O)OC1C2 OEPCINZNIXWOPJ-UHFFFAOYSA-N 0.000 description 1
- KWUJIHFBJZGYED-UHFFFAOYSA-N (8-ethyl-8-tricyclo[5.2.1.02,6]decanyl) prop-2-enoate Chemical compound C12CCCC2C2CC(OC(=O)C=C)(CC)C1C2 KWUJIHFBJZGYED-UHFFFAOYSA-N 0.000 description 1
- XQEZPZIEUGRMAC-UHFFFAOYSA-N (8-methyl-8-tricyclo[5.2.1.02,6]decanyl) prop-2-enoate Chemical compound C12CCCC2C2CC(OC(=O)C=C)(C)C1C2 XQEZPZIEUGRMAC-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- FANQEIMTCNGAGK-IZZDOVSWSA-N (e)-3-(4-hydroxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one Chemical compound C1=CC(C)=CC=C1C(=O)\C=C\C1=CC=C(O)C=C1 FANQEIMTCNGAGK-IZZDOVSWSA-N 0.000 description 1
- VLLPVDKADBYKLM-UHFFFAOYSA-M 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate;triphenylsulfanium Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 VLLPVDKADBYKLM-UHFFFAOYSA-M 0.000 description 1
- VFYOQDXWCJRSTG-UHFFFAOYSA-N 1,1-bis(1-adamantyl)ethyl prop-2-enoate Chemical compound C1C(C2)CC(C3)CC2CC13C(OC(=O)C=C)(C)C1(C2)CC(C3)CC2CC3C1 VFYOQDXWCJRSTG-UHFFFAOYSA-N 0.000 description 1
- 125000005658 1,2-cycloheptylene group Chemical group 0.000 description 1
- 125000005654 1,2-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([*:2])C([H])([*:1])C1([H])[H] 0.000 description 1
- 125000005837 1,2-cyclopentylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([*:2])C1([H])[H] 0.000 description 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 description 1
- 125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 description 1
- 125000005659 1,3-cycloheptylene group Chemical group 0.000 description 1
- 125000005655 1,3-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([*:2])C1([H])[H] 0.000 description 1
- 125000005838 1,3-cyclopentylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:2])C([H])([H])C1([H])[*:1] 0.000 description 1
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 125000005660 1,4-cycloheptylene group Chemical group 0.000 description 1
- 125000004955 1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([H])C1([H])[*:2] 0.000 description 1
- 125000004958 1,4-naphthylene group Chemical group 0.000 description 1
- SGUVLZREKBPKCE-UHFFFAOYSA-N 1,5-diazabicyclo[4.3.0]-non-5-ene Chemical compound C1CCN=C2CCCN21 SGUVLZREKBPKCE-UHFFFAOYSA-N 0.000 description 1
- WNDABSCBNOUSTE-UHFFFAOYSA-M 1-(4-butoxynaphthalen-1-yl)thiolan-1-ium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.C12=CC=CC=C2C(OCCCC)=CC=C1[S+]1CCCC1 WNDABSCBNOUSTE-UHFFFAOYSA-M 0.000 description 1
- JQIQJUCEFIYYOJ-UHFFFAOYSA-M 1-(4-butoxynaphthalen-1-yl)thiolan-1-ium;trifluoromethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)F.C12=CC=CC=C2C(OCCCC)=CC=C1[S+]1CCCC1 JQIQJUCEFIYYOJ-UHFFFAOYSA-M 0.000 description 1
- KZVBBTZJMSWGTK-UHFFFAOYSA-N 1-[2-(2-butoxyethoxy)ethoxy]butane Chemical compound CCCCOCCOCCOCCCC KZVBBTZJMSWGTK-UHFFFAOYSA-N 0.000 description 1
- BOGFHOWTVGAYFK-UHFFFAOYSA-N 1-[2-(2-propoxyethoxy)ethoxy]propane Chemical compound CCCOCCOCCOCCC BOGFHOWTVGAYFK-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- LIPRQQHINVWJCH-UHFFFAOYSA-N 1-ethoxypropan-2-yl acetate Chemical compound CCOCC(C)OC(C)=O LIPRQQHINVWJCH-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- DMFAHCVITRDZQB-UHFFFAOYSA-N 1-propoxypropan-2-yl acetate Chemical compound CCCOCC(C)OC(C)=O DMFAHCVITRDZQB-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- PZGWADBXBXAQQA-UHFFFAOYSA-M 2,4-bis(fluoromethyl)benzenesulfonate;triphenylsulfanium Chemical compound [O-]S(=O)(=O)C1=CC=C(CF)C=C1CF.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 PZGWADBXBXAQQA-UHFFFAOYSA-M 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- CLAQFLLBRVLVSC-UHFFFAOYSA-N 2-(3-bicyclo[2.2.1]heptanyl)propan-2-yl prop-2-enoate Chemical class C1CC2C(C(C)(OC(=O)C=C)C)CC1C2 CLAQFLLBRVLVSC-UHFFFAOYSA-N 0.000 description 1
- AOLVIBOFADCKFE-UHFFFAOYSA-N 2-(8-tricyclo[5.2.1.02,6]decanyl)propan-2-yl prop-2-enoate Chemical compound C12CCCC2C2CC(C(C)(OC(=O)C=C)C)C1C2 AOLVIBOFADCKFE-UHFFFAOYSA-N 0.000 description 1
- GDQWVPZPTFVESV-UHFFFAOYSA-M 2-(trifluoromethyl)benzenesulfonate;triphenylsulfanium Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1C(F)(F)F.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 GDQWVPZPTFVESV-UHFFFAOYSA-M 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- BYACHAOCSIPLCM-UHFFFAOYSA-N 2-[2-[bis(2-hydroxyethyl)amino]ethyl-(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)CCN(CCO)CCO BYACHAOCSIPLCM-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- AEPWOCLBLLCOGZ-UHFFFAOYSA-N 2-cyanoethyl prop-2-enoate Chemical compound C=CC(=O)OCCC#N AEPWOCLBLLCOGZ-UHFFFAOYSA-N 0.000 description 1
- ZBZGUECSBGUYJC-UHFFFAOYSA-N 2-cyclohexylpropan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)(C)C1CCCCC1 ZBZGUECSBGUYJC-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- FSVQAZDYQRQQKH-UHFFFAOYSA-N 2-methylbutan-2-yl prop-2-enoate Chemical compound CCC(C)(C)OC(=O)C=C FSVQAZDYQRQQKH-UHFFFAOYSA-N 0.000 description 1
- WHFKYDMBUMLWDA-UHFFFAOYSA-N 2-phenoxyethyl acetate Chemical compound CC(=O)OCCOC1=CC=CC=C1 WHFKYDMBUMLWDA-UHFFFAOYSA-N 0.000 description 1
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- JFUOAGBSDGCVES-UHFFFAOYSA-N 3-but-2-enyl-4-methylpyrrolidine-2,5-dione Chemical compound CC=CCC1C(C)C(=O)NC1=O JFUOAGBSDGCVES-UHFFFAOYSA-N 0.000 description 1
- JVUAYVUZADWJBK-UHFFFAOYSA-N 3-cyanopropyl prop-2-enoate Chemical compound C=CC(=O)OCCCC#N JVUAYVUZADWJBK-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- QMYGFTJCQFEDST-UHFFFAOYSA-N 3-methoxybutyl acetate Chemical compound COC(C)CCOC(C)=O QMYGFTJCQFEDST-UHFFFAOYSA-N 0.000 description 1
- VCNYEJFEMXFKTG-UHFFFAOYSA-N 3-methylpentan-3-yl prop-2-enoate Chemical compound CCC(C)(CC)OC(=O)C=C VCNYEJFEMXFKTG-UHFFFAOYSA-N 0.000 description 1
- CZECMMUQQDHWTR-UHFFFAOYSA-N 3-prop-2-enoyloxyadamantane-1-carboxylic acid Chemical compound C1C(C2)CC3CC2(OC(=O)C=C)CC1(C(=O)O)C3 CZECMMUQQDHWTR-UHFFFAOYSA-N 0.000 description 1
- GPIUUMROPXDNRH-UHFFFAOYSA-N 3647-74-3 Chemical compound C1C2C3C(=O)NC(=O)C3C1C=C2 GPIUUMROPXDNRH-UHFFFAOYSA-N 0.000 description 1
- IICCLYANAQEHCI-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3',6'-dihydroxy-2',4',5',7'-tetraiodospiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 IICCLYANAQEHCI-UHFFFAOYSA-N 0.000 description 1
- UNDXPKDBFOOQFC-UHFFFAOYSA-N 4-[2-nitro-4-(trifluoromethyl)phenyl]morpholine Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=CC=C1N1CCOCC1 UNDXPKDBFOOQFC-UHFFFAOYSA-N 0.000 description 1
- YXZXRYDYTRYFAF-UHFFFAOYSA-M 4-methylbenzenesulfonate;triphenylsulfanium Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 YXZXRYDYTRYFAF-UHFFFAOYSA-M 0.000 description 1
- PSCOCYYMRITEJO-UHFFFAOYSA-N 4-methylbenzenesulfonic acid hydroiodide Chemical compound I.CC1=CC=C(S(O)(=O)=O)C=C1 PSCOCYYMRITEJO-UHFFFAOYSA-N 0.000 description 1
- TYMLOMAKGOJONV-UHFFFAOYSA-N 4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1 TYMLOMAKGOJONV-UHFFFAOYSA-N 0.000 description 1
- HEMYIEDNNZJZSV-UHFFFAOYSA-N 4-prop-2-enoyloxybutanoic acid Chemical compound OC(=O)CCCOC(=O)C=C HEMYIEDNNZJZSV-UHFFFAOYSA-N 0.000 description 1
- IEAJQNJSHYCMEK-UHFFFAOYSA-N 5-methoxy-2,5-dimethylhexanoic acid Chemical compound COC(C)(C)CCC(C)C(O)=O IEAJQNJSHYCMEK-UHFFFAOYSA-N 0.000 description 1
- TYOXIFXYEIILLY-UHFFFAOYSA-N 5-methyl-2-phenyl-1h-imidazole Chemical compound N1C(C)=CN=C1C1=CC=CC=C1 TYOXIFXYEIILLY-UHFFFAOYSA-N 0.000 description 1
- PHJQKXAHYOASPO-UHFFFAOYSA-N 5-oxo-4-oxatricyclo[4.2.1.03,7]-nonan-2-yl acrylate Chemical compound O=C1OC2C(OC(=O)C=C)C3CC1C2C3 PHJQKXAHYOASPO-UHFFFAOYSA-N 0.000 description 1
- XHLKOHSAWQPOFO-UHFFFAOYSA-N 5-phenyl-1h-imidazole Chemical compound N1C=NC=C1C1=CC=CC=C1 XHLKOHSAWQPOFO-UHFFFAOYSA-N 0.000 description 1
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 0 CC(*)(C*)*(OC(C1CC2C3C1)C3OC2=O)=O Chemical compound CC(*)(C*)*(OC(C1CC2C3C1)C3OC2=O)=O 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- WJYIASZWHGOTOU-UHFFFAOYSA-N Heptylamine Chemical compound CCCCCCCN WJYIASZWHGOTOU-UHFFFAOYSA-N 0.000 description 1
- HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 description 1
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical class CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- CKNQQGABCZLMQI-UHFFFAOYSA-N [3,3,3-trifluoro-2-hydroxy-2-(trifluoromethyl)propyl] prop-2-enoate Chemical compound FC(F)(F)C(C(F)(F)F)(O)COC(=O)C=C CKNQQGABCZLMQI-UHFFFAOYSA-N 0.000 description 1
- NVJPBZCLWGTJKD-UHFFFAOYSA-N [bis(4-tert-butylphenyl)-lambda3-iodanyl] trifluoromethanesulfonate Chemical compound CC(C)(C)c1ccc(cc1)[I](OS(=O)(=O)C(F)(F)F)c1ccc(cc1)C(C)(C)C NVJPBZCLWGTJKD-UHFFFAOYSA-N 0.000 description 1
- CMEVQVVKINQEGA-UHFFFAOYSA-N [fluoro(hydroxy)methyl] prop-2-enoate Chemical compound OC(F)OC(=O)C=C CMEVQVVKINQEGA-UHFFFAOYSA-N 0.000 description 1
- KYIKRXIYLAGAKQ-UHFFFAOYSA-N abcn Chemical compound C1CCCCC1(C#N)N=NC1(C#N)CCCCC1 KYIKRXIYLAGAKQ-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000004729 acetoacetic acid derivatives Chemical class 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- GPRLTFBKWDERLU-UHFFFAOYSA-N bicyclo[2.2.2]octane Chemical compound C1CC2CCC1CC2 GPRLTFBKWDERLU-UHFFFAOYSA-N 0.000 description 1
- MDUKBVGQQFOMPC-UHFFFAOYSA-M bis(4-tert-butylphenyl)iodanium;(7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonate Chemical compound C1CC2(CS([O-])(=O)=O)C(=O)CC1C2(C)C.C1=CC(C(C)(C)C)=CC=C1[I+]C1=CC=C(C(C)(C)C)C=C1 MDUKBVGQQFOMPC-UHFFFAOYSA-M 0.000 description 1
- DJBAOXYQCAKLPH-UHFFFAOYSA-M bis(4-tert-butylphenyl)iodanium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.C1=CC(C(C)(C)C)=CC=C1[I+]C1=CC=C(C(C)(C)C)C=C1 DJBAOXYQCAKLPH-UHFFFAOYSA-M 0.000 description 1
- SDAQQOKKCSSGPU-UHFFFAOYSA-M bis(4-tert-butylphenyl)iodanium;2,4-difluorobenzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=C(F)C=C1F.C1=CC(C(C)(C)C)=CC=C1[I+]C1=CC=C(C(C)(C)C)C=C1 SDAQQOKKCSSGPU-UHFFFAOYSA-M 0.000 description 1
- ILYGGWOGJKVSLD-UHFFFAOYSA-M bis(4-tert-butylphenyl)iodanium;2-(trifluoromethyl)benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1C(F)(F)F.C1=CC(C(C)(C)C)=CC=C1[I+]C1=CC=C(C(C)(C)C)C=C1 ILYGGWOGJKVSLD-UHFFFAOYSA-M 0.000 description 1
- IBWLSQDQZDVNSS-UHFFFAOYSA-M bis(4-tert-butylphenyl)iodanium;4-(trifluoromethyl)benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=C(C(F)(F)F)C=C1.C1=CC(C(C)(C)C)=CC=C1[I+]C1=CC=C(C(C)(C)C)C=C1 IBWLSQDQZDVNSS-UHFFFAOYSA-M 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000002592 cumenyl group Chemical group C1(=C(C=CC=C1)*)C(C)C 0.000 description 1
- 150000003997 cyclic ketones Chemical class 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- 125000004956 cyclohexylene group Chemical group 0.000 description 1
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 1
- 239000004914 cyclooctane Substances 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- WYACBZDAHNBPPB-UHFFFAOYSA-N diethyl oxalate Chemical compound CCOC(=O)C(=O)OCC WYACBZDAHNBPPB-UHFFFAOYSA-N 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012156 elution solvent Substances 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- CKSRFHWWBKRUKA-UHFFFAOYSA-N ethyl 2-ethoxyacetate Chemical compound CCOCC(=O)OCC CKSRFHWWBKRUKA-UHFFFAOYSA-N 0.000 description 1
- GFUIDHWFLMPAGY-UHFFFAOYSA-N ethyl 2-hydroxy-2-methylpropanoate Chemical compound CCOC(=O)C(C)(C)O GFUIDHWFLMPAGY-UHFFFAOYSA-N 0.000 description 1
- ZANNOFHADGWOLI-UHFFFAOYSA-N ethyl 2-hydroxyacetate Chemical compound CCOC(=O)CO ZANNOFHADGWOLI-UHFFFAOYSA-N 0.000 description 1
- IJUHLFUALMUWOM-UHFFFAOYSA-N ethyl 3-methoxypropanoate Chemical compound CCOC(=O)CCOC IJUHLFUALMUWOM-UHFFFAOYSA-N 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 125000005348 fluorocycloalkyl group Chemical group 0.000 description 1
- 125000000457 gamma-lactone group Chemical group 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 125000002510 isobutoxy group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])O* 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical class CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- NSPJNIDYTSSIIY-UHFFFAOYSA-N methoxy(methoxymethoxy)methane Chemical compound COCOCOC NSPJNIDYTSSIIY-UHFFFAOYSA-N 0.000 description 1
- BDJSOPWXYLFTNW-UHFFFAOYSA-N methyl 3-methoxypropanoate Chemical compound COCCC(=O)OC BDJSOPWXYLFTNW-UHFFFAOYSA-N 0.000 description 1
- RSHHLLPATMBHLF-UHFFFAOYSA-N methyl 5-oxo-2-prop-2-enoyloxy-4-oxatricyclo[4.2.1.03,7]nonane-9-carboxylate Chemical compound O1C(=O)C2C(C(=O)OC)C3C(OC(=O)C=C)C1C2C3 RSHHLLPATMBHLF-UHFFFAOYSA-N 0.000 description 1
- UNBCAWPOIGWLFH-UHFFFAOYSA-N methyl 7-oxo-4-prop-2-enoyloxy-6-oxabicyclo[3.2.1]octane-2-carboxylate Chemical compound COC(=O)C1CC(OC(=O)C=C)C2OC(=O)C1C2 UNBCAWPOIGWLFH-UHFFFAOYSA-N 0.000 description 1
- 229940057867 methyl lactate Drugs 0.000 description 1
- ZQJAONQEOXOVNR-UHFFFAOYSA-N n,n-di(nonyl)nonan-1-amine Chemical compound CCCCCCCCCN(CCCCCCCCC)CCCCCCCCC ZQJAONQEOXOVNR-UHFFFAOYSA-N 0.000 description 1
- COFKFSSWMQHKMD-UHFFFAOYSA-N n,n-didecyldecan-1-amine Chemical compound CCCCCCCCCCN(CCCCCCCCCC)CCCCCCCCCC COFKFSSWMQHKMD-UHFFFAOYSA-N 0.000 description 1
- CLZGJKHEVKJLLS-UHFFFAOYSA-N n,n-diheptylheptan-1-amine Chemical compound CCCCCCCN(CCCCCCC)CCCCCCC CLZGJKHEVKJLLS-UHFFFAOYSA-N 0.000 description 1
- DIAIBWNEUYXDNL-UHFFFAOYSA-N n,n-dihexylhexan-1-amine Chemical compound CCCCCCN(CCCCCC)CCCCCC DIAIBWNEUYXDNL-UHFFFAOYSA-N 0.000 description 1
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 1
- OOHAUGDGCWURIT-UHFFFAOYSA-N n,n-dipentylpentan-1-amine Chemical compound CCCCCN(CCCCC)CCCCC OOHAUGDGCWURIT-UHFFFAOYSA-N 0.000 description 1
- 125000006606 n-butoxy group Chemical group 0.000 description 1
- GMTCPFCMAHMEMT-UHFFFAOYSA-N n-decyldecan-1-amine Chemical compound CCCCCCCCCCNCCCCCCCCCC GMTCPFCMAHMEMT-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- NJWMENBYMFZACG-UHFFFAOYSA-N n-heptylheptan-1-amine Chemical compound CCCCCCCNCCCCCCC NJWMENBYMFZACG-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- PXSXRABJBXYMFT-UHFFFAOYSA-N n-hexylhexan-1-amine Chemical compound CCCCCCNCCCCCC PXSXRABJBXYMFT-UHFFFAOYSA-N 0.000 description 1
- MFHKEJIIHDNPQE-UHFFFAOYSA-N n-nonylnonan-1-amine Chemical compound CCCCCCCCCNCCCCCCCCC MFHKEJIIHDNPQE-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004923 naphthylmethyl group Chemical group C1(=CC=CC2=CC=CC=C12)C* 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- RNVCVTLRINQCPJ-UHFFFAOYSA-N ortho-methyl aniline Natural products CC1=CC=CC=C1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000006551 perfluoro alkylene group Chemical group 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 125000001484 phenothiazinyl group Chemical class C1(=CC=CC=2SC3=CC=CC=C3NC12)* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- NLDFTWSUPLJCQD-UHFFFAOYSA-N prop-1-en-2-yl propanoate Chemical compound CCC(=O)OC(C)=C NLDFTWSUPLJCQD-UHFFFAOYSA-N 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- ILVGAIQLOCKNQA-UHFFFAOYSA-N propyl 2-hydroxypropanoate Chemical compound CCCOC(=O)C(C)O ILVGAIQLOCKNQA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003220 pyrenes Chemical class 0.000 description 1
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000004728 pyruvic acid derivatives Chemical class 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- 229940081623 rose bengal Drugs 0.000 description 1
- 229930187593 rose bengal Natural products 0.000 description 1
- STRXNPAVPKGJQR-UHFFFAOYSA-N rose bengal A Natural products O1C(=O)C(C(=CC=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 STRXNPAVPKGJQR-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 230000005469 synchrotron radiation Effects 0.000 description 1
- NZNVBGIQMWGYRR-UHFFFAOYSA-N tert-butyl 2-phenylbenzimidazole-1-carboxylate Chemical compound N=1C2=CC=CC=C2N(C(=O)OC(C)(C)C)C=1C1=CC=CC=C1 NZNVBGIQMWGYRR-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- CROWJIMGVQLMPG-UHFFFAOYSA-N tert-butyl benzimidazole-1-carboxylate Chemical compound C1=CC=C2N(C(=O)OC(C)(C)C)C=NC2=C1 CROWJIMGVQLMPG-UHFFFAOYSA-N 0.000 description 1
- MTBKGWHHOBJMHJ-UHFFFAOYSA-N tert-butyl imidazole-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1C=CN=C1 MTBKGWHHOBJMHJ-UHFFFAOYSA-N 0.000 description 1
- KMUNFRBJXIEULW-UHFFFAOYSA-N tert-butyl n,n-bis(2-hydroxyethyl)carbamate Chemical compound CC(C)(C)OC(=O)N(CCO)CCO KMUNFRBJXIEULW-UHFFFAOYSA-N 0.000 description 1
- WIURVMHVEPTKHB-UHFFFAOYSA-N tert-butyl n,n-dicyclohexylcarbamate Chemical compound C1CCCCC1N(C(=O)OC(C)(C)C)C1CCCCC1 WIURVMHVEPTKHB-UHFFFAOYSA-N 0.000 description 1
- UQEXYHWLLMPVRB-UHFFFAOYSA-N tert-butyl n,n-dioctylcarbamate Chemical compound CCCCCCCCN(C(=O)OC(C)(C)C)CCCCCCCC UQEXYHWLLMPVRB-UHFFFAOYSA-N 0.000 description 1
- QJONCGVUGJUWJQ-UHFFFAOYSA-N tert-butyl n,n-diphenylcarbamate Chemical compound C=1C=CC=CC=1N(C(=O)OC(C)(C)C)C1=CC=CC=C1 QJONCGVUGJUWJQ-UHFFFAOYSA-N 0.000 description 1
- RQCNHUCCQJMSRG-UHFFFAOYSA-N tert-butyl piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1 RQCNHUCCQJMSRG-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 125000005951 trifluoromethanesulfonyloxy group Chemical group 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- FAYMLNNRGCYLSR-UHFFFAOYSA-M triphenylsulfonium triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 FAYMLNNRGCYLSR-UHFFFAOYSA-M 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 125000006839 xylylene group Chemical group 0.000 description 1
Landscapes
- Materials For Photolithography (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
(i)R3、R4及びR5は、炭素数4〜20の1価の脂環式炭化水素基もしくはその誘導体、又は炭素数1〜4の直鎖状もしくは分岐状のアルキル基を示し、この中の少なくとも1つは炭素数4〜20の1価の脂環式炭化水素基である。
(ii)R3、R4及びR5のいずれか2つが互いに結合して、それぞれが結合している炭素原子も含めて炭素数4〜20の2価の脂環式炭化水素基もしくはその誘導体を形成し、残りの1つが炭素数4〜20の1価の脂環式炭化水素基もしくはその誘導体、又は炭素数1〜4の直鎖状もしくは分岐状のアルキル基である。〕
(A)成分である樹脂(以下、「樹脂(A)」という)は、その分子鎖の一方あるいは両方の末端に下記一般式(1)で表される基(以下「末端基(1)という」)を有する。
(i)R3、R4及びR5は、炭素数4〜20の1価の脂環式炭化水素基もしくはその誘導体、又は炭素数1〜4の直鎖状もしくは分岐状のアルキル基を示し、この中の少なくとも1つは炭素数4〜20の1価の脂環式炭化水素基である。
(ii)R3、R4及びR5のいずれか2つが互いに結合して、それぞれが結合している炭素原子も含めて炭素数4〜20の2価の脂環式炭化水素基もしくはその誘導体を形成し、残りの1つが炭素数4〜20の1価の脂環式炭化水素基もしくはその誘導体、又は炭素数1〜4の直鎖状もしくは分岐状のアルキル基である。〕
(メタ)アクリル酸、(メタ)アクリル酸−3−ヒドロキシアダマンタン−1−イルエステル、(メタ)アクリル酸−5(6)−ヒドロキシビシクロ[2.2.1]ヘプト−2−イルエステル、(メタ)アクリル酸−9(10)−ヒドロキシテトラシクロ[6.2.1.13,6.02,7.]ドデカ−4−イル、(メタ)アクリル酸カルボキシルメチルエステル、(メタ)アクリル酸−2−カルボキシルエチルエステル、(メタ)アクリル酸−3−カルボキシルプロピルエステル、(メタ)アクリル酸−3−カルボキシアダマンタン−1−イルエステル、(メタ)アクリル酸−5(6)−カルボキシビシクロ[2.2.1]ヘプト−2−イルエステル、(メタ)アクリル酸−9(10)−カルボキシテトラシクロ[6.2.1.13,6.02,7.]ドデカ−4−イルエステル、(メタ)アクリル酸シアノメチルエステル、1−(メタ)アクリル酸−2−シアノエチルエステル、1−(メタ)アクリル酸−3−シアノプロピルエステル、(メタ)アクリル酸−3−シアノアダマンタン−1−イル、(メタ)アクリル酸−5(6)−シアノビシクロ[2.2.1]ヘプト−2−イルエステル、(メタ)アクリル酸−9(10)−シアノテトラシクロ[6.2.1.13,6.02,7.]ドデカ−4−イルエステル、;
(メタ)アクリル酸−t−ブチルエステル、(メタ)アクリル酸−2−メチル−2−プロピルエステル、(メタ)アクリル酸−2−メチル−2−ブチルエステル、(メタ)アクリル酸−2−エチル−2−ブチルエステル、(メタ)アクリル酸−3−エチル−3−ブチルエステル;
(メタ)アクリル酸メチルエステル、(メタ)アクリル酸エチルエステル、(メタ)アクリル酸n−プロピルエステル、(メタ)アクリル酸シクロペンチルエステル、(メタ)アクリル酸シクロヘキシルエステル、(メタ)アクリル酸アダマンタン−1−イルエステル、(メタ)アクリル酸ビシクロ[2.2.1]ヘプト−2−イルエステル、(メタ)アクリル酸−7,7−ジメチルビシクロ[2.2.1]ヘプタ−1−イルエステル、(メタ)アクリル酸トリシクロ[5.2.1.02,6]デカ−8−イルエステル、(メタ)アクリル酸テトラシクロ[6.2.1.13,6.02,7.]ドデカ−4−イルエステル;
(メタ)アクリル酸−7−オキソ−6−オキサ−ビシクロ[3.2.1]オクタ−4−イルエステル、(メタ)アクリル酸−2−メトキシカルボニル−7−オキソ−6−オキサ−ビシクロ[3.2.1]オクタ−4−イルエステル、(メタ)アクリル酸−2−オキソテトラヒドロピラン−4−イルエステル、(メタ)アクリル酸−4−メチル−2−オキソテトラヒドロピラン−4−イルエステル、(メタ)アクリル酸−4−エチル−2−オキソテトラヒドロピラン−4−イルエステル、(メタ)アクリル酸−4−プロピル−2−オキソテトラヒドロピラン−4−イルエステル、(メタ)アクリル酸−5−オキソテトラヒドロフラン−3−イルエステル、(メタ)アクリル酸−2,2−ジメチル−5−オキソテトラヒドロフラン−3−イルエステル、(メタ)アクリル酸−4,4−ジメチル−5−オキソテトラヒドロフラン−3−イルエステル、(メタ)アクリル酸−2−オキソテトラヒドロフラン−3−イルエステル、(メタ)アクリル酸−4,4−ジメチル−2−オキソテトラヒドロフラン−3−イルエステル、(メタ)アクリル酸−5,5−ジメチル−2−オキソテトラヒドロフラン−3−イルエステル、(メタ)アクリル酸−2−オキソテトラヒドロフラン−3−イルエステル、(メタ)アクリル酸−5−オキソテトラヒドロフラン−2−イルメチルエステル、(メタ)アクリル酸−3,3−ジメチル−5−オキソテトラヒドロフラン−2−イルメチルエステル、(メタ)アクリル酸−4,4−ジメチル−5−オキソテトラヒドロフラン−2−イルメチルエステル等が挙げられる。
本発明において使用される感放射線性酸発生剤は、露光により酸を発生する化合物であり、この酸の作用によって、樹脂(A)に存在する特定の基が解離し、その結果レジスト被膜の露光部がアルカリ現像液に易溶性となり、レジストパターンを形成することができる。
感放射線性樹脂組成物が、感放射線性酸発生剤から発生する酸の拡散を制御する酸拡散制御剤を添加することにより、レジストパターンの側壁の垂直性をより効果的に改善することができる。また、このような酸拡散制御剤を配合することにより、感放射線性樹脂組成物の貯蔵安定性が向上するとともに、レジストとしての解像度が更に向上し、また露光から現像処理までの引き置き時間(PED)の変動によるレジストパターンの線幅変化を抑えることができ、その結果、プロセス安定性に極めて優れた感放射線性樹脂組成物となり得る。
−溶解制御剤−
感放射線性樹脂組成物には、酸の作用により、アルカリ現像液に対する溶解性が高くなる性質を有する溶解制御剤を配合することもできる。このような溶解制御剤としては、例えば、フェノール性水酸基、カルボキシル基、スルホン酸基等の酸性官能基を有する化合物や、該化合物中の酸性官能基の水素原子をを酸解離性基で置換した化合物等を挙げることができる。前記溶解制御剤は、単独で又は2種以上を混合して使用することができる。溶解制御剤の配合量は、感放射線性樹脂組成物中の全樹脂成分100質量部に対し、通常、10質量部以下、好ましくは5質量部以下である。
感放射線性樹脂組成物には、感放射線性樹脂組成物の塗布性、ストリエーション、現像性等を改良する作用を示す界面活性剤を配合することもできる。このような界面活性剤としては、アニオン系、カチオン系、ノニオン系又は両性の界面活性剤のいずれでも使用することができるが、好ましくはノニオン系界面活性剤である。ノニオン系界面活性剤としては、例えば、ポリオキシエチレン高級アルキルエーテル類、ポリオキシエチレン高級アルキルフェニルエーテル類、ポリエチレングリコールの高級脂肪酸ジエステル類の他、以下商品名で、「KP」(信越化学工業製)、「ポリフロー」(共栄社油脂化学工業製)、「エフトップ」(トーケムプロダクツ製)、「メガファック」(大日本インキ化学工業製)、「フロラード」(住友スリーエム製)、「アサヒガード」及び「サーフロン」(旭硝子製)等の各シリーズ等を挙げることができる。界面活性剤は、単独で又は2種以上を混合して使用することができる。界面活性剤の配合量は、感放射線性樹脂組成物中の全樹脂成分100質量部に対し、界面活性剤の有効成分として、通常、2質量部以下、好ましくは1.5質量部以下である。
感放射線性樹脂組成物には、放射線のエネルギーを吸収して、そのエネルギーを感放射線性酸発生剤に伝達し、それにより酸の生成量を増加する作用を有し、感放射線性樹脂組成物の見掛けの感度を向上させることができる増感剤を配合することもできる。このような増感剤としては、例えば、アセトフェノン類、ベンゾフェノン類、ナフタレン類、ビアセチル、エオシン、ローズベンガル、ピレン類、アントラセン類、フェノチアジン類等を挙げることができる。これらの増感剤は、単独で又は2種以上を混合して使用することができる。増感剤の配合量は、感放射線性樹脂組成物中の全樹脂成分100質量部に対して、通常、50質量部以下、好ましくは30質量部以下である。
感放射線性樹脂組成物は、通常、使用時に各成分を溶剤に溶解して均一溶液とし、その後必要に応じて、例えば孔径0.2μm程度のフィルター等でろ過することにより、組成物溶液として調製される。
レジストパターンは以下のような方法により感放射線性樹脂組成物から形成することができる。上述のようにして調製された組成物溶液を、回転塗布、流延塗布、ロール塗布等の適宜の塗布手段によって、例えば、シリコンウエハー、アルミニウムで被覆されたウエハー等の基板上に塗布することにより、レジスト被膜を形成する。その後、場合により予め加熱処理(以下、「PB」という。)を行ったのち、所定のマスクパターンを介して、該レジスト被膜に露光する。
下記に示す化合物(8−1)53.92g(50モル%)、化合物(8−2)10.69g(10モル%)、化合物(8−3)35.38g(40モル%)を2−ブタノン187gに溶かし、更にジメチル2,2’−アゾビス(2−メチルプロピオネート)2.24g、3−メルカプトプロピオン酸3.5gを投入した単量体溶液を準備し、100gの2−ブタノンを投入した1000mlの三口フラスコを30分窒素パージした。窒素パージの後、三口フラスコ内を攪拌しながら80℃に加熱し、事前に準備した上記単量体溶液を滴下漏斗を用いて3時間かけて滴下した。滴下開始を重合開始時間とし、重合反応を6時間実施した。重合終了後、重合溶液は水冷することにより30℃以下に冷却し、2000gのメタノールへ投入し、析出した白色粉末をろ別した。
下記に示す化合物(9−1)24.31g(50モル%)、化合物(9−2)7.75g(15モル%)、化合物(9−3)17.94g(35モル%)を2−ブタノン150gに更にジメチル2,2’−アゾビス(2−メチルプロピオネート)1.01g、3−メルカプトプロピオン酸1.75gを投入した単量体溶液を準備し、100gの2−ブタノンを投入した1000mlの三口フラスコを30分窒素パージした。窒素パージの後、三口フラスコ内を攪拌しながら80℃に加熱し、事前に準備した上記単量体溶液を滴下漏斗を用いて3時間かけて滴下した。滴下開始を重合開始時間とし、重合反応を6時間実施した。重合終了後、重合溶液は水冷することにより30℃以下に冷却し、2000gのメタノールへ投入し、析出した白色粉末をろ別した。
下記に示す化合物(10−1)24.62g(50モル%)、化合物(10−2)5.77g(37モル%)、化合物(10−3)19.61g(13モル%)を2−ブタノン150gに溶解させ、更にジメチル2,2’−アゾビス(2−メチルプロピオネート)1.04g、3−メルカプトプロピオン酸1.75gを投入した単量体溶液を準備し、100gの2−ブタノンを投入した1000mlの三口フラスコを30分窒素パージした。窒素パージの後、三口フラスコ内を攪拌しながら80℃に加熱し、事前に準備した上記単量体溶液を滴下漏斗を用いて3時間かけて滴下した。滴下開始を重合開始時間とし、重合反応を6時間実施した。重合終了後、重合溶液は水冷することにより30℃以下に冷却し、2000gのメタノールへ投入し、析出した白色粉末をろ別した。
上記化合物(8−1)53.92g(50モル%)、化合物(8−2)10.69g(10モル%)、化合物(8−3)35.38g(40モル%)を2−ブタノン187gに溶かし、更にジメチル2,2’−アゾビス(2−メチルプロピオネート)2.24gを投入した単量体溶液を準備し、100gの2−ブタノンを投入した1000mlの三口フラスコを30分窒素パージした。窒素パージの後、三口フラスコ内を攪拌しながら80℃に加熱し、事前に準備した上記単量体溶液を滴下漏斗を用いて3時間かけて滴下した。滴下開始を重合開始時間とし、重合反応を6時間実施した。重合終了後、重合溶液は水冷することにより30℃以下に冷却し、2000gのメタノールへ投入し、析出した白色粉末をろ別した。
上記化合物(9−1)24.31g(50モル%)、化合物(9−2)7.75g(15モル%)、化合物(9−3)17.94g(35モル%)を2−ブタノン150gに更にジメチル2,2’−アゾビス(2−メチルプロピオネート)1.01g単量体溶液を準備し、100gの2−ブタノンを投入した1000mlの三口フラスコを30分窒素パージした。窒素パージの後、三口フラスコ内を攪拌しながら80℃に加熱し、事前に準備した上記単量体溶液を滴下漏斗を用いて3時間かけて滴下した。滴下開始を重合開始時間とし、重合反応を6時間実施した。重合終了後、重合溶液は水冷することにより30℃以下に冷却し、2000gのメタノールへ投入し、析出した白色粉末をろ別した。
上記化合物(10−1)24.62g(50モル%)、化合物(10−2)5.77g(37モル%)、化合物(10−3)19.61g(13モル%)を2−ブタノン150gに溶解させ、更にジメチル2,2’−アゾビス(2−メチルプロピオネート)1.04gを投入した単量体溶液を準備し、100gの2−ブタノンを投入した1000mlの三口フラスコを30分窒素パージした。窒素パージの後、三口フラスコ内を攪拌しながら80℃に加熱し、事前に準備した上記単量体溶液を滴下漏斗を用いて3時間かけて滴下した。滴下開始を重合開始時間とし、重合反応を6時間実施した。重合終了後、重合溶液は水冷することにより30℃以下に冷却し、2000gのメタノールへ投入し、析出した白色粉末をろ別した。
上記化合物(10−1)49.24g(100モル%)を2−ブタノン150gに溶解させ、更にジメチル2,2’−アゾビス(2−メチルプロピオネート)1.04g、3−メルカプトプロピオン酸1.75gを投入した単量体溶液を準備し、100gの2−ブタノンを投入した1000mlの三口フラスコを30分窒素パージした。窒素パージの後、三口フラスコ内を攪拌しながら80℃に加熱し、事前に準備した上記単量体溶液を滴下漏斗を用いて3時間かけて滴下した。滴下開始を重合開始時間とし、重合反応を6時間実施した。重合終了後、重合溶液は水冷することにより30℃以下に冷却し、2000gのメタノールへ投入し、析出した白色粉末をろ別した。
合成例1〜3及び比較合成例1〜4で得られた各樹脂と、以下に示す酸発生剤と、他の成分とを表1に示す割合で配合して均一溶液としたのち、孔径0.2μmのメンブランフィルターでろ過して、実施例1〜3及び比較例1〜4の各組成物溶液を調製した。得られた感放射線性樹脂組成物溶液を表2に示す条件にて露光して各種評価を行った。評価結果を表3に示す。ここで、部は、特記しない限り質量基準である。
(B−1):トリフェニルスルホニウム・ノナフルオロ−n−ブタンスルホネート
[酸拡散制御剤(C)]
(C−1):2−フェニルベンズイミダゾール
[溶剤(D)]
(D−1):プロピレングリコールメチルエーテルアセテート
(D−2):シクロヘキサノン
(1)感度:
ウエハー表面に膜厚770オングストロームのARC29(Brewer Science社製)膜を形成したシリコンウエハー(ARC29)を用い、各組成物溶液を、基板上にスピンコートにより塗布し、ホットプレート上にて、表2に示す条件でPBを行って形成した膜厚0.25μmのレジスト被膜に、ニコン製ArFエキシマレーザー露光装置(開口数0.75)を用い、マスクパターンを介して露光した。その後、表2に示す条件でPEBを行ったのち、2.38質量%のテトラメチルアンモニウムヒドロキシド水溶液により、25℃で60秒間現像し、水洗、乾燥して、ポジ型のレジストパターンを形成した。このとき、線幅0.11μmのライン・アンド・スペースパターン(1L1S)を1対1の線幅に形成する露光量を最適露光量とし、この最適露光量を感度とした。
最適露光量で解像される最小のライン・アンド・スペースパターンの寸法を解像度とした。
線幅0.16μmのライン・アンド・スペースパターン(1L1S)の方形状断面の下辺寸法L1と上辺寸法L2とを走査型電子顕微鏡により測定し、0.85≦L2/L1≦1を満足し、かつパターンプロファイルが裾を引いていない場合を、パターンプロファイルが”良好”であるとした。
最適露光量にて解像した110nm1L/1Sパターンの観測において、日立製測長SEM:S9220にてパターン上部から観察する際、線幅を任意のポイントで観測し、その測定ばらつきを3シグマで評価した。
Claims (2)
- (A)分子鎖の少なくとも一方の末端に下記一般式(1)で表される基を有し、かつアルカリ難溶性あるいは不溶性であり、酸の作用によりアルカリ易溶性となる樹脂であって、下記一般式(2)で表される繰り返し単位、及び下記一般式(3)で表される繰り返し単位を有する樹脂、及び
(B)感放射線性酸発生剤
を含有する感放射線性樹脂組成物。
(i)R3、R4及びR5は、炭素数4〜20の1価の脂環式炭化水素基もしくはその誘導体、又は炭素数1〜4の直鎖状もしくは分岐状のアルキル基を示し、この中の少なくとも1つは炭素数4〜20の1価の脂環式炭化水素基である。
(ii)R3、R4及びR5のいずれか2つが互いに結合して、それぞれが結合している炭素原子も含めて炭素数4〜20の2価の脂環式炭化水素基もしくはその誘導体を形成し、残りの1つが炭素数4〜20の1価の脂環式炭化水素基もしくはその誘導体、又は炭素数1〜4の直鎖状もしくは分岐状のアルキル基である。〕
- (C)酸拡散制御剤を含有する請求項1に記載の感放射線性樹脂組成物。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004312826A JP4645153B2 (ja) | 2004-10-27 | 2004-10-27 | 感放射線性樹脂組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004312826A JP4645153B2 (ja) | 2004-10-27 | 2004-10-27 | 感放射線性樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006126365A true JP2006126365A (ja) | 2006-05-18 |
JP4645153B2 JP4645153B2 (ja) | 2011-03-09 |
Family
ID=36721199
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004312826A Active JP4645153B2 (ja) | 2004-10-27 | 2004-10-27 | 感放射線性樹脂組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4645153B2 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007272194A (ja) * | 2006-01-24 | 2007-10-18 | Fujifilm Corp | ポジ型感光性組成物及びそれを用いたパターン形成方法 |
JP2007327983A (ja) * | 2006-06-06 | 2007-12-20 | Jsr Corp | 感放射線性樹脂組成物 |
JP2008046541A (ja) * | 2006-08-21 | 2008-02-28 | Jsr Corp | 上層膜形成組成物用樹脂、上層膜形成組成物、及びフォトレジストパターン形成方法 |
JP2008058538A (ja) * | 2006-08-30 | 2008-03-13 | Jsr Corp | 感放射線性樹脂組成物 |
JP2010002762A (ja) * | 2008-06-20 | 2010-01-07 | Fujifilm Corp | 液浸露光用レジスト組成物及びそれを用いたパターン形成方法 |
US9052594B2 (en) | 2006-01-24 | 2015-06-09 | Fujifilm Corporation | Positive photosensitive composition and method of forming pattern using the same |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1055069A (ja) * | 1996-08-09 | 1998-02-24 | Japan Synthetic Rubber Co Ltd | 感放射線性樹脂組成物 |
JP2001117232A (ja) * | 1999-10-19 | 2001-04-27 | Fuji Photo Film Co Ltd | 遠紫外線露光用ポジ型レジスト組成物 |
JP2001117231A (ja) * | 1999-10-19 | 2001-04-27 | Fuji Photo Film Co Ltd | 遠紫外線露光用ポジ型フォトレジスト組成物 |
JP2001330959A (ja) * | 2000-05-23 | 2001-11-30 | Jsr Corp | ポジ型感放射線性樹脂組成物 |
JP2002062657A (ja) * | 2000-06-09 | 2002-02-28 | Jsr Corp | 感放射線性樹脂組成物 |
JP2002311590A (ja) * | 2001-04-12 | 2002-10-23 | Jsr Corp | 感放射線性樹脂組成物 |
JP2004250377A (ja) * | 2003-02-20 | 2004-09-09 | Maruzen Petrochem Co Ltd | チオール化合物、共重合体及び共重合体の製造方法 |
JP2005122035A (ja) * | 2003-10-20 | 2005-05-12 | Fuji Photo Film Co Ltd | ポジ型レジスト組成物及びそれを用いたパターン形成方法 |
JP2006052373A (ja) * | 2004-04-12 | 2006-02-23 | Mitsubishi Rayon Co Ltd | レジスト用重合体 |
-
2004
- 2004-10-27 JP JP2004312826A patent/JP4645153B2/ja active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1055069A (ja) * | 1996-08-09 | 1998-02-24 | Japan Synthetic Rubber Co Ltd | 感放射線性樹脂組成物 |
JP2001117232A (ja) * | 1999-10-19 | 2001-04-27 | Fuji Photo Film Co Ltd | 遠紫外線露光用ポジ型レジスト組成物 |
JP2001117231A (ja) * | 1999-10-19 | 2001-04-27 | Fuji Photo Film Co Ltd | 遠紫外線露光用ポジ型フォトレジスト組成物 |
JP2001330959A (ja) * | 2000-05-23 | 2001-11-30 | Jsr Corp | ポジ型感放射線性樹脂組成物 |
JP2002062657A (ja) * | 2000-06-09 | 2002-02-28 | Jsr Corp | 感放射線性樹脂組成物 |
JP2002311590A (ja) * | 2001-04-12 | 2002-10-23 | Jsr Corp | 感放射線性樹脂組成物 |
JP2004250377A (ja) * | 2003-02-20 | 2004-09-09 | Maruzen Petrochem Co Ltd | チオール化合物、共重合体及び共重合体の製造方法 |
JP2005122035A (ja) * | 2003-10-20 | 2005-05-12 | Fuji Photo Film Co Ltd | ポジ型レジスト組成物及びそれを用いたパターン形成方法 |
JP2006052373A (ja) * | 2004-04-12 | 2006-02-23 | Mitsubishi Rayon Co Ltd | レジスト用重合体 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007272194A (ja) * | 2006-01-24 | 2007-10-18 | Fujifilm Corp | ポジ型感光性組成物及びそれを用いたパターン形成方法 |
US9052594B2 (en) | 2006-01-24 | 2015-06-09 | Fujifilm Corporation | Positive photosensitive composition and method of forming pattern using the same |
JP2007327983A (ja) * | 2006-06-06 | 2007-12-20 | Jsr Corp | 感放射線性樹脂組成物 |
JP2008046541A (ja) * | 2006-08-21 | 2008-02-28 | Jsr Corp | 上層膜形成組成物用樹脂、上層膜形成組成物、及びフォトレジストパターン形成方法 |
JP2008058538A (ja) * | 2006-08-30 | 2008-03-13 | Jsr Corp | 感放射線性樹脂組成物 |
JP4710762B2 (ja) * | 2006-08-30 | 2011-06-29 | Jsr株式会社 | 感放射線性樹脂組成物 |
JP2010002762A (ja) * | 2008-06-20 | 2010-01-07 | Fujifilm Corp | 液浸露光用レジスト組成物及びそれを用いたパターン形成方法 |
Also Published As
Publication number | Publication date |
---|---|
JP4645153B2 (ja) | 2011-03-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5578170B2 (ja) | 感放射線性樹脂組成物および重合体 | |
JP4182868B2 (ja) | 感放射線性樹脂組成物 | |
JP2013145384A (ja) | 感放射線性組成物及びそれに用いられる低分子量化合物の製造方法 | |
JP2009114381A (ja) | (メタ)アクリル酸エステル樹脂 | |
JPWO2011115190A1 (ja) | 感放射線性樹脂組成物 | |
JP4199958B2 (ja) | 感放射線性樹脂組成物 | |
JP4277420B2 (ja) | 感放射線性樹脂組成物 | |
JP4661397B2 (ja) | 感放射線性樹脂組成物 | |
JP4645153B2 (ja) | 感放射線性樹脂組成物 | |
JP4076360B2 (ja) | 感放射線性樹脂組成物 | |
WO2007148492A1 (ja) | ポジ型レジスト組成物およびレジストパターン形成方法 | |
JP2007065504A (ja) | レジスト組成物及びレジスト用重合体の製造方法 | |
JP2006301304A (ja) | 感放射線性樹脂組成物 | |
JP4513501B2 (ja) | 感放射線性樹脂組成物 | |
JP4254490B2 (ja) | 酸解離性基含有重合体および感放射線性樹脂組成物 | |
JP3843840B2 (ja) | 感放射線性樹脂組成物 | |
JP2010047668A (ja) | 重合体及び感放射線性組成物並びに単量体 | |
JP4069497B2 (ja) | 感放射線性樹脂組成物 | |
JP4134685B2 (ja) | 感放射線性樹脂組成物 | |
JP3968509B2 (ja) | 感放射線性樹脂組成物 | |
JP4802551B2 (ja) | 感放射線性樹脂組成物 | |
JP2004118136A (ja) | 感放射線性樹脂組成物 | |
KR20130028696A (ko) | 멀티-아미드 성분을 포함하는 포토레지스트 | |
JP2012155047A (ja) | 感放射線性組成物及びその製造方法 | |
JP2003241384A (ja) | 感放射線性樹脂組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070726 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100106 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100119 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100318 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100427 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100623 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100817 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100903 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20101109 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20101122 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131217 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4645153 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131217 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |