JP2005531626A5 - - Google Patents
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- JP2005531626A5 JP2005531626A5 JP2004516858A JP2004516858A JP2005531626A5 JP 2005531626 A5 JP2005531626 A5 JP 2005531626A5 JP 2004516858 A JP2004516858 A JP 2004516858A JP 2004516858 A JP2004516858 A JP 2004516858A JP 2005531626 A5 JP2005531626 A5 JP 2005531626A5
- Authority
- JP
- Japan
- Prior art keywords
- amount
- expressed
- fluorine
- group
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 claims description 18
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 7
- 239000011737 fluorine Substances 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000002798 polar solvent Substances 0.000 claims description 2
- 239000008346 aqueous phase Substances 0.000 claims 5
- 125000006575 electron-withdrawing group Chemical group 0.000 claims 5
- 239000002253 acid Substances 0.000 claims 4
- 239000002904 solvent Substances 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 239000002585 base Substances 0.000 claims 3
- -1 cationic sulfides Chemical class 0.000 claims 3
- 150000001768 cations Chemical class 0.000 claims 3
- 150000007944 thiolates Chemical class 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 2
- 230000026030 halogenation Effects 0.000 claims 2
- 238000005658 halogenation reaction Methods 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- 239000003125 aqueous solvent Substances 0.000 claims 1
- 230000031709 bromination Effects 0.000 claims 1
- 238000005893 bromination reaction Methods 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 239000002609 medium Substances 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000012071 phase Substances 0.000 claims 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 239000004071 soot Substances 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 claims 1
- PBKONEOXTCPAFI-UHFFFAOYSA-N TCB Natural products ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 4
- UENWRTRMUIOCKN-UHFFFAOYSA-N benzyl thiol Chemical group SCC1=CC=CC=C1 UENWRTRMUIOCKN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- QMOWRNGLGDZHAF-UHFFFAOYSA-N difluoromethylsulfanylmethylbenzene Chemical compound FC(F)SCC1=CC=CC=C1 QMOWRNGLGDZHAF-UHFFFAOYSA-N 0.000 description 1
- 239000003444 phase transfer catalyst Substances 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0208090A FR2841551B1 (fr) | 2002-06-28 | 2002-06-28 | Procede de synthese de derives a radical hydrogenofluoromethylene-sulfonyle |
| PCT/FR2003/001940 WO2004002951A2 (fr) | 2002-06-28 | 2003-06-24 | Procede de synthese de derives a radical hydrogenofluoromethylenesulfonyle |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005531626A JP2005531626A (ja) | 2005-10-20 |
| JP2005531626A5 true JP2005531626A5 (https=) | 2006-02-23 |
| JP4531561B2 JP4531561B2 (ja) | 2010-08-25 |
Family
ID=29724975
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004516858A Expired - Lifetime JP4531561B2 (ja) | 2002-06-28 | 2003-06-24 | ヒドロフルオロメチレンスルホニル基を含む誘導体の合成方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7534906B2 (https=) |
| EP (1) | EP1517888B1 (https=) |
| JP (1) | JP4531561B2 (https=) |
| CN (1) | CN100509776C (https=) |
| AT (1) | ATE395331T1 (https=) |
| AU (1) | AU2003260623A1 (https=) |
| CA (1) | CA2491207C (https=) |
| DE (1) | DE60320994D1 (https=) |
| FR (1) | FR2841551B1 (https=) |
| RU (1) | RU2346934C2 (https=) |
| WO (1) | WO2004002951A2 (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101110602B (zh) * | 2006-07-20 | 2010-05-12 | 上海高清数字科技产业有限公司 | 基于多状态控制的载波捕获系统和方法 |
| RU2495878C2 (ru) | 2007-12-21 | 2013-10-20 | Ф.Хоффманн-Ля Рош Аг | Гетероциклические антивирусные соединения |
| RU2409559C1 (ru) * | 2009-08-03 | 2011-01-20 | Павел Анатольевич Семенов | Способ получения 1,1-дифторэтансульфохлорида |
| CN110028390B (zh) * | 2019-05-28 | 2022-01-14 | 深圳大学 | 烷基二氟甲基醚类化合物的合成方法 |
| CN115594617B (zh) * | 2022-07-29 | 2024-02-06 | 苏州翔实医药发展有限公司 | 一种二氟甲基磺酰氯的合成方法 |
| CN116063208A (zh) * | 2023-02-13 | 2023-05-05 | 安徽省化工研究院 | 一种二氟甲烷磺酰氯的合成方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2469401A1 (fr) * | 1979-11-13 | 1981-05-22 | Rhone Poulenc Ind | Procede de preparation de difluoromethane sulfonates alcalins |
| JPS5780366A (en) * | 1980-11-06 | 1982-05-19 | Sagami Chem Res Center | Bromodifluoromethyl sulfide and its preparation |
| JPS57146749A (en) * | 1981-01-29 | 1982-09-10 | Ici Ltd | Difluoromethane sulfonic acid and manufacture |
| FR2540108B1 (fr) * | 1983-02-02 | 1985-12-27 | Rhone Poulenc Spec Chim | Procede de preparation de perhalogenoalkylthioethers |
| FR2599366B1 (fr) * | 1986-05-28 | 1988-08-26 | Rhone Poulenc Spec Chim | Procede de preparation du sulfure de benzyle et de trifluoromethyle |
| EP0313939B1 (en) * | 1987-10-26 | 1992-09-16 | ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) | Oxidation of thiols, disulfides and thiolsulfonates |
| DE3741309A1 (de) * | 1987-12-05 | 1989-06-15 | Bayer Ag | Verfahren zur herstellung von trifluormethansulfonsaeurechlorid |
| DE4333058A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Trifluorethylschwefelverbindungen aus Thiolaten und 1-Chlor-2,2,2-trifluorethan |
| JP3638357B2 (ja) * | 1994-11-01 | 2005-04-13 | 東洋化成工業株式会社 | ２，２−ジアルキル−３−アセトキシプロパンスルフォニルクロリドを製造する方法 |
| FR2730993B1 (fr) * | 1995-02-28 | 1997-04-04 | Rhone Poulenc Chimie | Procede de synthese de compose hydrocarbone fluore sur un carbone d'une chaine alcoyle |
| IL117534A0 (en) * | 1995-03-24 | 1996-07-23 | Rhone Poulenc Agrochimie | Reagent and process which are useful for grafting a substituted difluoromethyl group onto a compound containing at least one electrophilic function |
| FR2743072B1 (fr) * | 1995-12-27 | 1998-02-27 | Electricite De France | Procede de preparation d'acides perfluoroalcanecarboxyliques et perfluoroalcanesulfoniques |
-
2002
- 2002-06-28 FR FR0208090A patent/FR2841551B1/fr not_active Expired - Fee Related
-
2003
- 2003-06-24 RU RU2005102101/04A patent/RU2346934C2/ru not_active IP Right Cessation
- 2003-06-24 AT AT03761633T patent/ATE395331T1/de not_active IP Right Cessation
- 2003-06-24 CN CNB038179326A patent/CN100509776C/zh not_active Expired - Lifetime
- 2003-06-24 AU AU2003260623A patent/AU2003260623A1/en not_active Abandoned
- 2003-06-24 JP JP2004516858A patent/JP4531561B2/ja not_active Expired - Lifetime
- 2003-06-24 DE DE60320994T patent/DE60320994D1/de not_active Expired - Lifetime
- 2003-06-24 WO PCT/FR2003/001940 patent/WO2004002951A2/fr not_active Ceased
- 2003-06-24 EP EP03761633A patent/EP1517888B1/fr not_active Expired - Lifetime
- 2003-06-24 US US10/519,287 patent/US7534906B2/en not_active Expired - Fee Related
- 2003-06-24 CA CA2491207A patent/CA2491207C/fr not_active Expired - Fee Related
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