JP2006114747A - 半導体装置の製造方法 - Google Patents
半導体装置の製造方法 Download PDFInfo
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- JP2006114747A JP2006114747A JP2004301462A JP2004301462A JP2006114747A JP 2006114747 A JP2006114747 A JP 2006114747A JP 2004301462 A JP2004301462 A JP 2004301462A JP 2004301462 A JP2004301462 A JP 2004301462A JP 2006114747 A JP2006114747 A JP 2006114747A
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- film
- fluorine
- semiconductor device
- high dielectric
- manufacturing
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- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000004065 semiconductor Substances 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 86
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 86
- 239000011737 fluorine Substances 0.000 claims abstract description 86
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 37
- 239000010703 silicon Substances 0.000 claims abstract description 37
- 239000000758 substrate Substances 0.000 claims abstract description 34
- 230000008569 process Effects 0.000 claims abstract description 33
- 238000000137 annealing Methods 0.000 claims abstract description 32
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 22
- 239000007789 gas Substances 0.000 claims description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 238000009832 plasma treatment Methods 0.000 claims description 5
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 239000010408 film Substances 0.000 claims 13
- 239000010409 thin film Substances 0.000 claims 5
- 239000010410 layer Substances 0.000 description 20
- 229910004298 SiO 2 Inorganic materials 0.000 description 16
- 229910052751 metal Inorganic materials 0.000 description 15
- 239000002184 metal Substances 0.000 description 15
- 238000009792 diffusion process Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 230000004913 activation Effects 0.000 description 7
- 150000004645 aluminates Chemical class 0.000 description 6
- 238000000231 atomic layer deposition Methods 0.000 description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 4
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 229910021332 silicide Inorganic materials 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 125000001475 halogen functional group Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000002513 implantation Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910052747 lanthanoid Inorganic materials 0.000 description 3
- 150000002602 lanthanoids Chemical class 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910018503 SF6 Inorganic materials 0.000 description 2
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 2
- -1 ZrO 2 Chemical class 0.000 description 2
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- 229910052454 barium strontium titanate Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052914 metal silicate Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- QKCGXXHCELUCKW-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-2-ylamino)phenyl]phenyl]-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C=C4C=CC=CC4=CC=3)C=3C=C4C=CC=CC4=CC=3)C3=CC4=CC=CC=C4C=C3)=CC=C21 QKCGXXHCELUCKW-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 239000003870 refractory metal Substances 0.000 description 2
- SFZCNBIFKDRMGX-UHFFFAOYSA-N sulfur hexafluoride Chemical compound FS(F)(F)(F)(F)F SFZCNBIFKDRMGX-UHFFFAOYSA-N 0.000 description 2
- 229960000909 sulfur hexafluoride Drugs 0.000 description 2
- JOHWNGGYGAVMGU-UHFFFAOYSA-N trifluorochlorine Chemical compound FCl(F)F JOHWNGGYGAVMGU-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910019044 CoSix Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- 229910003182 MoCx Inorganic materials 0.000 description 1
- 229910015617 MoNx Inorganic materials 0.000 description 1
- 229910005883 NiSi Inorganic materials 0.000 description 1
- 229910005889 NiSix Inorganic materials 0.000 description 1
- 229910004156 TaNx Inorganic materials 0.000 description 1
- 229910008486 TiSix Inorganic materials 0.000 description 1
- 229910008764 WNx Inorganic materials 0.000 description 1
- 229910008328 ZrNx Inorganic materials 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229910052805 deuterium Inorganic materials 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000005224 laser annealing Methods 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Landscapes
- Electrodes Of Semiconductors (AREA)
- Formation Of Insulating Films (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004301462A JP2006114747A (ja) | 2004-10-15 | 2004-10-15 | 半導体装置の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004301462A JP2006114747A (ja) | 2004-10-15 | 2004-10-15 | 半導体装置の製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011004584A Division JP4985855B2 (ja) | 2011-01-13 | 2011-01-13 | 半導体装置の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006114747A true JP2006114747A (ja) | 2006-04-27 |
| JP2006114747A5 JP2006114747A5 (enExample) | 2007-11-22 |
Family
ID=36383007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004301462A Withdrawn JP2006114747A (ja) | 2004-10-15 | 2004-10-15 | 半導体装置の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2006114747A (enExample) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008078253A (ja) * | 2006-09-20 | 2008-04-03 | Sony Corp | 半導体装置の製造方法 |
| JP2008530770A (ja) * | 2005-01-13 | 2008-08-07 | インターナショナル・ビジネス・マシーンズ・コーポレーション | n−FET用途のためのHfSiN金属を形成する方法 |
| JP2008311661A (ja) * | 2007-06-15 | 2008-12-25 | Dongbu Hitek Co Ltd | 半導体素子及びそのゲート形成方法 |
| JP2010505281A (ja) * | 2006-09-26 | 2010-02-18 | アプライド マテリアルズ インコーポレイテッド | 欠陥パシベーションのための高kゲート積層構造に対するフッ素プラズマ処理 |
| JP2010212376A (ja) * | 2009-03-09 | 2010-09-24 | Toshiba Corp | 半導体装置の製造方法 |
| JP2011103459A (ja) * | 2009-10-07 | 2011-05-26 | Asm Internatl Nv | Pmosデバイスのゲートスタックのしきい値電圧を調整する方法 |
| US8431468B2 (en) | 2006-12-07 | 2013-04-30 | Infineon Technologies Ag | Noise reduction in semiconductor devices |
| JP2013175769A (ja) * | 2006-12-11 | 2013-09-05 | Sony Corp | 半導体装置の製造方法 |
| CN104347503A (zh) * | 2013-07-30 | 2015-02-11 | 中芯国际集成电路制造(上海)有限公司 | 一种半导体器件及其制造方法 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0685278A (ja) * | 1992-09-07 | 1994-03-25 | Hitachi Ltd | 半導体装置の製造方法 |
| JPH09266308A (ja) * | 1996-03-29 | 1997-10-07 | Nec Corp | 半導体装置の製造方法 |
| JPH1140803A (ja) * | 1997-07-15 | 1999-02-12 | Toshiba Corp | 半導体装置及びその製造方法 |
| JP2000022139A (ja) * | 1998-06-30 | 2000-01-21 | Toshiba Corp | 半導体装置及びその製造方法 |
| JP2002299614A (ja) * | 2001-03-30 | 2002-10-11 | Toshiba Corp | Mis型電界効果トランジスタ及びその製造方法及び半導体記憶装置及びその製造方法 |
| JP2003218082A (ja) * | 2002-01-23 | 2003-07-31 | Tokyo Electron Ltd | 基板処理方法および装置、半導体装置の製造装置 |
| WO2003100835A2 (en) * | 2002-05-20 | 2003-12-04 | Advanced Micro Devices, Inc. | Gate oxide process methods for high performance mos transistors by reducing remote scattering |
| JP2004193150A (ja) * | 2002-12-06 | 2004-07-08 | Toshiba Corp | 半導体装置および半導体装置の製造方法 |
| JP2004207560A (ja) * | 2002-12-26 | 2004-07-22 | Toshiba Corp | 半導体装置およびその製造方法 |
-
2004
- 2004-10-15 JP JP2004301462A patent/JP2006114747A/ja not_active Withdrawn
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0685278A (ja) * | 1992-09-07 | 1994-03-25 | Hitachi Ltd | 半導体装置の製造方法 |
| JPH09266308A (ja) * | 1996-03-29 | 1997-10-07 | Nec Corp | 半導体装置の製造方法 |
| JPH1140803A (ja) * | 1997-07-15 | 1999-02-12 | Toshiba Corp | 半導体装置及びその製造方法 |
| JP2000022139A (ja) * | 1998-06-30 | 2000-01-21 | Toshiba Corp | 半導体装置及びその製造方法 |
| JP2002299614A (ja) * | 2001-03-30 | 2002-10-11 | Toshiba Corp | Mis型電界効果トランジスタ及びその製造方法及び半導体記憶装置及びその製造方法 |
| JP2003218082A (ja) * | 2002-01-23 | 2003-07-31 | Tokyo Electron Ltd | 基板処理方法および装置、半導体装置の製造装置 |
| WO2003100835A2 (en) * | 2002-05-20 | 2003-12-04 | Advanced Micro Devices, Inc. | Gate oxide process methods for high performance mos transistors by reducing remote scattering |
| JP2004193150A (ja) * | 2002-12-06 | 2004-07-08 | Toshiba Corp | 半導体装置および半導体装置の製造方法 |
| JP2004207560A (ja) * | 2002-12-26 | 2004-07-22 | Toshiba Corp | 半導体装置およびその製造方法 |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008530770A (ja) * | 2005-01-13 | 2008-08-07 | インターナショナル・ビジネス・マシーンズ・コーポレーション | n−FET用途のためのHfSiN金属を形成する方法 |
| JP2008078253A (ja) * | 2006-09-20 | 2008-04-03 | Sony Corp | 半導体装置の製造方法 |
| JP2010505281A (ja) * | 2006-09-26 | 2010-02-18 | アプライド マテリアルズ インコーポレイテッド | 欠陥パシベーションのための高kゲート積層構造に対するフッ素プラズマ処理 |
| US8431468B2 (en) | 2006-12-07 | 2013-04-30 | Infineon Technologies Ag | Noise reduction in semiconductor devices |
| US11901454B2 (en) | 2006-12-11 | 2024-02-13 | Sony Group Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| US10868176B2 (en) | 2006-12-11 | 2020-12-15 | Sony Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| JP2013175769A (ja) * | 2006-12-11 | 2013-09-05 | Sony Corp | 半導体装置の製造方法 |
| US11404573B2 (en) | 2006-12-11 | 2022-08-02 | Sony Group Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| US9041058B2 (en) | 2006-12-11 | 2015-05-26 | Sony Corporation | Metal oxide semiconductor having epitaxial source drain regions and method of manufacturing same using dummy gate process |
| US9419096B2 (en) | 2006-12-11 | 2016-08-16 | Sony Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| US9502529B2 (en) | 2006-12-11 | 2016-11-22 | Sony Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| US9673326B2 (en) | 2006-12-11 | 2017-06-06 | Sony Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| US9865733B2 (en) | 2006-12-11 | 2018-01-09 | Sony Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| US10128374B2 (en) | 2006-12-11 | 2018-11-13 | Sony Corporation | Metal oxide semiconductor having epitaxial source drain regions and a method of manufacturing same using dummy gate process |
| JP2008311661A (ja) * | 2007-06-15 | 2008-12-25 | Dongbu Hitek Co Ltd | 半導体素子及びそのゲート形成方法 |
| JP2010212376A (ja) * | 2009-03-09 | 2010-09-24 | Toshiba Corp | 半導体装置の製造方法 |
| JP2011103459A (ja) * | 2009-10-07 | 2011-05-26 | Asm Internatl Nv | Pmosデバイスのゲートスタックのしきい値電圧を調整する方法 |
| CN104347503A (zh) * | 2013-07-30 | 2015-02-11 | 中芯国际集成电路制造(上海)有限公司 | 一种半导体器件及其制造方法 |
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